Symptom patterns, and perceptual and cognitive styles in subjects with multiple chemical sensitivity (MCS)

Multiple chemical sensitivity (MCS) is defined as a syndrome with multiple medically unexplained symptoms attributed to low levels of chemically unrelated substances in the environment. The etiology of this syndrome is still unclear. As MCS may be conceptualized as an atypical type of somatoform disorder, the purpose of the study was to examine whether MCS subjects show symptom patterns, personality traits, and perceptual and cognitive styles as typically found in somatoform patients. Nonsensitive controls (n=36) were compared to subjects with moderate (n=35) and high (n=35) MCS intensity with self-report psychological questionnaires and structured interviews for depression and somatoform disorders. The high MCS group scored significantly higher than the other two groups on self-report scales for somatoform symptoms and depression. Moreover, high MCS was strongly associated with the diagnosis of somatoform disorder, and weaker but still significantly with depression. In a stepwise multiple regression analysis, cognitions about environmental threat, trait anxiety, focus on autonomic sensations, and general environmental sensitivity predicted MCS symptoms in the total sample, explaining 53% of the variance. These results support the hypothesis that trait negativity and mechanisms of symptom perception and symptom amplification contribute to the enhanced symptom reports of MCS individuals.     

CHEMICAL MEASUREMENT OF MEAN TEMPERATURE

Mean temperature is employed universally as an index to the energy status of the environment, and to indicate probable reaction rates of physical and biological processes in nature. A versatile chemical method of temperature integration, based on the temperature dependence of sucrose hydrolysis, has been tested in central Pennsylvania. The chemical technique (after Pallmann) permits economical mass sampling of air, water, and soil temperatures in situations where conventional methods are too expensive or otherwise unsatisfactory. Short-wave radiation effects are negligible since the sensing elements are transparent. Repeatability is excellent: in field tests duplicate sensors yield the same mean temperature ± 0.02°C. Non-linearity of sensor response has been resolved, and the data can be related directly to measurements obtained in standard climatological networks. The technique can be used to good advantage in a variety of hydrological investigations, including evaporation, consumptive-use, and them pollution studies.     

OPTIMAL PROFITS UNDER ENVIRONMENTAL CONSTRAINTS: IMPLICATIONS OF NUTRIENT AND SEDIMENT STANDARDS1

To reduce nonpoint source pollution from nutrient, chemical, and sediment runoff, a number of environmental policy standards have been proposed. Such standards could be used to reduce nonpoint source pollution from nutrient, chemical, and sediment runoff to impaired water bodies. State governments can use voluntary approaches to meet nonpoint source pollution reduction goals. However, the practices that lower net returns will not be voluntarily adopted by farmers. Crop rotations and tillage practices may help producers to comply with the environmental standards while minimizing losses in farm profits. This study compares runoff from crop rotation practices and conventional continuous row cropping systems in Mississippi. The results are compared for different tillage systems in order to examine robustness of results. Nutrient runoff and sediment runoff are simulated using the Erosion Productivity Impact Calculator (EPIC). Sensitivity analysis of the sediment and nitrate reductions at 15 percent, 25 percent, and 35 percent are conducted. Under these scenarios, net returns are optimized under environmental constraints, and the marginal cost of sediment reduction ranges from US$1.61 to US$9.63 per ton depending on soil conditions, while the corresponding nitrate and phosphorus reductions costs range from US$1.21 to US$7.08 per kg and from US$0.09 to US$31.91, respectively. The empirical results from this study indicate that a nitrate reduction policy is relatively less costly than a sediment reduction policy. The results also demonstrate the importance of geophysical conditions and policy costs, which vary across regions.     

CONFLICTING PERSPECTWES ABOUT DETECTION LIMITS AND ABOUT THE CENSORING OF ENVIRONMENTAL DATA1

ABSTRACT: Current conventions for reporting analytical results from environmental samples brings the objectives of laboratory scientists into conflict with those of environmental scientists. The objective of chemical analyses is to provide estimates of the true composition of samples. Reported results must reflect the analytical uncertainty. Current conventions require left-censoring of those results below the Limit of Detection. The objective of statistical interpretation of environmental data is to provide estimates of the characteristics of ecosystems. Such statistical analyses are often confounded by left-censoring of analytical results. We review the different points of view and propose a compromise which recognizes these conflicting perspectives.     

