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建立了一端密闭、一端敞开且点火源位于密闭端时管道内火焰加速的一个简单模型,其解与试验结果一致。文章还探讨了将其应用于管道自动抑爆系统的可能性。 相似文献
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Coal dust explosion is one of the serious accidents in the coal industry. It is of great significance to study the flame suppression of coal dust explosions. In this paper, a novel active component NiB with amorphous structure for explosion suppression was synthesized by the chemical reduction method. Furthermore, the novel explosion suppressant NiB/Hβ-Al2O3 was prepared through the kneading method by loading novel amorphous NiB nanoparticles on Hβ-Al2O3 with the micro-mesoporous structure as the carrier. The morphology and structure of NiB/Hβ-Al2O3 were characterized by XRD, BET, SEM, and FTIR, which showed that the NiB/Hβ-Al2O3 has proper pore structure and NiB nanoparticles are uniformly distributed as active components for explosion suppression in suppressant. Hartmann tube was used to evaluate the inhibition of coal dust deflagration. The results showed that the flame propagation distance and velocity decreased with the increase of the explosion suppressant. When the addition of explosion suppressant was 30 wt%, the explosion of coal dust was suppressed effectively. Furthermore, combing with the analysis results of the products after coal dust deflagration, the physical and chemical inhibition mechanism of the novel NiB/Hβ-Al2O3 explosion suppressant on coal dust deflagration was put forward. 相似文献
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Flame Retardation and Smoke Suppression of PVC 总被引：1，自引：0，他引：1
ＦｌａｍｅＲｅｔａｒｄａｔｉｏｎａｎｄＳｍｏｋｅＳｕｐｐｒｅｓｓｉｏｎｏｆＰＶＣＷａｎｇＺｈｅｎｇｚｈｏｕ;Ｄ．Ｄ．Ｄｒｙｓｄａｌｅ（ＵｎｉｔｏｆＦｉｒｅＳａｆｅｔｙＥｎｇｉｎｅｅｒｉｎｇＵｎｉｖｅｓｉｔｙｏｆＥｄｉｎｂｕｒｇｈＥｄｉｎｂｕｒｇｈＥＨ... 相似文献
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To reveal clearly the effects of particle thermal characteristics on flame microstructures during organic dust explosions, three long-chain monobasic alcohols, solid at room temperature and similar in physical-chemical properties, were chosen to conduct experiments in a half-closed chamber. In the experiments, the dust materials were dispersed into the chamber by air to form dust clouds and the hybrids were ignited by an electrical spark. A high-speed optical schlieren system was used to record the flame propagation behaviors. A fine thermocouple and an ion current probe were respectively used to measure the flame temperature profile and the reaction behaviors of the combustion zone. Based on the experimental results, combustion behaviors and flame microstructures in dust clouds with different thermal characteristics were analyzed in detail. As a result, it was found that the dust flame surfaces were completely covered by cellular structures that significantly increased the flame frontal areas. Flame propagated more quickly and the number of the cellular cells increased as increasing the volatility of the particles. On the contrary, maximum temperature and the thickness of the preheated zone decreased as increasing the volatility of the particles. According to the ion current profile, the particles in the preheat zone were pyrolyzed to intermediate radicals and the radicals' fraction in the higher volatile dust flame was higher than that in the lower volatile dust flame. 相似文献
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In order to explore flame propagation characteristics during wood dust explosions in a semi-closed tube, a high-speed camera, a thermal infrared imaging device and a pressure sensor were used in the study. Poplar dusts with different particle size distributions (0–50, 50–96 and 96–180 μm) were respectively placed in a Hartmann tube to mimic dust cloud explosions, and flame propagation behaviors such as flame propagation velocity, flame temperature and explosion pressure were detected and analyzed. According to the changes of flame shapes, flame propagations in wood dust explosions were divided into three stages including ignition, vertical propagation and free diffusion. Flame propagations for the two smaller particles were dominated by homogeneous combustion, while flame propagation for the largest particles was controlled by heterogeneous combustion, which had been confirmed by individual Damköhler number. All flame propagation velocities for different groups of wood particles in dust explosions were increased at first and then decreased with the augmentation of mass concentration. Flame temperatures and explosion pressures were almost similarly changed. Dust explosions in 50–96 μm wood particles were more intense than in the other two particles, of which the most severe explosion appeared at a mass concentration of 750 g/m3. Meanwhile, flame propagation velocity, flame propagation temperature and explosion pressure reached to the maximum values of 10.45 m/s, 1373 °C and 0.41 MPa. In addition, sensitive concentrations corresponding to the three groups of particles from small to large were 500, 750 and 1000 g/m3, separately, indicating that sensitive concentration in dust explosions of wood particles was elevated with the increase of particle size. Taken together, the finding demonstrated that particle size and mass concentration of wood dusts affected the occurrence and severity of dust explosions, which could provide guidance and reference for the identification, assessment and industrial safety management of wood dust explosions. 相似文献
