Regional scale variability in sediment and nutrient delivery from small agricultural watersheds

Although many studies have pointed out the various controlling factors of sediment and nutrient delivery on a plot or watershed scale, little is known on the spatial variability of sediment and nutrient delivery on a regional scale. This study was conducted to reveal regional variations in sediment-associated nutrient delivery in central Belgium. Sediment deposited in 13 small retention ponds was sampled and analyzed for total phosphorus (TP), K, Mg, and Ca content. The TP content of the sediment deposits varied from 510 to 2001 mg P per kg sediment. Nutrients are predominantly fixed on the very fine sediment fraction (<16 microm), which is the reason why the nutrient trap efficiency of the ponds is only a fraction of the sediment trap efficiency. Average nutrient trap efficiency of the studied ponds varies between 4 and 31%, whereas sediment trap efficiency varies between 10 and 72%. For watersheds ranging from 7 to 4873 ha, sediment yield ranged between 1.2 and 20.6 Mg ha(-1) yr(-1), whereas TP export varied from 1.8 to 39.7 kg ha(-1) yr(-1). The observed spatial variability in nutrient losses is primarily attributed to regional variations in erosion and sediment yield values and to a far lesser degree to the spatial variations in fertilizer application. Redistribution of manure in the framework of an agricultural policy may increase the rate of nutrient delivery by ways of erosion and sediment transport.     

Development of environmental thresholds for streams in agricultural watersheds

Global increases in consumption of chemical nutrients, application of pesticides, and water withdrawal to enhance agricultural yield have resulted in degraded water quality and reduced water availability. Efforts to safeguard or improve environmental conditions of agroecosystems have usually focused on managing on-farm activities to reduce materials loss and conserve habitat. Another management measure for improving environmental quality is adoption of environmental performance standards (also called outcome-based standards). This special collection of six papers presents the results of four years of research to devise scientifically credible approaches for setting environmental performance standards to protect water quantity and quality in Canadian agriculturally dominated watersheds. The research, conducted as part of Canada's National Agri-Environmental Standards Initiative, aimed to identify Ideal Performance Standards (the desired environmental state needed to maintain ecosystem health) and Achievable Performance Standards (the environmental conditions achievable using currently available and recommended best available processes and technologies). Overviews of the papers, gaps in knowledge, and future research directions are presented. As humans, livestock, and wildlife (both terrestrial and aquatic) experience greater pressures to share the same limited water resources, innovative research is needed that incorporates a landscape perspective, economics, farm practices, and ecology to advance the development and application of tools for protecting water resources in agricultural watersheds.     

Phosphorus transport pathways to streams in tile-drained agricultural watersheds

Agriculture is a major nonpoint source of phosphorus (P) in the Midwest, but how surface runoff and tile drainage interact to affect temporal concentrations and fluxes of both dissolved and particulate P remains unclear. Our objective was to determine the dominant form of P in streams (dissolved or particulate) and identify the mode of transport of this P from fields to streams in tile-drained agricultural watersheds. We measured dissolved reactive P (DRP) and total P (TP) concentrations and loads in stream and tile water in the upper reaches of three watersheds in east-central Illinois (Embarras River, Lake Fork of the Kaskaskia River, and Big Ditch of the Sangamon River). For all 16 water year by watershed combinations examined, annual flow-weighted mean TP concentrations were >0.1 mg L(-1), and seven water year by watershed combinations exceeded 0.2 mg L(-1). Concentrations of DRP and particulate P (PP) increased with stream discharge; however, particulate P was the dominant form during overland runoff events, which greatly affected annual TP loads. Concentrations of DRP and PP in tiles increased with discharge, indicating tiles were a source of P to streams. Across watersheds, the greatest DRP concentrations (as high as 1.25 mg L(-1)) were associated with a precipitation event that followed widespread application of P fertilizer on frozen soils. Although eliminating this practice would reduce the potential for overland runoff of P, soil erosion and tile drainage would continue to be important transport pathways of P to streams in east-central Illinois.     

