Active capping demonstration in the Anacostia river,Washington, D.C.

An active capping demonstration project in Washington, D.C., is testing the ability to place sequestering agents on contaminated sediments using conventional equipment and evaluating their subsequent effectiveness relative to conventional passive sand sediment caps. Selected active capping materials include: (1) AquaBlokTM, a clay material for permeability control; (2) apatite, a phosphate mineral for metals control; (3) coke, an organic sequestration agent; and (4) sand material for a control cap. All of the materials, except coke, were placed in 8,000‐ft test plots by a conventional clamshell method during March and April 2004. Coke was placed as a 1.25‐cm layer in a laminated mat due to concerns related to settling of the material. Postcap sampling and analysis were conducted during the first, sixth, and eighteenth months after placement. Although postcap sampling is expected to continue for at least an additional 24 months, this article summarizes the results of the demonstration project and postcap sampling efforts up to 18 months. Conventional clamshell placement was found to be effective for placing relatively thin (six‐inch) layers of active material. The viability of placing high‐value or difficult‐to‐place material in a controlled manner was successfully demonstrated with the laminated mat. Postcap monitoring indicates that all cap materials effectively isolated contaminants, but it is not yet possible to differentiate between conventional sand and active cap layer performance. Monitoring of the permeability control layer indicated effective reductions in groundwater seepage rates through the cap, but also showed the potential for gas accumulation and irregular release. All of the cap materials show deposition of new contaminated sediment onto the surface of the caps, illustrating the importance of source control in maintaining sediment quality. © 2006 Wiley Periodicals, Inc.     

Evaluation of the physical stability,groundwater seepage control,and faunal changes associated with an AquaBlok® sediment cap

Active sediment caps are being considered for addressing contaminated sediment areas in surface‐water bodies. A demonstration of an active cap designed to reduce advective transport of contaminants using AquaBlok® (active cap material) was initiated in a small study area of the Anacostia River in Washington, D.C. The cap remained physically stable, demonstrated the ability to divert groundwater flow, and was recolonized with native organisms after 30 months of monitoring following cap placement. However, the long‐term performance of active caps associated with harsh environmental conditions, hydrogeological settings, and subsurface gas production needs to be further evaluated. © 2008 Wiley Periodicals, Inc.     

Root penetration through sealing layers at mine deposit sites.

To prevent acid mine drainage arising from oxygen and water penetration of sulphide-rich mine tailings, the tailings are covered with layers of dry sealing material. Plant roots have a great ability to penetrate dense materials, and if the roots are able to penetrate the sealing layer of a tailings deposit, its oxygen-shielding properties could be reduced. The objective of this study was to evaluate whether plant roots are able to penetrate sealing layers covering mine tailings deposits. Root penetration into layers of various sealing materials, such as clayey moraine (clay, 8-10%; silt, 22-37%; sand, 37-55%; gravel, 15-18%), moraine (unspecified), 6-mm bentonite (kaolin clay) fabric, lime and clay, Cefyll (mixture of pulverized coal fly ash, cement and water) and a mixture containing biosludge (30-35%) and bioashes (65-70%), was investigated. In the field, roots were studied by digging trenches alongside vegetation growing in 3- and 10-year-old mine sites. In the greenhouse root growth of Betula pendula, Pinus sylvestris, Poa pratensis and Salix viminalis were studied in compartments where the plants had been growing for 22 months. The results from the field experiment indicated that roots are able to penetrate both deep down in the cover layer (1.7 m) and also into the sealing layers of various materials, and even to penetrate hard Cefyll. The addition of nutrients in the top cover reduced deep root growth and thereby also penetration through the sealing layer. Low hydraulic conductivity of the sealing layer or a thick cover layer had less effect on root penetration. In the greenhouse experiment roots did not penetrate the thin bentonite fabric, due to low pH (2.1-2.7) that was created from the underlying weathered mine tailings. The clayey moraine was penetrated by all species used in the greenhouse experiment; Pinus sylvestris had the greatest ability to penetrate. To prevent root penetration of the other sealing layer, a suitable condition for the plants should be created in the upper part of the cover layer, namely a sufficient amount of plant nutrients. However, to define such a condition is difficult since different plant species have different requirements.     

