Risk and consequence analyses of hazardous chemicals in marshalling yards and warehouses at Ikonio/Piraeus harbour, Greece

The risk and the consequences of possible accidents at Ikonio (Piraeus harbour, Greece) are investigated and analyzed in this paper. At this harbour large cargoes of dangerous chemicals (toxic or flammable) are unloaded and stored in warehouses or in marshalling yards. Houses and a school are located near the plant and are directly exposed to danger in the case of an accident. The results were obtained by Breeze Hazard Professional software package, which contains several models for performing consequence modeling through quantitative risk assessment.     

Bayesian estimation and consequence modelling of deliberately induced domino effects in process facilities

Process facilities handling hazardous chemicals in large quantities and elevated operating conditions of temperature/pressure are attractive targets to external attacks. The possibility of an external attack on a critical installation, performed with an intention of triggering escalation of primary incidents into secondary and tertiary incidents, thereby increasing the severity of consequences needs to be effectively analysed. A prominent Petrochemical Industry located in Kerala, India was identified for studying the possibility of a deliberately induced domino effect. In this study, a dedicated Bayesian network is developed to model the domino propagation sequence in the chemical storage area of the industry, and to estimate the domino probabilities at different levels. This method has the advantage of accurately quantifying domino occurrence probabilities and identifying possible higher levels of escalations. Moreover, the combined effect from multiple units can be modelled easily and new information can be added into the model as evidences to update the probabilities. Phast (Process hazard analysis) software is used for consequence modelling to determine the impact zones of the identified primary and secondary incidents. The results of the case study show that such analyses can greatly benefit green field and brown field projects in determining the appropriate safety and security measures to be implemented or strengthened so as to reduce its attractiveness to external threat agents.     

HAZOP、LOPA和SIL方法的应用分析

通过概括介绍危险与可操作性分析(HAZOP)、保护层分析(LOPA)和安全完整性等级分析(SIL)三种方法的特点,总结三种分析方法之间的关系.LOPA分析是HAZOP分析的继续,可以解决HAZOP分析中残余风险不能定量化的不足,是对HAZOP分析结果的丰富和补充;SIL分析则在LOPA分析的基础上,进一步对需要增加的安全仪表系统(SIS)进行设计,并对LOPA分析结果进行验证,即HAZOP、LOPA分析是SIL分析的前期准备工作.因此,在详细介绍SIS的组成、安全生命周期阶段、SIL的选择确定方法以及SIL分析流程之前,也简要介绍了HAZOP、LOPA分析方法,梳理了两种方法的分析流程.最后通过引入示例来展示三种分析方法之间的关系.     

HAZOP分析中LOPA的应用研究

通过分析危险与可操作性研究(HAZOP)方法的不足和保护层分析(LOPA)方法的功能,提出将LOPA融入HAZOP分析中,能进一步提高HAZOP的事故预防能力和丰富HAZOP的分析结果。介绍LOPA基本方法,阐述LOPA融入HAZOP的机理、衔接关系及分析步骤,并通过一个化工工艺流程危险性分析实例说明LOPA的作用及如何将LOPA融入HAZOP分析中。结果表明:在HAZOP分析中融入LOPA方法,能实现对现有保护措施的可靠性进行量化评估,确定其消除或降低风险的能力,从而寻求是否需要附加减少风险的安全保护措施。     

基于LOPA逻辑的罐区多米诺效应定量风险评估*

为了更好地降低化工企业罐区事故造成多米诺效应的风险,提出1种基于保护层分析（LOPA）的定量风险评估程序。首先,阐述基于保护层分析(LOPA)逻辑的多米诺定量风险评估流程,即引入包括可用性、有效性及3种逻辑门定义及量化的安全屏障定量评估;然后,利用LOPA的分析逻辑将安全屏障融入多米诺定量风险评估框架中;最后,选取2×2 000 m3苯乙烯罐区为对象,识别防火层与喷淋冷却系统2种安全屏障并开展基于LOPA逻辑的罐区多米诺效应定量风险评估,得出安全屏障能有效地降低多米诺事故发生频率及罐区个人风险的结论。研究结果表明:该分析方法可为化工企业开展多米诺效应定量风险评估提供参考。     

