负压隔离器内病毒空气传播影响因素的研究

病毒活性及病毒气溶胶粒径是病毒空气传播实验中的重要影响因素.病毒活性主要与环境温湿度有关.为了研究负压隔离器内颗粒粒径的影响因素,测量了实际运行工况下的两种粒径的颗粒浓度,并对不同换气次数、送风温度下颗粒浓度和粒径分布进行数值模拟.结果表明,不同粒径颗粒分布规律趋于一致;增加换气次数会导致气流旋涡区域颗粒浓度升高;随着...     

Evaluation of the explosibility of malt grain dust based on static electrification during pneumatic transportation

The possibility of dust explosions by static electricity in a malt grain silo was investigated. Two kinds of experimental equipment were applied. One was to supply electrostatic charge in order to investigate the charge build up characteristics. The other was to transport the malt grain pneumatically in order to investigate the frictional charge accumulation in the transportation system.

The particle charge of the pulverized malt grain was in the order of 10⁻¹⁴ C. The particle charge of the malt grain was in the order of 10⁻⁹ C and the pipe charge in the transport system was also in the order of 10⁻⁹ C. The charge accumulated on both the pulverized particle and the grain particle were small in view of the incendiary potentiality. However, attention must be paid when the particles are dumped into isolated space. There might be a charge accumulation that will lead to the ignition of the dust cloud.     

Dust explosions: How should the influence of humidity be taken into account?

In this work, the influence of humidity on dust explosions of metallic (aluminium) and organic materials (icing sugar, polyethylene and magnesium stearate) has been studied. The impact of pre-humidification of powders on their ignition sensitivity, their volume resistivity and charge decay time has been assessed. The influence of humidity on explosion severity has also been studied by two methods: on the one hand, the dust sample was stored in a controlled workstation at constant relative humidity; on the other hand, the dry dust was dispersed in a humidity controlled atmosphere in the vessel.As expected, the effect of humidity strongly depends on the chemical nature of the particles. Experiments on powders volume resistivity and charge decay time have shown typical trends but have especially pointed out the inadequacy of some standards. Inhibition phenomena have been verified for polyethylene and magnesium stearate, whereas both inhibition and promotion have been observed for icing sugar and could be explained by an evolution of sucrose structure. Dry aluminium dust explosions in humid atmosphere show that water vapour inerts the explosion. However, when aluminium is stored at controlled humidity, the maximum rise of pressure rate increases with the water content, which is probably due to hydrogen generation.     

Deposition and Resuspension of Selected Aerosols Particles on Electrically Charged Filter Materials for Respiratory Protective Devices

The primary aim of the study was to analyse the non-steady state of filtration for selected electrostatic filter materials designed for use in respiratory protective devices. The obtained results showed that the filtration process in electrostatic filters was dependent in the main on the following factors: type of the filter material, electrostatic field strength of the material, and the charge of the aerosol.

To a lesser degree the filtration process depended on the sign of the charge and the relative humidity of the air. A significant correlation was found between the increase in the penetration and the decrease in breathing resistance while the filter was being loaded.

The effect of resuspension (tearing off and re-deposition of dust agglomerates inside the filter) on the filtration process very significant. It was also observed that under certain conditions electrostatic filter materials lost their protection properties.     

混合药物粉尘输运过程静电特性实验研

兽药制药粉尘加工工艺过程中,由于粉尘颗粒之间或颗粒与设备、管壁之间的碰撞、摩擦,导致装置内部静电荷量积聚,激发静电放电,粉尘燃烧或爆炸的事故频发。实验主要通过包括粉尘与管材摩擦的漏电电流测试和静电放电火花对粉尘云点燃敏感性测试两部分。结果表明:单一药物药粉的静电漏电电流随着管材管径的增大,管长的增长,静电漏电电流逐渐变大;随着倾斜角的增大,静电漏电电流先增大后降低;镀锌铁管的漏电电流大于PVC管,电荷逸散速度更快。单一兽药粉的粉尘云放电火花最小点燃能量随质量浓度的变化,呈现二次曲线的变化趋势。混合兽药粉与单一兽药粉的漏电电流和粉尘云放电火花最小点燃能量的测试结果的变化趋势是一致的。     

