Inputs and fates of petroleum hydrocarbons in a subtropical marine estuary

Inputs and fates of petroleum from a higly urbanized area to a subtropical marine estuary were investigated by measuring hydrocarbon concentrations in municipal wastewater treatment plants, urban stormwater drains, sediments, and benthic organisms in and around Tampa Bay, FL. The concentrations of petroleum hydrocarbons discharged from secondary and tertiary treatment plants in this area were lower than concentrations previously reported for other treatment plants in temperate regions. Samples collected from urban storm drains under base flow conditions were also low. The generally low levels of petroleum hydrocarbons in the sediments and organisms throughout Tampa Bay suggest that the bay is relatively pristine with respect to petroleum hydrocarbon contamination. Since it is unlikely that the anthropogenic input of hydrocarbons to this estuary is significantly lower than in other urbanized areas, we suggest that elevated annual temperatures in this subtropical system result in increased metabolic rates of microorganisms and more rapid degradation or metabolism of the petroleum hydrocarbons.     

Assessment of marine pollution in Izmir Bay: nutrient, heavy metal and total hydrocarbon concentrations

Izmir Bay (western Turkey) is one of the great natural bays of the Mediterranean. Izmir is an important industrial and commercial centre and a cultural focal point. The main industries in the region include food processing, oil, soap and paint production, chemical industries, paper and pulp factories, textile industries and metal processing. The mean concentrations showed ranges of 0.01-0.19 and 0.01-10 microM for phosphate, 0.10-1.8 and 0.12-27 microM for nitrate+nitrite, and 0.30-5.8 and 0.43-39 microM for silicate in the outer and middle-inner bays, respectively. The TNO(x)/PO(4) ratio is significantly lower than the Redfield's ratio and nitrogen is the limiting element in the middle-inner bays. Diatoms and dinoflagellates were observed all year around in the bay and are normally nitrogen limited. Metal concentrations ranged between Hg: 0.05-1.3, Cd: 0.005-0.82, Pb: 14-113 and Cr: 29-316 microg g(-1) in the sediments. The results showed significant enrichments during sampling periods from Inner Bay. Outer and middle bays show low levels of heavy metal enrichments except estuary of Gediz River. The concentrations of Hg, Cd and Pb in the outer bay were generally similar to the background levels from the Mediterranean. The levels gradually decreased over the sampling period. Total hydrocarbons concentrations range from 427 to 7800 ng g(-1) of sediments. The highest total hydrocarbon levels were found in the inner bay due to the anthropogenic activities, mainly combustion processes of traffic and industrial activities. The concentrations of heavy metals found in fish varied for Hg: 4.5-520, Cd: 0.10-10 and Pb: 0.10-491 microg kg(-1) in Izmir Bay. There was no significant seasonal variation in metal concentrations. An increase in Hg concentration with increasing length was noted for Mullus barbatus. A person can consume more than 2, 133 and 20 meals per week of fish in human diet would represent the tolerable weekly intake of mercury, cadmium and lead, respectively, in Izmir Bay. Heavy metal levels were lower than the results in fish tissues reported from polluted areas of the Mediterranean Sea.     

横沙岛潮滩沉积物中重金属的空间分布与累积

长期以来,长江流域的工农业及城市生活排污一直没有得到有效的控制,这必将对下游河口地区的生态环境造成直接或潜在的威胁。因此,针对横沙岛目前的潮滩环境进行研究,并就潮滩质量和发展趋势进行评价非常必要。通过对横沙岛潮滩表层沉积物中重金属元素空间分布与累积的统计学分析,得知横沙岛潮滩环境总体比较清洁,但多年来受城市工业废水和生活污水排放,以及城市汽车尾气和工业粉尘干湿沉降的影响,局部地区表现出较严峻的污染形势,Cu、Zn、Cr、Pb的最高浓度分别达到背景值的2.34、4.24、2.74和1.63倍。通过对潮滩表层沉积物粒度和有机质含量的分析,指出水动力条件、潮滩生物活化作用是影响重金属空间分布和累积的主要因素。     

Historical changes in the food and water supply systems of the New York City Metropolitan Area

The history of New York City (NYC) is much shorter than those of most European cities, but New York shares in common the problem of providing sufficient water and food to its inhabitants from its watershed and foodshed. These resource provision areas have grown over time and changed in character as they expanded in tandem with the growth of the city. In contrast to some cities, such as Paris, which historically has been supported by local food production, NYC??s status as a trade center has enabled the supply of food from distant sources from early in its history. NYC??s transportation system has rapidly evolved from early roads to canals, railroads, and modern surface and air transport networks. The development of the hydraulic engineering of the City??s reservoir, aqueduct, and tunnel system determined the extent of its water supply watersheds. Deviations from general growth trends in food and water consumption have occurred due to environmental and economic disruptions. As the growth of the city slowed in the last few decades, environmental technology has reduced the impact of the City on its environment, due to water metering, reduction of leakage, and improvements in waste treatment. However, per capita food consumption in the US continues to increase, with implications for the environmental health of New York and its region, as well as other centers of net anthropogenic nutrient inputs.     

