基于改进型灰色神经网络组合模型的空气质量预测

基于空气质量数据不足及波动较大的情况,将灰色GM（1,1）模型与人工神经网络模型组合并改进,建立改进型灰色神经网络组合模型。利用天津市2001—2008年PM10、SO2和NO2年均值作为原始数据预测2009—2010年PM10、SO2和NO2的浓度以进行模型精度检验,最后利用该模型预测2011—2015年天津市空气质量状况。结果表明,与灰色GM（1,1）模型、传统灰色神经网络组合模型相比,所建立的改进型灰色神经网络组合模型相对模拟误差小,预测结果更为可靠,可以用于空气质量预测。     

基于STIRPAT模型和Tapio脱钩模型的废水排放驱动因素研究——以重庆市为例

利用重庆市2000—2015年废水年排放量及社会经济统计数据,根据STIRPAT模型,通过相关性分析和岭回归分析获得人口数量、城镇化率、财富水平、COD年排放量、非第三产业占比与废水年排放量的关系,并采用Tapio脱钩模型界定人均GDP与废水年排放量之间的关系。结果表明:导致废水年排放量变化的3个主要驱动因素为财富水平、COD年排放量和人口数量;在观测时段内,重庆市存在"倒U"型环境库兹涅茨曲线。对重庆市废水年排放量进行分解,发现重庆市废水年排放量较为稳定,工业废水年排放量呈缓慢下降的趋势,而生活废水年排放量呈逐步上升的趋势,并逐渐成为重庆市废水排放的主要来源;重庆市经济增长与工业废水年排放量处于强脱钩与弱脱钩交替状态,而经济增长与生活废水年排放量始终处于弱脱钩状态。     

基于水质污染风险识别的人工湖需水研究

人工湖需水量是指维持湖区水量平衡、满足人工湖水质目标的供水量,人工湖需水量确定是人工湖水体工程设计的主要内容之一。以上虞滨海新城建设的人工湖为例,分析了人工湖建成后的可能污染源,采用TP质量守恒模型,预测了不同生活污水截污率、生态措施作用前后的人工湖需水量及水质要求。结果表明,当生活污水截污率为100%时,若供水TP≤0.10mg/L,则人工湖需水量为240万t/a;当生活污水截污率为95%时,若供水TP=0.05mg/L,不考虑生态措施作用,则人工湖需水量为1 600万t/a;当生活污水截污率为95%时,若供水TP=0.05mg/L,在生态措施作用下人工湖需水量为730万t/a。     

黄河入海口水质评价与预测

对黄河入海口2004-2011年的水质进行评价与预测,采用灰色聚类法分析水体DO、CODMn、NH3-N 3项指标,总结水质年均变化情况.建立水质GM(1,1)灰色预测模型,用实际水质指标值检验其精度,并用此模型预测未来4年水质变化趋势.结果表明,2004-2015年期间,黄河入海口水质在2004-2007年波动较大,但将越来越好,CODMn、NH3-N呈下降趋势,DO、达标率呈上升趋势,并通过灰色关联分析方法分析水质变化原因以期对黄河入海口水质分析预测与水体保护工作提供参考.     

天津市工业源挥发性有机物排放清单及区域分布研究

基于典型工业企业自主申报数据,采用排放因子法,建立了天津市工业源VOCs排放清单。经计算,天津市2014年工业源VOCs排放量为16.52万t,其中VOCs生产环节、储运和运输环节、以VOCs为原料的工艺过程、含VOCs产品的使用和排放环节以及其他环节的VOCs排放量分别为12.94万、0.07万、0.63万、1.80万、1.08万t,对天津市工业源VOCs排放总量的贡献率分别为78.33%、0.42%、3.81%、10.90%、6.54%。滨海新区工业源VOCs排放量最大,对天津市工业源VOCs排放总量的贡献率达88.25%,其中大港、临港经济区和天津经济技术开发区为滨海新区工业源VOCs排放的主要功能区。     

A/O工艺处理城市生活工业综合污水的耐受性研究

针对目前城市污水处理厂进水水质以生活污水为主转向以难生物处理的工业废水为主的现状,进行了A/O工艺的耐受性试验.结果表明:随着工业废水比例的增加,厌氧、好氧污泥活性都显著下降,厌氧污泥的耐受性较高;随着运行时间的延长,两类污泥的活性逐步得到不同程度的恢复;工业废水比例越高,活性恢复所需时间越长;两类污泥的协同代谢作用保证了出水效果.A/O工艺所能耐受的进水中制药废水、印染废水和生活污水的分配比(体积比)为3∶3∶4.     

燃煤工业锅炉大气污染物控制方案研究

基于中国燃煤工业锅炉大气污染物排放及治理现状,并结合国家相关产业政策和国内外技术发展趋势,以2008年为基准年,分析测算了2015、2020年燃煤工业锅炉大气污染物排放量,提出了适合中国国情的燃煤工业锅炉大气污染物控制技术路线.依据研究的控制方案,2015年,烟尘、二氧化硫及氮氧化物排放量分别为507万、458万、230万t;2020年,烟尘、二氧化硫及氮氧化物排放量分别为491万、423万、269万t.与2008年相比,大气污染物排放量变化不大,基本上做到了增容不增污.在此基础上,提出了燃煤工业锅炉大气污染物防治建议.     