Chemical, dimensional and morphological ultrafine particle characterization from a waste-to-energy plant

Waste combustion processes are responsible of particles and gaseous emissions. Referring to the particle emission, in the last years specific attention was paid to ultrafine particles (UFPs, diameter less than 0.1 μm), mainly emitted by combustion processes. In fact, recent findings of toxicological and epidemiological studies indicate that fine and ultrafine particles could represent a risk for health and environment. Therefore, it is necessary to quantify particle emissions from incinerators also to perform an exposure assessment for the human populations living in their surrounding areas.To these purposes, in the present work an experimental campaign aimed to monitor UFPs was carried out at the incineration plant in San Vittore del Lazio (Italy). Particle size distributions and total concentrations were measured both at the stack and before the fabric filter inlet in order to evaluate the removal efficiency of the filter in terms of UFPs. A chemical characterization of UFPs in terms of heavy metal concentration was performed through a nuclear method, i.e. Instrumental Neutron Activation Analysis (INAA), as well as a mineralogical investigation was carried out through a Transmission Electron Microscope (TEM) equipped with an Energy Dispersive Spectrometer (EDS) in order to evaluate shape, crystalline state and mineral compound of sampled particles.Maximum values of 2.7 × 10⁷ part. cm⁻³ and 2.0 × 10³ part. cm⁻³ were found, respectively, for number concentration before and after the fabric filter showing a very high efficiency in particle removing by the fabric filter. With regard to heavy metal concentrations, the elements with higher boiling temperature present higher concentrations at lower diameters showing a not complete evaporation in the combustion section and the consequent condensation of semi-volatile compounds on solid nuclei. In terms of mineralogical and morphological analysis, the most abundant compounds found in samples collected before the fabric filter are Na–K–Pb oxides followed by phyllosilicates, otherwise, different oxides of comparable abundance were detected in the samples collected at the stack.     

A RE-EVALUATION OF OBJECTIONS TO TREE PLANTING ON CONTAINMENT LANDFILLS

Legislation from developed countries indicates that planting trees on containment landfills is generally forbidden. Concerns centre on the supposition that tree roots can penetrate into and through capping materials, and will thus compromise control of water ingress into waste, and allow the escape of landfill gas. An associated anxiety is that if roots penetrate a clay cap they could cause desiccation and cracking of the clay through excessive moisture abstraction. It is also considered that trees growing on the relatively shallow soil above a landfill cap could be especially prone to uprooting. However, a review of the world literature indicates that maximum depths achieved by tree roots are usually between 1–2 m. Almost 90% of a tree's roots may be found in the upper 0.6 m of soil. Tree roots are highly sensitive to environmental conditions and their downward penetration can be restricted by a number of soil factors including compaction, poor aeration and infertility. A detailed study of these factors indicates that the materials used for capping landfill sites, such as HDPE (high density polyethylene) and compacted clays, can provide an effective barrier to downward root growth. The available information also suggests that tree roots are extremely unlikely to be a primary cause of desiccation cracking in a clay cap owing to their inability to extract more than about one-quarter of the total moisture held in a clay of the density required to ensure a permeability of 1×10⁻⁹m s⁻¹. Trees growing on landfill sites with a rootable soil depth of at least 1.5 m should be at no greater risk of windthrow than most forest trees on undisturbed sites. Methods are available to assess the likelihood of windthrow. In any event, windthrow should not cause disruption of a cap, due to the inability of tree roots to penetrate HDPE, or mineral materials compacted to a bulk density of 1.8 g cm⁻³.     

Sand Cap Placement and Cap Thickness Monitoring: A Case Study at a Confined Disposal Facility

Thin sediment capping is a commonly used technique to prevent mobilization of contaminants from sediments into the environment. A 70‐m‐deep subaqueous confined disposal facility (CDF, 350,000 m²) at Malmøykalven, Oslofjord, which received dredged contaminated sediments from Oslo Harbor, was capped with 148,900 m³ of sand in 2009. This research serves as a case study regarding some of the key considerations involved with the cap placement and monitoring of the cap layer. Uncertainty is included in all the cap thickness monitoring methods and a combined use of them provided a better understanding of the cap coverage and structure at the site. An open water disposal model (STFATE) was used to simulate the behavior of the barge‐released cap material. The modeling results were consistent with field observations regarding the material spread, and the results provided insight into the relatively high material losses calculated. Better knowledge obtained of material settling resulted in cap properties and cap monitoring methods that are useful when planning similar operations. ©2015 Wiley Periodicals, Inc.     