Transport and fate of nitrate in headwater agricultural streams in Illinois

Nitrogen inputs to the Gulf of Mexico have increased during recent decades and agricultural regions in the upper Midwest, such as those in Illinois, are a major source of N to the Mississippi River. How strongly denitrification affects the transport of nitrate (NO(3)-N) in Illinois streams has not been directly assessed. We used the nutrient spiraling model to assess the role of in-stream denitrification in affecting the concentration and downstream transport of NO(3)-N in five headwater streams in agricultural areas of east-central Illinois. Denitrification in stream sediments was measured approximately monthly from April 2001 through January 2002. Denitrification rates tended to be high (up to 15 mg N m(-2) h(-1)), but the concentration of NO(3)-N in the streams was also high (>7 mg N L(-1)). Uptake velocities for NO(3)-N (uptake rate/concentration) were lower than reported for undisturbed streams, indicating that denitrification was not an efficient N sink relative to the concentration of NO(3)-N in the water column. Denitrification uptake lengths (the average distance NO(3)-N travels before being denitrified) were long and indicated that denitrification in the streambed did not affect the transport of NO(3)-N. Loss rates for NO(3)-N in the streams were <5% d(-1) except during periods of low discharge and low NO(3)-N concentration, which occurred only in late summer and early autumn. Annually, most NO(3)-N in these headwater sites appeared to be exported to downstream water bodies rather than denitrified, suggesting previous estimates of N losses through in-stream denitrification may have been overestimated.     

Whole-stream response to nitrate loading in three streams draining agricultural landscapes

Physical, chemical, hydrologic, and biologic factors affecting nitrate (NO3(-)) removal were evaluated in three agricultural streams draining orchard/dairy and row crop settings. Using 3-d "snapshots" during biotically active periods, we estimated reach-level NO3(-) sources, NO3(-) mass balance, in-stream processing (nitrification, denitrification, and NO3(-) uptake), and NO3(-) retention potential associated with surface water transport and ground water discharge. Ground water contributed 5 to 11% to stream discharge along the study reaches and 8 to 42% of gross NO3(-) input. Streambed processes potentially reduced 45 to 75% of ground water NO3(-) before discharge to surface water. In all streams, transient storage was of little importance for surface water NO3(-) retention. Estimated nitrification (1.6-4.4 mg N m(-2) h(-1)) and unamended denitrification rates (2.0-16.3 mg N m(-2) h(-1)) in sediment slurries were high relative to pristine streams. Denitrification of NO3(-) was largely independent of nitrification because both stream and ground water were sources of NO3(-). Unamended denitrification rates extrapolated to the reach-scale accounted for <5% of NO3(-) exported from the reaches minimally reducing downstream loads. Nitrate retention as a percentage of gross NO3(-) inputs was >30% in an organic-poor, autotrophic stream with the lowest denitrification potentials and highest benthic chlorophyll a, photosynthesis/respiration ratio, pH, dissolved oxygen, and diurnal NO3(-) variation. Biotic processing potentially removed 75% of ground water NO3(-) at this site, suggesting an important role for photosynthetic assimilation of ground water NO3(-) relative to subsurface denitrification as water passed directly through benthic diatom beds.     

Physical and ecological thresholds for deposited sediments in streams in agricultural landscapes

Excessive sedimentation in streams and rivers remains a pervasive problem for the protection of aquatic habitat and the sustainability of aquatic communities. Whereas water quality criteria have been determined for suspended sediments in many jurisdictions across North America, comparably little has been done for deposited (also known as bedded) sediments. Through Canada's National Agri-Environmental Standards Initiative, assessment techniques and analytical tools were developed for estimating environmental thresholds for deposited sediments in agricultural watersheds in New Brunswick (NB) and Prince Edward Island (PEI) in the Atlantic Maritimes of Canada. Physical thresholds were developed through assessment of geomorphic metrics, which were then analyzed using y-intercept and 25th percentile approaches. For NB, there was strong agreement in physical thresholds for both analytical approaches (e.g., percent fines <2 mm were 7.5 for y-intercept and 6.9 for 25th percentile approaches). In contrast, physical thresholds for PEI differed considerably between approaches (e.g., percent fines <2 mm were 6.1 for y-intercept and 19.6 for 25th percentile approaches), likely due to a narrower range in agricultural land cover. Cross-calibration of our provisional physical thresholds for NB with ecological (i.e., benthic macroinvertebrate) assessments show that ecological thresholds, calculated as change-points in relationships between Ephemeroptera-Plecoptera-Trichoptera relative abundance or Modified Family Biotic Index and geomorphic criteria, were more liberal than physical thresholds. These results suggest that provisional thresholds developed using geomorphic criteria should demarcate change from the least disturbed condition and reduce the risk of sedimentation degrading benthic ecosystems.     

