挤塑型聚苯乙烯泡沫塑料着火温度实验研究

研究了挤塑型聚苯乙烯(XPS)保温材料两种不同着火方式下的着火温度。采用南京江宁仪器分析厂生产的DW-02型点着温度测定仪对XPS的着火温度进行了测定。利用辐射引燃仪得到了2.2 cm厚挤塑型保温板在不同加热功率下的着火温度。结果表明:DW-02型点着温度测定仪测得的挤塑型聚苯乙烯保温材料的点燃温度约为355℃;热辐射引燃仪测得的2.2 cm厚保温板在不同加热功率下的着火温度是365-370℃,且引燃时间随着辐射引燃仪加热功率的增大而逐渐缩短;明火火源比热流辐射容易引燃挤塑型聚苯乙烯保温板。研究结论对FDS模拟挤塑型聚苯乙烯燃烧特性时,材料热解参数的设定有指引作用,对实际工程中遴选合适的外墙保温材料具有重要的参考价值。     

外墙保温材料在火灾中的燃烧现象小尺寸实验研究

利用外墙保温材料的小尺寸燃烧实验来研究外墙保温材料在火灾过程中的燃烧特性,分析总结外墙保温材料在火灾过程中的燃烧现象.建立外墙保温材料火灾实验模型,对外墙保温材料火灾实验的实验方法以及数据测定方式进行了介绍.采用不同阻燃性质的保温材料,研究阻燃成分阻止竖向燃烧的效果.观察不同的保温材料在燃烧过程中的点燃性能.根据材料的阻燃性能、点火位置、固定方式的不同,总结燃烧痕迹的变化规律.分析非阻燃材料在燃烧的过程中的熔滴生成,发现产生的熔滴对未燃保温材料的点燃现象.观察不同的保温材料在燃烧过程中的烟气生成及烟气层的形成.通过小尺寸火灾试验的方法来研究建筑外墙保温材料火灾的特性,提出使用阻燃型外墙保温材料的必要性.     

电气管廊火场模拟分析与灭火有效性试验研究

针对三种不同尺寸的电气管廊试验环境,开展实体火试验,研究引火源、电缆类型及通风风速等因素对电气管廊火灾温度特性的影响,研究表明,电缆类型及引火源对火灾发展影响较大,通风风速对火灾温度特性产生规律性影响,不同尺寸的电气管廊内温度变化不存在比例关系。细水雾灭火系统可以有效扑灭电缆发热起火及外部火引燃的火灾,数值模拟结果可以较好的预测实体火试验结果。     

防火型家用救生舱舱体热环境与结构优化研究

为优化防火型家用救生舱舱体隔热设计,提出了适用于火灾工况的多重绝热结构设计方法,采用数值模拟和实验的方法研究了防火型家用救生舱舱体的温度分布,分析了12种不同围护结构形式下舱体的绝热保温性能,获得多重绝热结构的最优厚度及绝热材料的最优配比。研究成果可为防火型家用救生舱的隔热设计提供一定的理论支撑和工程设计参考。     

Characterization of Ti powders mixed with TiO2 powders: Thermal and kinetic studies

The fire and explosion risks of metal powders admixed with solid inertants have been extensively investigated for many years. However, it remains unclear why such solid mixtures have high potential fire and explosion risk even when mixed with high percentages of non-combustible solids. This paper investigates how to interpret these risks, from a microscopic perspective, with thermal and kinetic parameters including initial ignition temperature, mass unit exothermic energy, activation energy and risk index of spontaneous combustion. The results show that the initial ignition temperature based on TG (Thermogravimetry) analysis is related to ignition sensitivity, and increased with percentage of admixed solid inertant. The unit mass exothermic energy based on DSC (Differential scanning calorimetry) analysis is related to flame spread velocity. Activation energy and the risk index of spontaneous combustion can be used to explain the reactivity and spontaneous combustion hazard, respectively, of metal powders. We conclude that thermal and kinetic parameters may provide another way to describe the fire and explosion risk of combustible powders, especially for nano metal powders due to the laboratory safety in the normative tests for explosion parameter determination.     