武清县地区地下水中有机污染物研究

随着城市建设和工业的发展,大量的生活污水和工业废水排放到环境水体中,污水中的有毒、有害组分的有机物也随之带入水体. 北京是首都,人口密集、工业集中且门类繁多,城市污水总量为14.25亿方/年,其中工业污水占60％. 北京排污河为承担北京市污水排放而人     

保障城镇生活COD减排的污水处理程度及投资预测

城镇生活COD排放量的持续增加直接加大了COD减排压力,更加大了工业COD的减排压力.因此,加强城镇生活COD减排,预测其所需的污水处理设施及投资至关重要.按照2006-2010年城镇人均生活污水排放量年均递增率设置4种情景,预计为满足减排要求,2010年城市生活污水处理率约为67%～71%,城市环境基础设施建设投资可能达到2 000亿元.     

北方城市分季节SO_2允许排放量分配技术方法

北方城市采暖季和非采暖季污染源排放特征以及气象扩散条件具有显著差异,针对不同季节污染状况,利用排放绩效法,结合Calpuff环境空气质量模型建立了分季节SO2允许排放量分配技术方法,并以乌鲁木齐市为例进行应用,对2012年SO2分季节的允许排放量进行核算。结果表明,SO2年允许排放量为8.8×104 t,削减率为27.4%。其中采暖季电厂燃煤源、工业燃煤源的SO2允许排放量分别为0.99×104、2.3×104 t,非采暖季电厂燃煤源和工业燃煤源的SO2允许排放量分别为1.3×104、4.2×104 t,结果能满足乌鲁木齐市"总量减排和环境质量双达标"的要求。与传统方法相比,分季节核算污染物允许排放量能更好地实现环境容量的优化配置,引导企业合理地进行工业产量的季节分配。     

Real-time wastewater monitoring as tool to detect clandestine waste discharges into the sewage system

The entry of illegally discharged waste into the sewage system can cause serious damage to sewage pipes and harm the public domain. Besides industrial and communal sources, discharges from clandestine laboratories are of special forensic interest. Aim of this study is to investigate the possibility to detect clandestine discharges of possibly hazardous waste directly at the point of discharge. Tests were performed at a facility where real wastewater was pumped in a controlled way through an open sewage pipe above ground. Chloride, ammonia, pH and conductivity electrodes were investigated for their ability to detect discharges of different types of waste. Waste samples were diluted up to 50 times in a static wastewater environment and pH, conductivity and chloride electrodes were able to distinguish all waste dilutions from blank wastewater. These three electrodes were then used for dynamic tests by placing them inside flowing sewage water and discharging different types of liquid waste ten meters upstream of them. Parameters of the waste discharges like volume, time interval and speed of discharge were varied and the responses of the electrodes were collected. The dynamic tests showed that these three electrodes were able to pick up different waste discharges in a real wastewater environment. It was found that a high sampling rate of the sensors would be required to connect a certain discharge to a specific household connection. These findings highlight the possibility to locate illegal discharges, coming from a variety of sources, using the waste discharge itself.     

浙江农村生活污水处理设施水污染物排放标准修订需求分析与建议

以浙江《农村生活污水处理设施水污染物排放标准》(DB33/973—2015)的修订为研究切入点,对比了现行标准与国家和浙江农村生活污水治理的管理要求,分析了浙江农村生活污水处理现状并梳理其他省(自治区、直辖市)标准情况.研究发现DB33/973—2015已不符合浙江实际情况且不能满足浙江对农村生活污水的管理需求,必须开...     

Spatiotemporal coupling measurement of industrial wastewater discharge and industrial economy in China

With the industrial-level panel data on total output and wastewater discharge over the period of 1997 to 2018, this paper employs GIS and ESDA methods to empirically investigate the spatial relationship between industrial total output and wastewater discharge. In this paper, we empirically examine whether and how industrial wastewater discharge in a particular province may affect the wastewater discharge in its neighboring provinces. Results suggest that provinces (municipalities) with large-scale industrial sewage discharge are located along riversides and coastal areas and these discharges then gradually distribute to coastal, central, and western areas. Results also show a strong spatial autocorrelation of industrial wastewater discharge between the observed local province and its neighboring provinces which is increasing over time. In addition, there is also a significant spatial spillover effect of industrial wastewater discharge among neighboring provinces in China’s eastern and central regions, indicating a structural convergence of high-pollution industries.

