“城乡再生资源回收利用网络建设”专题征稿

再生资源回收利用网络的建设和完善是促进我国再生资源产业发展的重要途径。目前我国再生资源回收网络建设仍较为滞后,尤其在广大农村地区,资源往往得不到有效回收利用,而大量废弃又造成了环境面源污染。如何将城市再生资源回收利用网络建设的经验引入农村,形成城乡互动、循环高效的回收利用网络,拉动农村资源利用和环境保护水平的提升,值得深入思考。     

南京市低值再生资源回收现状及建议

低值再生资源具有一定循环利用价值。受多方面因素影响,目前回收率普遍偏低。在“十四五”期间,随着“两网融合”与垃圾分类工作的不断推进,低值再生资源的回收利用受到广泛关注。以南京市低值再生资源回收为例,介绍了2017—2021年南京市典型低值再生资源的回收情况,并进行了回收预测分析,对南京市低值再生资源回收行业发展提出了相关建议。     

汨罗市再生资源产业现状及发展战略研究

汨罗市作为我国循环经济重要领域--再生资源回收利用体系建设试点基地,再生资源产业历史悠久,已初步建立社会化的再生资源回收系统、加工利用系统和废弃物资无害化处置系统,取得显著的经济、社会和环境效益.在面向"十一五"的新时期,汨罗市必须针对再生资源产业存在的"两散一低"问题,立足科技创新,完善技术开发体系、创新网络体系、政策支持体系、管理服务体系,依托汨罗市再生资源产业园以产业集群的理念谋划再生资源产业未来发展战略.     

石家庄市农村再生资源回收体系建设的现状、存在问题及对策

石家庄市是再生资源回收体系建设试点城市,再生资源回收利用事业扎实推进,成绩显著,但石家庄市广大农村地区再生资源回收利用网络建设事业发展缓滞。分析了石家庄市农村再生资源回收体系建设的现状和存在的问题,对如何有效地推进农村再生资源回收利用事业发展,更好地促进农村生态文明和社会主义新农村建设提出建议和对策。     

废弃电器电子产品回收处理行业大会隆重召开

2014年5月6—7日,由中国再生资源回收利用协会电子废弃物回收处理分会组织,废弃电器电子产品回收处理行业大会在北京隆重召开。     

赴美培训考察报告

由中国再生资源回收利用协会组织的再生资源回收利用培训考察团一行11人,于2010年12月4—24日赴美进行了"再生资源回收利用管理与实践"培训考察,学习了美国再生资源回收利用的法律法规、先进理念,拜访了相关管理机构和企业,建立了交流渠道,找到了可供借鉴的经验。     

废弃电器电子产品回收处理行业大会圆满召开

2013年12月19-20日,中国再生资源回收利用协会电子废弃物回收处理分会（以下简称分会）在成都举办的废弃电器电子产品回收处理行业大会圆满召开。     

打造再生资源回收体系 建设“绿色北京”

北京市以建设资源节约型、环境友好型社会为指导,以建设"人文北京、科技北京、绿色北京"为目标,大力推进再生资源回收体系建设。介绍了北京市再生资源回收体系建设工作取得的初步成效及采取的措施,阐述了资源回收利用的新模式和新思路,以及推动北京市再生资源回收利用的下一步工作。     

宁夏再生资源回收利用现状、存在问题和对策

宁夏地区再生资源的回收利用,对推动当地循环经济的发展和环境保护起着非常重要的作用。通过实地调查研究,分析了宁夏再生资源回收利用行业的现状、特点及问题,并提出了发展当地再生资源回收利用行业的对策和建议。     

创新再生资源产业发展模式——清远华清园的探索

再生资源是指人类在生产、生活活动中废弃而失去利用价值,通过回收和加工,可以恢复或部分恢复其利用价值,重新成为工业原料的那一部分物质。     

Determination of the Thermal Efficiency of Pre-boilover Burning of a Slick of Oil on Water

The burning rate of a slick of oil on a water bed is calculated by a simple expression derived from a one-dimensional heat conduction equation. Heat feedback from the flame to the surface is assumed to be a constant fraction of the total energy released by the combustion reaction. The constant fraction (χ) is named the burning efficiency and represents an important tool in assessing the potential of in situ burning as a counter-measure to an oil-spill. The total heat release, as a function of the pool diameter, is obtained from an existing correlation. It is assumed that radiative heat is absorbed close to the fuel surface, that conduction is the dominant mode of heat transfer in the liquid phase and that the fuel boiling temperature remains constant. By matching the characteristic thermal penetration length scale for the fuel/water system and an equivalent single layer system, a combined thermal diffusivity can be calculated and used to obtain an analytical solution for the burning rate. Theoretical expressions were correlated with crude oil and heating oil, for a number of pool diameters and initial fuel layer thickness. Experiments were also conducted with emulsified and weathered crude oil. The simple analytical expression describes well the effects of pool diameter and initial fuel layer thickness permitting a better observation of the effects of weathering, emulsification and net heat feedback to the fuel surface. Experiments showed that only a small fraction of the heat released by the flame is retained by the fuel layer and water bed (of the order of 1%). The effect of weathering on the burning rate decreases with the weathering period and that emulsification results in a linear decrease of the burning rate with water content.     