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为实现主动抑制瓦斯爆炸,研制了高速抑爆响应系统。选用尺寸为150mm×150mm×1 600mm的有机玻璃管道,在CH4体积分数为9.5%的条件下进行响应系统测试实验。系统采用火焰传感器进行爆炸火焰探测,通过所设计的程序自主判定瓦斯爆炸的发生并输出控制电信号,以继电器或MOS管为电路控制开关,通过电磁阀控制抑爆剂的喷出。实验结果表明,火焰传感器探测、信号采集、爆炸判断、输出电信号的总平均耗时为22ms,抑爆剂开始释放的平均时刻为59.8ms,抑爆剂释放到管道顶端的平均时刻为79.8ms。而爆炸火焰传播到达喷头所在1.0m处平均时刻为176.2ms。实验表明该系统具有高速主动抑爆响应功能和良好的稳定性、可靠性。 相似文献
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To explore the inhibitory effects of CF3I and CO2 gas on the explosion pressure and flame propagation characteristics of 9.5% methane, a spherical 20 L experimental explosion device was used to study the effect of the gas explosion suppressants on the maximum explosion pressure, maximum explosion pressure rise rate and flame propagation speed of methane. The results indicated that with a gradual increase in the volume fraction of the gas explosion suppressant, the maximum explosion pressure of methane and maximum explosion pressure rise rate gradually decreased, and the time taken to reach the maximum explosion pressure and maximum explosion pressure rise rate was gradually delayed. At the same time, the flame propagation speed gradually decreased. Additionally, the time taken for the flame to reach the edge of the window and the time taken for a crack as well as a cellular structure to appear on the flame surface was gradually delayed. The fluid dynamics uncertainty was suppressed. The explosion pressure and flame propagation processes were markedly suppressed, but the flame buoyancy instability was gradually enhanced. By comparing the effects of the two gas explosion suppressants on the pressure and flame propagation characteristics, it was found that at the same volume fraction, trifluoroiodomethane was significantly better than carbon dioxide in suppressing the explosion of methane. By comparing the reduction rates of the characteristic methane explosion parameters at a volume fraction of 9.5%, it was observed that the inhibitory effect of 4% trifluoroiodomethane on the maximum explosion pressure was approximately 4.6 times that of the same amount of carbon dioxide, and the inhibitory effect of 4% trifluoroiodomethane on the maximum explosion pressure rise rate and flame propagation speed was approximately 2.7 times that of the same amount of carbon dioxide. The addition of 0.5%–1.5% trifluoromethane to 4% and 8% carbon dioxide can improve the explosion suppression efficiency of carbon dioxide. This enhancing phenomenon is a comprehensive manifestation of the oxygen-decreasing effect of carbon dioxide and the trifluoroiodomethane-related endothermic effect and reduction in key free radicals. 相似文献
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Transient computations with full hydrogen chemistry were performed to reveal the flame structure and extinguishment process of co-flow, hydrogen diffusion flame suppressed by water vapor. As the concentration of water vapor was increased, the flame detached away from the burner brim and formed an edge flame at the flame base. Water vapor showed larger chemical inhibition effect than nitrogen when extinguishing hydrogen flame, which was attributed to its enhanced third body effect in the reaction H + O2 + M = HO2 + M. The minimum extinguishing concentration (MEC) of water vapor and nitrogen was predicted by Senecal formula and perfectly stirred reactor (PSR) model respectively. The MECs predicted by PSR model agree with the MECs calculated by Fluent, which shows that 1) the flame extinction is controlled by the flame base, and 2) radiation absorption is negligible. The measured MECs are in a reasonable agreement with the values calculated by Fluent, which demonstrates the accuracy of the CFD model. A simple model was used to investigate the relative importance of extinguishing mechanisms of water vapor. The results show that in a co-flow configuration the thermal cooling and chemical inhibition effect are the main extinguishing mechanisms in suppressing hydrogen diffusion cup burner flame. 相似文献
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Experiments using an open space dust explosion apparatus and a standard 20 L explosion apparatus on nano and micron polymethyl methacrylate dust explosions were conducted to reveal the differences in flame and pressure evolutions. Then the effect of combustion and flame propagation regimes on the explosion overpressure characteristics was discussed. The results showed that the flame propagation behavior, flame temperature distribution and ion current distribution all demonstrated the different flame structures for nano and micron dust explosions. The combustion and flame propagation of 100 nm and 30 μm PMMA dust clouds were mainly controlled by the heat transfer efficiency between the particles and external heat sources. Compared with the cluster diffusion dominant combustion of 30 μm dust flame, the premixed-gas dominant combustion of 100 nm dust flame determined a quicker pyrolysis and combustion reaction rate, a faster flame propagation velocity, a stronger combustion reaction intensity, a quicker heat release rate and a higher amount of released reaction heat, which resulted in an earlier pressure rise, a larger maximum overpressure and a higher explosion hazard class. The complex combustion and propagation regime of agglomerated particles strongly influenced the nano flame propagation and explosion pressure evolution characteristics, and limited the maximum overpressure. 相似文献
