National and regional trends in ambient ozone measurements, 1975–1981

Long-term (1975–1981) and short-term (1980–1981) national and regional trends in ozone (O₃) are examined. The data used in this paper come from the U.S. Environmental Protection Agency's National Aerometric Data Bank (NADB). Air quality trends are presented for both the National Air Monitoring Sites (NAMS) and all other sites meeting the historical and data completeness criteria. Nationally, the composite average of the second-highest daily maximum 1-h O₃ values recorded at 209 sites decreased 14% between 1975 and 1981. An even greater improvement was observed in the estimated number of exceedances in the ozone season (July–September), which decreased 42%. Volatile organic compound (VOC) emissions decreased 9% during the same time period. The greater improvement observed in ozone levels appears to be a combination of reductions in VOC emissions and the change in the calibration procedure which took place between 1978 and 1979. Between 1980 and 1981, the majority of the 159 monitoring sites with data in both years decreased with a median rate of improvement of 8%. This is consistent with the 7% drop in VOC emissions during this period.     

三峡水库水质移动监测指标筛选方法研究

三峡水库水质移动监测体系构建对提升库区整体水质监测能力具有重要意义,其基础工作是科学筛选适合移动监测的水质指标。从三峡水库水质监测现状出发,分析三峡水库水质移动监测需求,并根据其水环境状况与移动监测特点,制定三峡水库水质移动监测指标选取原则。通过分析目前指标筛选的经典数学方法,并根据其不同特点与适用性,选用德尔菲法对水质移动监测指标进行初次筛选、主成分分析法进行第二次筛选,构成一套将定性筛选与定量筛选相结合的方式作为三峡水库水质移动监测指标选取方法,并以三峡库区长江干流典型断面江津大桥为例,用上述方法筛选出该断面移动监测指标为总氮、总磷、溶解氧、氟化物、铜、pH、COD、BOD、高锰酸盐指数、石油类、氨氮、汞、挥发酚与砷。研究结果可为三峡水库水质移动监测工作提供前期基础和理论支撑     

降雨和库水位升降对岩质岸坡的影响

三峡库区蓄水以来,库水位在145～175 m周期性波动,库水位升降是诱发岸坡变形失稳的重要因素之一。针对降雨和库水位升降以龚家方4#斜坡为例,运用自动化远程监测其变形和该区域降雨量,通过数据整理、分析,掌握降雨和库水位升降对滑坡变形的影响状况。结果表明: 在监测期间,个别时间段滑坡变形加剧是降雨和库水位升降共同作用的结果,个别时间段降雨、库水位升降分别为斜坡变形加剧的主导因素,斜坡变形与10日降雨量相关性最好。监测表明目前斜坡仍处于变形阶段,通过对该斜坡的变形监测, 可以定量的分析和描述斜坡的运动状态, 对三峡库区其他类似斜坡的研究具有重要的指导意义     

东洞庭湖水面面积变化监测及其与水位的关系

开展东洞庭湖水面面积长时间变化监测研究对于湖区洪涝旱灾监测、灾害评估等具有重要意义。采用2000~2017年的经过辐射一致性校正的Landsat Collection 1遥感数据集,在ENVI遥感数据处理平台下采用4种常见的水体提取方法（单波段阈值、多波段谱间关系、水体指数、支持向量机）开展了水面面积遥感提取方法比较及东洞庭湖区长时间序列水面面积提取,以此数据为基础开展了东洞庭湖区近18年来湖区水面面积年内和年际变化研究,并探讨了水面面积与城陵矶水文站水位之间的相关关系。结果显示：Landsat Collection 1遥感数据集具有较高的空间和时间分辨率,可以满足东洞庭区长时间序列水面面积提取,且水面面积提取精度较好;采用支持向量机方法提取的湖区多年水面面积平均值为569.9 km2,丰水期水面范围波动较大,而枯水期变化较小;湖区水面面积变化与城陵矶水位变化存在紧密相关关系,不管线性模型还是多项式模型均能准确地描述两者变化关系,受湖区地形分布特征影响,水面面积与水位之间的关系在丰水期较紧密,而枯水期两者之间的相关关系明显降低。     

Survey of tritium radioactivity in Lake Huron surface water

The tritium concentration in Lake Huron water has declined from a high measured in the late 1960s to a 1981 level of ～ 200 pCi/L, similar to literature values for the Great Lakes Waterways and other U.S. surface waters. All current levels for U.S. surface waters including our local water are well within the limits set by the EPA as a standard for drinking water.     

