Small-scale physical explosions in shock tubes in comparison with condensed high explosive detonations

A series of small-scale experiments involving physical explosions in a 1.6 l pressure vessel was carried out. Explosions were initiated by spontaneous rupture of an aluminium membrane on one side of the vessel at a pressure in the range 1–1.2 MPa. The pressure waves released were measured at different distances along two separate shock tubes, one 10 m long and 200 mm in diameter (closed at one end by the high pressure vessel) and the other 15 m long and 100 mm in diameter.TNT equivalency was used for predicting the blast wave characteristics after vessel rupture. TNT equivalency was used because equations for prediction of peak pressure and impulse of the blast wave in 1-D geometry after detonations of condensed explosives are known. Some experiments with an equivalent amount of real explosive were carried out for comparison with the theoretical and experimental data obtained. The applicability of the TNT equivalency method presented for calculations of maximum pressure and shock wave impulse generated after rupture of the pressure vessel in 1-D geometry is discussed.     

Flame behaviors and pressure characteristics of vented dust explosions at elevated static activation overpressures

Dust explosion venting experiments were performed using a 20-L spherical chamber at elevated static activation overpressures larger than 1 bar. Lycopodium dust samples with mean diameter of 70 μm and electric igniters with 0.5 KJ ignition energy were used in the experiments. Explosion overpressures in the chamber and flame appearances near the vent were recorded simultaneously. The results indicated that the flame appeared as the under-expanded free jet with shock diamonds, when the overpressure in the chamber was larger than the critical pressure during the venting process. The flame appeared as the normal constant-pressure combustion when the pressure venting process finished. Three types of venting processes were concluded in the experiments: no secondary flame and no secondary explosion, secondary flame, secondary explosion. The occurrence of the secondary explosions near the vent was related to the vent diameter and the static activation overpressure. Larger diameters and lower static activation overpressures were beneficial to the occurrence of the secondary explosions. In current experiments, the secondary explosions only occurred at the following combinations of the vent diameter and the static activation overpressure: 40 mm and 1.2 bar, 60 mm and 1.2 bar, 60 mm and 1.8 bar.     

Explosion of solvent vapor in a ring partition of the floating roof

The relative importance of the vapor cloud explosion (VCE) hazard has grown in recent years. Many of large disasters were attributed to the VCE. This article introduced an explosion accident of solvent vapor in a ring partition of floating roof in detail. Source of explosive materials and ignition reason were analyzed, and the blast equivalency in ring partition was estimated in the specific conditions. The case would provide a reference for preventing the similar accident.     

Experimental and numerical investigation of confined explosion in a blast chamber

An experimental blast program consisting of four tests was conducted in a blast chamber to investigate the effects of cylindrical charges on the peak reflected overpressure and impulse on the wall of the chamber. The charge mass varied from 0.095 kg to 0.2 kg and the standoff distance remained constant at 1.5 m and 1.3 m for the axial and radial directions, respectively. Eight pressure transducers were used in each test to measure the reflected overpressures on confined chamber walls at key locations. A high speed camera was used to record footage of each blast event. The test results indicated that UFC-3-340-02 (Unified Facilities Criteria, 2008) gives a significantly lower prediction for the axially oriented cylindrical charge, and also underestimates the radially oriented cylinder. Another purpose of the blast program was to develop an experimental data set which would validate the AUTODYN model. This would enable the validated AUTODYN model to be used with confidence to generate the overpressure and impulse distribution on a structural element for varying parameters such as the charge shape and charge orientations. Based on the simulated results a new blast model for cylindrical charges has been proposed by considering blast loading on the same level as the charge across the longitudinal direction.     

Experimental study on unconfined methane explosion: Explosion characteristics and overpressure prediction method

Explosion accidents have become the main threat for the high-efficiency use of cleaner gas energy sources, such as natural gas. During an explosion, obstacle causing flame acceleration is the main reason for the increase of the explosion overpressure, which still remains to be fully understood. In this research, field experiments were conducted in a 1 m³ cubic frame apparatus to investigate the effect of built-in obstacles on unconfined methane explosion. Cage-like obstacles were constructed using square steel rods with different cross section size. The results demonstrated that the flame could get accelerated due to the hydrodynamic instability and obstacle-induced turbulence, which enhanced the explosion overpressure. In the near field, the overpressure wave travelled slower and the maximum overpressure could almost keep constant. Reducing the cross section size, or increasing the obstacle height or the obstacle number per layer could determine the rise of the maximum overpressure, the maximum pressure rising rate and the overpressure impulse. For uniformly constructed obstacles, self-similar theory was chosen to measure the influence of the hydrodynamic instability, and a parameter β was adopted to measure the flame acceleration caused by obstacle-induced turbulence, the value of which was 2 in this research. Based on the acoustic theory, an overpressure prediction model was proposed and the predicted results agreed with the measured values better than previous models, such as TNT equivalency model and TNO multi-energy model.     