考虑非独立保护层影响的LOPA改进策略研究

针对LOPA在识别保护层方面的局限性,通过考虑非独立保护层的影响,将非独立保护层分为不满足有效性与不满足独立性2类进行分析,针对不同类型的非独立保护层分别应用引入削减系数以及与故障树分析（FTA）集成的方法对传统LOPA进行改进,并结合具体案例验证其适用性。研究结果表明:改进方法的计算结果较传统方法计算结果降低了1个数量级,避免了传统方法过于保守的评价结果;通过对传统方法的改进,克服了LOPA在识别保护层方面以及场景频率计算方面的局限性,有助于拓展其使用范围。     

Using consequence analysis on some chlorine operation hazards and their possible effects on neighborhoods in central Taiwan

The applications of chlorine have been broadly used in many industrial products, such as bleaching agents, synthetic rubbers, plastics, disinfectants, iron chlorides, fire refractory materials, insecticides, and anti-freezers, etc. According to the Taiwan Environmental Protection Administration (TEPA), more than 30 thousand tons were used in the year 2000. In addition, there were more than 12 reported incidents from 2000 to 2003—mostly on using chlorine as disinfectants (five) and as process agents (four).

This study investigated 15 chlorine operation plants in central Taiwan. These chlorine usages included bleaching agents, disinfectants, iron chloride, synthesizing rubber plastics, and others. Thirteen plants were located in the industrial parks and two were in or near residential zones. The consequence analysis were used three different methods to analyze the worst-case scenarios (WCSs) and alternative release case scenarios (ACSs) in order to compare impact zones for applying various active and passive mitigation systems, such as confined space, scrubber, water-spray, and so no. For two plants in or near residential zones, multi-layers mitigation systems and operation limits should be implemented in order to enforce more stringent protection measures. However, there was no specific regulation for chlorine plants operated at different locations, such as industrial parks or residential zones. In order to reduce chemical accidents and their impacts on public safety, our results suggest that source mitigation/management and warning systems should be adopted simultaneously.     

An innovative and comprehensive approach for the consequence analysis of liquid hydrogen vessel explosions

Hydrogen is one of the most suitable solutions to replace hydrocarbons in the future. Hydrogen consumption is expected to grow in the next years. Hydrogen liquefaction is one of the processes that allows for increase of hydrogen density and it is suggested when a large amount of substance must be stored or transported. Despite being a clean fuel, its chemical and physical properties often arise concerns about the safety of the hydrogen technologies. A potentially critical scenario for the liquid hydrogen (LH₂) tanks is the catastrophic rupture causing a consequent boiling liquid expanding vapour explosion (BLEVE), with consequent overpressure, fragments projection and eventually a fireball. In this work, all the BLEVE consequence typologies are evaluated through theoretical and analytical models. These models are validated with the experimental results provided by the BMW care manufacturer safety tests conducted during the 1990's. After the validation, the most suitable methods are selected to perform a blind prediction study of the forthcoming LH₂ BLEVE experiments of the Safe Hydrogen fuel handling and Use for Efficient Implementation (SH₂IFT) project. The models drawbacks together with the uncertainties and the knowledge gap in LH₂ physical explosions are highlighted. Finally, future works on the modelling activity of the LH₂ BLEVE are suggested.     

Inherent risk assessment—A new concept to evaluate risk in preliminary design stage

Quantitative Risk Assessment (QRA) has been a very popular and useful methodology which is widely accepted by the industry over the past few decades. QRA is typically carried out at a stage where complete plant has been designed and sited. At that time, the opportunity to include inherent safety design features is limited and may incur higher cost. This paper proposes a new concept to evaluate risk inherent to a process owing to the chemical it uses and the process conditions. The risk assessment tool is integrated with process design simulator (HYSYS) to provide necessary process data as early as the initial design stages, where modifications based on inherent safety principles can still be incorporated to enhance the process safety of the plant. The risk assessment tool consists of two components which calculate the probability and the consequences relating to possible risk due to major accidents. A case study on the potential explosion due to the release of flammable material demonstrates that the tool is capable to identify potential high risk of process streams. Further improvement of the process design is possible by applying inherent safety principles to make the process under consideration inherently safer. Since this tool is fully integrated with HYSYS, re-evaluation of the inherent risk takes very little time and effort. The new tool addresses the lack of systematic methodology and technology, which is one of the barriers to designing inherently safer plants.     