Change in a butterfly community on a gradually overgrowing site

Monitoring of day-active butterflies by water pan traps method over the period 2001–2012 was conducted on a gradually overgrowing habitat in Ko?ick? kotlina basin (Slovakia). Totally, 1457 individuals of 57 species of butterflies were caught and evaluated. Monitoring revealed significant changes in the butterfly community which might be a consequence of a gradual overgrown of the study area. During the research, 12 butterfly species have disappeared from the study area. The monitoring provided results which point to the necessity of appropriate management for conservation of rare and protected butterfly species.     

Pesticides in shallow groundwater of Bahawalnagar, Muzafargarh, D.G. Khan and Rajan Pur districts of Punjab, Pakistan

In Pakistan there is little data on environmental contamination of rural water sources by pesticides. This study evaluated pesticide contamination of groundwater in four intensive cotton growing districts. Water samples were collected from 37 rural open wells in the areas of Bahwalnagar, Muzafargarh, D.G. Khan and Rajan Pur districts of Punjab and analysed for eight pesticides which are mostly used. Information on types of pesticide used and distance to nearest pesticide mixing area and application areas was obtained for each site. From the eight pesticides analysed, six pesticides were detected in the water samples. Only cypermethrin and cabosulfan were not detected. The percentage of detection of bifenthrin, lambda-cyhalothrin, carbofuran, endosulfan, methyl parathion and monocrotophos was, respectively 13.5%, 5.4%, 59.4%, 8%, 5.4% and 35.1% in July; 16.2%, 13.55%, 43.2%, 8%, N.D. (not detected) and 24.3% in October. Maximum contamination levels (MCLs) established by the U.S. Environmental Protection Agency for drinking water were not exceeded. The study has shown the need for monitoring pesticide contamination in rural water resources, and the development of drinking water quality standards for specific pesticides in Pakistan. The conclusions and recommendations will be disseminated to senior decision makers in central and local governments, extension agents and farmers.     

Evaluation of 38 years of radiological environmental data for the nuclear research facility in South Africa

Environmental monitoring has been conducted at the South African National Nuclear Research Facility (Necsa site) for the past 38 years. Included in this monitoring programme was the assessment of water, fish and sediment samples. The objective of this project was to review the data of these assessments to establish if the Necsa activities had any impact on the environment. An assessment of the management of discharge limits was included in the review. Fluctuations in the data reviewed can partly be ascribed to errors in sampling techniques and analysis methods, but mostly to external factors. Two main external factors identified during the review were: dilution effects based on the flowrate in the Crocodile River and the percentage of full capacity of the Hartbeespoort Dam, and the atmospheric fallout from nuclear weapons testing. In this project, the impact of these factors were investigated with the help of correlation coefficient calculations and graphs. It was concluded that the flowrate of the Crocodile River and percentage full capacity of the Hartbeespoort Dam did have an impact on the beta activity measured in water and fish samples, and the (nat)U activities measured in water samples. The measured fallout from nuclear weapons testing in the southern hemisphere also had an impact on the beta activity in water. The assessment of the environmental monitoring data also showed that accidental releases were measurable in the environment. The added routine impact to a member of the public downstream from Necsa was on average an annual dose of 0.54 microSv more than that to a person living upstream from Necsa, which is considered insignificant in international radiation protection norms. The conclusion can be made that the monitoring programme is successful in satisfying its main objective, which is to determine the effects of the discharges on the environment and the immediate population.     