DISTRIBUTION OF NITRATE AND ORTHOPHOSPHATE IN SELECTED STREAMS IN CENTRAL NEBRASKA1

ABSTRACT: The Central Nebraska Basins is one of 60 study units in the National Water-Quality Assessment Program of the U.S. Geological Survey. The study unit includes the Platte River and two major tributaries, the Loup and Elkhorn Rivers. Agriculture is the predominant land use in the study unit, with only eight urbanized communities exceeding a population of 10,000. Water samples were collected from selected streams in the study unit during 1993–1995. The data were used to assess the distribution of nitrogen compounds and phosphorus in the streams and to relate the concentrations of these constituents to environmental settings. This article focuses on dissolved nitrate and orthophosphate. Dissolved nitrate concentrations were highest (90th percentiles were less than 7.0 milligrams per liter as nitrogen) in areas with extensive cropland and pasture, where chemical fertilizers are intensively applied. Synoptic measurements conducted in March and August 1994 indicate that relatively little residual fertilizer, as nitrate, applied during a single crop-growing season enters streams. Dissolved nitrate concentrations showed a seasonal pattern, being highest during winter months and lowest during the late spring and summer. Dissolved orthophosphate concentrations tended to be low across the study unit, 90 percent of all analyses did not exceed 1.7 milligrams per liter as phosphorus.     

Sensitivity and uncertainty analysis of agro-ecological modeling for saffron plant cultivation using GIS spatial decision-making methods

The main objective of this research is to model the uncertainty associated with GIS-based multi-criteria decision analysis (MCDA) for crop suitability assessment. To achieve this goal, an integrated approach using GIS-MCDA in association with Monte Carlo simulation (MCS) and global sensitivity analysis (GSA) were applied for Saffron suitability mapping in East-Azerbaijan Province in Iran. The results of this study indicated that integration of MCDA with MCS and GSA could improve modeling precision by reducing data variance. Results indicated that applying the MCS method using the local training data leads to computing the spatial correlation between criteria weights and characteristics of the study area. Results of the GSA method also allow us to obtain the priority of criteria and identify the most important criteria and the variability of outputs under uncertainty conditions for model inputs. The findings showed that, commonly used primary zoning methods, without considering the interaction effects of variables, had significant errors and uncertainty in the output of MCDA-based suitability models, which should be minimized by the advanced complementarity of sensitivity and uncertainty analysis.     

EFFECTS OF SLUDGE AND CHEMICAL FERTILIZER APPLICATION ON RUNOFF WATER QUALITY1

ABSTRACT: Simulated rainfall was used on experimental field plots to compare the effect of chemical fertilizer and sludge application on sediment, nitrogen, and phosphorus in runoff from no-till and conventional tillage systems. Chemical fertilizer application under the no-till system resulted in the least amount of total N and P in surface runoff. However, sludge application under the no-till system resulted in the least amount of NO₃-N and sediment in surface runoff. The worst water quality scenarios were observed when either sludge or chemical fertilizer were surface-applied under a conventional tillage system. Nitrogen losses from the conventional tillage system were minimized when sludge was incorporated into the soil. However, phosphorus and sediment yield from such a system were significantly higher when compared to phosphorus and sediment yield from the no-till system. The results from this study indicate that the use of sludge on agricultural land under a no-till system can be a viable alternative to chemical fertilizer for nitrogen and phosphorus control in runoff. A more cautious approach is recommended when the sludge is incorporated into the soil in a conventional tillage system because of potential for high sediment and phosphorus yield in surface runoff.     

A HYBRID COMPUTER PROGRAM FOR PREDICTING THE CHEMICAL QUALITY OF IRRIGATION RETURN FLOWS1

ABSTRACT. A hybrid computer program was developed to predict the water and salt outflow from a river basin in which irrigation is the major user of water. The model combines a chemical model which predicts the quality of water percolated through a soil profile with a general hydrologic model. The chemical model considers the reactions that occur in the soil, including the exchange of calcium, magnesium, and sodium cations on the soil complex, and the dissolution and precipitation of gypsum and lime. The chemical composition of the outflow is a function of these chemical processes within the soil, plus the blending of undiverted inflows, evaporation, transpiration, and the mixing of sub surface return flows with groundwater. The six common ions of western waters, namely calcium (Ca⁺⁺), magnesium (Mg⁺⁺), sodium (Na⁺), sulfate (SO₄⁼), chloride (Cl^?), and bicarbonate (HCO₃^?) were considered in the study. Total dissolved solids (TDS) outflow was obtained by adding the individual ions. The overall model operates on a monthly time unit. The model was tested on a portion of the Little Bear River basin in northern Utah. The model successfully simulated measured outflows of water and each of the six ions for a 24-month period. The usefulness of the model was demonstrated by a management study of the prototype system. For example, preliminary results indicated that the available water supply could be used to irrigate additional land without unduly increasing the salt outflow from the basin. With minor adjustments the model can be applied to other hydrologic areas.     