Limited occurrence of denitrification in four shallow aquifers in agricultural areas of the United States

The ability of natural attenuation to mitigate agricultural nitrate contamination in recharging aquifers was investigated in four important agricultural settings in the United States. The study used laboratory analyses, field measurements, and flow and transport modeling for monitoring well transects (0.5 to 2.5 km in length) in the San Joaquin watershed, California, the Elkhorn watershed, Nebraska, the Yakima watershed, Washington, and the Chester watershed, Maryland. Ground water analyses included major ion chemistry, dissolved gases, nitrogen and oxygen stable isotopes, and estimates of recharge date. Sediment analyses included potential electron donors and stable nitrogen and carbon isotopes. Within each site and among aquifer-based medians, dissolved oxygen decreases with ground water age, and excess N(2) from denitrification increases with age. Stable isotopes and excess N(2) imply minimal denitrifying activity at the Maryland and Washington sites, partial denitrification at the California site, and total denitrification across portions of the Nebraska site. At all sites, recharging electron donor concentrations are not sufficient to account for the losses of dissolved oxygen and nitrate, implying that relict, solid phase electron donors drive redox reactions. Zero-order rates of denitrification range from 0 to 0.14 micromol N L(-1)d(-1), comparable to observations of other studies using the same methods. Many values reported in the literature are, however, orders of magnitude higher, which is attributed to a combination of method limitations and bias for selection of sites with rapid denitrification. In the shallow aquifers below these agricultural fields, denitrification is limited in extent and will require residence times of decades or longer to mitigate modern nitrate contamination.     

The impact of agricultural runoff on the quality of two streams in vegetable farm areas in Ghana

A study of two small streams at Akumadan and Tono, Ghana, was undertaken during the rain and dry season periods between February 2005 and January 2006 to investigate the impact of vegetable field runoff on their quality. In each stream we compared the concentration of current-use pesticides in one site immediately upstream of a vegetable field with a second site immediately downstream. Only trace concentrations of endosulfan and chlorpyrifos were detected at both sites in both streams in the dry season. In the wet season, rain-induced runoff transported pesticides into downstream stretches of the streams. Average peak levels in the streams themselves were 0.07 microg L(-1) endosulfan, 0.02 microg L(-1) chlorpyrifos (the Akumadan stream); 0.04 microg L(-1) endosulfan, 0.02 microg L(-1) chlorpyrifos (the Tono stream). Respective average pesticide levels associated with streambed sediment were 1.34 and 0.32 microg kg(-1) (the Akumadan stream), and 0.92 and 0.84 microg kg(-1) (the Tono stream). Further investigations are needed to establish the potential endosulfan and chlorpyrifos effects on aquatic invertebrate and fish in these streams. Meanwhile measures should be undertaken to reduce the input of these chemicals via runoff.     

Influence of soil moisture and land use history on denitrification end-products

We investigated the effects of recent moisture history on the relative production of N2O and N2 during denitrification in soil from cropped and successional ecosystems. The soils were pedogenically identical but had been managed differently for the past decade. Sieved soils were amended with nitrate, glucose, and water. Long-wet and short-wet incubations received 80 and 0%, respectively, of prescribed water 2 d before incubation and the rest just before incubation. The N2O and N2 production and N2O mole fraction (N2O/[N2O + N2]) were measured using acetylene inhibition. The N2 production and soil 15N enrichment were measured by 15N-gas evolution. The response of N2O mole fraction to moisture history differed by ecosystem. Mean N2O mole fraction in the successional system was about the same for long-wet and short-wet treatments (0.34 and 0.33, respectively). For the cropped system, however, the N2O mole fraction was 0.36 for the long-wet and 0.90 for the short-wet treatment. Thus, in the cropped system a much smaller proportion of end product was N2O if soil had been wet for 2 d. For N2 fluxes, the isotope method gave the same pattern (r = 0.92) but only about one-third the magnitude, suggesting that N2 derived from two distinct pools. Differences in response of N2O mole fraction for successional and cropped soils may be due to differences in microbial communities. Further knowledge of ecosystem differences with respect to N2O mole fraction and recent moisture history may improve modeled estimates of local and global N2O fluxes.     