库房火灾事故中弹药热安全性研究

为研究不同火灾条件下弹药发生慢速烤燃的升温速率,以典型地面仓库和舰船舱室火灾为研究对象,建立仿真模型,模拟计算发生火灾时弹药贮存环境的热激源强度及其演化规律,针对发动机在此类环境下的热安全性开展仿真计算,分析其响应规律。研究结果表明：不同火灾条件下弹药慢速烤燃的升温速率有很大区别且往往高于标准慢速烤燃试验常用的升温速率3.3 K/h。随着慢速烤燃升温速率的提高,发动机烤燃点火时间提前,点火时刻发动机中间位置温度下降,两端温度升高,且点火位置向发动机喉部移动。研究结果可以指导弹药库房的设计及弹药安全性增强设计。     

聚苯乙烯外墙保温系统火灾风险影响因素分析

为了研究聚苯乙烯外墙保温系统火灾风险的问题,对比了3种火灾测试方法,分别是基于ISO 5660的小尺寸锥形量热计实验方法、基于ISO 9705的大尺寸实验方法和基于BS 8414的全尺寸实验方法。讨论了3种方法评测外墙保温系统火灾风险的适用性,进一步在比较分析热释放速率、临界热流强度、火蔓延情况、火灾行为以及实验后样品完整性等参数的基础上,得到了影响聚苯乙烯外墙保温系统火灾风险的关键因素。结果表明:虽然空腔的形成在此类系统火灾中不可避免,但系统保护层的严密性和完整性决定了空腔火蔓延的危险性以及聚苯乙烯在系统内的融化流动及燃烧特性。针对聚苯乙烯外墙保温系统火灾风险影响因素,进一步给出了此类系统的防火措施。     

Fire tests on defective tank-car thermal protection systems

Many railway tank-cars carrying hazardous materials are thermally protected from fire impingement by thermal insulation and a steel jacket applied to the outside of the tank-car shell. Over time, it is possible that the thermal insulation will sag, rip, degrade, or be crushed under the steel jacket. A thermographic technique to determine whether or not a tank has insulation deficiencies has been developed, but it is necessary to determine which thermal deficiencies do not affect a tank’s survivability in a fire and which thermal deficiencies must be repaired. In order to develop a guideline in assessing thermal defects, a thermal model and experimental data would be beneficial.A series of fire tests were performed on a quarter-section tank-car mock-up to assist in developing a guideline and to provide validation data for a thermal model. Twelve fire tests, with constant, credible, simulated pool fire conditions, were performed on the tank-car mock-up with various insulation deficiencies. An infrared thermal imaging camera was used to measure the tank wall temperature. The thermal images were useful in determining the temperature profiles across the defects at different times and the transient temperature behaviour at different locations.It was seen that the properly installed thermal protection system significantly reduced the heat transfer from the fire to the tank wall. It was also seen that the steel jacket alone (i.e. 100% defect) acted as a radiation shield and provided a significant level of protection. With small defects, it was observed that the surrounding protected material provided a cooling effect by thermal conduction. A square defect greater than about 40 cm on each side should be considered significant, because unlike smaller defects, there is little benefit from the surrounding material as far as the peak defect temperature is concerned.     

古商业街木结构建筑防火间距的数值模拟研究

古商业街木结构建筑较多,防火间距先天不足,发生火灾后蔓延迅速,有必要开展木结构建筑引燃特性研究以获得合理的防火间距设置参数.以古商业街为研究对象,以临界温度和热辐射强度作为着火建筑对面木结构建筑被引燃的判定指标,综合考虑环境风速、建筑间距、火源功率、喷淋系统等因素,运用火灾动力学模拟软件FDS分析系列火灾场景下的温度和...     

基于锥形量热仪的几种防火布燃烧性能研究

生产企业常在电缆或者贵重高危机器处设置防火布来保护生产设备设施的消防安全,选取五种常用的防火布:石棉纤维防火布、陶瓷纤维防火布、硅胶防火布、涂胶防火布、碳素纤维防火布,通过锥形量热仪实验研究不同辐射强度对防火布燃烧性能的影响。结果表明:点燃时间的均方根倒数与辐射强度之间呈现线性关系;在35 kW/m~2辐射强度工况下,碳素纤维防火布的热释放速率最大,达到272.59 kW/m~2,有效燃烧热的峰值也最大,达到529.52 kJ/g;综合比较各样品的燃烧性能,防火能力强弱顺序为:硅胶防火布石棉纤维防火布陶瓷纤维防火布碳素纤维防火布涂胶防火布。     

东北林区火烧防火线方法研究

火烧防火线在东北林区应用广泛,是预防森林火灾的重要措施.这项工作由于受天气、可燃物、点火技术等各方面因素影响较大,应用时具有一定的风险性.本文针对火烧防火线过程中,用火条件的选择、点火技术的运用以及用火安全等方面加以分析.     