Sensitivity Analysis of Aggregated Indices for Integrated Assessment with a Case Study of the Mid-Atlantic Region

Environmental indicators are often aggregated into a single index for various purposes in environmental studies. Aggregated indices derived from the same data set can differ, usually because the aggregated indices' sensitivities are not thoroughly analyzed. Furthermore, if a sensitivity analysis is carried out, it is not presented in a transparent fashion to policy decision-makers. This paper presents a method of generating various aggregated environmental indices and analyzing their sensitivities via the use of the fuzzy set concept. Results show that several insights into the environmental conditions of the study area (e.g., the distribution of good or bad values of indicators at a watershed and or across the region) can be revealed in the sensitivity analysis of aggregated indices.     

THE INFLUENCE OF SETTINGS AND ENVIRONMENTAL EVENTS ON METAMOTIVATIONAL STATE AND AROUSAL: FURTHER TESTS OF REVERSAL THEORY ON ASIAN SAMPLES

The two studies reported further test reversal theory hypotheses concerning human psychological responses to different types of settings and environmental events on an Asian sample. In study 1, individuals in four settings representing different combinations of metamotivational state and arousal level (telic and paratelic/low arousal; telic and paratelic/high arousal) completed the telic state measure (TSM; Svebak & Murgatroyd, 1985). Significant differences between participants' mean scores across the four settings were obtained for TSM items serious–playful, planning–spontaneous, felt arousal, preferred arousal, effort and arousal discrepancy. In study 2 different environmental events in the same setting (changes in reading tasks), used in a crossover design, were used to induce reversals in individuals' operative metamotivational states. The results obtained from TSM scores pretask 1, between tasks and posttask 2. indicated significant time-of-testing interaction effects on the TSM serious–playful, planning–spontaneous and effort items. In addition, a main effect for TSM felt arousal was found. These results showed that reversals in metamotivational states were induced by the environmental event and that felt arousal scores increased across the three administrations of the TSM.     

IMPACT OF COAL SURFACE MINING AND RECLAMATION ON SURFACE WATER CHEMICAL CONCENTRATIONS AND LOAD RATES IN THREE OHIO WATERSHEDS1

ABSTRACT: Information is lacking on the watershed scale effects of mining and reclaiming originally undisturbed watersheds for coal on surface water chemical concentrations and load rates for a variety of constituents. These effects were evaluated on three small, geologically dissimilar watersheds subjected to surface mining in Ohio. Comparisons were made between phases of land disturbances using ratios of average concentrations and load rates: Phase 1 (natural), subphases of Phase 2 (mining and reclamation), and subphases of Phase 3 (partial reclamation and final condition) using 4,485 laboratory analyses of 34 constituents. Average concentration and load rate ratios were categorized into three classes—minor, moderate, and substantial. Mining and reclamation (M/R) affected flow duration curves in different ways‐baseflow changes were variable, but high flows generally increased. The average concentration ratios for all sites were classified as 15 percent “minor,” 36 percent “moderate,” and 49 percent “substantial” (average ratio of 2.4.) Generally load rate ratios increased due to mining and reclamation activities (average ratio of 3.3). Minor, moderate, and substantial impacts were found on average for 7 percent, 23 percent, and 70 percent, respectively, of load rate ratios. The impact of M/R on average load rates was not necessarily the same as on average concentrations due to changed hydrology and can be opposite in effect. The evaluation of the impacts of M/R requires knowledge of changing hydrologic conditions and changing supplies and rates of release of chemicals into streams. Median sediment concentration ratio is an indicator of average constituent load rate ratio of a wide variety of chemical constituents and is useful for development of best management practices to reduce chemical loads. The site at which diversion ditches were not removed during final reclamation sustained large chemical load rates, and removal of diversions at the other mined site reduced load rates. Revegetation of poorly reclaimed areas decreased chemical load rates. Chemical load rates were sensitive to geology, mining, and reclamation methods, diversions, and changing hydrology, concentration flow rate regressions, and watershed areas.     