Grazing management effects on sediment, phosphorus, and pathogen loading of streams in cool-season grass pastures

Erosion and runoff from pastures may lead to degradation of surface water. A 2-yr grazing study was conducted to quantify the effects of grazing management on sediment, phosphorus (P), and pathogen loading of streams in cool-season grass pastures. Six adjoining 12.1-ha pastures bisected by a stream in central Iowa were divided into three treatments: continuous stocking with unrestricted stream access (CSU), continuous stocking with restricted stream access (CSR), and rotational stocking (RS). Rainfall simulations on stream banks resulted in greater ( < 0.10) proportions of applied precipitation and amounts of sediment and P transported in runoff from bare sites than from vegetated sites across grazing treatments. Similar differences were observed comparing vegetated sites in CSU and RS pastures with vegetated sites in CSR pastures. Bovine enterovirus was shed by an average of 24.3% of cows during the study period and was collected in the runoff of 8.3 and 16.7% of runoff simulations on bare sites in CSU pastures in June and October of 2008, respectively, and from 8.3% of runoff simulations on vegetated sites in CSU pastures in April 2009. Fecal pathogens (bovine coronavirus [BCV], bovine rotavirus group A, and O157:H7) shed or detected in runoff were almost nonexistent; only BCV was detected in feces of one cow in August of 2008. Erosion of cut-banks was the greatest contributor of sediment and P loading to the stream; contributions from surface runoff and grazing animals were considerably less and were minimized by grazing management practices that reduced congregation of cattle by pasture streams.     

Use of watershed characteristics to select control streams for estimating effects of metal mining wastes on extensively disturbed streams

Impacts of sediments and heavy metals on the biota of streams in the copper-mining district of southwestern Montana were examined by comparing aquatic communities of impacted streams with those of control streams. Control streams were chosen through the use of a technique that identifies similar streams based on similarities in their watershed characteristics. Significant differences between impacted and control sites existed for surface substrate, riparian vegetation, and the number of macroinvertebrate taxa. These results revealed that: (a) chemical and physical habitats at the impacted sites were disrupted, (b) the presence of trout was an inadequate measure of ecological integrity for these sites, and (c) watershed classification based on a combination of mapped terrestrial characteristics provided a reasonable method to select control sites where potential control sites upstream and downstream were unsuitable.     

Phytoestrogens and mycotoxins in Iowa streams: an examination of underinvestigated compounds in agricultural basins

This study provides the first broad-scale investigation on the spatial and temporal occurrence of phytoestrogens and mycotoxins in streams in the United States. Fifteen stream sites across Iowa were sampled five times throughout the 2008 growing season to capture a range of climatic and crop-growth conditions. Basin size upstream from sampling sites ranged from 7 km2 to > 836,000 km2. Atrazine (herbicide) also was measured in all samples as a frame-of-reference agriculturally derived contaminant. Target compounds were frequently detected in stream samples: atrazine (100%), formononetin (80%), equol (45%), deoxynivalenol (43%), daidzein (32%), biochanin A (23%), zearalenone (13%), and genistein (11%). The nearly ubiquitous detection of formononetin (isoflavone) suggests a widespread agricultural source, as one would expect with the intense row crop and livestock production present across Iowa. Conversely, the less spatially widespread detections of deoxynivalenol (mycotoxin) suggest a more variable source due to the required combination of proper host and proper temperature and moisture conditions necessary to promote Fusarium spp. infections. Although atrazine concentrations commonly exceeded 100 ng L(-1) (42/75 measurements), only deoxynivalenol (6/56 measurements) had concentrations that occasionally exceeded this level. Temporal patterns in concentrations varied substantially between atrazine, formononetin, and deoxynivalenol, as one would expect for contaminants with different source inputs and processes of formation and degradation. The greatest phytoestrogen and mycotoxin concentrations were observed during spring snowmelt conditions. Phytoestrogens and mycotoxins were detected at all sampling sites regardless of basin size. The ecotoxicological effects from long-term, low-level exposures to phytoestrogens and mycotoxins or complex chemicals mixtures including these compounds that commonly rake place in surface water are poorly understood and have yet to be systematically investigated in environmental studies.     

