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1.
Results with the EPRI 2.5 MW(e) Integrated Environmental Control Pilot Plant (IECPP) indicate the interrelationship of particulate penetration, SO2 scrubber operation, waste production, and waste properties. Tests compared a fabric filter/wet scrubber and ESP/wet scrubber, the latter operated to simulate 1979 New Source Performance Standards (NSPS), 1971 NSPS, and pre-NSPS ESP units. Tests were conducted with low-sulfur coal producing a flue gas concentration of400ppm; flue gas spiking could be used to increase SO2 to 2000 ppm. Scrubber waste was dewatered in a thickener and vacuum belt filter (to 55 percent solids content), and mixed with fly ash. The pilot SO2 scrubber—when preceded by an ESP and forced to operate in zero-discharge—captured less SO2 than when preceded by a fabric filter. Also, scrubber operation with the ESP produced a greater quantity of waste with difficult handling characteristics, as compared to operation with the fabric filter. These difficulties occurred with particulate penetration above 0.10 lb/MBtu, which could reduce reagent utilization to 80percent. These results are attributable to inhibited limestone dissolution due to accumulation of an aluminum/fluoride compound. For both lowsulfur and simulated high-sulfur test conditions, allowing wastewater discharge to purge aluminum/fluoride content restored performance to design levels. Particulate control efficiency also affected solid waste physical properties. The fabric filter/wet scrubber produced the lowest solid waste permeability (10?8 cm/s). ESP operation at 1979 NSPS and pre-1971 NSPS ESPs increased solid waste permeability to 10?7 and 10?6 cm/s, respectively. These results are meaningful for SO2 scrubbers both for new plants and for retrofit to units with pre-NSPS ESPs, and could become significant with the increasing trend to restricted water discharge.  相似文献   

2.
In this study, removing sulfur dioxide (SO2), nitrogen oxides (NO(x)), and mercury (Hg) from simulated flue gas was investigated in two laboratory-sized bubbling reactors that simulated an oxidizing reactor (where the NO and Hg(0) oxidation reactions are expected to occur) and a wet limestone scrubber, respectively. A sodium chlorite solution was used as the oxidizing agent. The sodium chlorite solution was an effective additive that enhanced the NO(x), Hg, and SO2 capture from the flue gas. Furthermore, it was discovered that the location of the sodium chlorite application (before, in, or after the wet scrubber) greatly influences which pollutants are removed and the amount removed. This effect is related to the chemical conditions (pH, absence/presence of particular gases) that are present at different positions throughout the flue gas cleaning system profile. The research results indicated that there is a potential to achieve nearly zero SO2, NO(x), and Hg emissions (complete SO2, NO, and Hg removals and -90% of NO(x) absorption from initial values of 1500 ppmv of SO2, 200 ppmv of NO(x), and 206 microg/m3 of Hg(0)) from the flue gas when sodium chlorite was applied before the wet limestone scrubber. However applying the oxidizer after the wet limestone scrubber was the most effective configuration for Hg and NO(x) control for extremely low chlorite concentrations (below 0.002 M) and therefore appears to be the best configuration for Hg control or as an additional step in NO(x) recleaning (after other NO(x) control facilities). The multipollutant scrubber, into which the chlorite was injected simultaneously with the calcium carbonate slurry, appeared to be the least expensive solution (when consider only capital cost), but exhibited the lowest NO(x) absorption at -50%. The bench-scale test results presented can be used to develop performance predictions for a full- or pilot-scale multipollutant flue gas cleaning system equipped with wet flue gas desulfurization scrubber.  相似文献   

3.
A novel two-stage wet electrostatic precipitator (ESP) has been developed using a carbon brush pre-charger and collection plates with a thin water film. The electrical and particle collection performance was evaluated for submicrometer particles smaller than 0.01- 0.5 micrometer in diameter by varying the voltages applied to the pre-charger and collection plates as well as the polarity of the voltage. The collection efficiency was compared with that calculated by the theoretical models. The long-term performances of the ESP with and without water films were also compared in tests using Japanese Industrial Standards dust. The experimental results show that the carbon brush pre-charger of the two-stage wet ESP had approximately 10% particle capture, while producing ozone concentrations of less than 30 ppb. The produced amounts of ozone are significantly lower than the current limits set by international agencies. The ESP also achieved a high collection rate performance, averaging 90% for ultrafine particles, as based on the particle number concentration at an average velocity of 1 m/sec corresponding to a residence time of 0.17 sec. Higher particle collection efficiency for the ESP can be achieved by increasing the voltages applied to the pre-charger and the collection plates. The decreased collection efficiency that occurred during dust loading without water films was completely avoided by forming a thin water film on the collection plates at a water flow rate of 6.5 L/min/m(2).  相似文献   