Investigative consequence analysis: A case study research of beirut explosion accident

Around 15:00 GMT on August 4th, an explosion occurred in the warehouse facility storing Ammonium Nitrate (AN) at Beirut port, Lebanon. The explosion resulted in more than 178 fatalities and injured more than 6500 people, and also left an estimated 300,000 people homeless and registered as an equivalent to a 3.3 magnitude earth quake. The accident was considered to be the largest of its kind and the most severe anthropological disaster of the decade, the financial loss the nation was subjected to post the explosion was estimated to be around $ 15 billion as informed by the governor. The storage conditions of ammonium nitrate at Beirut port is not definitively known to anyone, and there is no documentation provided so far from the authorities regarding the same. This work focuses on the investigation & consequence analysis of the explosion using TNT equivalent approach. The overpressure and the impulse obtained from TNT calculations are used in probit models to assess the damages caused on human beings and structures. The results obtained in this investigative approach are then utilized to provide an analytical inference relative to the damage proxy map reported by the advance rapid imaging analysis team from NASA. Also, this work examines the existing standards, fire safety measures and legal regulations for ammonium nitrate facilities in the region. AN explosion during storage like other fire and explosion accidents are definitely preventable owing to the technological advancements and developments to prevent or extinguish controllable fires. The significance of this work relates to the methods for calculation of consequences of explosion that are happening due to the storage of highly hazardous explosive materials in excessive quantities and insists the necessity of incorporating adequate safety measures while storing such reactive and hazardous materials.     

Risk analysis of a cross-regional toxic chemical disaster by using the integrated mesoscale and microscale consequence analysis model

The rapidly growing capacity and scale of the world's petrochemical industries have forced many plants to have an even larger amount of hazardous substances. Once a serious leak occurs, the outcome of the effect zone could be very large or even uncontrollable just like the Bhopal disaster. In order to assess the risk of a cross-regional damage, this study aims to develop a model that can combine the benefits of both CFD model of the microscale simulation and the Gaussian dispersion model of the mesoscale simulation.The developed integrated model is employed on a toxic chemical tank leak accident of a process plant within an industrial park in order to explore the consequences and the risk of the toxic gas dispersion on three different scopes; one is the accident site, the second is the long-distance transmission route of the mesoscale area and the third is a target city. According to the simulation's results, it is obvious that the complexity of the structure surrounding the leaking tank will eventually affect the maximum ground concentration, the cloud shapes and cloud dilution rate, while the released gas is under dispersion. On the other hand, since the simple Gaussian dispersion model doesn't consider the above impacts, its calculation results will have many differences as compared to the realistic situation. This integrated model can be used as a tool for estimating the risk on a microscale or mesoscale areas and it can produce better results when an environmental impact analysis is required for a larger hazardous chemical process.     

Occupational risks and the value and modelling of a measurement of severity

In studies of occupational risks, severity, which is a component of the estimation of every risk, appears as a multifaceted entity assessable according to numerous criteria. A method of measuring the degree of severity of the consequences of potentially dangerous events would be of undeniable value to organisations seeking to improve their understanding of the complexity of such events. The need to control severity is highlighted by scientifically acquired improvements in the understanding of occupational risks, by certain new regulatory obligations in Europe, and by some requirements in the financial management of organisations. We put forward a statistical way of integrating several constituent elements of severity and hence of determining a relevant, synthetic, one-dimensional index. This is achieved by means of principal component analysis (PCA), which is used here to calculate a resultant severity, as in some physical measurements. We also investigate how severity may be statistically modelled, with the aim of contributing to the quantitative assessment of occupational risks. The choice of parametric models is detailed and illustrated by the search for a suitable model for workplace accidents in an organisational setting. The practical value of modelling severity is two-fold. First, one is able to study the distribution of the numerical values of severity over a continuum (a theoretically infinite numerical set) rather than through a limited number of arbitrarily defined categories. Second, with a generally applicable parametric model, one can estimate the law of probability of a measurement of severity in a particular situation, notably recent or new. Lastly, the statistical concept of risk curve is defined and discussed. The goal is to incorporate the severity component into the risk assessment in the form of a probability law, thus circumventing the difficulties associated with an analysis of scenarios.     