Herbicides and herbicide degradation products in Upper Midwest agricultural streams during August base-flow conditions

Herbicide concentrations in streams of the U.S. Midwest have been shown to decrease through the growing season due to a variety of chemical and physical factors. The occurrence of herbicide degradation products at the end of the growing season is not well known. This study was conducted to document the occurrence of commonly used herbicides and their degradation products in Illinois, Iowa, and Minnesota streams during base-flow conditions in August 1997. Atrazine, the most frequently detected herbicide (94%), was present at relatively low concentrations (median 0.17 microg L(-1)). Metolachlor was detected in 59% and cyanazine in 37% of the samples. Seven of nine compounds detected in more than 50% of the samples were degradation products. The total concentration of the degradation products (median of 4.4 microg L(-1)) was significantly greater than the total concentration of parent compounds (median of 0.26 microg L(-1)). Atrazine compounds were present less frequently and in significantly smaller concentrations in streams draining watersheds with soils developed on less permeable tills than in watersheds with soils developed on more permeable loess. The detection and concentration of triazine compounds was negatively correlated with antecedent rainfall (April-July). In contrast, acetanalide compounds were positively correlated with antecedant rainfall in late spring and early summer that may transport the acetanalide degradates into ground water and subsequently into nearby streams. The distribution of atrazine degradation products suggests regional differences in atrazine degradation processes.     

Effectiveness of grassed waterways in reducing runoff and sediment delivery from agricultural watersheds

Grassed waterways (GWWs) drain surface runoff from fields without gullying along the drainageway. Secondary functions include reducing runoff volume and velocity and retaining sediments and harmful substances from adjacent fields. Grass cover (sward)-damaging sedimentation in the GWW is commonly reduced by frequent mowing, but in doing so the effectiveness of the waterway relative to the secondary functions is reduced. Our objectives were to (i) evaluate whether the maintenance of a GWW can be reduced if on-site erosion control is effective, (ii) measure the effectiveness of such a GWW, and (iii) analyze the underlying mechanisms. A long-term (1994-2000) landscape experiment was performed in four watersheds, where two had GWWs for which maintenance was largely neglected. An intensive soil conservation system was established on all fields. Runoff and sediment delivery were continuously measured in the two watersheds with GWWs and in their paired watersheds that were similar, but without GWWs. Runoff was reduced by 90 and 10% for the two sets of paired watersheds, respectively. The different efficiencies of the GWWs resulted from different layouts (doubled width and flat-bottomed vs. v-shaped drainageway). The GWWs reduced sediment delivery by 97 and 77%, respectively, but the sward was not damaged by sedimentation. Grain sizes > 50 microm were settled due to gravity in both GWWs. Smaller grain sizes were primarily settled due to infiltration, which increased with a more effective runoff reduction. In general, the results indicated a high potential of GWWs for reducing runoff volume and velocity, sediments, and agrochemicals coming from agricultural watersheds.     

Riparian vegetation and channel morphology impact on spatial patterns of water quality in agricultural watersheds

A model based on theKLS factors of the Universal Soil Loss Equation (USLE) accurately predicted temporal dynamics and relative peak levels of suspended solids, turbidity, and phosphorus in an agricultural watershed with well-protected streambanks and cultivation to the stream edge. Fine suspended solids derived from surface runoff appeared to be a major component of the suspended solids in this stream. The model did not predict the same parameters in a watershed with unstable channel substrates, exposed streambanks, and heterogeneity in riparian vegetation and channel morphology. The rate of increase in concentration of the water quality parameters was higher than predicted in areas without riparian vegetation and with unstable substrates. Peak levels were higher than predicted where unstable channel substrates occurred, and potential energy of the stream was high because of stream alterations (removal of near-stream vegetation and creation of a uniform, straight channel). Timing of the peak levels of suspended solids, turbidity, and phosphorus in these areas seemed related to major flushes of discharge due to delayed inputs from the surface or subsurface or both or to rapid urban drainage. Higher suspended solids concentration in this stream seemed to involve larger quantities of large particles. Thus, the USLE may not adequately predict relative water quality conditions within a watershed when variation in channel morphology and riparian vegetation exists. We make the following recommendations:

