The Water Quality of some Tropical Freshwater Bodies in Uyo (Nigeria) Receiving Municipal Effluents, Slaughter-House Washings and Agricultural Land Drainage

The water quality of some tropical fresh-water bodies in Uyo (Nigeria) was investigated for two years in relation to point and non-point source city effluents and slaughter-house washings discharged into them. Streams which received city effluents and slaughter-house washings were degraded in quality with acidic water (pH =5.26±0.83 to 6.20±0.56), low oxygenation (2.46±1.30 to 3.88±0.29 mgl^–1), high biochemical oxygen demand (4.96±0.66 to 8.20±0.82 mgl^–1) and chemical oxygen demand (88.60±3.50 to 146.36±9.86 mgl^–1) than non-effluent receiving streams. High acidity in streams is due mainly to the acidic nature of underground water which replenishes the streams. Nutrient levels were high indicating enrichment from highly fertilized farmlands and slaughter-house washings. The concentrations of most of the hydrochemical variables were significantly lower in non-effluent than effluent-receiving streams. Some of the hydrochemical variables (total alkalinity, dissolved oxygen, nitrate, phosphate and conductivity) exhibited pronounced seasonality regimes with significant correlations with rainfall indicating its influence on the chemical hydrology of the water bodies. Land use in the catchment influenced water quality through inflow of nutrients, organic and inorganic contaminants and siltation. Pollution in the impacted streams is attributed mainly to episodic events.     

Impact of Vegetative Cover on Runoff and Soil Erosion at Hillslope Scale in Lanjaron, Spain

Soil loss and surface runoff patterns over a four-year period (1997–2000) were studied in erosion plots from three hillslopes under different vegetative covers (Rosmarinus officinalis, Triticum aestivum and natural-spontaneous vegetation) in Lanjaron (Alpujarras) on the south flank of the Sierra Nevada of southeast Spain. The erosion plots were located on the hillslopes at 35.5% incline, at 1,480 m in altitude and with 41.8 m² (21 m×1.9 m) in area. The vegetative covers were tested for effectiveness in controlling the surface runoff and soil loss production. The highest runoff and erosion values, ranging from 114.1 to 1.7 mmyr^–1 and from 14,564.3 to 6.6 kgha^–1yr^–1, respectively, over the entire study period, were measured under the Triticum aestivum. In the Rosmarinus officinalis, runoff ranged from 7.9 to 1.3 mmyr^–1 and erosion from 156.4 to 2.3 kgha^–1yr^–1, while on the hillslope under natural-spontaneous vegetation, runoff ranged from 4.4 to 0.9 mmyr^–1 and erosion from 322.3 to 2.2 kgha^–1yr^–1. According to the results the vegetative covers of Rosmarinus officinalis and natural-spontaneous vegetation reduced the soil losses by 99 and 98%, with respect to the Triticum aestivum, and the runoff losses by 94 and 96%, respectively. Also, the Rosmarinus officinalis and natural-spontaneous plants influenced infiltration by intercepting much of the rainfall water respect to the Triticum aestivum. Monitoring allowed more direct linkages to be made between management practices and their impacts on runoff and soil erosion, thereby enabling to identify problems and take appropriate preventive measures to improve the management practices.     

Monitoring air pollution in Kano municipality by chemical analysis of Scots Pine (Pinus sylvestris L.) needles for sulphur content

The distribution of environmental pollutant, sulphur, over Kano municipality was monitored on the basis of the chemical analysis of Scots Pine (Pinus sylvestris L.) needles collected from randomly selected sampling points over the period 1995–1996. Of the five zones in which the municipal area was subdivided, two could be regarded as least polluted, two as moderately polluted and one zone as heavily polluted. The mean value of all measurements in the metropolis amounted to 1940 gg^–1 S with a co-efficient of variation of 38 percent.     

Basis of energy crop selection for biofuel production: Cellulose vs. lignin

This paper investigates the suitability of Jerusalem artichoke (Helianthus tuberosus L.), fiber hemp (Cannabis sativa L.), energy sunflower (Helianthus annuus L.), Amur silver-grass (Miscanthus sacchariflorus), and energy grass cultivar (cv) Szarvasi-1 for biofuel production in Northern climatic conditions. Above ground biomass, bioethanol production yield, and methane production yield are used as indicators to assess the bio-energy potential of the culture. Results presented show that energy crops of Southern origin produce 30–70% less biomass than in the origin region. Nonetheless, both perennial and annual energy crops produce high above ground biomass yields (660–1280 g m^–2) for Northern climatic conditions. Experimental results show that bioethanol yield is dependent on cellulose content of the biomass. The higher the cellulose content, the higher the bioethanol yield. The biogas production on the other hand, depends on lignin content. The lower the lignin content the higher the biogas yield. Therefore, the selection of the energy crop for bioethanol production should be based on high cellulose content, while for biogas production it should rather be based on the low lignin content.     