4.
A turbulent wet scrubber was designed and developed to scrub particulate matter (PM) at micrometer and submicrometer levels from the effluent gas stream of an industrial coal furnace. Experiments were conducted to estimate the particle removal efficiency of the turbulent scrubber with different gas flow rates and liquid heads above the nozzle. Particles larger than 1 µm were removed very efficiently, at nearly 100%, depending upon the flow rate, the concentration of the dust-laden air stream, and the water level in the reservoir. Particles smaller than 1 µm were also removed to a greater extent at higher gas flow rates and for greater liquid heads. Pressure-drop studies were also carried out to estimate the energy consumed by the scrubber for the entire range of particle sizes distributed in the carrier gas. A maximum pressure drop of 217 mm H2O was observed for a liquid head of 36 cm and a gas flow rate of 7 m3/min. The number of transfer units (NTU) analysis for the efficiencies achieved by the turbulent scrubber over the range of particles also reveals that the contacting power achieved by the scrubber is better except for smaller particles. The turbulent scrubber is more competent for scrubbing particulate matter, in particular PM2.5, than other higher energy or conventional scrubbers, and is comparable to other wet scrubbers of its kind for the amount of energy spent.

Implications: The evaluation of the turbulent scrubber is done to add a novel scrubber in the list of wet scrubbers for industrial applications, yet simple in design, easy to operate, with better compactness, and with high efficiencies at lower energy consumption. Hence the turbulent scrubber can be used to combat particulate from industrial gaseous effluents and also has a scope to absorb gaseous pollutants if the gases are soluble in the medium used for particles capture.  相似文献   

5.
Electrostatic precipitation is considered as an effective technology for fine particle removal. A lab-scale wet electrostatic precipitator (ESP) with wire-to-plate configuration was developed to study particle migration and collection. The performance of the wet ESP was evaluated in terms of the corona discharge characteristics, total removal efficiency and fractional removal efficiency. The corona discharge characteristics and particle removal abilities of the wet ESP were investigated and compared with dry ESP. Particle removal efficiency was influenced by discharge electrode type, SO2 concentration, specific collection area (SCA) and particle/droplet interaction. Results showed that the particle removal efficiency of wet ESP was elevated to 97.86% from 93.75% of dry ESP. Three types of discharge electrodes were investigated. Higher particle removal efficiency and larger migration velocity could be obtained with fishbone electrode. Particle removal efficiency decreased by 2.87% when SO2 concentration increased from 0 ppm to 43 ppm as a result of the suppression of corona discharge and particle charging. The removal efficiency increased with higher SCA, but it changed by only 0.71% with the SCA increasing from 25.0 m2/(m3/s) to 32.5 m2/(m3/s). Meanwhile, the increasing of particle and droplet concentration was favorable to the particle aggregation and improved particle removal efficiency.

Implications: This work tends to study the particle migration and collection under spraying condition. The performance of a wet electrostatic precipitator (ESP) is evaluated in terms of the corona discharge characteristics, total particle removal efficiency, and fractional particle removal efficiency. The effects of water droplets on particle removal, especially on removal of particles with different sizes, is investigated. The optimization work was done to determine appropriate water consumption, discharge electrode type, and specific collection area, which can provide a basis for wet ESP design and application.  相似文献   