1. Models to predict water quality effects of management programs should combine a terrestrial phase (which details hydrologic and erosion processes associated with surface runoff) with an aquatic phase (which details hydrologic processes of scour and sediment transport in channels). The impact of near-channel areas on these hydrologic processes should receive special attention.
2. Sampling schemes should be designed to account for the impact on water quality of both watershed land surface and inand near-channel processes. In order to help distinguish sources of suspended solids, researchers should emphasize analysis of size distribution of particles transported.
3. Best management systems for improving the broadest range of water resources in agricultural watersheds need to be based on an expanded “critical area” approach, which includes identification of critical erosive and depositional areas in both terrestrial and aquatic environments.

     

Radionuclides as indicators of sediment transport in agricultural watersheds that drain to Lake Erie

An issue in evaluating the success of agricultural management practices is the speed that eroded particles make their way through the downstream waters. In this study at Old Woman Creek (OWC) and Rock Creek (RC), two largely agricultural watersheds in Ohio, the flux of sediment and radionuclides (7Be, 210Pb, and 137Cs) in thunderstorm runoff was examined to better understand transport of eroded agricultural soils. The hydrograph in an agricultural area under no-till was similar in timing, but of lesser magnitude, than the hydrograph from a similar-sized area under conventional tillage. The activities of 210Pb and 7Be are linearly correlated and are higher in suspended sediments derived from no-till subbasins than those derived from conventionally tilled subbasins. A suspended sediment plume, identified by its unique radionuclide signature, was traced through 17 km of OWC stream channel in approximately 13.4 h (0.35 m/s). The downstream exponential decrease of 7Be activities in suspended sediments 3 to 12 h after passage of the sediment plume was used to estimate transport distances of suspended sediment from 2 to 17 km, respectively. Transport distances of suspended sediments were also calculated from wave kinematics and indicate that at OWC suspended sediment transport distances were longer in streams draining areas of no-till (19-26 km) than in the streams draining areas of conventional tillage (6-15 km). Suspended sediments travel 7 to 22 km at RC. The transport distances are long relative to the lengths of the stream channel and indicate that erosion control methods implemented in the watershed should be reflected quickly in downstream waters.     

Spatial variability of nitrous oxide emissions and their soil-related determining factors in an agricultural field

To evaluate spatial variability of nitrous oxide (N2O) emissions and to elucidate their determining factors on a field-scale basis, N2O fluxes and various soil properties were evaluated in a 100- x 100-m onion (Allium cepa L.) field. Nitrous oxide fluxes were determined by a closed chamber method from the one-hundred 10- x 10-m plots. Physical (e.g., bulk density and water content), chemical (e.g., total N and pH), and biological (e.g., microbial biomass C and N) properties were determined from surface soil samples (0-0.1 m) of each plot. Geostatistical analysis was performed to examine spatial variability of both N2O fluxes and soil properties. Multivariate analysis was also conducted to elucidate relationships between soil properties and observed fluxes. Nitrous oxide fluxes were highly variable (average 331 microg N m(-2) h(-1), CV 217%) and were log-normally distributed. Log-transformed N2O fluxes had moderate spatial dependence with a range of >75 m. High N2O fluxes were observed at sites with relatively low elevation. Multivariate analysis indicated that an organic matter factor and a pH factor of the principal component analysis were the main soil-related determining factors of log-transformed N2O fluxes. By combining multivariate analysis with geostatistics, a map of predicted N2O fluxes closely matched the spatial pattern of measured fluxes. The regression equation based on the soil properties explained 56% of the spatially structured variation of the log-transformed N2O fluxes. Site-specific management to regulate organic matter content and water status of a soil could be a promising means of reducing N2O emissions from agricultural fields.     