瓶级聚酯切片静电起电特性试验研究*

为了分析瓶级聚酯切片（PET）生产过程中分析筛处理量对其静电带电特性的影响,基于颗粒振动摩擦带电模拟试验,研究单颗粒PET振动摩擦带电饱和量以及多颗粒PET振动带电荷质比数据。结果表明:瓶级PET产品静电半衰期超过80 ks;PET单颗粒与金属分析筛碰撞摩擦时带电量随振动时间增加趋于饱和,且单粒子荷质比大小可超过16 nC·g-1;随着分析筛内PET总质量增加,PET颗粒间碰撞几率增加,但PET的荷质比值迅速降低。利用工业振动筛处理PET时,应尽量提高总颗粒处理量以控制颗粒带电,抑制静电对粉尘吸附作用,有利于脱除切片中携带的粉尘。     

空调通风管道中细颗粒物凝并规律研究

基于颗粒群平衡模型和布朗扩散作用对空调通风管道中细颗粒物的凝并规律进行了研究。通过对不同入口处细颗粒物的体积分数和入口风速对细颗粒物凝并现象的数值模拟分析,得到的主要结论为细颗粒物的体积分数和入口风速对于管道中细颗粒物的凝并具有显著影响。在布朗扩散作用下的细颗粒物凝并现象主要发生在粒径小于1μm的颗粒,当粒径大于1μm时,布朗扩散作用对于颗粒的凝并无明显影响。     

敏感条件对粉尘云最小点火能的影响规律分析

为使粉尘云最小点火能实验测量更准确,从多个方面分析影响最小点火能的测量因素,并根据粉尘云状态、粉尘颗粒固有性质、点火电路等几个方面对影响粉尘云最小点火能的因素,即敏感条件进行了分类。在实验测量中,具体归纳为:粉尘浓度、粉尘湿度、粉尘粒度及其分布、粉尘挥发份含量、粉尘温度(环境温度)、粉尘云的湍流度、粉尘分散质量、粉尘云初始压力、环境氧浓度、电极材料、电极直径和电极末端曲率、电极间距、电火花持续时间、点火延迟时间、电火花能量密度、火花触发电路、可燃气体影响、实验次数等18个影响因素。重点分析了敏感条件对最小点火能的影响规律,从粉尘云点火机理和过程出发,着重分析一些敏感条件对最小点火能影响的内在原因和实质。     

Electrostatic ignition hazards arising from fuel flow in plastic pipelines

The use of electrically insulating synthetic materials, such as plastics, for fuel pipelines and other fuel handling components is now becoming widespread. In the case of buried or underground pipelines in filling station forecourts the use of these materials offers superior corrosion resistance and increased longevity. This in turn reduces the risk of pollution due to fuel leakage. It is well reported that the flow of fuel under certain conditions in metal pipes can produce significant levels of electrostatic charge on the fuel. Little work, however, has been undertaken on plastic pipe where charge can accumulate at the fuel/pipe wall interface.This paper reports on tests performed on a full-scale, high-density, polyethylene pipework system. During the tests, an iso-octane/toluene fuel mix of controlled and known electrical conductivity was transferred through the system at varying flow rates. Both buried and free-standing pipeline configurations were simulated. A number of test runs were performed yielding considerable data relating to the resultant electrostatic activity including electrostatic potential, the nature and location of electrostatic discharges and the discharge energy. The influence of components such as in-line valves and couplings, which have a metallic component, are also evaluated. The extensive data resulting from this study are presented graphically. The paper concludes with an analytical section and draws important conclusions with regard to the parameters influencing the degree of ignition hazard present.     

