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脱硫剂微观结构对脱硫性能的影响 总被引:6,自引:2,他引:4
采用扫描电镜和压汞仪对3种贝壳和1种石灰石的微观结构及孔径分布进行了测量,采用热重分析方法对各种脱硫剂的脱硫性能进行了测试.比较发现,各种贝壳煅烧后的晶粒呈薄片状,晶粒之间孔径均大于0.2μm,比孔容较大;石灰石煅烧后晶粒呈颗粒状,晶粒之间孔径多数在0.01~0.16μm之间,比表面积很大,但比孔容较小.贝壳中直径大于0.2μm的气孔,允许气体扩散至颗粒内部,气孔表面同时参加脱硫反应,且反应过程中不易被反应产物所堵塞,脱硫反应进行较彻底,钙利用率较高.另外,在满足气体扩散的前提下,减小孔径尺寸,增加反应比表面积,将对脱硫反应有利. 相似文献
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研究了AI-Si(质量分数为24.3%和AI-Si(质量分数为29.2%)合金在机械搅拌作用下初晶硅形貌变化的工艺参数,半固态料坯的制备方法和半固态挤压成形的工艺方法。实验结果表明605℃是该成分范围的过共晶铝硅合金合适的半固态搅拌温度,在该温度下恒温搅拌50min可有效地改变板条状初晶硅的形态,获得平均直径为200μm的球状化的初晶硅;在上述优化的半固态工艺条件下采用挤压铸造工艺获得了优质的近终成形圆盘形零件。 相似文献
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利用高温变形实验 ,研究了 14 2 0铝锂合金在不同变形条件下的变形行为 ,获得合金的塑性图、变形抗力图、晶粒尺寸 变形程度关系图 ,确定出合金的锻造工艺参数 :锻造温度为 35 0~4 2 0℃ ,临界变形程度为 8%~ 10 % ,变形速率以低速为宜。结合实际情况 ,制定出合理的、经济的14 2 0铝锂合金模锻件成形工艺 ,即 6 0 0 0t水压机上多方锻开坯→车成锥体→ 80 0 0t卧式挤压机上终压模成形。生产出的 14 2 0合金模锻件尺寸精度高 ,综合性能优良。 相似文献
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目的 探究服役Super304H钢管外壁粗晶组织演变及其对高温力学性能的影响,为超超临界机组运行管理与安全评估提供技术支持。方法 针对不同服役时间的Super304H耐热钢管,开展显微组织演变及650 ℃高温拉伸力学性能研究,着重探讨钢管外壁奥氏体晶粒异常长大、第二相析出长大及其对钢管高温力学性能的影响规律。结果 服役态Super304H钢管中的第二相以富铜相、MX相及M23C6相为主,其外壁奥氏体晶粒异常长大,形成粗晶区,而靠近内壁钢管中的奥氏体晶粒长大不明显,为细晶区。相对于细晶区,粗晶区奥氏体晶界及晶内析出更多的第二相,尺寸更大,弥散度降低,导致粗晶区高温拉伸性能显著降低。结论 长期高温运行的Super304H耐热钢管应加强监督,消除因外壁奥氏体晶粒异常长大而带来的胀管等安全隐患。 相似文献
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森林与径流关系——一致性和复杂性 总被引:17,自引:1,他引:16
@论文综述国外近一个世纪以来在配对集水区研究方面所取得的结论,从水的自然属性出发,从森林变化对径流(年径流量、洪峰与枯水径流)的影响,径流响应的干扰临界值及水文恢复各方面探讨森林变化与径流关系的一致性与复杂性。森林变化与径流关系的一致性主要表现在由较长时间尺度表达的年径流量上。绝大多数的配对集水区的试验研究表明,采伐森林就会增加年径流量,而在荒地上造林就会减少年径流量。而由较短时间尺度表达的洪峰径流与枯水流量则呈现较大的复杂性和难预估性。综述表明,对径流特别是洪峰与枯水径流的定义及分析方法的不同也是造成森林与径流关系复杂性的重要原因。森林与径流关系的复杂性要求人们在研究及应用其关系时就必须有系统观,必须考虑植被、径流与其它过程(土壤变化、气候变化等)的相互作用。论文还认为尽管配对集水区试验作为一种研究方法为研究者提供了许多可靠的结论,但由于许多研究者只把集水区看作是“黑箱”Q从而对认识森林与径流关系的复杂性有一定的局限性。未来的研究应把配对集水区的试验与其它对过程的研究技术(同位素、GIS等技术)结合起来。 相似文献
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真菌和细菌对染料的吸附脱色及再生能力的研究 总被引:9,自引:0,他引:9
进行了真菌和细菌共培养对染料的吸附脱色和吸附脱色能力再生的研究。结果表明,青霉菌G-1首先对偶氮染料S-119、蒽醌染料艳紫KN-B(C.I.Reactive violet 22)水溶液中染料进行快速吸附去除,菌丝对同种染料的吸附速度随菌丝培养液中葡萄糖浓度的增加而加快,吸附染料的G-1菌丝在与细菌的共培养中完成对染料的脱色降解,脱色速度受培养液中葡萄和氮源浓度影响较大,从吸附速率和完全脱色时间综合评价,以葡萄糖浓度为5g/L、酒石酸铵为20mmol/L的培养基中培养的菌丝对染料的吸附脱色效果最好,吸附在菌丝上的艳紫KN-B脱色后菌丝吸附脱色能力得到再生,菌丝对100mg/L的艳紫KN-B染料水溶液可重复处理4次。青霉菌G-1对酸性染料废水处理3h,色度去除率为75.9%,吸附染料的菌丝在与细菌共培养中完成对染料的脱色,对试验所用染料废水,菌丝的处理能力获得1次再生。 相似文献
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Fuellen G 《Die Naturwissenschaften》2008,95(6):469-481
The analysis of the ever-increasing amount of biological and biomedical data can be pushed forward by comparing the data within and among species. For example, an integrative analysis of data from the genome sequencing projects for various species traces the evolution of the genomes and identifies conserved and innovative parts. Here, I review the foundations and advantages of this "historical" approach and evaluate recent attempts at automating such analyses. Biological data is comparable if a common origin exists (homology), as is the case for members of a gene family originating via duplication of an ancestral gene. If the family has relatives in other species, we can assume that the ancestral gene was present in the ancestral species from which all the other species evolved. In particular, describing the relationships among the duplicated biological sequences found in the various species is often possible by a phylogeny, which is more informative than homology statements. Detecting and elaborating on common origins may answer how