Integration of fuzzy reliability analysis and consequence simulation to conduct risk assessment

Losses of containment within the natural gas network, located in most populated areas, could cause environmental damage, injuries, or even death. Accordingly, it is pivotal to adopt proper approaches to assess and mitigate the risk arising from potential losses. Within this context, it is required to exploit solid reliability and consequence analysis techniques. To this end, this paper presents a methodology established on the integration of a Fuzzy Bayesian Network and consequence simulation. The Bayesian Network is more flexible and realistic than classic approaches because it can consider conditional probabilities and prior information. Furthermore, Leaky Noisy-OR Gates are exploited to allow an easier filling of the Conditional Probability Tables. This task is performed through expert elicitation, adopting Intuitionistic Fuzzy Set Theory and Similarity Aggregation Method. Finally, the severity analysis is performed via a software, named Safeti, which provides an accurate evaluation of the consequences. To show the applicability of the framework, a pressure regulator of a Natural Gas Regulating and Metering Station is considered as case study. The proposed approach can assist asset managers in evaluating the risk arising from the operations, and, accordingly, it can guide them in making maintenance-related decisions to assure the safety of the operations.     

Learning from the application of nuclear probabilistic safety assessment to the chemical industry

This paper introduces the new approach of risk analysis established by the French Ministry of the Environment and develops the benefits of applying nuclear probabilistic safety assessment approaches to the chemical industry.In the aftermath of the AZF disaster in Toulouse on 21 September 2001, a new law was proposed by the French government asking for the investigation of all representative scenarios and the assessment of the probability of the resulting dangerous phenomena to demonstrate an acceptable level of safety. Therefore, any accident is investigated from a global point of view, according to its gravity and its probability.In 2000, the French Ministry of the Environment asked the Institute for Radiological Protection and Nuclear Safety (IRSN), and in particular its Systems and Risk Protection Assessment (SESPRI) and its Industrial Risks, Fire and Containment Assessment and Study (SERIC) departments, to conduct a Probabilistic Safety Assessment (PSA) study of an LPG distribution facility, specially for the BLEVE scenario. This study has showed the power of PSA for defining and prioritizing actions to be carried out to improve safety of facilities; however, it requires credible data for reliability and failure of the equipment, not available in generic failure databases.Since 2007, IRSN has taken several initiatives in collaboration with operators in order to provide more precise and representative failure rates for main safety equipment, ready to use in future PSA relative to LPG plants.     

极端海况下海洋石油结构的风险评估

根据中国海上石油工业缺乏独立的风险评价体系的现状 ,笔者对极端海况进行了环境荷载的联合概率分析 ,利用随机模拟技术 ,求解结构的失效概率 ,提出结构失效分析的新方法 ,并利用DNV提供的历史数据 ,对结构失效的后果做了适当分析。以埕北 12 C井组平台作为实例 ,对平台甲板高程 (AirGap)失效分析进行了实例计算。结果表明 ,使用多维联合极值分布理论及相应的求解方法 ,是离岸工程结构物风险评估的重要手段。     

On risk-based maintenance: A comprehensive review of three approaches to track the impact of consequence modelling for predicting maintenance actions

Since gas plants are progressively increasing near urban areas, a comprehensive tool to plan maintenance and reduce the risk arising from their operations is required. To this end, a comparison of three Risk-Based Maintenance methodologies able to point out maintenance priorities for the most critical components, is presented in this paper. Moreover, while the literature is mostly focused on probabilistic analysis, a particular attention is directed towards consequence analysis throughout this study. The first developed technique is characterized by a Hierarchical Bayesian Network to perform the occurrence analysis and a Failure Modes, Effects and Criticality Analysis to assess the magnitude of the adverse outcomes. The second approach is a Quantitative Risk Analysis carried out via a software named Safeti. Finally, another software called Synergi Plant is adopted for the third methodology, which provides a Risk-Based Inspection plan, through a semiquantitative risk analysis. The proposed study can assist asset manager in adopting the most appropriate methodology to their context, while highlighting priority components. To demonstrate the applicability of the approaches and compare their rankings, a Natural Gas Regulating and Measuring Station is considered as case study. The results showed that the most suited method strongly depends on the available data.     

Risk analysis and assessment methodologies in the work sites: On a review, classification and comparative study of the scientific literature of the period 2000-2009

The objective of this work is to determine and study, analyze and elaborate, classify and categorize the main risk analysis and risk-assessment methods and techniques by reviewing the scientific literature. The paper consists of two parts: a) the investigation, presentation and elaboration of the main risk-assessment methodologies and b) the statistical analysis, classification, and comparative study of the corresponding scientific papers published by six representative scientific journals of Elsevier B.V. covering the decade 2000-2009. The scientific literature reviewing showed that the risk analysis and assessment techniques are classified into three main categories: (a) the qualitative, (b) the quantitative, and (c) the hybrid techniques (qualitative-quantitative, semi-quantitative). The qualitative techniques are based both on analytical estimation processes, and on the safety managers-engineers ability. According to quantitative techniques, the risk can be considered as a quantity, which can be estimated and expressed by a mathematical relation, under the help of real accidents’ data recorded in a work site. The hybrid techniques, present a great complexity due to their ad hoc character that prevents a wide spreading. The statistical analysis shows that the quantitative methods present the highest relative frequency (65.63%) while the qualitative a lower one (27.68%). Furthermore the hybrid methods remain constantly at a very low level (6.70%) during the entire processing period.     