Towards a clean Izmit Bay

The elongated semi-enclosed Bay of Izmit, which receives both domestic and industrial wastes, has been monitored by measuring its physical and biochemical parameters for 2 years, 1994-1995. It is clear that there are two distinct water masses. The upper layer has been occupied by the less saline (22-26 ppt) waters of the Black Sea origin; whereas the lower layer contains saline (38.5 ppt) Mediterranean waters. The seasonal variations in the biochemical characteristics were dependent on the bay's two-layer flow system. If one considers the distribution of transparency in the upper bay waters, it has been observed that the Secchi disk depth (SDD) decreases from west to east. Furthermore, these depths are limited by the high primary productivity associated with the low concentrations of nutrients observed during the spring. Discharges of wastes into the surface waters significantly affect the biological production and oxygen consumption in the lower layer. Within the last 10 years, 80% of organic matter has been removed from industrial wastewater. However, organic loads from the domestic wastewaters have doubled because of the growth in the surrounding population. Fortunately, as a result, the total organic loads in the bay have not changed significantly within the last 10 years.     

Anthropogenic influence on the water quality in Guanabara Bay, Rio de Janeiro, Brazil

Guanabara Bay is a 384-km² coastal bay with 70% of the population of the metropolitan area of Rio de Janeiro located within its drainage basin. The water quality of the Bay is impacted by domestic and industrial runoff, of which only 15% has been adequately treated. However, based on a 14-year monitoring program, the water quality for most of Guanabara Bay remains acceptable because of intense tidal flushing, and we failed to find a worsening of conditions during the 14-year study. The inner shallow regions of the Bay, the western and northwestern parts, receive most of the drainage from metropolitan Rio de Janeiro. It is here that the water quality is alarmingly poor, characterized by hypertrophic conditions and occasional hypoxic events. Fecal coliform counts in these inner reaches of the Bay are 4–100 times higher than the maximum acceptable count for recreational waters. Hypertrophic conditions prevail in Guanabara Bay, which is characterized by low dissolved oxygen, high biochemical oxygen demand, peaks in fecal coliform, and extremely high chlorophyll-a concentrations, which reflect high quantities of nutrients entering the system. These anthropogenic pressures are a threat to planktonic and benthic communities and are reminiscent of San Francisco Bay 30 years ago. The Guanabara Bay water quality could be returned to pre-1950 conditions, but it would require sufficient political will and economic investment to ensure that at least 80–90% of the domestic and industrial sewage were treated adequately. Electronic Publication     

Monitoring of eutrophication and nutrient limitation in the Izmir Bay (Turkey) before and after Wastewater Treatment Plant

The distribution of inorganic nutrients and phytoplankton chlorophyll-a was investigated and N/P ratios were determined in Izmir Bay during 1996-2001. The average concentrations showed ranges of 0.01-0.19 and 0.01-10 microM for phosphate-phosphorus; 0.11-1.8 and 0.13-27 microM for (nitrate+nitrite)-nitrogen, 0.30-4.1 and 0.50-39 microM for silicate and 0.02-4.3 and 0.10-26 microg l(-1) for chlorophyll-a in the outer and middle-inner bays, respectively. The results are compared with the values obtained from the relatively unpolluted waters of the Aegean Sea. The N/P ratio is significantly lower than the assimilatory optimal (N/P=15:1) in conformity with Redfield's ratio N/P=16:1. Nitrogen is the limiting element in the Izmir Bay. Phosphate, which originates from detergents, is an important source for eutrophication in the bay, especially in the inner bay. In early 2000, a Wastewater Treatment Plant (WTP) began to treat domestic and industrial wastes. This plant treats the wastes about 60% capacity between 2000 and 2001. The sampling periods cover before and after treatment plant. Although the capacity of wastewater plant is sufficient for removal of nitrogen from the wastes, it is inadequate for removal of phosphate. This is also in accordance with the decreasing N/P ratios observed during 2000-2001 (after WTP) in the middle-inner bays.     