Review of the kinetics of alkaline degradation of cellulose in view of its relevance for safety assessment of radioactive waste repositories

The degradation of cellulose (a substantial component of low- and intermediate-level radioactive waste) under alkaline conditions occurs via two main processes: a peeling-off reaction and a basecatalyzed cleavage of glycosidic bonds (hydrolysis). Both processes show pseudo-first-order kinetics. At ambient temperature, the peeling-off process is the dominant degradation mechanism, resulting in the formation of mainly isosaccharinic acid. The degradation depends strongly on the degree of polymerization (DP) and on the number of reducing end groups present in cellulose. Beyond pH 12.5, the OH^- concentration has only a minor effect on the degradation rate. It was estimated that under repository conditions (alkaline environment, pH 13.3-12.5) about 10% of the cellulosic materials (average DP = 1000-2000) will degrade in the first stage (up to 10⁵ years) by the peeling-off reaction and will cause an ingrowth of isosaccharinic acid in the interstitial cement pore water. In the second stage (10⁵-10⁶ years), alkaline hydrolysis will control the further degradation of the cellulose. The potential role of microorganisms in the degradation of cellulose under alkaline conditions could not be evaluated. Proper assessment of the effect of cellulose degradation on the mobilization of radionuclides basically requires knowing the concentration of isosaccharinic acid in the pore water. This concentration, however, depends on several factors such as the stability of ISA under alkaline conditions, sorption of ISA on cement, formation of sparingly soluble ISA-salts, etc. A discussion of all the relevant processes involved, however, is far beyond the scope of the presented overview.     

Study of Aging Characteristics of Ternary Blends of Polyethylenes—II

Six film samples of low-density polypropylene (LDPE)/linear LDPE (LLDPE)/high-density polypropylene (HDPE) with varying ratios of LDPE (20–45 ... wt%) and LLDPE (25–50 wt%) having a fixed amount of HDPE at 30 wt% were prepared by blown film extrusion technique. The samples were aged at four different temperatures, 55°, 70°, 85°, and 100°C, for four different time periods in the interval of between 150 hours and up to 600 hours. The change in the structure of various constituents and the formation of various oxygenated (peroxy and hydroperoxy) and unsaturated groups during thermo-oxidative degradation was discussed by infrared spectroscopy. The visiosity-average molecular weight was found to have decreased slowly in the initial aging hours and temperatures, whereas it decreased by 10% with its previous value tensile strength that is, 100°C when aged for 600 hours. The tensile strength of the sample first increased by 67% at 55°C and 89% at 70°C up to 450 hours, whereas the values increased by 52.5% at 85°C and 33.9% at 100°C when aged for 150 hours and then decreased. The percentage elongation at break increased by 2.7% at 55°C and 10.7% at 70°C for 150 and 300 hours of aging, respectively, whereas the percentage decreased when aged at 85°C and 100°C for up to 600 hours of aging. The values of gel content (percent) increased and initial degradation temperature decreased with aging time and temperature.     

Calculation of carbon balances for evaluation of the biodegradability of polymers

Establishing carbon balances has been proven to be an applicable and powerful tool in testing biodegradability of polymers. In controlled degradation tests at a 4-L scale with the model polymer poly(-hydroxybutyrate) (PHB), it was shown that the degree of degradation could not be determined with satisfactory accuracy from CO₂ release alone. Instead, the course of degradation was characterized by means of establishing carbon balances for the degradation of PHB withAcidovorax facilis and a mixed culture derived from compost. Different analytical methods for determining the different carbon fractions were adapted to the particular test conditions and compared. Quantitative determination of biomass and residual polymer were the main problems in establishing carbon balances. Amounts of biomass derived from protein measurements depend strongly on assumptions of the protein content of the biomass. Selective oxidation of biomass with hypochlorite was used as alternative, but here problems arose from insoluble metabolic products. Determination of soluble components with the method of chemical oxygen demand (COD) also includes empirical assumptions but seems acceptable if the dissolved carbon fraction is in the range of some 10% total carbon. Results confirm both analytical assays and theoretical approaches, in ending up at values very close to 100%, within an acceptable standard deviation range under test conditions comparable to standard test practice.Paper presented at the Bio/Environmentally Degradable Polymer Society—Third National Meeting, June 6–8, 1994, Boston, Massachusetts.     