6.
Electrolyzed water (EW) is an effective disinfectant with a wide range of pH. EW in acid range was proved to be an ammonia absorbent which make it valuable for wet scrubbers used in animal feeding operations (AFOs). This study aimed to optimize the design and operating parameters of a wet scrubber with EW spray for ammonia removal, based on the size distribution of droplets, the property of EW and the reduction efficiency of ammonia. The optimized parameters included droplet size, nozzle flow rates, pH and available chlorine concentration (ACC) of EW, nozzle number at single stage, stage number, initial ammonia concentration and air speed in the duct. The ammonia removal efficiency increased with the decrease of droplet size and the increase of flow rate. The pH values of EW showed significant influence on ammonia removal efficiency (P ? 0.05), while ACC of the EW showed no significant influence (P > 0.05). For inlet ammonia concentration of 70 ppm with one and three spray stages, the wet scrubber with EW (pH = 1.35) spray was able to reduce 55.8 ± 4.3 % and 97.2 ± 3.0 % of ammonia, respectively, when the nozzles with 0.9 mm orifice diameter operated at a flow rate of 1.20 L min-1. Response surface analysis showed that orifice diameter, nozzle flow rate, and their combination were all significant factors impacting ammonia removal efficiency for both pH =1.35 and 5.50 at a 95% confidence level. Optimal ammonia removal efficiency was obtained at orifice diameter 0.9 mm and flow rate 1.20 L min-1 within the selected range. The results of this study demonstrated that wet scrubber with EW spray could be a very effective and feasible ammonia mitigation technology for animal feeding operation.

Implications: It is difficult to effectively reduce ammonia emitted from the animal feeding operations (AFOs). Both the acidity and disinfection effects of electrolyzed water (EW) make it a potential absorbent used for spray in wet scrubber to reduce the ammonia and microorganisms. Based on some preliminary field test results, lab tests were conducted to optimize the design and operation parameters of a wet scrubber with EW spray to improve the ammonia removal efficiency. A better understanding of the application and influence factors of the wet scrubber with EW spray can contribute to effective mitigation of ammonia emission from animal houses and improve the atmosphere air quality.  相似文献   


7.
收尘区脉冲供电对电除尘器收集性能的影响   总被引:2,自引:0,他引:2  
建立了双区电除尘器实验模型,研究了预荷电压、不同供电方式下极板间距、电极型式对双区电除尘器收尘效果的影响.结果表明:随着预荷电压逐渐升高,除尘效率也随之增加,双区除尘效果明显优于单区的除尘效果.脉冲供电对电除尘器的除尘性能影响明显,与直流供电相比,脉冲供电对PM25的分级效率可提高16.9%;在较高的电压时,极板间距为...  相似文献   

8.
The high collection efficiencies that are required nowadays to meet the stricter pollution control standards necessitate the use of high-energy scrubbers, such as the venturi scrubber, for the arrestment of fine particulate matter from exhaust gas streams. To achieve more energy-efficient particle collection, several venturi stages may be used in series. This paper is principally a theoretical investigation of the performance of a multiple-stage venturi scrubber, the main objective of the study being to establish the best venturi design configuration for any given set of operating conditions. A mathematical model is used to predict collection efficiency vs pressure drop relationships for particle sizes in the range 0.2–5.0 μm for one-, two-, three- and four-stage scrubbers. The theoretical predictions are borne out qualitatively by experimental work. The paper shows that the three-stage venturi produces the highest collection efficiencies over the normal operating range except for the collection of very fine particles at low pressure drops, when the single-stage venturi is best. The significant improvement in performance achieved by the three-stage venturi when compared with conventional single-stage operation increases as both the particle size and system pressure drop increase.  相似文献   

9.
This paper includes results from pilot plant studies and early field demonstration units and a discussion of the application of the limestone wet scrubbing process to a low sulfur syb-butuminous coal. This latter application required the development of a hybrid two stage scrubber to enable collection of the fine particulate matter as well as removal of a significant amount of the sulfur dioxide.  相似文献   

10.
Theoretical calculations and experimental measurements show that the collection of small aerosol particles (0.05 to 5 micron diameter range) by water droplets in spray scrubbers can be substantially increased by electrostatically charging the droplets and particles to opposite polarity. Measurements with a 140 acfm two chamber spray scrubber (7 seconds gas residence time) showed an increase in the overall particle collection efficiency from 68.8% tit uncharged conditions to 93.6% at charged conditions, with a dioctyl phthalate aerosol (1.05 μm particle mass mean diameter and 2.59 geometric standard deviation). The collection efficiency for 0.3 μm particles increased from 35 to 87% when charged. During 1973–1974 a 1000 acfm pilot plant electrostatic scrubber was constructed inside a 40 ft trailer for evaluation on controlling particu-late emissions from pulp mill operations (funded by Northwest Pulp and Paper Association). Field tests performed on the particle emissions exhausting from SO2 absorption towers treating the gases from a magnesium based sulfite recovery boiler have shown particle collection efficiencies ranging from about 60 to 99% by weight, depending on the electrostatic scrubber operating conditions. Energy requirements for the University of Washington electrostatic scrubber are about 0.5 hp/1000 acfm (350 Watts/1000 acfm) including gas pressure drop, water pressure drop, and electrostatic charging of the water spray droplets and the particles.  相似文献   