Toxicity and uptake of mercurials in a cyanobacterium

Nostoc calcicola cells exposed to mercuric chloride (0.05–0.25 M), methyl mercuric chloride (0.05–0.15 M) and the fungicide ceresan (phenyl mercuric acetate; 0.05–0.20 M) showed sensitivity in the sequence: methyl mercury3) over phenyl mercuric acetate (0.51×10³); inorganic mercury occupied the intermediate position with a bioconcentration factor of 1.32×10³. The data infer that larger molecules of organomercurials may not be taken up by cells at the rate and extent comparable to the smaller species.     

Arsenic levels in the marine ecosystem off the Kuwait coast, Arabian Gulf

Arsenic levels in seawater, microplankton (diatoms and dinoflagellates), shrimp (Penaeus semisulcatus), mollusc (Cerithium scabridum) and five types of fish (Maid, Nakroor, Nuwaiby, Suboor and Sheim) in five sampling stations (I–V) off the Kuwait coast were determined during the years 1995 to 1999. The maximum mean concentration of arsenic was observed in the order; the five fish (0.50–0.78 g g^–1)> mollusc (0.26 g g^–1)> shrimp (0.23 g g^–1)> particulate matter (0.03 g g^–1)> water and phytoplankton (0.02 g g^–1) from all the sites of the Kuwait coast. Station II possessed the maximum arsenic levels. In comparison with the arsenic levels in other parts of the globe, low arsenic levels were observed in most of the marine organisms off the Kuwait Coast. However, an increasing trend in arsenic concentrations was anticipated due to rapid local industrialization and on account of recent spills of arsenic compounds.     

Determination of urinary lead in school children in Manzini, Swaziland, Southern Africa

Two hundred and fifty-seven urine samples collected from school children living in the Manzini region, Swaziland, were analysed for lead (Pb), using a graphite furnace atomic absorption spectrometer. The mean urine lead concentration for the urban schools ranged from 0.038–0.040 gml^–1, while that for the rural schools ranged from 0.017–0.022 gml^–1. The observed range shown by the urban schools was above the normal (for healthy humans) urine lead concentration of 0.035 gml^–1. However, the mean urine lead concentration for the rural schools was found to be lower than this value. The mean urine lead concentration for the urban schools was significantly higher than that of the rural schools. The differences in the mean urine lead concentrations for boys and girls from both urban and rural schools were found not to be significant, despite the higher values shown by the girls. The difference in lead concentrations between urban and rural schools in Manzini was thought to be due to the traffic density within the urban area.     

A Baseline Study on Water Resources of the Tourist Island, Pulau Perhentian, Peninsular Malaysia, from an Ecological Perspective

Ambient water quality and bacterial populations in the water resources of Pulau Perhentian, a Marine Park of Malaysia, were studied during a peak tourist arrival, off-monsoon period. The overall water and bacteriological quality of swimming/boating sites in the island is at an acceptable condition, although the conductivity (0.88–60 mS m^–1) due to high dissolved solid concentrations is slightly high, when compared with the recommended standard and published guidelines for the protection/maintenance of recreation water and its aesthetic enjoyment (Universiti Malaya, Department of Environment, Malaysia, 1986). However, the bacteriological quality of the drinking/bathing water wells is poor, with faecal coliform counts (2 up to 1,600 MPN per 100 ml sample water) exceeding the permissible levels defined for raw water supplies (with or without treatment). This suggests that the groundwater, seepage and run-off into the wells is contaminated. Contrary to the belief of the water users being interviewed in a social survey, the untreated drinking/bathing water is not bacteria-free. The excessive counts are attributable to deoxygenated conditions (12–42 percent corresponding to 0.9–3.3 mg l^–1) prevailing in the wells, high total suspended solids (up to 202 mg l^–1) which promote bacterial growth, lack of adequate sewerage systems to receive effluents from lavatories of dwellings, chalets and resorts, as well as the lack of centralised water treatment plants and storage tanks to cope with water scarcity and waterway contamination.     