An overpressure-time history model of methane-air explosion in tunnel-shape space

This study investigated methane-air explosion in tunnel-shape space and developed an overpressure-time history model based on numerical results. The findings revealed that for the progressively vented gas explosion with movable steel obstacles in a 20 m long tunnel, the inner peak overpressure increased as the activation pressure of the tunnel top cover got higher but remained below 6 bar. However, as the activation pressure increased to 8 bar or higher, the peak inner overpressure remained unchanged. As the segment cover panel became wider, the peak pressure was almost unchanged, but the pressure duration and impulse declined significantly. The peak pressure and impulse increased as the tunnel length vary from 10 to 30 m. With fixed tunnel length, higher blast pressure but lower impulse was observed as the inner obstacles were closer or the activation pressure of obstacles was higher. It is also found that a local enlarged space in the tunnel enhanced the peak pressure significantly. An overpressure time history model for the tunnel with fixed top cover and enlarged end zone was established. The model considered activation pressure of vent cover, area and length of vent opening, methane concentration, number and blockage ratio of fixed obstacles was developed to calculate the overpressure and corresponding time at characteristic points of the pressure-history curve. The cubic Hermite interpolation algorithm and a specially tuned formula consisting of the power and exponential function were used to interpolate pressure values between characteristic points. The proposed model can predict both the peak pressure and the overpressure time history with acceptable accuracy.     

A quantitative correlation of evaluating the flame speed for the BST method in vapor cloud explosions

In recent decades, vapor cloud explosions (VCEs) have occurred frequently and resulted in numerous personnel injuries and large property losses. As a main concern in the petrochemical industry, it is of great importance to assess the consequence of VCEs. Currently, the TNT equivalency method (TNT EM), the TNO multi-energy method (TNO MEM), and the Baker-Strehlow-Tang (BST) method are widely used to estimate the blast load from VCEs. The TNO MEM and BST method determine the blast load from blast curves based on the class number and the flame speed, respectively. To quantitatively evaluate the flame speed for the BST method, the experimental data is adopted to validate the confinement specific correlation (CSC) for the determination of the class number in the TNO MEM. As a bridge, a quantitative evaluation correlation (QEC) between CSC correlation and the flame speed is established and the blast wave shapes corresponding to different flame speeds are proposed. CFD software FLACS was used to verify the quantitative correlation with the numerical models of three geometrical scales. It is found that the calculated flame speeds by the QEC are in good agreement with the simulated ones. A petrochemical plant is selected as a realistic scenario to analyze the TNT EM, TNO MEM, BST method and FLACS simulations in terms of the positive-phase side-on overpressure and impulse at different distances. Compared with the flame speed table, the predicted overpressure from BST curves determined by the proposed QEC is closer to that from FLACS and more conservative. Furthermore, the predicted results of different methods are compared with each other. It is found that the estimated positive-phase side-on overpressure and impulse by the TNO MEM are the largest, and the estimated impulse by the TNT EM is the smallest. Moreover, the estimated overpressure and impulse are larger in the higher reactivity gas.     

The application of pressure–impulse curves in a blast exceedance analysis

The magnitude of damage due to a vapor cloud explosion can be estimated in many ways, ranging from look-up tables to quantitative risk analysis. An explosion overpressure analysis is a routine part of compliance with the American Petroleum Institute (API) Recommended Practice (RP) 752 when evaluating occupied buildings in a facility that processes flammable or reactive materials. In many cases, a risk-based approach is useful because consequence modeling studies often indicate major problems for buildings at existing facilities. One of the most common risk-based methods, overpressure exceedance, incorporates a wide range of potential explosion scenarios coupled with the probability of each event to develop the probability of exceeding a given overpressure at specific locations. But this and other methods that only use overpressure may not represent an accurate building response. By combining the risk-based methodology of the exceedance analysis with pressure and impulse data in the form of pressure–impulse (P–I) curves, a better measure of building damage can be generated. P–I curves for blast loading determination have been in use for decades, and allow the user to determine levels of damage based on a predicted overpressure and its corresponding impulse. Curves have been published for entire buildings, individual structural members, window breakage, and even consequences to humans. This paper will explore application of P–I curves for building damage, and will highlight some of the benefits, as well as some of the potential problems, of using P–I curves.     