Linking high resolution mass spectrometry data with exposure and toxicity forecasts to advance high-throughput environmental monitoring

There is a growing need in the field of exposure science for monitoring methods that rapidly screen environmental media for suspect contaminants. Measurement and analysis platforms, based on high resolution mass spectrometry (HRMS), now exist to meet this need. Here we describe results of a study that links HRMS data with exposure predictions from the U.S. EPA's ExpoCast™ program and in vitro bioassay data from the U.S. interagency Tox21 consortium. Vacuum dust samples were collected from 56 households across the U.S. as part of the American Healthy Homes Survey (AHHS). Sample extracts were analyzed using liquid chromatography time-of-flight mass spectrometry (LC–TOF/MS) with electrospray ionization. On average, approximately 2000 molecular features were identified per sample (based on accurate mass) in negative ion mode, and 3000 in positive ion mode. Exact mass, isotope distribution, and isotope spacing were used to match molecular features with a unique listing of chemical formulas extracted from EPA's Distributed Structure-Searchable Toxicity (DSSTox) database. A total of 978 DSSTox formulas were consistent with the dust LC–TOF/molecular feature data (match score ≥ 90); these formulas mapped to 3228 possible chemicals in the database. Correct assignment of a unique chemical to a given formula required additional validation steps. Each suspect chemical was prioritized for follow-up confirmation using abundance and detection frequency results, along with exposure and bioactivity estimates from ExpoCast and Tox21, respectively. Chemicals with elevated exposure and/or toxicity potential were further examined using a mixture of 100 chemical standards. A total of 33 chemicals were confirmed present in the dust samples by formula and retention time match; nearly half of these do not appear to have been associated with house dust in the published literature. Chemical matches found in at least 10 of the 56 dust samples include Piperine, N,N-Diethyl-m-toluamide (DEET), Triclocarban, Diethyl phthalate (DEP), Propylparaben, Methylparaben, Tris(1,3-dichloro-2-propyl)phosphate (TDCPP), and Nicotine. This study demonstrates a novel suspect screening methodology to prioritize chemicals of interest for subsequent targeted analysis. The methods described here rely on strategic integration of available public resources and should be considered in future non-targeted and suspect screening assessments of environmental and biological media.     

A method for estimating dietary intake of environmental trace contaminants: Cadmium — a case study

Variations in either food content or dietary habit affect dietary intake of trace contaminants. Trace contaminants enter the human food chain through many environmental pathways, including contamination of water used for drinking or irrigation, sludge used on cropland, fertilizers and other agricultural chemicals, chemicals leached from disposal sites to water, or airborne deposition on soil, water, or crops. A flow chart (Fig. 1) summarizes these pathways.Dietary exposure to environmental trace contaminants places some segments of the U.S. population at substantially higher risk than others. A methodology to calculate population distribution curves for dietary intake of trace contaminants is presented in this report, using cadmium (Cd) as the specific example. This methodology can be applied both to calculate the distribution of daily individual intake of trace contaminants, as well as to estimate the size of the potentially at-risk population. The methodology is developed with both a stochastic approach and a matrix approach. The matrix approach is coded as program SCOPE, and the stochastic as program MONTE.The dietary habits of the U.S. population were determined by using computer codes to analyse and synthesize an array of dietary data. The 15- to 20-yr-old male population was selected for analysis because this group has the largest gram-caloric intake of any age-sex classification. Data from the U.S. Department of Agriculture and the Food and Drug Administration were analyzed to define Cd concentration distribution for 34 food categories, into which 1880 food items were classified. Food consumption frequency histograms were generated with this information, using data synthesis routines and SCOPE.A 1974 FDA survey of metal concentrations in selected foods at 71 U.S. sampling sites yielded tabular, truncated frequency histograms for Cd concentrations in 32 of the food categories studied. Histograms were then constructed by integrating consumption and Cd concentration for each food category for the total diet.The World Health Organization (WHO) recommended in 1972 a tolerable limit of Cd intake of approximately 70 μg per day. A comparison of SCOPE and MONTE total diet Cd intake frequency histograms indicates the likelihood of high Cd intake, at-rick populations. SCOPE results predict that approximately 13% of the 15- to 20-yr-old males studied ingest Cd at a rate greater than 70 μg per day. MONTE predicts that 14%, with a 12–17% range, ingest amounts greater than the WHO-recommended limit on a daily basis. This percentage represents a potential at-risk population. The actual at-risk population would be those persons who consistently ingest more than 70 μg/day.The percentage of the population projected to ingest more than 70 μg of Cd per day needs to be defined by geography, ethnicity, race, and dietary preference in order to fully evaluate Cd intake risks and to set parameters for epidemiological surveys needed for confirmation. Assuming validity for this methodology, there is justification for preventing significant increases in Cd dietary intake by way of man's activities.     