富拉尔基发电总厂200MW机组除尘器改造

对富拉尔基发电总厂5号炉的设计条件进行了分析，针对燃用低硫煤，飞灰比电阻高，场地较小，除尘效率要求高的情况，在电除尘器的设计上采取有效措施，达到了排放要求。     

Effects of temperature on the release of nutrient elements of solid organic materials under conditions of oversaturation

The effects of temperature on the release of chemical components of six solid organic materials under conditions of oversaturation were investigated in this paper. The six materials were peat moss (PM), weathered coals (WC), charred rice husks (CRH), sawdust (Sd), turfgrass clippings (TC), and chicken manure (CM). Significant differences were observed in the available nitrogen and phosphorus content of the aqueous extracts of organic materials at different temperatures. The available nitrogen content in aqueous extracts of PM and WC at 25 °C was higher than that registered at 15 °C and 35 °C. Available nitrogen content in the aqueous extracts of CRH, Sd, TC, and WC at 35 °C was higher than at 15 °C and 25 °C. The available phosphorus content in the aqueous extracts of organic materials at 35 °C was higher than that available at 15 °C and 25 °C, with the exception of Sd. In addition, the release of available phosphorus in the aqueous solution of organic materials at different temperatures varied constantly for 108 h. The release of potassium (K⁺) and sodium (Na⁺) ions in the aqueous extracts of organic materials was basically steady over time, with the exception of CM. High temperature (35 °C) may significantly hasten the release of K⁺ from organic substrates (except for WC) with low temperatures significantly inhibiting release of K⁺ in Sd and CRH. High temperatures (35 °C) might significantly facilitate the release of Na⁺ in CM and TC. However, no significant differences were manifested in the release of Na⁺ from organic substrates at different temperatures, with the exception of CM and TC. Moreover, no significant differences were observed in the release of calcium, magnesium and iron ions with time, nor were there any significant differences in the contents of iron ions in the aqueous extracts of organic materials at different temperatures. The results indicate that multiple mediums should be pretreated in water for a week before being used for planting. They should be used when all mineral elements of organic materials are steady and ignoring the effect of organic mediums.     

Selection of adsorbents for treatment of leachate: batch studies of simultaneous adsorption of heavy metals

The simultaneous adsorption of copper (Cu), cadmium (Cd), nickel (Ni), and lead (Pb) ions from spiked deionized water and spiked leachate onto natural materials (peat A and B), by-product or waste materials (carbon-containing ash, paper pellets, pine bark, and semi-coke), and synthetic materials (based on urea-formaldehyde resins, called blue and red adsorbents) or mixtures thereof was investigated. The adsorbents that gave the highest metal removal efficiencies were peat A, a mixture of peat B and carbon-containing ash, and a mixture of peat A and blue. At an initial concentration of 5 mg/l for each metal, the removal of each species of metal ion from spiked water and spiked leachate solutions was very good (>90%) and good (>75%), respectively. When the initial concentration of each metal in the solutions was twenty times higher (100 mg/l), there was a noticeable decrease in the removal efficiency of Cu²⁺, Cd²⁺, and Ni²⁺, but not of Pb²⁺. Langmuir monolayer adsorption capacities, q_m, on peat A were found to be 0.57, 0.37, and 0.36 mmol/g for Pb²⁺, Cd²⁺, and Ni²⁺, respectively. The order of metal adsorption capacity on peat A was the same in the case of competitive multimetal adsorption conditions as it was for single-element adsorption, namely Pb²⁺ > Cd²⁺ ≥ Ni²⁺. The results show that peat alone (an inexpensive adsorbent) is a good adsorbent for heavy metal ions.     

袋式除尘器气流分布数值计算研究

采用结构化/非结构化混合网格技术、多孔介质模型及k-ε两方程湍流模型,对某袋式除尘器及进出口管道内的气体流场进行了数值计算.计算结果表明,合理布置导流板后,袋式除尘器两箱体流量偏差为1.8％;除尘器下游滤袋单元处理气量偏大,中游滤袋单元处理气量较小,最大流量与最小流量偏差为22.3％;靠近除尘器进口处灰斗内存在气流回流特性,易造成粉尘的二次附着现象.     

Kinetics of Hydrolytic Degradation of PLA

The chemical recycling of poly(lactic acid) (PLA) to its monomer is crucial to reduce both the consumption of renewable resources for the monomer synthesis and the environmental impact related to its production and disposal. In particular, the production of lactic acid from PLA wastes, rather than from virgin raw materials, it is also possible to achieve considerable primary energy savings. The focus of this work is to analyse deeply the PLA hydrolytic decomposition by means of a kinetic model based on two reactions mechanism. To this end, new experimental data have been gathered in order to investigate a wider temperature range (from 140 to 180 °C) and to extend the water/PLA ratio up to 50 % of PLA by weight. The reported results clearly highlight that more than 95 % of PLA is hydrolyzed to water-soluble lactic acid within 120 min, when it is hydrolyzed within 160–180 °C. Furthermore, the kinetic constant is highly influenced by reaction temperature. The proposed “two reactions” kinetic mechanism complies satisfactorily with the experimental data under analysis.     

Effect of depth of landfill on the characteristics of soil-like material of aged waste: a case study of Bhalswa dumpsite,India

Journal of Material Cycles and Waste Management - This study characterizes the municipal solid waste (MSW) accumulated for more than 25 years at Bhalswa dumpsite, Delhi, India. 50...