Consequence analysis by means of characteristic curves to determine the damage to buildings from bursting spherical vessels

Since the damage suffered by buildings as a consequence of explosions usually affect the people inside them, it is important to take it into account when performing consequence analysis. The aim of this paper is to provide a methodology to estimate consequences to buildings from pressure waves produced by spherical vessel burst. This is done by combining characteristic overpressure–impulse–distance curves [González Ferradás, E., Diaz Alonso, F., Sanchez Perez, J.F., Miñana Aznar, A., Ruiz Gimeno, J. and Martinez Alonso, J., 2006, Characteristic overpressure–impulse–distance curves for vessel burst, Process Safety Progress, 25(3): 250–254] with PROBIT equations. The main advantage of this methodology is that it allows an overview of all the magnitudes involved, as damage is shown in the same graph as the overpressure, impulse and distance. In this paper diagrams and equations are presented to determine minor damage to buildings (broken windows, displacement of doors and window frames, tile displacement, etc.), major structural damage (cracks in walls, collapse of some walls) and collapse (the damage is so extensive that the building is partially or totally demolished).     

Modeling crash severity by considering risk indicators of driver and roadway: A Bayesian network approach

Introduction: Traffic crashes could result in severe outcomes such as injuries and deaths. Thus, understanding factors associated with crash severity is of practical importance. Few studies have deeply examined how prior violation and crash experience of drivers and roadways are associated with crash severity. Method: In this study, a set of risk indicators of road users and roadways were developed based on their prior violation and crash records (e.g., cumulative crash frequency of a roadway), in order to reflect certain aspect or degree of their driving risk. To explore the impacts of those indicators on crash severity and complex interactions among all contributing factors, a Bayesian network approach was developed, based on citywide crash data collected in Kunshan, China from 2016 to 2018. A variable selection procedure based on Information Value (IV) was developed to identify significant variables, and the Bayesian network was employed to explicitly explore statistical associations between crash severity and significant variables. Results: In terms of balanced accuracy and AUCs, the proposed approach performed reasonably well. Bayesian modeling results indicated that the prior crash/violation experiences of road users and roadways were very important risk indicators. For example, migrant workers tend to have high injury risk due to their dangerous violation behaviors, such as retrograding, red-light running, and right-of-way violation. Furthermore, results showed that certain variable combinations had enhanced impacts on severity outcome than single variables. For example, when a migrant worker and a non-motorized vehicle are involved in a crash happening on a local road with high cumulative violation frequency in the previous year, the probability for drivers suffering serious injury or fatality is much higher than that caused by any single factor. Practical applications: The proposed methodology and modeling results provide insights for developing effective countermeasures to reduce crash severity and improve traffic system safety performance.     

Developing a new alternative risk assessment framework in the work sites by including a stochastic and a deterministic process: A case study for the Greek Public Electric Power Provider

An individual method cannot achieve the optimum risk-assessment result in the worksites, and future perspectives should focus on the parallel application of a deterministic approach with a stochastic approach. In particular, the risk analysis and assessment techniques of the deterministic (DET) approach are classified into three main categories: (a) the qualitative, (b) the quantitative, and (c) the hybrid techniques (qualitative-quantitative, semi-quantitative). Furthermore, the stochastic (STO) approach includes the classic statistical approach (CSA) and the accident forecasting modeling (AFM). The objective of this paper is triple: (a) the presentation and classification of the main risk analysis and risk assessment methods and techniques of the deterministic approach and the stochastic approach as well, (b) the development and presentation of a new alternative risk assessment framework (called as STODET) including a stochastic and a deterministic process, and (c) the application of STODET in the Greek Public Power Corporation (PPC) by using occupational accidents that have been recorded, during the 17-year period of 1993-2009. In particular, the STODET application proves that required actions (or suppressive measures) are essential and must be taken in a medium-term period (1 working year) for abolishing the hazard sources.