Global monitoring of carbon dioxide in the atmosphere

The historic development of the scientific interest in monitoring CO₂ in the atmosphere is the subject of this article. Particular emphasis is placed upon activities initiated by the USA in the 1950s which led to the establishment of the Mauna Loa Observatory and further developed into the existing world-wide monitoring system for air constituents and air pollution operated under the auspices of the World Meteorological Organization, a major contributer to the Global Environmental Monitoring System of the UN Environment Programme. Recent studies on the feasibility of monitoring the background level of CO₂ at stations throughout the world have indicated considerable difficulties resulting from the influences of the biosphere. These problems have led WMO to adopt new criteria for CO₂ monitoring station locations which are presented in a discussion of future needs and plans for global monitoring of CO₂ in the atmosphere.     

Some industrial effluents in Durgapur and their impact on the Damodar river

The industrial waste effluents from two industries of Durgapur have been traced along the course of Tamla Nalah at selected sites up to its confluence with the Damodar river and downstream. There are evidences of contamination of the river with toxic pollutants—ammonia, phenol, cyanide, sulphide, and trace mercury from Tamla Nalah. The upstream river water (Durgapur barrage), which is believed to be fairly pure, is actually not much better than the downstream river water. Monitoring data for about a year are presented and discussed.     

Rethinking assessment of drought impacts: a systemic approach towards sustainability

Although impacting primarily economic sectors, droughts may also initiate dynamic mechanisms that have socio-environmental consequences on sustainability of the impacted areas. To date, most research has dealt with the economic impacts of droughts, with minimal attention being paid to the dynamics of damaging mechanisms associated with socio-environmental impacts. Using a systemic approach, this paper develops a method of identifying the dynamic structures responsible for the consequences of drought. Considering the impacts of recent droughts in Iran, the paper presents a conceptual model, underpinned by a Limits to Growth archetype to explain how different drought impacts are triggered. Moreover, adopting the Viability Loops concept, a range of strategies and indices are suggested as monitoring tools to sustain socio-economic life in a drought-impacted area. The provinces of Hamadan (with water abundance), and Yazd and Isfahan (with water scarcity) in Iran have been selected to illustrate the proposed methodology. Results show a higher vulnerability to droughts in the water-rich region due to dependence on water abundance as opposed to the water-poor regions, which are well adapted to water scarcity conditions.     

An assessment of the impact of motorway runoff on a pond, wetland and stream

The impact of soil filtered runoff from a section of the M25 outer London motorway (constructed in 1981) on a pond, wetland and stream in a nature reserve was investigated by monitoring water, sediment. The tissues of the emergent plants Typha latifolia and Glyceria maxima collected from the pond were analysed for the heavy metals, Cd, Pb, Cu and Zn. Macroinvertebrates were monitored in the stream and biotic indices applied to the data. The plant tissue concentrations for Typha and Glyceria show decreasing metal concentrations from root to rhizome to leaf. This trend has previously been reported for Typha exposed to runoff although the tissue concentrations are lower in this study with the exception of Cd in root tissue. The Biological Monitoring Working Party (BMWP) score and Average Score Per Taxon (ASPT) for the stream at sites above and below the pond outlet are lower than the scores recorded by the Environment Agency for England and Wales at an upstream site above the Pond/Wetland. The sites have an Overall Quality Index of 'moderate water quality', and there is no evidence of a deterioration of biologically assessed water quality between them. The results of the study show the long-term impact on sediment of filtered road runoff discharges to a natural wetland and pond located in a nature reserve. The use of natural wetlands for the discharge of road runoff is inadvisable. Constructed wetlands in combination with other structures including settlement trenches and ponds should be considered as an alternative treatment option.     