Experimental study on explosion characteristics of ethanol-gasoline blended fuels

In the present work, a series of experiments have been performed to analyze the explosion characteristics of ethanol-gasoline with various blended ratios (0%, 5%, 10%, 15%, 30%, 50%, 70%, 80%, and 100%). A vented rectangular vessel with a cross-section of 100 mm × 100 mm, 600 mm long and a 40 mm diameter vent on the top is used to carry out the experiments. The flame propagation is recorded by a phantom high-speed camera with 5000 fps, while the histories of the explosion overpressure are measured by two PCB pressure sensors and the explosion sound pressure level is obtained by a CRY sound sensor. The results indicate that the maximum overpressure and flame propagation speed increases linearly as the blended ratio increases when the initial volume of blended fuel is 1.0 mL; While the change of explosion overpressure and flame propagation speed shows a trend of decreasing at first and then increasing as the concentration increases to 1.8 mL. It is also found that the peak of the sound pressure level exceeds 100 dB under all tests, which would damage the human's hearing. What's more, relationships between explosion overpressure and sound pressure level are examined, and the change of the maximum overpressure can be reflected to some extent by the measurement of the maximum sound pressure level. The study is significant to reveal the essential characteristic of the explosion venting process of ethanol-gasoline under different initial blended ratios, and the results would help deepen the understanding of ethanol-gasoline blended fuels explosion and the assessment of the explosion hazardous.     

Duct-venting of dust explosions in a 20 L sphere at elevated static activation overpressures

Ducts are often recommended in the design of dust explosion venting in order to discharge materials to safe locations. However, the maximum reduced overpressure increases in a duct-vented vessel rather than in a simply vented vessel. This needs to be studied further for understanding the duct-venting mechanism. Numerous duct-vented dust explosion experiments were conducted, using a 20 L spherical chamber at elevated static activation overpressures, ranging from 1.8 bar to 6 bar. Duct diameters of 15 mm and 28 mm, and duct lengths of 0 m (simply venting), 1 m and 2 m, were selected. Explosion pressures both in the vessel and in the duct were recorded by pressure sensors, with a frequency of 5 kHz. Flame signals in the duct were also obtained by phototransistors. Results indicate that the secondary explosion occurring in the duct increases the maximum reduced overpressure in the vessel. The secondary explosion is greatly affected by the duct diameter and static activation overpressure, and hence influences the amplification of the maximum reduced overpressure. Larger static activation overpressure decreases the severity of the secondary explosion, and hence decreases the increment in the maximum reduced overpressure. The secondary pressure peak is more obvious as the pressure accumulation is easier in a duct with a smaller diameter. However, the increment of the maximum reduced overpressure is smaller because blockage effect, flame front distortion, and turbulent mixing due to secondary explosion are weaker in a narrow duct. The influence of duct length on the maximum reduced overpressure is small at elevated static activation overpressures, ranging from 1.8 bar to 6 bar at 15 mm and 28 mm duct diameters.     

Numerical and reduced-scale experimental investigation of blast wave shape in underground transportation infrastructure

When an explosion occurs in a tunnel, the study of the blast wave quickly becomes complicated, owing to the multiple propagation patterns of the blast wave (incident wave, regular and Mach reflections) and to the geometrical conditions. Considering this problem, two patterns can be revealed. Near the explosive, the well-known free-field pressure wave can be observed. After multiple reflections on the tunnel's walls, this overpressure behaves like a one-dimensional (1D) wave. One aim of this paper is to determine the position of this transition spherical-to-planar wave propagation in a tunnel using both numerical and reduced-scale experiments, and thereby validate the dedicated law established in a previous work.For this purpose, a detonation of TNT in a tunnel with a cross-section of up to 55 m² is considered. Results show good agreement between the numerical simulations and experiments. The transition zone between the three-dimensional (3D) and the 1D wave is well detected. An application to a simplified subway station is also investigated which shows that significant planar waves can be transmitted to the neighboring stations via the junction tunnels.     

Characteristic overpressure–impulse–distance curves for the detonation of explosives, pyrotechnics or unstable substances

A number of models have been proposed to calculate overpressure and impulse from accidental industrial explosions. When the blast is produced by explosives, pyrotechnics or unstable substances, the TNT equivalent model is widely used. From the curves given by this model, data are fitted to obtain equations showing the relationship between overpressure, impulse and distance. These equations, referred to here as characteristic curves, can be fitted by means of power equations, which depend on the TNT equivalent mass. Characteristic curves allow determination of overpressure and impulse at each distance.     