Characterization of metal concentration,heavy metal elution,and desalination behavior of municipal solid waste incineration bottom and grate sifting deposition ash based on particle size

Resource and environmental safety protocols of incineration residues were evaluated by analyzing the metal concentration, heavy metal elution, desalination behavior, and chlorine removal ratio owing to particle size differences between bottom ash (BA) and grate sifting deposition ash (GA). In the total content test, Cl, Zn, and Cr in the incinerator BA exceeded the cement acceptance standard (Cl: 1000 mg/kg; Zn: 1700 mg/kg, and Cr: 170 mg/kg) at almost all of the particle sizes, while Au, Ag, Pd, and Zn had high contents in the GA. When using BA as a construction material, heavy metal elution values and contents are restricted as per the product quality standards based on the Japanese soil pollution control law. Lead within the BA and GA exceeded the standard values for most particle sizes. We predicted that there would be a limit on the elution of K by only washing with water. The removal ratio of total chlorine by particle size was approximately 20–70%, where the effect of the particle size on the removal ratio was small, suggesting that the elution of chlorine was complete in approximately 6 hours. These results contribute to information on the recycling of BA and GA.

     

PREPARATION OF CERAMIC MEMBRANE FILTERS,FROM WASTE FLY ASH,SUITABLE FOR HOT GAS CLEANING

The preparation and performance of ceramic membrane filters made from fly ash from coal-fired power stations were investigated. The porous and crack-free ceramic composite membrane was prepared by dip-coating a stainless steel mesh in a slurry of fly ash. Membrane properties investigated included pore structure, permeability and mechanical strength. The ash membrane filter shows great potential for the filtration and microfiltration of high-temperature gas-particulate streams, and re-uses waste fly ash composed of multiple oxides with a wide size distribution. The median pore size of the tested membrane was 2.3μm and the differential pressure gradient was 0.9 kPa l⁻¹min⁻¹, which is comparable to fabric filters currently in use in some New South Wales power stations. The high mechanical strength of the membrane was caused by fusion of the glassy material in the fly ash. Since the membrane consists of metal and ceramic composities, it also shows good flexibility.     

Use of waste brick as a partial replacement of cement in mortar

The aim of this study is to investigate the use of waste brick as a partial replacement for cement in the production of cement mortar. Clinker was replaced by waste brick in different proportions (0%, 5%, 10%, 15% and 20%) by weight for cement. The physico-chemical properties of cement at anhydrous state and the hydrated state, thus the mechanical strengths (flexural and compressive strengths after 7, 28 and 90 days) for the mortar were studied. The microstructure of the mortar was investigated using scanning electron microscopy (SEM), the mineralogical composition (mineral phases) of the artificial pozzolan was investigated by the X-ray diffraction (XRD) and the particle size distributions was obtained from laser granulometry (LG) of cements powders used in this study. The results obtained show that the addition of artificial pozzolan improves the grinding time and setting times of the cement, thus the mechanical characteristics of mortar. A substitution of cement by 10% of waste brick increased mechanical strengths of mortar. The results of the investigation confirmed the potential use of this waste material to produce pozzolanic cement.     

Assessment of factors affecting household solid waste generation and its composition in Gulberg Town,Lahore, Pakistan

This paper analyzes and compares the findings of the characterization study of collected solid waste from households of three different socioeconomic groups in Lahore, Pakistan, over the four seasons, i.e. Spring (March–April, 2008), Summer (May–June, 2008), Monsoon (August–September, 2008) and Winter (December 2008 and January 2009). The generation rate of waste was 0.96 kg/cap/day for high-income, 0.73 kg/cap/day for middle and 0.67 kg/cap/day for low-income group. The average of total household solid waste (HSW) generation is 0.79 kg/cap/day (including 0.75 kg/cap/day for spring, 0.77 kg/cap/day for summer, 0.86 kg/cap/day for monsoon and 0.76 kg/cap/day. The breakdown for the major physical components of the waste shows that organic waste accounts for the largest proportion (67.46 %). The relations between waste generation rates by physical category and subcategory, in addition to factors such as socioeconomic groups (population density levels, household income and household size), seasonal variation, and daily variation (difference of HSW generation among days of a week) were also analyzed. Statistical analysis shows that there was no significant difference in overall waste generation among days of a week. A significant difference between the seasons for food waste, cardboard, PET, HDPE, other hazardous waste, battery cells, and dust and stone (p < 0.001) was found. The generation rates were found to be higher when compared to other developing countries.     