Radioactivity in environmental samples: Calibration standards measurement methods,quality assurance,and data analysis

The numerous environmental radioactivity measurements made by and for the U.S. Environmental Protection Agency (U.S. EPA) include measurements on samples of water, urine, food, milk, and air filters. Calibration standards are listed which are available in the form of water solutions and soils for a wide range of radionuclides. Method validation procedures for U.S. EPA approval include protocol development and single-laboratory and multiple-laboratory evaluation for precision and accuracy. Interlaboratory comparison studies are conducted for both cross-check and performance evaluation samples and involve 295 federal, state, and local laboratories. For water samples, 80%–90% of the participating laboratories are within the control limits for most of the radionuclides measured; however, some problem areas exist, especially for radium-228 and strontium-89 and -90. For milk and food samples, more than 90% of the laboratories are within control limits for cobalt-60 and cesium-137 but some problems exist for the measurement of strontium-90, iodine-131, and potassium-40. For tritium, 91% of the laboratories are within the control limit for water samples and 87% are within the control limits for the urine samples. The laboratory performance for air filter samples shows some problems for gross beta, strontium-90 and cesium-137 measurements.     

Redox chemistry of sulphate and uranium in a phosphogypsum tailings dump

The present study aims to assess the effect of redox conditions existing within the tailings dump on the stability of phosphogypsum (e.g. sulphate reduction) and uranium(VI). Phosphogypsum sampling and in-situ measurements were carried out at a coastal tailings dump in Vasiliko Cyprus, pH, E_H and solubility experiments were performed in simulated laboratory systems and thermodynamic calculations using MINTEQA2. Generally, in the open tailings dump oxidizing conditions predominate stabilizing sulphur and uranium in their hexavalent oxidation states. On the other hand, after the application of a soil/vegetative cover and in the presence of natural organic matter, anoxic conditions prevail (E_H < −70 mV) resulting in S(VI) and U(VI) reduction to S(−II) and U(IV), respectively. Although, the sulphide anion can form very insoluble compounds with heavy metal ions (e.g. Cd(II), Pb(II) etc.) and U(IV) oxide has very low solubility, partial reduction of sulphate to sulphide within gypsum may affect the stability of phosphogypsum resulting in enhanced erosion of the material by rain- and seawater and washing out of contaminants in particulate/colloidal form.     

Specifying information needs: improving the working methodology

Specification of information needs is an important step in the design of monitoring networks. Within the framework of Monitoring Strategy 2000+, a programme of the Dutch Directorate General of Public Works and Water Management (Rijkswaterstaat) which seeks to provide innovation in the monitoring sector, a method has been developed to link water management policy to monitoring through specification of information needs. Over the past 2 years, this method has been applied in several projects within the Rijkswaterstaat organisation. Use of this method has led to improvements in the monitoring practice and was judged very positively by the people involved. Nevertheless, the main obstacle to employing the method was the actual translation of policy matters into information products. A special study is carried out, focusing on this aspect within the method, to provide the participants of a project with a mental framework that enables them to clearly specify their information needs. The major requirements for this mental framework are that all participants have a clear view of the process (system), and that they are able to relate their contribution to this process and to the contributions of others (transparency). The first step of the process is to focus the attention of stakeholders on the information they will actually need for decision-making. The next step is to confront the different expressed opinions through the method of the 'devil's advocate', which implies criticising the results of the first step by finding as many as possible arguments against these opinions. This should force the stakeholders to better specify their arguments. The method, its improvements and the results of one pilot project will be discussed in this paper. Electronic Publication     