11.
A large number of pressurized coal gasification processes being developed propose to use venturi scrubbers for particulate removal at high pressures. Theoretical predictions based on venturi scrubber performance models indicate that particle collection efficiency will decrease severely in these high gas pressure applications.

An exploratory theoretical and experimental program was performed to study the effect of gas pressure on venturi scrubber performance. Experiments were done on a 0.47 m3/s (1000 acfm) pilot scale venturi scrubber. Particle collection performance was determined as a function of scrubber pressure drop for venturi scrubbers operating In the range of 1-10 atm total pressure. Experimental results confirmed that the particle collection efficiency of venturi scrubbers decreases for a given scrubber pressure drop as total gas pressure Is increased. To achieve the same particle collection efficiency, the pressure drop across a venturi scrubber operated at 10 atm Is about 10 times that of the same scrubber operated at 1 atm pressure.  相似文献   

12.
An experimental investigation has been carried out to examine the effect of scale-up on the performance of scrubbers for a wide range of operating conditions. A pilot plant with a maximum air flow rate of 400 cfm and a water flow rate of 4 gpm was used for this study. For the same operating conditions, the performance of 1.5 in. orifice type scrubber was found better than that of 1.0 in. size. The results were categorized according to the size of the particles, classed as large (1.5 to 3.5μ diam), medium (0.6 to 1.5μ diam) and small (less than O.6μ diam). Although the magnitude of improvement of the collection efficiency was dependent on the operating conditions, differences to the extent of 20% were obtained. The improvement of the collection efficiency for the larger scrubber was found to be due to the influence of the main stream turbulence.  相似文献   

13.
ABSTRACT

A novel two-stage wet electrostatic precipitator (ESP) has been developed using a carbon brush pre-charger and collection plates with a thin water film. The electrical and particle collection performance was evaluated for submicrometer particles smaller than 0.01~0.5 μm in diameter by varying the voltages applied to the pre-charger and collection plates as well as the polarity of the voltage. The collection efficiency was compared with that calculated by the theoretical models. The long-term performances of the ESP with and without water films were also compared in tests using Japanese Industrial Standards dust. The experimental results show that the carbon brush pre-charger of the two-stage wet ESP had approximately 10% particle capture, while producing ozone concentrations of less than 30 ppb. The produced amounts of ozone are significantly lower than the current limits set by international agencies. The ESP also achieved a high collection rate performance, averaging 90% for ultrafine particles, as based on the particle number concentration at an average velocity of 1 m/sec corresponding to a residence time of 0.17 sec. Higher particle collection efficiency for the ESP can be achieved by increasing the voltages applied to the pre-charger and the collection plates. The decreased collection efficiency that occurred during dust loading without water films was completely avoided by forming a thin water film on the collection plates at a water flow rate of 6.5 L/min/m2 Zukeran, A., Ikeda, Y., Ehara, Y., Matsuyama, M., Ito, T., Takahashi, T., Kawakami, H. and Takamatsu, T. 1999. Two-Stage-Type Electrostatic Precipitator Re-entrainment Phenomena under Diesel Flue Gases. IEEE. Trans. Ind. Appl, 35: 346351. [Crossref], [Web of Science ®] [Google Scholar].