Economical and environmental implications of solid waste compost applications to agricultural fields in Punjab,Pakistan

Application of municipal solid waste compost (MSWC) to agricultural soils is becoming an increasingly important global practice to enhance and sustain soil organic matter (SOM) and fertility levels. Potential risks associated with heavy metals and phosphorus accumulations in surface soils may be minimized with integrated nutrient management strategies that utilize MSWC together with mineral fertilizers. To explore the economic feasibility of MSWC applications, nutrient management plans were developed for rice–wheat and cotton–wheat cropping systems within the Punjab region of Pakistan. Three-year field trials were conducted to measure yields and to determine the economic benefits using three management strategies and two nutrient doses. Management strategies included the application of mineral fertilizers as the sole nutrient source and application of mineral fertilizers in combination with MSWC with and without pesticide/herbicide treatments. Fertilizer doses were either based on standard N, P and K recommendations or on measured site-specific soil plant available phosphorus (PAP) levels. It was found that combining MSWC and mineral fertilizer applications based on site-specific PAP levels with the use of pesticides and herbicides is an economically and environmentally viable management strategy. Results show that incorporation of MSWC improved soil physical properties such as bulk density and penetration resistance. The PAP levels in the surface layer increased by the end of the trials relative to the initial status. No potential risks of heavy metal (Zn, Cd, Cr, Pb and Ni) accumulation were observed. Treatments comprised of MSWC and mineral fertilizer adjusted to site-specific PAP levels and with common pest management showed highest cumulative yields. A basic economic analysis revealed a significantly higher cumulative net profit and value-to-cost ratio (VCR) for all site-specific doses.     

Sensor-based control in eddy current separation of incinerator bottom ash

A sensor unit was placed online in the particle stream produced by an eddy current separator (ECS) to investigate its functionality in non-ferrous metals recovery. The targeted feed was the 1–6 mm size fraction bottom ash from a municipal waste incinerator. The sensor unit was attached to the ECS splitter, where it counted in real-time metal and mineral particles and accurately measured the grade of the stream in the metals product. Influence of segregation (e.g. due to particle size or density) on the metals concentrate were detected and studied using the sensor data collected at different splitter distances. Tests were performed in the laboratory and in a bottom ash processing plant with two different types of ECS and two sources of bottom ash with different moisture content. The measured metal grades matched the manual analyses with errors 0%, 1.5% and 3.1% for moist, dry and very wet feed, respectively. For very wet feed the ECS metals recovery dropped, which was observed from the strongly reduced particle counts and the large changes in cumulative particle properties. The measured sample proved representative for the whole metals concentrate if it is collected at a representative position within the metals particle trajectory fan produced by the ECS. ECS-performance proved sensitively dependent on splitter distance, since a 10 mm shift may result in 10% change in metal recovery and 18% change in grade. The main functionalities of the sensor unit are determined as online quality control and facilitation of automatic control over the ECS splitter distance. These functionalities translate in significant improvements in ECS metals recovery which in turn is linked to economic benefits, increased recycling rate of scrap metals and a further reduction of the ecological drawbacks of incinerator bottom ash.     

Kinetic vaporization of heavy metals during fluidized bed thermal treatment of municipal solid waste

Heavy metals volatilization during thermal treatment of model solid waste was theoretically and experimentally investigated in a fluidized bed reactor. Lead, cadmium, zinc and copper, the most four conventional heavy metals were investigated. Particle temperature model and metal diffusion model were established to simulate the volatilization of CdCl₂ evaporation and investigate the possible influencing factors. The diffusion coefficient, porosity and particle size had significant effects on metal volatilization. The higher diffusion coefficient and porosity resulted in the higher metal evaporation. The influence of redox conditions, HCl, water and mineral matrice were also investigated experimentally. The metal volatilization can be promoted by the injection of HCl, while oxygen played a negative role. The diffusion process of heavy metals within particles also had a significant influence on kinetics of their vaporization. The interaction between heavy metals and mineral matter can decrease metal evaporation amount by forming stable metallic species.     