活性炭常温吸附实验研究

活性炭因有较大的比表面积和经济易得性,常作为气体吸附法净化气体的吸附剂。SO2是大气环境质量指示的一个重要大气环境因子,其排放被严格控制。SO2的吸附受多种因素影响,本研究选取商品粒状活性炭作为样品,在常温、常压、相对湿度RH=0%、用SO2标气和N2模拟配制气体的条件下,进行了活性炭物理吸附SO2的穿透曲线和吸附容量的研究,结果显示该商品活性炭实验吸附穿透曲线和吸附容量随其颗粒直径的减小而增加,吸附曲线也由陡峭变平坦。所得实验结果为商品活性炭的使用提供实验数据支撑。     

Effect of particle size and dust layer size on ignition characteristics of PMMA dust layer on hot surface

Deposition of combustible dust on a hot surface is a hidden danger of fire. In this work, polymethylmethacrylate (PMMA) dust was selected to analyse the influence of dust layer diameter, dust particle size and dust layer thickness on the ignition characteristics of PMMA dust layer. Critical heating temperatures and ignition time had been measured. The STA-GC/MS-FTIR analysis was used to determine that the main products of PMMA pyrolysis were MMA, CO, CO₂, and C₂H₄, of which CO and C₂H₄ were transported to the ambient to cause gas phase combustion on the surface of the dust layer. For 10 mm thick dust layer, the critical heating temperatures of 5 μm PMMA, 100 nm PMMA, and 30 μm PMMA were 300 °C, 330 °C, and 320 °C. As the thickness of the dust layer increased, the gas transport path became longer, the critical heating temperature and ignition time increased. The characteristic particle size (D [3,2]) was utilized to represent the true particle size, and the ignition time increased with the increase of the characteristic particle size. The increase in the diameter of the dust layer had a slight effect on the temperature history and ignition time of the dust layer.     

焊接作业厂房烟尘扩散规律研究与响应面分析

为研究焊接烟尘在多因素耦合作用下的扩散规律，通过在某小型焊接车间进行实验，将不同温度、湿度、风速3种影响因素进行耦合分析，测定不同环境条件下焊接车间内的烟尘浓度。采用Design Expert软件进行Box Behnken实验设计，构建电焊焊接烟尘浓度在3因素3水平条件下的二次回归响应曲面模型，通过研究二次模型实验因素间交互作用，了解二次项对烟尘浓度影响因素的排序，并简要分析电焊烟尘的治理措施。研究结果表明:温度、湿度、风速3个因素均为显著影响；二次项显示因素影响RhV（相对湿度与风速）>TRh（环境温度与相对湿度）>TV（环境温度与风速）。     

Electrostatic hazards of charging of bedclothes and ignition in medical facilities

We investigated the charge generated on bedclothes (cotton and polyester) during bedding exchange with different humidities and the ignitability of an alcohol-based hand sanitizer (72.3 mass% ethanol) due to static spark with different temperatures to identify the hazards of electrostatic shocks and ignitions occurring previously in medical facilities. The results indicated that charging of the polyester bedclothes may induce a human body potential of over about 10?kV, resulting in shocks even at a relative humidity of 50%, and a human body potential of higher than about 8?kV can cause a risk for the ignition of the hand sanitizer. The grounding of human bodies via footwear and flooring, therefore, is essential to avoid such hazards (or to reduce such risks).     

Suppression of premixed flames with inert particles

Dispersal of inert particles on a flame front is one of the techniques employed to suppress explosions. The current study investigates the influence of micron-sized (75–90 μm) inert (sand) particles on the laminar burning velocity of methane-air premixtures of different equivalence ratios (0.9–1.2) and reactant temperatures (297, 350, 400 K) using a Bunsen-burner type experimental apparatus. When an inert particle interacts with the flame zone, it extracts energy from the flame, thereby acting like a heat sink and hence reducing the flame temperature. Results show that for sand particle size in the range of 75–90 μm, a concentration of 380–520 g/m³ is necessary for extinction of a methane-air flame at ambient temperature. An increase in reactant temperature reduces the heat-sink effect necessitating a higher concentration of sand to extinguish the flame. A mathematical model is developed to generalize the results and make them applicable to a wide range of parameters.     

