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为了实现乙烯废碱液的“零排放”,基于某石化厂乙烯废碱液湿式空气氧化出水具有的高硫酸根、高碳酸根、高有机污染物的特点及“零排放”的处理要求,开展了乙烯废碱液的“零排放”工艺路线比选,确定了以冷冻结晶工艺为核心的技术路线,并通过水质分析、溶解度和超溶解度曲线的测定确定了冷冻结晶的主要工艺参数,实现了乙烯废碱液的“零排放”与资源化利用。经预测,采用该工艺后可以使硫酸钠回收率达到93.3%,产品TOC含量不高于30 mg/kg。 相似文献
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介绍了河津发电厂目前的用水、排水情况及工业废水零排放实施方案,对方案实施后的效果进行了预测,同时对废水零排放实施后运行中可能出现的问题进行了分析并提出了建议。 相似文献
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火力发电厂全厂废水零排放 总被引:11,自引:3,他引:11
讨论了火电厂废水类型、排放标准及治理与回用原则,研究了全厂废水零排放的准确含义、约束条件、影响因素、主要内容以及国内外应用示例,为实施火电厂全厂废水零排放提供参考。 相似文献
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神头第二发电厂废水零排放工程实施可行性研究 总被引:7,自引:3,他引:4
针对神头第二发电厂水务管理的现状进行了分析研究,提出了与国外先进水平的差距,提出2套切实可行的方案,说明火电厂水务管理“零排放”是可以实现的。 相似文献
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大型燃煤空冷电厂实施节水最大化、废水零排放 总被引:3,自引:0,他引:3
首次提出大型燃煤空冷电厂不仅使全厂“节水最大化,还能使排放最小化(零排放)”的理念。介绍了国外两个大型燃煤直接空冷电厂示例,详述了国内新建2×600 MW燃煤直接空冷电厂的水务关系、废水处理与回用以及高浓废水最终处置,实现全厂废水零排放。说明大型(300 MW6、00 MW级)燃煤空冷电厂是实施“节水最大化、排放最小化”的最佳模式。 相似文献
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The degradation of cellulose (a substantial component of low- and intermediate-level radioactive waste) under alkaline conditions
occurs via two main processes: a peeling-off reaction and a basecatalyzed cleavage of glycosidic bonds (hydrolysis). Both
processes show pseudo-first-order kinetics. At ambient temperature, the peeling-off process is the dominant degradation mechanism,
resulting in the formation of mainly isosaccharinic acid. The degradation depends strongly on the degree of polymerization
(DP) and on the number of reducing end groups present in cellulose. Beyond pH 12.5, the OH- concentration has only a minor effect on the degradation rate. It was estimated that under repository conditions (alkaline
environment, pH 13.3-12.5) about 10% of the cellulosic materials (average DP = 1000-2000) will degrade in the first stage
(up to 105 years) by the peeling-off reaction and will cause an ingrowth of isosaccharinic acid in the interstitial cement pore water.
In the second stage (105-106 years), alkaline hydrolysis will control the further degradation of the cellulose. The potential role of microorganisms in
the degradation of cellulose under alkaline conditions could not be evaluated. Proper assessment of the effect of cellulose
degradation on the mobilization of radionuclides basically requires knowing the concentration of isosaccharinic acid in the
pore water. This concentration, however, depends on several factors such as the stability of ISA under alkaline conditions,
sorption of ISA on cement, formation of sparingly soluble ISA-salts, etc. A discussion of all the relevant processes involved,
however, is far beyond the scope of the presented overview. 相似文献
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Deepak Srivastava 《Journal of Polymers and the Environment》2004,12(1):27-33
Six film samples of low-density polypropylene (LDPE)/linear LDPE (LLDPE)/high-density polypropylene (HDPE) with varying ratios of LDPE (20–45 ... wt%) and LLDPE (25–50 wt%) having a fixed amount of HDPE at 30 wt% were prepared by blown film extrusion technique. The samples were aged at four different temperatures, 55°, 70°, 85°, and 100°C, for four different time periods in the interval of between 150 hours and up to 600 hours. The change in the structure of various constituents and the formation of various oxygenated (peroxy and hydroperoxy) and unsaturated groups during thermo-oxidative degradation was discussed by infrared spectroscopy. The visiosity-average molecular weight was found to have decreased slowly in the initial aging hours and temperatures, whereas it decreased by 10% with its previous value tensile strength that is, 100°C when aged for 600 hours. The tensile strength of the sample first increased by 67% at 55°C and 89% at 70°C up to 450 hours, whereas the values increased by 52.5% at 85°C and 33.9% at 100°C when aged for 150 hours and then decreased. The percentage elongation at break increased by 2.7% at 55°C and 10.7% at 70°C for 150 and 300 hours of aging, respectively, whereas the percentage decreased when aged at 85°C and 100°C for up to 600 hours of aging. The values of gel content (percent) increased and initial degradation temperature decreased with aging time and temperature. 相似文献
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J.L. Torero Stephen M. OlenickJ.P. Garo J.P. Vantelon 《Spill Science & Technology Bulletin》2003,8(4):379-390
The burning rate of a slick of oil on a water bed is characterized by three distinct processes, ignition, flame spread and burning rate. Although all three processes are important, ignition and burning rate are critical. The former, because it defines the potential to burn and the latter because of the inherent possibility of boilover. Burning rate is calculated by a simple expression derived from a one-dimensional heat conduction equation. Heat feedback from the flame to the surface is assumed to be a constant fraction of the total energy released by the combustion reaction. The constant fraction (χ) is named the burning efficiency and represents an important tool in assessing the potential of in situ burning as a counter-measure to an oil spill. By matching the characteristic thermal penetration length scale for the fuel/water system and an equivalent single layer system, a combined thermal diffusivity can be calculated and used to obtain an analytical solution for the burning rate. Theoretical expressions were correlated with crude oil and heating oil, for a number of pool diameters and initial fuel layer thickness. Experiments were also conducted with emulsified and weathered crude oil. The simple analytical expression describes well the effects of pool diameter and initial fuel layer thickness permitting a better observation of the effects of weathering, emulsification and net heat feedback to the fuel surface. Experiments showed that only a small fraction of the heat released by the flame is retained by the fuel layer and water bed (of the order of 1%). Ignition has been studied to provide a tool that will serve to assess a fuels ease to ignite under conditions that are representative of oil spills. Two different techniques are used, piloted ignition when the fuel is exposed to a radiant heat flux and flash point as measured by the ASTM D56 Tag Closed Cup Test. Two different crude oils were used for these experiments, ANS and Cook Inlet. Crude oils were tested in their natural state and at different levels of weathering, showing that piloted ignition and flash point are strong functions of weathering level. 相似文献