Analysis of a system for remote, dry removal of solidified mixed waste

This paper describes a novel technology for the removal of solidified radioactive waste from underground storage tanks at the DOE Hanford site in southeast Washington. The process involves the use of a unique high pressure system which pulverizes the hardened saltcake with stainless steel pellets to a powder for easy vacuum removal. The steel pellets can be magnetically separated from the waste material for re-use. Specifically this study analyzes the effects of various steel abrasives, pressure of the air stream, and stand-off distance on removal rates and penetration depth on simulated saltcake samples using the high pressure technique. A full-scale test set-up and protocol were implemented to allow for comprehensive testing. To insure reproducibility of the method, tests were then run for the optimum removal parameters. A time-dependent test was also conducted to determine the relationship of removal rates to length of pressure blasts. The results of these tests revealed that stand-off distance and pressure could be positively correlated to removal volumes. Additionally, a statistical analysis confirmed that nozzle angle is independent of removal rate. This study demonstrated that the pellet ‘blaster’ technique is a safe, effective method for removal of radioactive wastes without any increase in either waste mass or volume.     

The municipal solid waste system and solid waste characterization at the municipality of Veles, Macedonia

A short-term study to characterize the solid waste stream in the Municipality of Veles, Macedonia, was performed during a 1 week period in the summer of 2002. In this study, several important parameters of the municipal solid waste stream were assessed. It was estimated that the average daily generation rate is 1.06+/-0.56 kg/cap/day, while the specific weights of the uncompacted and compacted solid waste are approximately 140.5 kg/m3 and 223 kg/m3, respectively. Furthermore, it was estimated that the daily generated volume of uncompacted waste is 7.5+/-4 L/cap/day. Although the short-term study is characterized by numerous limitations, in the absence of other existing data, such a study with direct measurements could significantly contribute to the development of an efficient solid waste management system in countries with economies in transition like Macedonia.     

Mineral wool waste in Europe: a review of mineral wool waste quantity,quality, and current recycling methods

The construction and demolition (C&D) industry has been identified as a major source of waste. European Union legislation states that, by 2020, 70 % of C&D waste must be prepared for reuse, recycled or recovered. European Union member states must increase their C&D waste recycling percentages in order to meet this binding target. Utilization of mineral wool waste, often considered unrecyclable, could improve the recycling percentage of C&D waste. In this article, mineral wool production and waste volumes are estimated based on information from the Eurostat database. A literature survey is conducted to collect information about mineral wool material properties, current recycling methods, and barriers to recycling of mineral wool, and suitable methods for separating mineral wool from C&D waste streams and the economic viability of mineral wool recycling are discussed. It is noted that accurate estimation of mineral wool waste volumes is problematic due to the fragmented nature of available data. Based on the literature review, current methods for recycling mineral wool waste include utilization of mineral wool waste as a raw material in various products. Barriers to recycling include economic questions and issues related to the purity and health effects of mineral wool waste. Material properties of mineral wool waste, such as fire resistance, could provide improved properties in products utilizing mineral wool waste as a raw material.     

Analysis of gas flow behavior in an annular fluidized-bed reactor for polystyrene waste treatment

The characteristics of bubble properties and the chaotic flow behavior of gas were investigated in an annular fluidized bed (0.102 m in inner diameter and 2 m in height) because the behavior of gas flow in such a reactor is one of the important factors governing reactor operation, reactor performance, and the reaction itself. Pressure fluctuations as a state variable for the analysis of gas flow behavior were measured and analyzed. Bubble properties were determined by adopting the cross-correlation function of pressure fluctuations. The resultant chaotic flow behavior of gas was interpreted by means of chaotic parameters such as the Kolmogorov entropy. It was found that the Kolmogorov entropy could be utilized effectively to explain the nonlinear dynamic behavior of gas-solid flow in the annular fluidized bed. The pierced length and rising velocity of bubbles increased with increasing gas velocity, bed temperature, and particle size of the bed material. The bubble frequency increased with increasing gas velocity and bed temperature, while it decreased with increasing particle size of the bed material. Correlations to predict the bubble properties in annular fluidized-bed reactors were suggested.     