RESPONSE OF PHYSICAL AND CHEMICAL PARAMETERS TO ELIMINATING THERMAL STRATIFICATION IN A RESERVOIR1

ABSTRACT The effects of maintaining a 19 ha Colorado montane reservoir in a thermally destratified condition for one year were evaluated. Water temperatures were kept nearly vertically agd horizontally isothermal throughout the year. The weighted mean temperature of the lake was 1-4°C colder in winter and 1-2°C warmer in summer than normal. Deep water in summer was up to 6°C warmer than typical hypolimnion temperatures, but summer surface temperature was unaltered. Without destratification dissolved oxygen depletion develops in summer and winter, but by eliminating stratification, oxygen was kept near saturation throughout the year. Alkalinity, pH, conductivity, and total residue were not significantly affected. Seston decreased which was probably due to declines in planktonic diatom populations. Increases in iron and manganese did not occur in deep water during destratification. Calcium concentrations increased slightly. Magnesium and most anions (chloride, nitrate-N, and silica) were not greatly altered, but sulfate concentration was reduced. Artificial destratification, as a reservoir management tool, will be very useful in altering chemical problems; particularly increasing oxygen and decreasing iron and manganese concentrations.     

REGIONAL SCALE TREND MONITORING OF INDICATORS OF TROPHIC CONDITION OF LAKES1

ABSTRACT: The U.S. Environmental Protection Agency has proposed a sample survey design to answer questions about the ecological condition and trends in condition of U.S. ecological resources. To meet the objectives, the design relies on a probability sample of the resource population of interest (e.g., a random sample of lakes) each year on which measurements are made during an index period. Natural spatial and temporal variability and variability in the sampling process all affect the ability to describe the status of a population and the sensitivity for trend detection. We describe the important components of variance and estimate their magnitude for indicators of trophic condition of lakes to illustrate the process. We also describe models for trend detection and use them to demonstrate the sensitivity of the proposed design to detect trends. If the variance structure that develops during the probability surveys is like that synthesized from available databases and the literature, then the trends in common indicators of trophic condition of the specified magnitude should be detectable within about a decade for Secchi disk transparency (0.5–1 percentiyear) and total phosphorus (2–3 percent/year), but not for chlorophyll-a (> 3–4 percent/year), which will take longer.     

Environmental justice in Nigeria: A narration of residents’ experience in Ile-Ife

The sharing of environmental cost by residents in various residential areas in the developing world is perceived to be unfair. This study therefore assessed residents’ experiences of environmental justice in Ile-Ife, Nigeria. Three residential areas were identified in the study area and samples were selected using systematic sampling. Using availability and condition of urban infrastructure, severity of environmental problems and residents’ involvement in environmental issues, the study examined environmental justice in the study area. The study established a variation in environmental issues across identified residential areas. The severity of environmental problem measured through an index tagged Severity of Environmental Problem (SEPI) revealed that environmental problems was most severe in the core (SEPI = 4.00), followed by the peripheral area (SEPI = 3.71) and least in the transition area (SEPI = 3.56). On the condition of available environmental infrastructure, the study revealed that the conditions of infrastructure were most improved in the peripheral area (ICI = 3.07), followed by the core (ICI = 2.67) and the least in the transition area (ICI = 2.42). The study concluded that residents’ experiences of environmental justice differ significantly across the different residential zones as reflected by residents’ socio-economic characteristics. Furthermore, it established that age, gender, educational status, and number of years spent in the area can be used to explain the differences in residents’ experience of environmental justice in the study area. To enhance the liveability, the study recommends adequate provision of environmental amenities needed by each category of people in the city.     

CHEMICAL ANALYSIS OF CO2 REMOVAL IN TRAY AERATORS1

ABSTRACT: This paper presents a discussion of the chemistry of CO₂ removal in tray aerators, and different sets of equations that are applicable to several initial water chemical conditions are proposed. These chemical equations and a statistical model to predict the kinetic constant were tested with field data observed by other researchers in pilot units and in a full scale plant. The water temperature in their experiments was around 15°C.     

Prioritizing ecological and human welfare risks from environmental stresses

The ecological systems of Earth are subjected to a wide array of environmental stresses resulting from human activities. The development of appropriate environmental protection and management policies and the appropriate allocation of resources across environmental stresses require a systematic evaluation of relative risks. The data and methodologies for comprehensive ecological risk assessment do not exist, yet we do have considerable understanding of econological stress-response relationships. A methodology is presented to utilize present knowledge for assignment of relative risks to ecological systems and human welfare from anthropogenic stresses. The resultant priorities, developed for the US Environmental Protection Agency's (EPA) relative risk reduction project, highlight global climate change, habitat alteration, stratospheric ozone depletion, and species depletion as the highest environmental risks, significantly diverging from the present emphasis by EPA and the public on toxic chemical issues. Enhanced attention to ecological issues by EPA and development of ecological risk assessment methodologies that value ecological and economic issues equitably are key recommendations.     