Comparative study of transport processes of nitrogen, phosphorus, and herbicides to streams in five agricultural basins, USA

Agricultural chemical transport to surface water and the linkage to other hydrological compartments, principally ground water, was investigated at five watersheds in semiarid to humid climatic settings. Chemical transport was affected by storm water runoff, soil drainage, irrigation, and how streams were linked to shallow ground water systems. Irrigation practices and timing of chemical use greatly affected nutrient and pesticide transport in the semiarid basins. Irrigation with imported water tended to increase ground water and chemical transport, whereas the use of locally pumped irrigation water may eliminate connections between streams and ground water, resulting in lower annual loads. Drainage pathways in humid environments are important because the loads may be transported in tile drains, or through varying combinations of ground water discharge, and overland flow. In most cases, overland flow contributed the greatest loads, but a significant portion of the annual load of nitrate and some pesticide degradates can be transported under base-flow conditions. The highest basin yields for nitrate were measured in a semiarid irrigated system that used imported water and in a stream dominated by tile drainage in a humid environment. Pesticide loads, as a percent of actual use (LAPU), showed the effects of climate and geohydrologic conditions. The LAPU values in the semiarid study basin in Washington were generally low because most of the load was transported in ground water discharge to the stream. When herbicides are applied during the rainy season in a semiarid setting, such as simazine in the California basin, LAPU values are similar to those in the Midwest basins.     

Removal of selenate in simulated agricultural drainage water by a rice straw bioreactor channel system

Removal of selenium (Se) from agricultural drainage water is important in protecting wetland wildlife. Three flow-through bioreactor channel systems (BCSs), each with three channels filled with rice (Oryza sativa L.) straw, were set in the laboratory to determine removal of selenate [Se(VI)] (1020 microg L(-1)) from drainage water with a salinity of 10.4 dS m(-1), a pH of 8.1, and a nitrate (NO3-) range of 0 to 100 mg L(-1). Results showed that the rice straw effectively reduced Se(VI) during 122 to 165 d of the experiments. Calculation of Se mass in the three BCSs showed that 89.5 to 91.9% of the input Se(VI) was reduced to red elemental Se [Se(0)], where 96.6 to 98.2% was trapped in the BCSs. Losses of each gram of rice straw were almost equal to the removal of 1.66 mg of Se from the drainage water as a form of red Se(0), indicating that rice straw is a very effective organic source for removing Se(VI) from drainage water.     

Specific conductance and ionic characteristics of farm canals in the everglades agricultural area

Specific conductance in farm canals of the Everglades Agricultural Area (EAA) in south Florida is an important water quality parameter that was categorized as a parameter of concern according to an observed frequency of >5% excursions over the Class III water quality criterion and needed to be addressed as a part of the Everglades Regulatory Program. This study was conducted to evaluate specific conductance in farm canals of the EAA. Specific conductance was monitored at 10 representative farms (a total of 12 pump stations) in the EAA using multi-parameter water quality data loggers, for periods ranging from 24 to 83 mo. Cation and anion concentrations were also determined. Nonparametric Mann-Kendall trend analyses and Sen's slope analysis of specific conductance were conducted to determine specific conductance trends. Mean specific conductance ranged from 0.74 to 1.68 dS m(-1) and only 2 of the 10 farms were above the State Class III water quality criterion of 1.275 dS m(-1). Statistically significant downward trends were observed at 3 of the 10 farms. Determination of ion compositions in grab samples at 8 of the 10 farms indicated that the major ions contributing to the increase in specific conductance in the EAA were Cl-, HCO3-, and Na+. Mean Na/Cl ratios in most of the EAA canals ranged from 0.57 to 0.78, whereas those of SO4/Cl ranged from 0.46 to 0.98. Investigation of historical data and literature indicates that elevated specific conductance in parts of the EAA is a natural phenomenon due to entrapment of connate seawater in the Everglades formation. Sulfur contributes minor increases in specific conductance in the EAA with probable sources from organic soil mineralization, ground water, Lake Okeechobee, and S fertilizers.