A mechanical pre-treatment process for the valorization of useful fractions from spent batteries

In this paper the authors propose a full-scale plant aimed to pre-treat spent batteries in order to obtain cleaned useful fractions (magnetic and non-magnetic metals, paper, plastic, a fine-sized material made of a metal-carbon mixture). The treating process was designed after having analyzed and tested a representative sample coming from the whole amount of spent batteries collected in 1 month by the public service in and around Turin. The analyses performed on the sample allowed the authors to determine its in-percentage composition in term of type of batteries: 60-70% b.w. (by weight) alkaline, 25-30% b.w. Zn-C and 5-10% b.w. other types. For each type, the composition in term of size (AAA or LR03; AA or LR6; C or LR14; D or LR20; 9 V or 6F22A; 4.5 V or 3R12A) has also been determined.The treatment for the recovery of secondary raw materials foresees the following phases:

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separation of useful types/sizes of exhaust batteries to undergo further treatments by means of a first sieving process;

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liberation of the single components taking advantage of a crushing operation;

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separation of a fine-sized material (to subject to pyro or hydro metallurgic recovery) from a coarse-sized material (to send to secondary smelt foundries and incinerators) by means of a second sieving phase.

On the basis of the results obtained from the crushing/sieving laboratory tests and the chemical characterization, a full-scale plant able to treat about 76,000 t/y of spent batteries has been designed. The cost analysis performed on the proposed treatment plant has given back a unit pre-treatment cost equal to 3€ per ton of processed spent batteries.     

Non-Point-Source Impacts on Stream Nutrient Concentrations Along a Forest to Urban Gradient

We conducted statistical analyses of a 10-year record of stream nutrient and sediment concentrations for 17 streams in the greater Seattle region to determine the impact of urban non-point-source pollutants on stream water quality. These catchments are dominated by either urban (22–87%) or forest (6–73%) land cover, with no major nutrient point sources. Stream water phosphorus concentrations were moderately strongly (r²=0.58) correlated with catchment land-cover type, whereas nitrogen concentrations were weakly (r²=0.19) and nonsignificantly (at < 0.05) correlated with land cover. The most urban streams had, on average, 95% higher total phosphorus (TP) and 122% higher soluble reactive phosphorus (SRP) and 71% higher turbidity than the most forested streams. Nitrate (NO₃), ammonium (NH₄), and total suspended solids (TSS) concentrations did not vary significantly with land cover. These results suggest that urbanization markedly increased stream phosphorus concentrations and modestly increased nitrogen concentrations. However, nutrient concentrations in Seattle region urban streams are significantly less than those previously reported for agricultural area streams.     

Study on the hydrolysis/precipitation behavior of Keggin Al13 and Al30 polymers in polyaluminum solutions

The hydrolysis/precipitation behaviors of Al³⁺, Al₁₃ and Al₃₀ under conditions typical for flocculation in water treatment were investigated by studying the particulates' size development, charge characteristics, chemical species and speciation transformation of coagulant hydrolysis precipitates. The optimal pH conditions for hydrolysis precipitates formation for AlCl₃, PAC_Al13 and PAC_Al30 were 6.5–7.5, 8.5–9.5, and 7.5–9.5, respectively. The precipitates' formation rate increased with the increase in dosage, and the relative rates were AlCl₃ ? PAC_Al30 > PAC_Al13. The precipitates' size increased when the dosage increased from 50 μM to 200 μM, but it decreased when the dosage increased to 800 μM. The Zeta potential of coagulant hydrolysis precipitates decreased with the increase in pH for the three coagulants. The iso-electric points of the freshly formed precipitates for AlCl₃, PAC_Al13 and PAC_Al30 were 7.3, 9.6 and 9.2, respectively. The Zeta potentials of AlCl₃ hydrolysis precipitates were lower than those of PAC_Al13 and PAC_Al30 when pH > 5.0. The Zeta potential of PAC_Al30 hydrolysis precipitates was higher than that of PAC_Al13 at the acidic side, but lower at the alkaline side. The dosage had no obvious effect on the Zeta potential of hydrolysis precipitates under fixed pH conditions. The increase in Zeta potential with the increase in dosage under uncontrolled pH conditions was due to the pH depression caused by coagulant addition. Al–Ferron research indicated that the hydrolysis precipitates of AlCl₃ were composed of amorphous Al(OH)₃ precipitates, but those of PAC_Al13 and PAC_Al30 were composed of aggregates of Al₁₃ and Al₃₀, respectively. Al³⁺ was the most un-stable species in coagulants, and its hydrolysis was remarkably influenced by solution pH. Al₁₃ and Al₃₀ species were very stable, and solution pH and aging had little effect on the chemical species of their hydrolysis products. The research method involving coagulant hydrolysis precipitates based on Al–Ferron reaction kinetics was studied in detail. The Al species classification based on complex reaction kinetic of hydrolysis precipitates and Ferron reagent was different from that measured in a conventional coagulant assay using the Al–Ferron method. The chemical composition of Al_a, Al_b and Al_c depended on coagulant and solution pH. The Al_b measured in the current case was different from Keggin Al₁₃, and the high Al_b content in the AlCl₃ hydrolysis precipitates could not used as testimony that most of the Al³⁺ was converted to highly charged Al₁₃ species during AlCl₃ coagulation.