Phytoestrogens and mycotoxins in Iowa streams: an examination of underinvestigated compounds in agricultural basins

This study provides the first broad-scale investigation on the spatial and temporal occurrence of phytoestrogens and mycotoxins in streams in the United States. Fifteen stream sites across Iowa were sampled five times throughout the 2008 growing season to capture a range of climatic and crop-growth conditions. Basin size upstream from sampling sites ranged from 7 km2 to > 836,000 km2. Atrazine (herbicide) also was measured in all samples as a frame-of-reference agriculturally derived contaminant. Target compounds were frequently detected in stream samples: atrazine (100%), formononetin (80%), equol (45%), deoxynivalenol (43%), daidzein (32%), biochanin A (23%), zearalenone (13%), and genistein (11%). The nearly ubiquitous detection of formononetin (isoflavone) suggests a widespread agricultural source, as one would expect with the intense row crop and livestock production present across Iowa. Conversely, the less spatially widespread detections of deoxynivalenol (mycotoxin) suggest a more variable source due to the required combination of proper host and proper temperature and moisture conditions necessary to promote Fusarium spp. infections. Although atrazine concentrations commonly exceeded 100 ng L(-1) (42/75 measurements), only deoxynivalenol (6/56 measurements) had concentrations that occasionally exceeded this level. Temporal patterns in concentrations varied substantially between atrazine, formononetin, and deoxynivalenol, as one would expect for contaminants with different source inputs and processes of formation and degradation. The greatest phytoestrogen and mycotoxin concentrations were observed during spring snowmelt conditions. Phytoestrogens and mycotoxins were detected at all sampling sites regardless of basin size. The ecotoxicological effects from long-term, low-level exposures to phytoestrogens and mycotoxins or complex chemicals mixtures including these compounds that commonly rake place in surface water are poorly understood and have yet to be systematically investigated in environmental studies.     

搅拌棒吸附萃取技术在环境样品分析中的应用

搅拌棒吸附萃取(SBSE)是继固相微萃取(SPME)之后的又一种无溶剂的用于痕量有机物分离和浓缩的技术,其萃取涂层体积大,具有灵敏度高、检出限低、重现性好、不使用有机溶剂等优点。适用于环境样品中挥发性及半挥发性有机物的痕量分析。本文综述了SBSE在环境样品分析中的应用,以及该技术的应用展望。     

The Relationship Between Environmental Concern and Acceptability of Environmental Impacts among Visitors to Two U.S. National Park Settings

This study examined the relationship between environmental concern and ratings of acceptability of environmental impacts among visitors at two national park settings. Based on the concept of a social ecological paradigm shift, it was hypothesized that individuals with greater levels of environmental concern are less accepting of environmental impacts in national parks than individuals with lesser degrees of concern. Sample data came from Cape Lookout National Seashore (N=392) and Moores Creek National Battlefield (N=236), two national park units in the south-eastern U.S.A. Environmental concern was measured by the New Ecological Paradigm scale. Acceptability was measured by visitor responses to 25 items covering different types of environmental park impacts. Analysis of variance and Tukey's means comparison procedure were used to test for differences between groups defined by levels of environmental concern on impact acceptability. Significant relationships were found between environmental concern and 15 of the 25 specific impacts in the Cape Lookout sample and 13 significant relationships were found in the Moores Creek sample. However, the relationships between environmental concern and acceptability varied somewhat across the two samples. These findings suggested that individuals with greater environmental concern were less accepting (or tolerant) of certain types of park impacts, while individuals with lesser degrees of environmental concern were more accepting of certain park impacts. Differences across the study settings were attributed to the different orientations of park visitors between the two national park units and recency effects. While the data reported are preliminary, they should be informative for park management purposes, particularly in the determination of standards for park impacts.     

Achieving environmental excellence through TQEM strategic alliances

Generally speaking, today's TQEM initiatives do not improve a firm's activities beyond the shipping dock and onto consumer and postconsumer use and reuse. Although internal TQEM efforts do improve environmental impacts of a firm's operations, most firms remain focused on the traditional bottom-line objective of increasing throughput. For these reasons, most firms implementing TQEM miss the many opportunities to improve environmental performance (including cost and quality) through asset recovery, resource sharing, and reuse. However, by taking the advantages of teamwork beyond corporate boundaries, firms can close the loop on environmental improvements. Inter-firm teaming for environmental advantage, which we define as TQEM alliancing, initiates a cyclical approach to environmental performance improvement. It does so by forging strategic relationships among firms that can leverage each other's environmental weaknesses. TQEM allying is a round-robin game plan. In this article, the authors show how it allows firms to take their environmental improvement initiatives beyond regulatory compliance (and into proactivity), beyond pollution control (to total pollution avoidance), and beyond profitability (for a quantitative as well as qualitative bottom line), because firms will be integrating external as well as internal functions across different business domains.