滇池流域城市雨水综合利用浅析

滇池流域属水资源贫乏地区,城市雨水综合利用不失为缓解缺水、减免内涝的一个好途径.城市雨水利用条件已经成熟,通过尽快制定城市雨水利用规划和一系列法律法规,建设完善的雨水收集利用系统,必将推动滇池流域城市雨水综合利用的快速有效发展.     

北京市清水与再生水协同利用优化模型

开展协同利用清水与再生水的城市供水系统优化研究具有重要的科学意义和广阔的应用前景.为促进城市水资源高效利用,基于多水源转换关系以及再生水生产能力和利用潜力,构建了面向多区域多部门的城市清水与再生水协同利用优化模型,并以水资源严重短缺的北京市为例进行实证研究.设置规划方案基准情景和规划替代方案情景,分别优化了清水与再生水的协同利用方案以及再生水厂群的运行方案.在规划方案基准情景下,再生水占研究区用水总量的32%,分别占农业、工业、环境用水量的60%、30%和42%.海淀区和石景山区再生水供给矛盾将较为突出.相比之下,规划替代方案情景可以获得更高的经济效益,总效益增加6. 21亿元,同时能增加再生水利用量36. 59%、减少清水用量14. 02%.规划替代方案能更加充分地利用现有设施,促进水资源循环利用.此外,还提供了在现有设施条件下,再生水利用量由政策规划值逐渐提升至最佳规模过程中再生水厂群的运行过渡方案.本文建立的研究方法具有较广泛的适用性,可用于解决其它具有再生水利用潜力地区的水资源短缺问题.     

滇池流域城市雨水综合利用浅析

滇池流域属水资源贫乏地区,城市雨水综合利用不失为缓解缺水、减免内涝的一个好途径。城市雨水利用条件已经成熟,通过尽快制定城市雨水利用规划和一系列法律法规,建设完善的雨水收集利用系统,必将推动滇池流域城市雨水综合利用的快速有效发展。     

天津市再生水利用现状的调查与研究

天津是一个资源性缺水城市,文章通过对天津市供排水需求与现状进行分析.论述了再生水在农田水利、工业、景观河道、民用等各方面的使用现状和发展前景,阐明了再生水在天津水资源利用领域的重要性.从技术角度分析了再生水处理的几种途径以及天津再生水利用规划、现状与存在的问题,提出天津市再生水利用的总体设想与建议.     

中新天津生态城水资源节约利用研究

水是城市发展的基础性自然资源和战略性经济资源,而水环境则是生态城建设所依托的生态基础设施之一。为了更合理地解决城市水资源的资源性短缺和利用性短缺等问题,以中新天津生态城水资源节约利用为例,在对天津中新生态城水环境现状和水环境系统进行分析的基础上,从再生水利用、雨水收集、海水淡化等方面入手,结合景观绿地及其灌溉系统、生态城各项规划导则以及梯度水价等管理措施探索性地研究了生态城节水的各项措施,为其他城市的水资源节约利用提供借鉴。     

对再生水利用的分析及思考

随着社会经济的持续发展和城市化步伐的加快,人们对水资源的需求日益增加;面对有限的水资源,再生水因水量稳定可控、环保可持续的特点而倍受关注,再生水的应用也在国内外城市广泛开展.现阶段对再生水技术层面的研究已经较为成熟,有必要从规划的角度出发,对国内外再生水回用的方向和不同阶段的再生水回用率情况进行梳理,避免不同地区再生水回用率标准的同质化,为科学合理的确定再生水回用途径和回用目标提供参考和依据,有效推动水资源可持续发展.     

新疆再生水补给地下含水层的可行性探讨——以乌鲁木齐市为例

利用再生水补给地下含水层是再生水利用的前沿领域,在干旱缺水的新疆开展再生水补给地下含水层,是缓解水资源紧缺、地下水超采、水重复利用率低及水污染严重等问题的有效途径。以乌鲁木齐市为例,通过分析城市水资源供需、再生水利用及水环境现状,考虑地下含水层空间条件及工程场地条件,对干旱区城市再生水补给地下含水层的优势和可行性进行探讨,并针对干旱区特殊的自然地理条件,提出了开展该项工作需要研究的重点问题。建议在新疆干旱区尽早开展再生水补给地下水的研究与实践工作,以促进城市再生水的安全利用,提早获得环境、经济和社会效益。     

城市雨水的综合利用

利用城市雨水是解决城市水资源短缺,减少城市洪灾的有效途径,控制城市雨水径流污染是改善城市生态环境的重要组成部分,城市雨水作为综合利用的水资源有着广泛的发展前途.     

海岛地区非常规水资源开发利用现状及保障对策研究

中国海岛众多,且多数海岛属于丘陵区,普遍存在水资源紧缺的问题.非常规水资源可以增加水资源供给,将是海岛地区解决水资源危机的重要途径.本文通过分析海岛地区海水淡化,主要介绍了海水淡化应用现状、存在的问题和不足,探讨了雨水利用的方法,包括雨水收集、存在的问题和不足,对污水回用进行了探讨,对非常水资源的开发利用现状及存在的问题,提出了海岛地区开发利用非常规水资源的保障对策,为海岛地区水资源可持续利用提供了参考.     

黄河流域主要城市再生水利用状况及潜力分析

研究系统分析了黄河流域9个省(自治区)及68个主要城市的水资源状况、供水用水状况、污水处理与再生利用状况及再生水利用潜力。2020年,黄河流域68个主要城市再生水利用总量为18.1亿m3,预计未来年利用量仍有22.0亿~25.9亿m3的增长空间。黄河流域不同城市再生水利用量和利用率存在明显差异。黄河上游11个城市的再生水利用率在25%以下;中下游20个城市的再生水利用率在30%以下,低于国家规划目标。对于黄河上游兰州、包头等城市,中下游榆林、太原、济源和泰安等城市,需进一步加快推进污水资源化利用,提高再生水利用率。今后需进一步拓展再生水利用途径,特别是提高工业利用水平,加强再生水配置利用规划、再生水利用分类统计等工作。     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.