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根据海上油气生产平台的特点及灭火需求,分析了海上平台现有灭火系统及灭火剂的综合性能及缺陷,对新型灭火系统的安全性、环保特性、灭火剂的毒性及灭火效能等方面进行对比和分析,对采用新灭火技术替代平台现有灭火装置的应用可行性进行探讨,分析显示:新型灭火剂Novec1230比目前海上平台应用的其他气体灭火剂在安全环保灭火性能上更具优势。 相似文献
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Explosions are the main types of accidents causing casualties in underground coal mines. Research on the mechanisms of gas explosions is needed as a basis for the development of techniques and strategies for explosion prevention, suppression, and mitigation. The prevention of loss in explosion accidents and inquiries into their causes require understanding of the explosion process of methane in air. Because of the high cost and safety issues in full scale experiments, the experiments with small scale ducts have become a key alternative approach. Whether the experimental results at small scales agree with those at full scales needs to be investigated to validate the significance of the experimental results at small scale. Numerical simulation was used to obtain the explosion characteristics of a methane-air mixture in a gallery or duct. If the grid size is too fine in the numerical simulation for a methane-air explosion it is difficult to calculate using the present computer resource. If the grid size is too coarse, the considerable error may result. The effect of grid size on results of calculation depends on the scenario being investigated. The effect of grid sizes on simulation accuracy was analyzed in this work. The overpressure and temperature distributions and the flame propagation for the deflagration of methane-air mixtures in a gallery or duct were obtained by the AutoReaGas code at three different scales. The geometry of investigated objects and the grids in the calculation domain were similar in the three cases. The calculated overpressures vary with the scale. The calculated temperatures do not vary with the scale for the three cases. 相似文献
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The production of materials with dimensions in the nanometre range has continued to increase in recent years. In order to ensure safety when handling these products, the hazard potential of such innovative materials must be known. While several studies have already investigated the effects of explosions (such as maximum explosion pressure and maximum pressure rise) of powders with primary particles in the nanometre range, little is known about the ignition temperatures and flame velocities. Therefore, the minimum ignition temperature (MIT) of metallic nano powders (aluminium, iron, copper and zinc) was determined experimentally in a so called Godbert-Greenwald (GG) oven. Furthermore, the flame velocities were determined in a vertical tube. In order to better classify the test results, the tested samples were characterised in detail and the lower explosion limits of the tested dust samples were determined. Values for the burning velocity of aluminium nano powders are higher compared to values of micrometre powders (from literature). While MIT of nanometre aluminium powders is within the range of micrometre samples, MIT of zinc and copper nano powders is lower than values reported in literature for respective micrometre samples. 相似文献
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Bend structures are common in process industries. These bends containing three typical angles (90°, obtuse angle and acute angle) are often incorporated into pipes or ducts at different positions. In our experiments, the effect of both the bend angle and bend position on flame acceleration was studied. Flame acceleration in a pipe bend can be divided into three stages. The flame speeds increased before the bend and increased again after decreasing for a short distance in the bend. Flame reversing decreased the flame speeds in the bend and led to additional turbulence, which enhanced flame acceleration after the bend. The flame acceleration in three different pipe bend angles had similar trends. The decreasing amplitude of the flame speed in the bend increased with a decrease in the bend angles. The flame speeds in the bend were ordered such that 52° <90° <145°. However, the maximum flame speeds in the pipe were in the opposite order. Additionally, both the flame speeds in the bends and the maximum flame speeds in the whole pipes increased as the bend’s position away from ignition point increased. 相似文献
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蒸汽灭火系统在酒类作业场所有着广阔的应用前景.通过全淹没和局部保护实验对蒸汽抑制熄灭酒精池火的有效性进行了研究.实验结果表明,全淹方式难以有效控火,但是布局合理的局部保护方式能够有效熄灭酒精池火.蒸汽灭火过程中稀释O2浓度的灭火机理起到的作用较小,蒸汽的火焰拉伸效果是其主导灭火机理. 相似文献
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金属网阻火器设计参数的优化选择 总被引：7，自引：0，他引：7
就不同的火焰速度，应采用合理的金属同参数进行了研究，得出了临界消焰速度和金属网形状系数（ｄ／Ｗ）以及金属同层数之间的实验式。提出了网与网之间的理想间隔，并研究出多层金属网的最佳故数。按照本文提出的有关论据，便可在设计金属网阻火器时，对有关参数进行优化选择。 相似文献