Numerical investigation and analysis of indoor gas explosion: A case study of “6·13” major gas explosion accident in Hubei Province,China

Taking the ' 6·13 ′ major gas explosion accident in Shiyan, Hubei Province, China as an example, three problems were studied in this work: (1)The determination of the volume of natural gas involved in the explosion; (2)The propagation process of shock wave inside the building and the damage evolution process of the accident-related building; (3)The overpressure and fragment injury to the person outside the building. Through the numerical simulation in ANSYS/LS-DYNA software, the volume of natural gas involved in the explosion is determined to be 10240 × 1400 × 400 cm (length × width × height) from three perspectives: the damage to the building, the distribution of overpressure inside the building, and the TNT equivalent of the explosion energy. The simulation results are in good line with the accident, which verifies the effectiveness of the scheme and the accuracy of the numerical model. Based on the reasonable filling scheme, the propagation process of shock waves inside the building, the damage evolution process of the building, and the injury ranges of overpressure and fragments outside the building are analyzed. It can be found that the propagation of shock waves in confined space is complex and variable. The explosion shock waves are first reflected and superimposed in the watercourse, resulting in pressure rise. At about 8ms, the shock waves rushed into the first-floor space of the building, and the maximum overpressure was about 0.56 MPa. At about 50 ms, the shock waves rushed into the second-floor space, and the maximum overpressure was about 0.139 MPa. The first and second-floor slabs and infilled walls were almost completely destroyed. The interior walls of the infilled walls are mainly collapsed, and the exterior walls are ejection around the building as the center. The peak displacement and peak velocity of the interior walls of each floor are about 15% of the exterior walls. The fragments which cause fragment injury mainly come from the retaining wall above the watercourse, the maximum velocity is about 89 m/s, and the maximum displacement is 8.9 m. The safety distance of fragment injury is about 8.8 m, while the safety distance of overpressure injury is about 4.6 m. The lethal distance of fragment injury is greater than that of overpressure injury. Compared with the distance between different damage levels of overpressure injury, the difference in fragment injury is small. Therefore, the safety assessment at the engineering level only needs to consider the safety distance of fragment injury. This study can provide suggestions for evaluating the damage of natural gas cloud explosions in confined spaces and is helpful for accident investigation and safety protection.     

Study of the explosion parameters of vapor–liquid diethyl ether/air mixtures

The knowledge of the vapor–liquid two-phase diethyl ether (DEE)/air mixtures (mist) on the explosion parameters was an important basis of accident prevention. Two sets of vapor–liquid two-phase DEE/air mixtures of various concentrations were obtained with Sauter mean diameters of 12.89 and 22.90 μm. Experiments were conducted on vapor–liquid two-phase DEE/air mixtures of various concentrations at an ignition energy of 40.32 J and at an initial room temperature and pressure of 21 °C and 0.10 MPa, respectively. The effects of the concentration and particle size of DEE on the explosion pressure, the explosion temperature, and the lower and upper flammability limits were analyzed. Finally, a series of experiments was conducted on vapor–liquid two-phase DEE/air mixtures of various concentrations at various ignition energies. The minimum ignition energies were determined, and the results were discussed. The results were also compared against our previous work on the explosion characteristics of vapor–liquid two-phase n-hexane/air mixtures.     

燃料空气炸药一次引爆爆炸效应实验研究

为了提高燃料空气炸药（FAE）爆炸威力,设计制备了不同相态的FAE,并采用光测和电测方法,开展了开放空间下FAE一次引爆对比实验研究。结果表明:固态、液固混合及液态FAE被一次引爆后,均存在引爆中心装药、抛撒燃料、点火和爆炸4个阶段,云雾存续时间均长于等质量TNT装药的相应值,随着距离增加,固态FAE爆炸场超压变化规律为“减少-增加-减少”,其值高于等质量TNT装药的相应值;液态、液固混合FAE爆炸场超压变化规律为“增加-减少”,远场超压高于等质量TNT装药的相应值。     

液体火箭共底破裂爆炸安全设防距离

针对航天发射场一旦发生低温推进剂泄漏而导致火箭爆炸,会对人员和财产造成重大损失的问题,采用TNT当量模型和TNO(The Netherlands Organization)多能模型计算不同摩尔百分比的氢氧推进剂混合反应时产生爆炸冲击波的危害性,并模拟爆炸冲击波造成的事故影响范围,然后对两种模型的仿真结果加以对比分析,根据最不利原则选取出最终需要的结果,最后划分出安全设防距离。由仿真结果可知,不同的氢氧混合摩尔百分比造成的爆炸后果不同,同时TNT当量模型在爆炸近场处高估了爆炸超压值,在爆炸远场处低估了爆炸超压值,而TNO多能模型在理论上有效地对这一缺陷进行了弥补。对航天发射场的安全布局起到了一定的参考价值。     