Enhanced oil recovery: Environmental issues and state regulatory programs

During 1977–1978, Oak Ridge National Laboratory (ORNL) prepared environmental impact assessments for nine U.S. Department of Energy-sponsored enhanced oil recovery (EOR) field demonstration projects located in six states and reviewed the oil regulations for all oil-producing states. These evaluations revealed some potentially important environmental impacts associated with EOR including (1) pollution of land and surface waters from spills or leaks of oil and brine or other chemicals, (2) loss of biota, (3) excessive erosion and sedimentation (mostly in hilly terrain) and subsequent deterioration of surface-water quality, (4) contamination of groundwater, and (5) excessive air emissions from thermal operations. Potential groundwater impacts include (1) production of toxic and carcinogenic substances from synergistic interactions among chemicals used primarily in the micellar-polymer flooding technique, (2) formation of acid waters with small amounts of oil and metal residues and oxides from in situ combustion, and (3) corrosion of well casings and potential leaks of hydrogen sulfide primarily from injection of miscible carbon dioxide. For use of EOR techniques to expand in an environmentally acceptable manner, environmental planning (including monitoring, protection measures, and reclamation strategies) must be an integral part of the initial project development. Acceptable monitoring, prevention, mitigation, and reclamation procedures are available for most of the identified environmental problems, but the best techniques may not be known by operators or required by law. Most states have stringent controls for plugging abandoned wells and disposal of waste material, but these may not be enforced because of limited staff and funds. However, other environmental considerations, e.g., reclamation plans, water quality and other monitoring programs, and abandonment plans, are often lacking. The need for additional environmental planning and monitoring requirements specific to the oil-production industry is emphasized. States are encouraged to continue strengthening and upgrading their oil-regulatory programs to safeguard the environment. More studies are needed on (1) toxicity and carcinogenicity of chemicals used in injection processes, (2) evaluation of groundwater monitoring methods, and (3) reclamation procedures for soils contaminated by oil and brine.     

Significant issues in water resources policy

The difficulties in resolving water resource policy questions are analogous in many ways to the difficulties in resolving energy policy questions — technical, legal, institutional and social. Federal involvement in water resources began in 1809 and continues to the present time. The most recent comprehensive study was the Second National Water Assessment by the U.S. Water Resources Council in 1979. Conclusions reached were that water quality and quantity and surface and ground water are artificial distinctions, that water policies should reflect national needs and priorities, that flood control must be accelerated and drinking water quality protected and that more decisions should be made at a local level while integrated into national planning and development. Though the study disaggregated the U.S. into 106 subregions, its projections of a single future rather than a range of futures gives an erroneous sense of predictability to the work. To help resolve the major problems, inadequate supply and contamination and flooding and erosion, ultrasophisticated mathematical models are widely utilized without sufficient verification. A more tractable approach for policy studies would be to use simplified semi-empirical models rather than first principle models. Possibly more important, policy resolution awaits social value resolution which means that the policies adopted must be flexible, incremental, and non-divisive.     

Using the Q10 model to simulate E. coli survival in cowpats on grazing lands

Microbiological quality of surface waters can be affected by microbial load in runoff from grazing lands. This effect, with other factors, depends on the survival of microorganisms in animal waste deposited on pastures. Since temperature is a leading environmental parameter affecting survival, it indirectly impacts water microbial quality. The Q₁₀ model is widely used to predict the effect of temperature on rates of biological processes, including survival. Objectives of this work were to (i) evaluate the applicability of the Q₁₀ model to Escherichia coli inactivation in bovine manure deposited on grazing land (i.e., cowpats) and (ii) identify explanatory variables for the previously reported E. coli survival dynamics in cowpats. Data utilized in this study include published results on E. coli concentrations in natural and repacked cowpats from research conducted the U.S. (Virginia and Maryland), New Zealand, and the United Kingdom. Inspection of the datasets led to conceptualizing E. coli survival (in cowpats) as a two-stage process, in which the initial stage was due to growth, inactivation or stationary state of the population and the second stage was the approximately first-order inactivation. Applying the Q₁₀ model to these datasets showed a remarkable similarity in inactivation rates, using the thermal time. The reference inactivation rate constant of 0.042 (thermal days)^− 1 at 20 °C gave a good approximation (R² = 0.88) of all inactivation stage data with Q₁₀ = 1.48. The reference inactivation rate constants in individual studies were no different from the one obtained by pooling all data (P < 0.05). The rate of logarithm of the E. coli concentration change during the first stage depended on temperature. Duration of the first stage, prior to the first-order inactivation stage and the initial concentration of E. coli in cowpats, could not be predicted from available data. Diet and age are probable factors affecting these two parameters however, until their environmental and management predictors are known, microbial water quality modeling must treat them as a stochastic source of uncertainty in simulation results.