Evaluation of bioaccessible arsenic in fly ash by an in vitro method and influence of particle-size fraction on arsenic distribution

A huge amount of fly ash is produced by coal-fired power plants every year in China and leads to increasing environmental problems associated with disposal and treatment. It will be very helpful for the study of management and disposal of solid waste to understand the bioaccessibility and environmental behaviors of arsenic in fly ash. In this paper, an in vitro physiologically-based extraction test was applied to estimate the solubility and bioaccessibility of arsenic in fly ash in the human gastrointestinal tract. The fly ash samples were sieved into different fractions with different particle sizes (100–60, 60–10, 10–2.5, <2.5 μm). The influence of particle size on both total and bioaccessible arsenic was also investigated. The results demonstrated that arsenic concentrations in fly ash were significantly correlated with particle size. The proportion of bioaccessible arsenic (gastric and intestinal arsenic) accounting for the total arsenic was in the range of 36–67 %. The statistic analysis indicated that total arsenic in fly ash was linearly correlated with bioaccessible arsenic. The results illustrated that bioaccessible arsenic was dominated by total arsenic.     

Analytical study on the suitability of using bentonite coated gravel as a landfill liner material

This study investigates the feasibility of using bentonite coated gravel (BCG) as a liner material for waste landfills. BCG has proven to be a very effective capping material/method for the remediation of contaminated sediments in aquatic environments. The concept of BCG is similar to that of peanuts/almonds covered with chocolate; each aggregate particle has been covered with the clayey material. Laboratory tests were aimed at evaluating regulated and non-regulated factors for liner materials, i.e., permeability and strength. Tests included X-ray diffraction, methylene blue absorption, compaction, free swelling, permeability, 1D consolidation, triaxial compression and cone penetration. The compactive efforts used for this study were the reduced Proctor, standard Proctor, intermediate Proctor, modified Proctor and super modified Proctor. The compactive energy corresponding to each effort, respectively, is as follows: 355.5, 592.3, 1196.3, 2693.3, and 5386.4 kJ/m(3). Results revealed that even though aggregate content represents 70% of the weight of the material, hydraulic conductivities as low as 6 x 10(-10)cm/s can be achieved when proper compactive efforts are used. Compressibility is very low for this material even at low (or no) compactive efforts. Results also demonstrated how higher compactive efforts can lower the permeability of BCG; however, over-compaction creates fractures in the aggregate core of BCG that could increase permeability. Moreover, higher compactive efforts create higher swelling pressures that could compromise the performance of a barrier constructed using BCG. As a result of this study, moderate compactive efforts, i.e., intermediate Proctor or modified Proctor, are recommended for constructing a BCG barrier. Using moderate compactive efforts, very low hydraulic conductivities, good workability and good trafficability are easily attainable.     

Optimal bulking agent particle size and usage for heat retention and disinfection in domestic wastewater sludge composting

Composting of two types of sludge produced in wastewater treatment plants, raw sludge (RS) and anaerobically digested sludge (ADS), has been systematically studied by means of the experimental design technique. The results have been analyzed using a full factorial experimental design in order to determine the optimal conditions for composting such sludges in terms of bulking agent particle size and bulking agent:sludge volumetric ratio, two of the key parameters to ensure an optimal performance of the composting process. The objective function selected was a simulated death kinetics of Salmonella, which was chosen as a model pathogen microorganism to represent the disinfection of the material. For both types of sludge, optimal values were found at 5mm bulking agent particle size and 1:1 bulking agent:sludge volumetric ratio when a Gaussian function was fitted to the experimental data. Pilot scale experiments using optimal values obtained were successfully undertaken and confirmed a full disinfection of the sludge by means of the composting process. A mathematical model to simulate the disinfection performance of a composting material is presented. The model can be applied to simulate the disinfection performance of a given pathogen.