     

China’s industrial gray water footprint assessment and implications for investment in industrial wastewater treatment

Industrial wastewater is the largest contributor of toxic pollutants and third-largest contributor of nutrients to bodies of water in China, and understanding the characteristics of such pollution is important for water pollution control. In this study, the industrial gray water footprint (GWF) of each industry sector in China’s 31 provinces in 2015 was calculated to identify the pollution characteristics of industrial wastewater discharge and determine how to efficiently allocate investment to pollution reduction. We show that the total industrial GWF of China was 300 billion m³ in 2015 and that the major pollutants were petroleum pollutant (PP), ammonia nitrogen (NH₃-N), volatile phenol (VP), and chemical oxygen demand (COD). The water pollution level (WPL) was higher than 1 in Ningxia, Shanxi, Hebei, Tianjin, Shanghai, Henan, and Shandong, indicating that industrial pollution exceeded the carrying capacity of local water bodies in these seven regions. Given equivalent total investment, a scenario that takes the total reduction of the industrial GWF weighted by the WPL in each region as the investment target can better allocate funds to control industrial wastewater pollution in regions with high WPLs relative to a scenario in which investment targets the reduction of the unweighted total industrial GWF. For further industrial GWF reduction in regions with high WPLs, it is crucial to adjust the industrial structure and to upgrade relevant technologies.

     

Evaluation of adverse biological effects induced by pollution in the Bilbao Estuary (Spain)

The physical nature of the Bilbao Estuary (Spain) has been highly modified since the end of the last century, mainly by means of dyking, canalization, and dredging to meet the needs of navigation. Together with its industrial use, the estuary is also used for the disposal of domestic sewage. Until the completion of a sewerage plan in the year 2002, the sewage of about 1 million people and the wastes from industries will continue to be discharged into this 15-km-long estuary with a limited freshwater flow of 25 m(3) s(-1). An abrupt decrease in faunal abundance followed by defaunation characterized the biotic response to the disturbance in almost three-quarters of its tideway. Relationships between biotic and environmental variables were investigated using the BIO-ENV procedure of the PRIMER computer package. Gross organic enrichment, water oxygen depletion and anaerobic sediment conditions appear to be the dominant anthropogenic influences on the Bilbao Estuary. It is concluded that the level of wastewater discharges into the estuary may substantially drop below that concentration which assures the protection and propagation of native heterotrophic resources within sediments. Biological monitoring is thus essential to assess the efficacy of the sewerage plan promoted by the local Water Authority.     

炼油厂汽提废水预处理工业试验

炼油厂汽提废水含较高浓度的酚 ,会对污水处理场产生冲击。采用上流式曝气生物滤池对废水进行预处理工业试验 ,取得了满意的试验结果 :出水酚浓度低于 9.0mg/L ,酚降解率 >90 % ,完全可以消除它对污水处理场的冲击。并通过工业试验为工艺设计和工业运行确定了有关参数和运行条件。     

活性污泥法处理味精厂废水的工艺优化

经过总结与改进武汉味全食品有限公司近 5年污水处理工艺、设备 ,结果表明 ,经过增加三级曝气池、罗茨鼓风机等工艺改进 ,SS由 132mg/L降为 112mg/L ;NH3 N由 119mg/L降为 37 6mg/L ;Ar OH由 0 0 1mg/L降为 0 0 0 9mg/L ;BOD5由 5年前的 34 6mg/L降为现在的 2 1 2mg/L ;COD由 5年前的 117mg/L降为现在的 6 2 6mg/L ;运行成本由 85 0万降到 4 5 0万 ,通过此工艺的改进及优化 ,基本达到国家污水排放标准 ,完全达到行业排放标准     

城市产业水污染控制优化研究——以株洲市为例

针对城市产业水污染状况，应用产业结构和工业行业结构优化模型，试图找出城市产业结构调整方法。研究以株洲市为例，根据株洲市产业结构和行业结构特点对模型进行改进和最优化计算。计算结果表明，产业和行业生产用水的调整可以减少废水排放量和实现经济增长。在此基础上，提出了株洲市产业和行业凋整方案，以期实现城市经济发展与环境保护协调发雇。     

城市产业水污染控制优化研究--以株洲市为例

针对城市产业水污染状况,应用产业结构和工业行业结构优化模型,试图找出城市产业结构调整方法.研究以株洲市为例,根据株洲市产业结构和行业结构特点对模型进行改进和最优化计算.计算结果表明,产业和行业生产用水的调整可以减少废水排放量和实现经济增长.在此基础上,提出了株洲市产业和行业调整方案,以期实现城市经济发展与环境保护协调发展.     

污水处理工程--两段式活性污泥工艺

我国中小城市的污水处理通常有如下特点(1 )工业废水所占比重较大,甚至超过50 %,致使要处理的城市污水的污染物浓度较高,污染物负荷变化较大 ;(2)城市财政状况比较紧张,可用于建设污水处理厂的资金有限.两段式活性污泥工艺是对传统活性污泥工艺的改进,在好氧处理之前采用一个缺氧或厌氧段,用于有机物的水解酸化或生物除磷.两段式工艺有以下优点处理效率高、工程投资和日常运行费用低,更适合我国国情.本文以两个工程项目为例,论述了两段式活性污泥工艺的工程设计与实际应用.山东省招远市污水处理厂于1999年7月投入运行,处理后排放水中的污染物指标低于设计值.蓬莱市污水处理厂工程即将竣工,设计处理能力20000m3 /d,工程总投资约1200万元,远远低于目前国内的平均水平.