IMPLICATIONS Current two-stage electrostatic precipitators (ESPs) have several technical problems such as a drop in collection efficiencies by small-particle re-entrainment during rapping and corrosion of metallic electrodes of the ESPs by corrosive gases. This paper evaluates a novel two-stage ESP that uses a nonmetallic pre-charger and water film collection plates to avoid the above mentioned problems of other ESPs. This ESP can be used not only for industrial applications but also for residential purposes because it has a high removal performance for fine particles with low ozone generation and maintains its efficiency due to the continuous cleaning of the collection plates with water film.  相似文献   

14.
The term “wet scrubber” or simply “scrubber,” for the purpose of this report, is intended to include any device using liquid to effect the removal of solid or liquid particles which are entrained in process air or gas streams. This guide is intended to provide information required for the selection and performance evaluation of all types of scrubbers installed for the primary purpose of removing such particulates from any process gas stream. It is not intended to cover scrubbers for the collection of gaseous and/or vapor constituents which involve gas absorption mechanisms.  相似文献   

15.
Emissions of fine particulate matter, PM2.5, in both primary and secondary form, are difficult to capture in typical dry electrostatic precipitators (ESPs). Wet (or water-based) ESPs are well suited for collection of acid aerosols and fine particulates because of greater corona power and virtually no re-entrainment. However, field disruptions because of spraying (misting) of water, formation of dry spots (channeling), and collector surface corrosion limit the applicability of current wet ESPs in the control of secondary PM2.5. Researchers at Ohio University have patented novel membrane collection surfaces to address these problems. Water-based cleaning in membrane collectors made of corrosion-resistant fibers is facilitated by capillary action between the fibers, maintaining an even distribution of water. This paper presents collection efficiency results of lab-scale and pilot-scale testing at FirstEnergy's Bruce Mansfield Plant for the membrane-based wet ESP. The data indicate that a membrane wet ESP was more effective at collecting fine particulates, acid aerosols, and oxidized mercury than the metal-plate wet ESP, even with approximately 15% less collecting area.  相似文献   

16.
Airborne microorganisms, especially the pathogenic microorganisms, emitted from animal feeding operations (AFOs) may harm the environment and public health and threaten the biosecurity of the farm and surrounding environment. Electrolyzed water (EW), which was considered to be an environmentally friendly disinfectant, may be a potential spraying medium of wet scrubber for airborne microorganism emission reduction. A laboratory test was conducted to investigate the airborne bacteria (CB) removal efficiency of the wet scrubber by EW spray with different designs and operating parameters. Both the available choline (AC) initial loss rate and AC traveling loss rate of acidic electrolyzed water (AEW; pH = 1.35) were much higher than those of slightly acidic electrolyzed water (SAEW; pH = 5.50). Using one spraying stage with 4 m sec?1 air speed in the duct, the no detect lines (NDLs) of SAEW (pH = 5.50) for airborne Escherichia coli, Staphylococcus aureus, and Salmonella enteritidis removal were all 50 mg L?1, whereas the NDLs of AEW (pH = 1.35) for airborne E. coli, S. aureus, and S. enteritidis removal increased to 70, 90, and 90 mg L?1, respectively. The NDLs of SAEW (pH = 5.50) for airborne E. coli, S. aureus, and S. enteritidis were lower than those of AEW (pH = 1.35) at single spraying stage. Increase in the number of stages lowered the NDLs of both SAEW (pH = 5.50) and AEW (pH = 1.35) for airborne E. coli, S. aureus, and S. enteritidis. EW with a higher available chlorine concentration (ACC) was needed at air speed of 6 m sec?1 to reach the same airborne CB removal efficiency as that at air speed of 4 m sec?1. The results of this study demonstrated that EW spray wet scrubbers could be a very effective and feasible airborne CB mitigation technology for AFOs.

Implications: It is difficult to effectively reduce airborne bacteria emitted from animal feeding operations (AFOs). Electrolyzed water (EW) with disinfection effect and acidity is a potential absorbent for spray in wet scrubber to remove microorganisms and ammonia. Based on the field test results, a laboratory experiment we conducted this time was to optimize the design and operation parameters to improve the airborne bacteria removal efficiency. A better understanding of the EW application in the wet scrubber can contribute to the mitigation of airborne bacteria from animal houses and improve the atmosphere air quality.  相似文献   


17.
Choi KI  Lee DH  Osako M  Kim SC 《Chemosphere》2007,66(6):1131-1137
Wet scrubber is one of the most conventional types of air pollutant control devices (APCDs), which is specially designed to treat dust and acidic gases in the flue gas simultaneously. In spite of its outstanding ability to control them, however, wet scrubbers have been considered as potential contaminant sources that may increase PCDD/DF concentrations in the flue gas. In this study, we investigated the change of PCDD/DF concentrations at the inlets and outlets of seven wet scrubbers, and compared them with other published data. With a multi-regression analysis of dust concentrations and temperature at the inlets and outlets of given wet scrubbers, we developed an empirical model to understand factors dominating the change of PCDD/DF concentrations. As a result, we confirmed that the changes of PCDD/DF concentrations in wet scrubbers are closely related to their concentrations at the inlets, which would usually be determined by the type of APCDs installed upstream of the wet scrubber.  相似文献   