滇池福保湾底栖硅藻的时空分布

为了揭示入湖河流的污染负荷对滇池福保湾沿岸带底栖硅藻群落的影响,在不同季节采集研究了该湖湾6个样点的底栖硅藻样品,分析其群落结构的物种组成、细胞密度和多样性指数等。研究发现：东部沿岸区在调查期间的大多数月份是极小曲壳藻（Achnanthes minutissima）占绝对或主要优势,其相对丰富度最高可达79.5%;在1~7月份,西部沿岸区的优势种类主要是异极藻属（Gomphonema〖WTBZ〗 spp.）,污染最为严重的河口区是耐污性的具柄双眉藻〖WTBX〗（Amphora pediculus）和两栖菱形藻（Nitzschia amphibia）占优势,而在调查的中后期,极小曲壳藻逐渐发展为这两区的优势种类。同时发现底栖硅藻密度随着与河口间距离的增加而逐渐升高。以上结果表明入湖河流的污染负荷对受纳湖湾底栖硅藻的密度和时空变化有较大影响。     

环杭州湾“葡萄串”式组合城市研究

环杭州湾上海、杭州、宁波等六城市 ,城市之间社会、经济相互联系密切 ,交通等基础设施日益完善 ,特别是杭州湾大桥的建设 ,形成了沪、杭、甬之间的两小时交通“金三角”区。当今世界城市群、城市带、城市圈在各地兴起 ,杭州湾地区完全有可能形成环杭州湾“葡萄串”式组合城市。本文在分析杭州湾城市发展现状和城市组合重要作用的基础上 ,提出了环杭州湾组合城市空间布局的设想。     

History of the urban environmental imprint: introduction to a multidisciplinary approach to the long-term relationships between Western cities and their hinterland

This paper introduces a series of 11 studies on the relationships between large Western cities (Paris, London, Brussels, Vienna, Barcelona, Athens, New York, Providence) and their surrounding territories over a long historical time period. The concept of hinterland is introduced to designate a rural territory structured by its function of supplying the city with food, fuel, water and other material. The papers question the usefulness of this concept in the current globalized world, where cities are often considered as simple nodes of a network of worldwide trade exchanges, but where new citizen aspirations for reconnecting urban and rural territories are emerging.     

武汉市工业“三废”污染状况计量模型研究

根据武汉市1987~2003年经济状况（以人均GDP表示）与工业“三废”污染物排放量的统计数据，借助SPSS和EXCEL软件系统，分析了人均GDP与工业“三废”污染物排放量之间的相关关系,并建立了两者之间的计量模型。通过研究发现：武汉市工业“三废”污染物（如工业废水、工业废水中的Cr+6、工业废气中SO2、工业粉尘和工业固废等排放量，工业固体废弃物产生量）除工业固体废弃物产生与排放量在EKC曲线的左边、还处于两难区间外，其余的曲线已过或正处于EKC转折点，说明武汉市工业“三废”污染状况开始向良性化方向发展。在武汉市环境没有遭到完全破坏、资源没有完全耗竭时，根据研究结果， 进行了“烫平”武汉市工业“三废” 排放量EKC曲线走势的可行性分析。     

The energy consumption of Paris and its supply areas from the eighteenth century to the present

Since the eighteenth century and the industrial revolution, cities have experienced great changes in their metabolism, and particularly in their energy consumption: transitions from one energy source to another, growing per capita consumption, and total consumption to cite but a few. These changes also impact urban energy supply areas and supply distance. This paper estimates Paris??s energy demand in both final and primary terms since the eighteenth century and gives an illustration of long-term socio-ecological interactions in an interdisciplinary perspective, connecting energy flow analysis, and historical research. It gives an overview of energy supply areas and assesses the distance between supply sites and the city. Paris??s annual total energy requirement (TER) was about 19?GJ per capita at the beginning of the eighteenth century and reached 30?GJ per capita in 1800; the supply area remained nearly the same with an average supply distance (D_avg) of 200?km. During the nineteenth century, Paris??s population increased fivefold, and energy transitioned from biomass to fossil fuel. Per capita TER remained stable, whereas Paris??s supply area moved progressively toward coal basins, in connection with the tremendous change in transport systems. As a consequence, the D_avg grew to 270?km around 1870. During the twentieth century, and especially since the Interwar period, per capita TER increased considerably (to 26?GJ/cap/year in 1910, 47?GJ/cap/year in 1946 and 126?GJ/cap/year in 2006). The internationalization of the energy supply and the shift to petroleum and natural gas also increased the remoteness of the supply sites: the D_avg equaled 3850?km in 2006.     