The use of footwear insulation values measured on a thermal foot model.

The use of physiological data from human tests in modelling should consider background data, such as activity, environmental factors and clothing insulation on the whole body. The present paper focuses on local thermal comfort of feet with special attention on the effects of physical changes of footwear thermal properties. An alternative test method is available for footwear thermal testing besides the standard method. The possibility to use insulation values acquired on a thermal foot model in practice is shown here. The paper describes the correlation between cold and pain sensations, and foot skin temperatures of the subjects and relates these to insulation measured on a thermal foot model. Recommendations are made for footwear choice according to environmental temperature.     

高压开关柜阻燃绝缘件在役老化诱发着火事故的综合分析

高压开关柜长期连续运行在高温高湿环境下,内部的阻燃绝缘件会老化而导致性能劣化,进而引起电弧击穿乃至着火事故。为揭示绝缘件样品老化对其击穿与引燃特性的影响机制,针对已在役运行12年开关柜内老化阻燃固封极柱样品和同配方新样品,开展了微观形貌、热重-差示扫描量热、热重-红外光谱和微量燃烧特性综合分析。结果表明：开关柜内的长期电热应力易使环氧树脂绝缘材料的微观结构产生破坏,内部易产生孔洞和裂纹,导致其绝缘性能下降;开关柜内的高温环境易使绝缘材料内部分子链缓慢断裂,导致老化样品更易受热分解;同时,柜内高温高湿环境既可使其材料内部孔隙吸湿而降低绝缘性能,还易导致磷系阻燃剂吸潮氧化,降低其阻燃性能;最后,与新样品相比,12年老化样品在升温初期的燃烧释热更高,一旦形成击穿电弧,更易着火燃烧。研究结果为高压开关柜因绝缘件老化失效而形成击穿起火事故提供了分析要点,并可作为未来更高性能阻燃绝缘件的优化设计依据。     

窗口火作用下建筑幕墙外保温系统防火性能的试验

建筑幕墙外保温系统火灾事故发生频率高,火灾危险性大,其防火安全性能已成为社会关注的焦点。采用大尺度实体火试验方法,选取具有代表性的金属幕墙保温系统和保温装饰板外保温系统作为试验对象,对防火隔离带和防火封堵位于墙体不同位置的4种工况,开展了一系列窗口火试验。通过采集试验表观现象、火焰蔓延特性、温度分布特性、系统损坏特征等耐火性能试验数据,综合比较分析了不同工况下不同燃烧性能等级的建筑幕墙外保温系统的耐火性能。结果表明,建筑幕墙上下贯通的空腔结构加剧了火蔓延的烟囱效应,存在较大的安全隐患。防火封堵可以阻断空腔中的热对流,防火隔离带可以阻隔材料之间的热传导,二者均可以有效抑制火焰在垂直和水平方向上的蔓延,大幅提高建筑幕墙外保温系统的防火性能。在建筑外墙窗口上方、水平线1及水平线2下方20 mm处分别设置宽度为100 mm的防火封堵和宽度为300 mm的防火隔离带时,系统具有较好的防火性能,综合考虑实际工程的应用性和经济性,可将其设为防火构造设计的基准参数。     

Evaluation of CFD simulations of transient pool fire burning rates

Fire is the most commonly occurring major accident hazard in the chemical and process industries, with industry accident statistics highlighting the liquid pool fire as the most frequent fire event. Modelling of such phenomena feeds heavily into industry risk assessment and consequence analyses. Traditional simple empirical equations cannot account for the full range of factors influencing pool fire behaviour or increasingly complex plant design. The use of Computational Fluid Dynamics (CFD) modelling enables a greater understanding of pool fire behaviour to be gained numerically and provides the capability to deal with complex scenarios.This paper presents an evaluation of the Fire Dynamics Simulator (FDS) for predictive modelling of liquid pool fire burning rates. Specifically, the work examines the ability of the model to predict temporal variations in the burning rate of open atmosphere pool fires. Fires ranging from 0.4 to 4 m in diameter, involving ethanol and a range of liquid hydrocarbons as fuels, are considered and comparisons of predicted fuel mass loss rates are compared to experimental measurements.The results show that the liquid pyrolysis sub-model in FDS gives consistent model performance for fully predictive modelling of liquid pool fire burning rates, particularly during quasi-steady burning. However, the model falls short of predicting the subtleties associated with each phase of the transient burning process, failing to reliably predict fuel mass loss rates during fire growth and extinction. The results suggest a range of model modifications which could lead to improved prediction of the transient fire growth and extinction phases of burning for liquid pool fires, specifically, investigation of: ignition modelling techniques for high boiling temperature liquid fuels; a combustion regime combining both infinite and finite-rate chemistry; a solution method which accounts for two- or three-dimensional heat conduction effects in the liquid-phase; alternative surrogate fuel compositions for multi-component hydrocarbon fuels; and modification of the solution procedure used at the liquid-gas interface during fire extinction.     