Experimental investigation and modelling of aluminum dusts explosions in the 20 L sphere

An experimental investigation was carried out on the influences of dust concentration, particle size distribution and humidity on aluminum dust explosion. Tests were mainly conducted thanks to a 20 L explosion sphere. The effect of humidity was studied by storing the aluminum particles at constant relative humidity until the sorption equilibrium or by introducing water vapour in the explosion vessel. The tested particles sizes ranged from a volume median diameter of 7 to 42 μm and the dust concentrations were up to 3000 g m^?3.Among other results, the strong influence of the particle size was pointed out, especially when the Sauter mean diameter is considered. These results stressed the predominance of the specific surface area on the mass median particle diameter.The effect of water on aluminum dust explosion was decoupled: on the one hand, when water adsorption occurs, hydrogen generation leads to an increase of the explosion severity; on the other hand, when the explosion of dried aluminum powder occurs in a humid atmosphere, the inhibiting effect of humidity is put forward.A model based on mass and heat balances, assuming a shrinking core model with chemical reaction limitation, leads to a satisfactory representation of the pressure evolution during the dust explosion.     

硫磺研磨起电特性的研究

工业生产硫磺粉的过程中,由于静电等因素导致生产过程中容易发生燃烧爆炸事故。本文就是为硫磺粉的生产安全进行基础研究。国内硫磺粉爆炸事故几乎一个月发生一次,给设备和人员带来很大的安全威胁。不同材料的特性是不同的,摩擦产生静电的情况也不一样,本实验主要研究硫磺粉和粉碎设备中主要材料摩擦产生静电的情况,了解硫磺粉的静电特性,为减少静电的产生或者消除静电寻找途径。硫磺粉碎设备———机械磨中主要的材料类型是不锈钢、刚玉和碳化钨,用这三种材料制成的研磨罐对硫磺粉进行研磨,测试表明硫磺全部带负电荷,碳化钨罐研磨起电效率最高,刚玉罐起电效果最小,静电量会随着时间的增加达到平衡。用不同粒径的硫磺粉进行研磨,实验表明粒径较大的硫磺粉比粒径小的硫磺粉产生的静电略少。     

Computational fluid dynamics simulation of fog clouds due to ambient air vaporizers

Ambient air vaporizers (AAVs) are widely used to regasify liquefied industrial gases, which are liquefied for transport and storage. Depending on the conditions (temperature and relative humidity) of ambient air and AAV effluent, the potential exists for the formation of fog as the two fluids mix with each other. This has raised some regulatory and environmental concerns that the fog cloud may impact human activities in the vicinity of the AAV arrays.This paper describes a CFD-based modeling approach to predict the formation, dispersion and dissipation of a fog cloud due to AAV operation. The model uses the psychrometrics equations to determine when saturated air conditions are reached and to calculate mass and energy transfer between the moist air and the fog cloud. A parametric study is presented, based on an array of 6 AAVs, to demonstrate the effects of wind speed and AAV discharge elevation on the behavior of the fog cloud.     

不同粒径易自燃煤常温氧化实验研究*

为探究易自燃煤在常温条件下的氧化特性,自行设计煤常温封闭氧化实验装置,采用实验研究与回归分析2种方法,分析易自燃煤发生氧化反应的气体变化过程,探究3种粒径煤样在20 ℃有限空间内的耗氧与产气特征。结果表明:易自燃煤样在16 d常温封闭氧化过程中,容器内O2体积浓度呈指数衰减、CO和CO2体积浓度呈指数增长的变化规律;在0.06~0.83 mm范围内,粒径越大,易自燃煤耗氧速率越大,CO和CO2产生速率则先增大后减小;介于中间的粒径为0.13~0.25 mm易自燃煤氧化反应最强烈,更容易发生氧化。研究结果对揭示生产环境温度下煤粒粒径对煤自燃的影响有一定的意义。     

环境温湿度及风速对消防服热舒适属性影响的定量研究

为量化环境条件对消防服热舒适性能的影响,选取我国02式消防服,测量其在不同环境温度、湿度及风速条件下的热阻和湿阻并得出拟合公式;通过回归分析法分析环境条件对热阻和湿阻的影响,提出其对热阻和湿阻影响的数学模型。结果表明:风速对热阻和湿阻的影响较大,而环境温度和湿度对热阻及湿阻的影响较少;风速与整体热阻及整体湿阻呈负相关,而风速与固有热阻和固有湿阻呈正相关。该研究可为消防服热舒适性能测试及高性能防护装备研发提供理论指导。