The pollution status and the toxicity of surface sediments in Izmit Bay (Marmara Sea), Turkey

Izmit Bay is one of the most polluted and populated enclosed sea in Turkey. It has been the centre of industrial activities for the last 30 years. Seven major sources enter the bay waters along the north coastline of the bay. This investigation forms part of continuing ecotoxicology studies in the Izmit Bay designed to constrain and minimise the pollution caused by flourishing industry and a growing population. Sediments sampled from the mouths of the major discharges of Izmit Bay were analysed for their organic carbon, total polycyclic aromatic hydrocarbon (t-PAH) and trace inorganic element (Cd, Al, As, Pb, Hg and Cu) contents and compared with those found in the sediments from the reference station in the outer bay (in the Marmara Sea). The toxicity of sediments was determined in the bulk and elutriate samples by using algal (Phaeodactylum tricornutum) batch bioassays. Chemical data showed that the sediments collected from the inner sites of the bay have been contaminated with Cd, Hg, As and PAHs. Organic carbon contents were also found higher. All the major industrial discharges into the bay are now biologically treated but bioassays performed with bulk sediments revealed that the recent sediments are toxic to the microalgae throughout the bay. The results are consistent with the previous toxicity studies performed with the industrial discharges.     

Problems of urban environment: A case study of Jodhpur,India

This paper attempts to analyze the environmental problems of Jodhpur city in terms of air quality, water supply, wastewater disposal, and solid waste management. Maps have been prepared to show the boundaries of municipal circles responsible for the disposal of solid wastes. Areas of comparatively higher degrees of air pollution have also been demarcated on the maps. The daily output of urban refuse and the intensity of urban refuse for wards within Jophpur's walled city versus for wards outside the walled city have been cartographically depicted.     

Medieval London and its supply hinterlands

The essay reviews the impact of London??s demands for food, drink and fuel on the farming systems and specialisation in the regions from which it drew supplies. Focusing on the well-recorded period around 1,300, when London was a major but second-ranking European city, it makes comparisons with other European cities in the same period and with London in later centuries, as the city developed a world role. Despite its small size by modern standards, medieval London??s impact on its hinterland was distinct, dynamic, highly commercialised and extensive. It shaped rural landscapes and agrarian practices in ways which in key respects conform to modern theories of spatial specialisation. London??s environmental influence operated within an international context, where the opening up of distant resources could affect choices concerning specialisation in and close to the city. Demographic change and shifts in consumption arising from changing standards of living were also influential. This left a marked ??urban footprint?? in production, marketing and the generation of waste. Moreover, its distinctive political context influenced London??s attitude towards managing its supply chains, differentiating it from many of its European counterparts. Medieval observers recognised those landscapes and their connection with the city, but did not theorise them in present-day terms.     

城市水源地建设中的水权交易理论与实践述评

水源地是城市水资源可持续供给的重要空间载体。伴随城市化的快建发展，城市水资源供求压力日起紧张，城市水源地在保障城市水资源可持续供给方面的作用日益突出。本文从城市化过程中的水资源需求变化出发，揭示水源地在城市可持续发展中的战略地位，评析我国水桓交易的理论研究进展，在此基础上提出我国城市水源地建设保护过程中水权交易的走势判断。     

Comparative sediment quality assessment in different littoral ecosystems from Spain (Gulf of Cadiz) and Brazil (Santos and São Vicente estuarine system)