建构筑物周边爆破施工安全控制距离及分析方法研究

为研究在居民区附近开展大面积爆破施工的安全可行性以及安全控制距离标准,采用数值模拟方法,分析了地铁车辆段爆破施工对周边高压线及居民楼的影响,根据分析结果,给出了安全控制距离及关键控制指标,说明采用数值模拟的方法适用于类似工况的可行性。另外,研究发现,在居民楼附近进行地铁车辆段爆破施工风险较高,建议在距建构筑物100 m范围内采用静态爆破或机械开挖的方式进行施工。     

Assessment of an accidental vapour cloud explosion: Lessons from the Indian Oil Corporation Ltd. accident at Jaipur,India

On 29 October 2009, at 19:30 IST, a devastating vapour cloud explosion occurred in a large fuel storage area at the Indian Oil Corporation (IOC) Depot in Jaipur, India, generating significant blast pressure. As a consequence of this explosion, the entire installation was destroyed, buildings in the immediate vicinity were heavily damaged, and windowpane breakages were found up to 2 km from the terminal. The IOC estimated that the total loss from the fire and explosion was approximately INR 2800 million.Ironically, as a storage site, the Jaipur terminal was not highly congested, and thus was not considered to have adequate potential for a vapour cloud explosion (VCE). Nevertheless, the prima facie evidences indicate that this was a case of VCE. Therefore, the main objective of this study is to quantify the potential overpressures due to vapour cloud explosions (VCEs) using the Process Hazard Analysis DNV Norway based PHAST 6.51 Software. The results are validated by the extent of the damage that had occurred. The estimation of the VCE shows that a maximum 1.0 bar overpressure was generated in the surrounding area. The initial assessment of the accident data roughly estimates the release mode, time, and amount of vaporized fuel. A more accurate estimate has been obtained by modelling the dispersion of vapour clouds in the surrounding atmosphere, which reveals trends and relationships for the occurrence of vapour cloud explosions.     

Influence of vacuum degree on the effect of gas explosion suppression by vacuum chamber

In order to study the influence of vacuum degree on gas explosion suppression by vacuum chamber, this study used the 0.2 mm thick polytetrafluoroethylene film as the diaphragm of vacuum chamber to carry out a series of experiments of gas explosion suppression by vacuum chamber with the vacuum degree from −0.01 MPa to −0.08 MPa. The experimental results show that: under the condition of any vacuum degree, vacuum chamber can effectively suppress the explosion flame and overpressure; as vacuum degree changes, the effect of gas explosion suppression using vacuum chamber is slightly different. Vacuum chamber has obvious influence on propagation characteristics of the explosion flame. After explosion flame passes by vacuum chamber, the flame signal weakens, the flame thickness becomes thicker, and the flame speed slows down. With the increase of the vacuum degree of vacuum chamber, the flame speed can be prevented from rising early by vacuum chamber. The higher the vacuum degree is, the more obviously the vacuum chamber attenuates the explosion overpressure, the smaller the average overpressure is, and the better effect of the gas explosion suppression is. Vacuum chamber can effectively weaken the explosion impulse under each vacuum degree. From the beginning of −0.01 MPa, the vacuum chamber can gradually weaken explosion impulse as the vacuum degree increases, and the effect of gas explosion suppression gradually becomes better. When the vacuum degree is greater than −0.04 MPa, the increase of vacuum degree can make the explosion overpressure decrease but have little influence on the explosion impulse. Therefore, the vacuum chamber has the preferable suppression effect with equal to or greater than −0.04 MPa vacuum degree.     

密闭管道瓦斯爆炸冲击波冲量及压力上升速率的实验研究

针对矿井瓦斯爆炸破坏模式主要在压力破坏和冲量破坏的研究,实验分析瓦斯在密闭管道发生爆炸时瓦斯浓度对冲击波冲量及压力上升速率的影响,利用管道中距离点火源不同位置的压力传感器测试了不同浓度瓦斯的爆炸压力,对冲击波冲量及压力上升速率进行分析,为防爆抑爆提供依据。研究结果显示:在管道中距离点火源的不同位置上,当浓度为9.5%时,瓦斯爆炸冲击波冲量及压力上升速率最大;由于超压衰减和传播距离的增加,在距离点火源4m和8m时压力冲量较大;在瓦斯浓度较低的范围内瓦斯爆炸时,其压力上升速率增长较快,而随着浓度的增加在较宽的浓度范围内,能较稳定地维持在高位值。