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S. Urstadt J. Augusta R. -J. Müller W. -D. Deckwer 《Journal of Polymers and the Environment》1995,3(3):121-131
Establishing carbon balances has been proven to be an applicable and powerful tool in testing biodegradability of polymers. In controlled degradation tests at a 4-L scale with the model polymer poly(-hydroxybutyrate) (PHB), it was shown that the degree of degradation could not be determined with satisfactory accuracy from CO2 release alone. Instead, the course of degradation was characterized by means of establishing carbon balances for the degradation of PHB withAcidovorax facilis and a mixed culture derived from compost. Different analytical methods for determining the different carbon fractions were adapted to the particular test conditions and compared. Quantitative determination of biomass and residual polymer were the main problems in establishing carbon balances. Amounts of biomass derived from protein measurements depend strongly on assumptions of the protein content of the biomass. Selective oxidation of biomass with hypochlorite was used as alternative, but here problems arose from insoluble metabolic products. Determination of soluble components with the method of chemical oxygen demand (COD) also includes empirical assumptions but seems acceptable if the dissolved carbon fraction is in the range of some 10% total carbon. Results confirm both analytical assays and theoretical approaches, in ending up at values very close to 100%, within an acceptable standard deviation range under test conditions comparable to standard test practice.Paper presented at the Bio/Environmentally Degradable Polymer Society—Third National Meeting, June 6–8, 1994, Boston, Massachusetts. 相似文献
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This article presents a mathematical model which describes the sodium chromate (VI) production process with the use of chromic waste as a substitution of natural raw materials. This model is a function of selected process parameters common for all of the examined alternatives and based on equations of material balance. Optimization of the elaborated technological alternatives of the production process with use of recycling of chromic waste has been evaluated by determining the extreme value of the quality indicator WJ. This indicator defines the quantity of waste created in the process. Optimization results enabled the selection of the optimal technological solution from all of the alternatives possible for use in industrial practice. Negative values of the indicator prove that there is the possibility of introducing to the process a larger quantity of waste than the one obtained in the process and transported to the storage heaps. 相似文献
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M. van der Zee J. H. Stoutjesdijk P. A. A. W. van der Heijden D. de Wit 《Journal of Polymers and the Environment》1995,3(4):235-242
The biodegradability of oxidized starch and inulin has been studied in relation to the degree of periodate oxidation to dialdehyde derivatives, by measuring oxygen consumption and mineralization to carbon dioxide. A higher degree of oxidation of dialdehyde starch and dialdchyde inulin results in a lower rate at which the polymers are biodegraded. It is demonstrated that the biodegradation rate of dialdehyde inulin derivatives decreases more than that of equivalent starch derivatives. The differences in biodegradation behavior between dialdehyde starch and dialdehyde inulin, resulting from comparable modifications, are discussed in terms of conformational structure. 相似文献
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Methyleneureas are condensation products of urea and formaldehyde of different molecular mass and solubility; they are used in large amounts both as resins, binders, and insulating materials for industrial applications, as well as a slow-release nitrogen fertilizer for greens, lawns, or in bioremediation processes. In the present study, the microbial breakdown of these products was investigated. The nitrogen was released as ammonia and urea, and the formaldehyde released immediately oxidized via formiate to carbon dioxide. The enzymatic mechanism of metabolization of methyleneureas was studied in microorganisms isolated from soil, which were able to use these compounds as the sole source of nitrogen for growth. A strain of the Gram-negative bacterium Ralstonia paucula (formerly Alcaligenes sp. CDC group IVc-2) completely degraded methylenediurea and dimethylenetriurea to urea, ammonia, formaldehyde, and carbon dioxide. The enzyme initiating this degradation (methylenediurease) was purified and turned out to be different from the previously described enzyme from Ochrobactrum anthropi with regard to its regulation of expression and physicobiochemical properties. Fungal degradation of methyleneureas may occur via the formation of organic acids, thus leading to a nonenzymatic degradation of methyleneureas, which are unstable under acidic conditions. 相似文献