The goal of this work was to establish comparisons among environmental degradation in different areas from Southern Spain (Gulf of Cádiz) and Brazil (Santos and S?o Vicente estuary), by using principal component analyses (PCA) to integrate sediment toxicity (amphipods mortality) and chemical-physical data (Zn, Cd, Pb, Cu, Ni, Co, V, PCBs, PAHs concentrations, OC and fines contents). The results of PCA extraction of Spanish data showed that Bay of Cádiz, CA-1 did not present contamination or degradation; CA-2 exhibited contamination by PCBs, however it was not related to the amphipods mortality. Ría of Huelva was the most impacted site, showing contamination caused principally by hydrocarbons, in HV-1 and HV-2, but heavy metals were also important contaminants at HV-1, HV-2 and HV-3. Algeciras Bay was considered as not degraded in GR-3 and -4, but in GR-3' high contamination by PAHs was found. In the Brazilian area, the most degraded sediments were found in the stations situated at the inner parts of the estuary (SSV-2, SSV-3, and SSV-4), followed by SSV-6, which is close to the Submarine Sewage Outfall of Santos - SSOS. Sediments from SSV-1 and SSV-5 did not present chemical contamination, organic contamination or significant amphipod mortality. The results of this investigation showed that both countries present environmental degradation related to PAHs: in Spain, at Ría of Huelva and Gudarranque river's estuary areas; and in Brasil, in the internal portion of the Santos and S?o Vicente estuary. The same situation is found for heavy metals, since all of the identified metals are related to toxicity in the studied areas, with few exceptions (V for both Brazil and Spain, and Cd and Co for Brazilian areas). The contamination by PCBs is more serious for Santos and S?o Vicente estuary than for the investigated areas in Gulf of Cádiz, where such compound did not relate to the toxicity.     

基于演化树模型的长江三角洲城市紧凑度综合评价

紧凑城市是一种高效的城市空间组织模式,对实现城市可持续发展战略具有重要意义。通过密度、规模、结构和强度维度建立紧凑城市四维理论模型,并以此为基础构建由4个二级指标和12个三级指标组成的城市紧凑度综合评价演化树模型。通过对长江三角洲16个核心城市实证分析,评价结果显示：整体城市紧凑度下降,且影响紧凑度因素存在区际差异;在空间上,紧凑城市大致呈现沪杭甬沿线高于南北两翼的空间格局;从演化过程上分析,城市紧凑度与城市发展阶段发展水平具有一定的关联性,城市化率和产业结构与城市紧凑度呈现显著正相关。近年来开发区分散建设、城市建设用地面积扩张等因素是造成长三角城市紧凑度下降的重要原因,交通、医疗等公共服务设施投入不足、分布不均及政府有限的约束力也在一定程度上制约城市的紧凑发展模式。因此,需要在未来加强协调市场和政府两种力量以推动城市发展的高效高质     

City surface solid waste in Nigerian cities

Within the last few years, uncleared solid wastes, in the form of heaps, have become a common sight in many Nigerian streets and open spaces. In order to assess the magnitudes of these wastes, a survey of selected 15 Nigerian cities was conducted for 2 months in 1982 with a team of 116 enumerators. It was found that the volumes of these uncleared wastes ranged from about 2 × 10⁶ kg/yr to as high as 56 × 10⁶ kg/yr in the cities studies. It was also found that the areas within a radius of 0.5 km of the city centres accounted for about 40% of these uncleared volumes of solid wastes.As distances increased from the city centres, the volumes of these wastes tended to decline. Therefore, it was determined that the main problem areas for uncleared solid wastes are in and around the city centres. These areas should demand special attention by city waste disposal agents.     

Natural and anthropogenic hydrocarbon inputs to sediments of Patos Lagoon Estuary, Brazil

The Patos Lagoon Estuary, southern Brazil, is an area of environmental interest not only because of tourism, but also because of the presence of the second major port of Brazil, with the related industrial and shipping activities. Thus, potential hydrocarbon pollution was examined in this study. Sediment samples were collected at 10 sites in the estuary, extracted, and analyzed by GC-FID and GC-MS for composition and concentration of the following organic geochemical markers: normal and isoprenoid alkanes, petroleum biomarkers, linear alkylbenzenes (LABs), and polycyclic aromatic hydrocarbons (PAHs). The total concentrations varied from 1.1 to 129.6 microg g(-1) for aliphatic hydrocarbons, from 17.8 to 4510.6 ng g(-1) for petroleum biomarkers, from 3.2 to 1601.9 ng g(-1) for LABs, and from 37.7 to 11,779.9 ng g(-1) for PAHs. Natural hydrocarbons were mainly derived from planktonic inputs due to a usual development of blooms in the estuary. Terrestrial plant wax compounds prevailed at sites located far from Rio Grande City and subject to stronger currents. Anthropogenic hydrocarbons are related to combustion/pyrolysis processes of fossil fuel, release of unburned oil products and domestic/industrial waste outfalls. Anthropogenic hydrocarbon inputs were more apparent at sites associated with industrial discharges (petroleum distributor and refinery), shipping activities (dry docking), and sewage outfalls (sewage). The overall concentrations of anthropogenic hydrocarbons revealed moderate to high hydrocarbon pollution in the study area.