18.
This paper presents a study on the simultaneous removal of SO2, NO(x) and Hg (both Hg0 and Hg2+) from a simulated flue gas by oxidant injection in a bench-simulated wet limestone scrubber for a wide range of slurry pH. The slurry pH strongly influenced the chemical mechanism in the scrubber and, therefore, affected pollutant removal. This paper also examines the potential ClO2(gas) reemission from a developed multipollutant scrubber at different slurry pHs. To better understand the chemical mechanisms at each slurry pH and to apply a mass balance to the process, detailed product ion analyses were performed for all experiments. Ion analysis covered three different chlorine species (chlorite, chloride, chlorate), sulfate, nitrite and nitrate. Different NO(x) removal efficiencies and mechanisms were found in acidic and alkaline pHs in the multipollutant scrubber. The acidic solution was favorable for NO and Hg0 oxidation, but increasing the slurry pH above 7.0 was disadvantageous for NO and Hg oxidation/removal. However the rate of NO(x) absorption (by percentage) was higher for the alkaline solution.  相似文献   

19.
Particulate mass concentration, particle size distribution, and particle chemical composition measurements have been conducted on the gases exhausting from a chromic acid anodizing process tank. Particle mass concentrations in the 200 to 20,000 μg/m3 range were measured using open-faced filters (47 mm diameter) adjacent to the process tank liquid and with closed filters (90 mm diameter) in the exhaust duct. Particle size distributions, measured using University of Washington Mark 3 and Mark 20 Cascade Impactors, showed the particle aerodynamic mass median diameter was about 3 microns. Chemical analysis of the particle samples obtained by the Modified EPA Method 5 sampling train, the Mark 20 UW Cascade Impactors, and by the 47 mm and 90 mm diameter filters showed Cr+6 concentrations in the 20 to 1,500 μg/m3 range with over 99 percent of the chromium in particles larger than 1.0 microns diameter. An integrating nephelometer was used to measure the light scattering coefficient of the exhaust gases upstream of the wet scrubber. The light scattering coefficient increased by a factor of about 2–3 over the background level during the 40 minute time period while a part was being anodized. The bscat values ranged from 3 × 10?5 to 3 × 10?4 meters?1 for the aerosol particles less than about 6 microns aerodynamic diameter.  相似文献   

20.
ABSTRACT

Wet electrostatic precipitators (WESPs) are modern-era pollution control systems specifically designed to capture ultrafine particles as well as acid mist, highly resistive and sticky particles; however, this requires the use of expensive corrosion-resistant metal alloys. The work presented here is part of a continuing study at Ohio University aimed at reducing the cost of WESPs by using a novel combination of a polymer collector surfaces with a hybrid composite discharge electrode. In this study, a hybrid composite discharge electrode was tested, for the first time, inside a semi-pilot-scale experimental setup, with collection surfaces consists of a vertical array of strands. Particle laden gases were passed through this array of polymer ropes, which were kept wet by a small flow of water. The discharge electrodes were composite laminates of carbon fibers in a polymer matrix enclosing a metal mesh. The preliminary results showed that this new integrated system of composite discharge electrode and polymer collector surfaces can match or exceed the performance of a conventional metal alloy electrostatic precipitator (ESP) with metal discharge electrodes. There are additional advantages due to the system being compact, lightweight, and highly corrosion resistant.

Implications: This study focused on integrating and assessing performance of a novel hybrid composite electrode (HCE) inside semi-pilot novel cross-flow electrostatic precipitator at conditions typically observed in coal-fired power plant exhausts. The results were collected for particulate collection efficiencies and were compared with a rigid metal electrode. The HCE outperformed metal electrode by showing higher particulate collection efficiency. This result showcases substantial potential for these two new technologies (HCE and cross-flow system) as a substitute for conventional metal based wet ESPs.  相似文献   

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