certain biological sequences developed, and predict what sequences are in a particular species and what their function is. Such knowledge transfer from sequences in one species to the homologous sequences of the other is based on the principle of 'my closest relative looks and behaves like I do', often referred to as 'guilt by association'. To enable knowledge transfer on a large scale, several automated 'phylogenomics pipelines' have been developed in recent years, and seven of these will be described and compared. Overall, the examples in this review demonstrate that homology and phylogeny analyses, done on a large (and automated) scale, can give insights into function in biology and biomedicine. 相似文献
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以泉水来源的伊宁市城市水系,具有特有城市标志的同时对伊宁市起着重要的生态、景观、润泽作用。近年来,城市建设的快速发展给伊宁市水系带来了新的问题。文章以如何保护好伊宁市城市水系为出发点,以现场调查及相关数据为基础,对现状问题进行分析,提出了城市水系保护方面的一些建议对策。 相似文献
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韩文峰 《安全.健康和环境》2011,11(3):40-43
以某联合站为例,根据油气集输联合站站场功能,将联合站划分为油气处理、储运及污水处理3个单元,对各单元发生火灾爆炸事故的可能条件进行分析,并利用DNV公司的SAFETI软件对事故后果进行模拟计算,根据事故影响范围数据,提出相应的安全措施。 相似文献
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Pesticides and trace elements in cannabis: Analytical and environmental challenges and opportunities
Caley B. Craven Nicholas Wawryk Ping Jiang Zhongshan Liu Xing-Fang Li 《环境科学学报(英文版)》2019,31(11):82-93
Cannabis is increasingly used for both medicinal and recreational purposes with an estimate of over 180 million users annually. Canada has recently legalized cannabis use in October 2018, joining several states in the United States of America (e.g., Colorado, California, and Oregon) and a few other countries. A variety of cannabis products including dry flowers, edibles, and oil products are widely consumed. With high demand for cannabis products worldwide, the quality of cannabis and its related products has become a major concern for consumer safety. Various guidelines have been set by different countries to ensure the quality, safety, and efficacy of cannabis products. In general, these guidelines require control of contaminants including pesticides, toxic elements, mycotoxins, and pathogens, as well as residual solvents in regard to cannabis oil. Accordingly, appropriate analytical methods are required to determine these contaminants in cannabis products for quality control. In this review, we focus on the current analytical challenges and method development for detection of pesticides and toxic elements in cannabis to meet various guidelines. 相似文献
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A total of 2931 women randomized to either transabdominal CVS, transceirvical CVS, or amniocentesis were studied. Unless intended or unintended abortion had occurred, they had completed up to 28 weeks of pregnancy. No significant difference was seen between total fetal loss in the transabdominal CVS group and the amniocentesis group (6.5 and 6.8 per cent, respectively, SE difference = 0.92 per cent, p = 0.01). The total fetal loss in the transcervical CVS group was 10.1 per cent. After pooling our data with data from the Canadian randomized study and the American non-randomized study, the difference in risk between trans-cervical CVS and amniocentesis was 1.8 per cent (SE difference = 0.64 per cent, p = 0.8). When the number of failed procedures and those cases evaluated as infeasible for the assigned method-for anatomical reasons-are compared, the overall sampling efficacy is poorer transcervically than transabdominally. 相似文献