不同挥发分煤尘层最低着火温度变化规律研究

针对煤化工等行业的沉积煤尘热自燃问题,运用煤尘层最低着火温度测试系统,研究了不同挥发分煤尘层的着火状态、不同挥发分及不同厚度煤尘层最低着火温度的变化规律。结果表明:煤尘层厚度为5 mm时,挥发分质量分数大于35%的煤尘在较低温度便出现着火现象,肉眼很容易观察到火星的出现,温度曲线波动剧烈,而对于挥发分质量分数小于15%的煤尘,通过煤尘层内部"温度达到450℃"来判断其着火;在灰分质量分数相当的情况下,煤尘层最低着火温度随挥发分增加呈严格递减的趋势变化;得到了煤尘层厚度和最低着火温度的函数关系式,通过试验得到了挥发分质量分数为37.45%煤尘的重要常数M和N。     

辐射热流条件下多层电缆着火的数值模拟

通过CFD计算软件对锥形量热燃烧实验条件下的多层电缆着火性能进行数值模拟计算,对比相应CONE电缆燃烧实验结果,其计算结果表明所建立的电缆模型所得计算结果能够较好预测电缆着火时间。在此基础上,对护套层、绝缘层厚度、线芯层直径等参数对着火时间的影响进行了分析,发现护套层厚度对着火时间影响最大,线芯层对着火时间影响较小;当护套层及绝缘层厚度达到一定数值之后,电缆着火时间将不再发生变化。另外,因为电缆由多层热特性各异的材料组成,不能简单的划分为热薄材料或者热厚材料,但就所模拟电缆而言,其着火时间在不同的热辐射强度下分别表现出与热薄材料或者热厚材料相似的变化规律。     

直立型ESFR喷头货架实体火试验研究

为研究直立型ESFR喷头对高架仓库的保护性能以及配水支管对灭火性能的影响,将K202直立型ESFR喷头安装在DN50的配水支管上,在10.5 m净空高度下分别开展5层和6层货架的实体火试验,测量喷头开启时间、开启数量、吊顶下温度、点火位置正上方钢梁温度及货品烧损量等试验参数。结果表明:不超过3只的ESFR喷头会在火灾初期迅速启动,喷头启动后,火势得到快速抑制,整个试验过程中火均未蔓延至邻排货架。K202直立型ESFR喷头能有效保护储物为箱装不发泡塑料的高架仓库,外径不超过60 mm的配水支管或类似的障碍物对直立型ESFR喷头灭火性能无明显影响。     

番龙眼木的热分解失重及动力学研究

木材热解是木材类火灾事件的先导过程,是引起后续的阴燃、着火、燃烧和火焰蔓延等各种现象的重要因素,因此研究木材的热解非常重要。采用热重分析法对番龙眼木的热重特性及反应动力学进行研究。在空气气氛下,研究样品粒径、试验气氛和升温速率对番龙眼木热解特性的影响。对番龙眼木的热解反应过程的分析,采用Flynn-Wall-Ozawa积分法、Kissinger最大速率法和atava-esták积分法对动力学进行处理。试验得到了一些热解动力学的参数,并推断出不同温升速率下番龙眼木的动力学最概然机理方程为反应级数函数,n=4     

森林自燃火灾中的凋落物辐射升温特性研究——以岳麓山为例

为研究森林火灾的凋落物辐射升温特性,设计一套森林凋落物温升速率测定实验装置,从岳麓山采样并通过辐射加热实验观察凋落层内部各点温升状况,采用红外热像仪辅助拍摄着火过程。分析处理7组不同月份的实验数据,获得森林凋落物的温时曲线、温度关联曲线,并建立温升速率关于含水率与表观密度的关联方程。研究表明:温升初期横向温升速率高于纵向温升速率,着火时刻附近纵向温升速率快于横向;岳麓山森林凋落物着火温度区间为340～350℃,在本实验条件下平均着火时间为420 s;各测点温升规律一致,热源基点处达到着火点时的周围温度在200℃左右。