应用模糊数学法评价扬州市内城河水质研究

采用模糊数学法对扬州市内城河"十一五"期间的水质监测数据进行了综合评价。评价结果表明:扬州内城河水质较差,2005年-2010年内城河对Ⅴ类水质隶属度最大。总磷、氨氮和五日生化需氧量为主要污染因子。可见内城河水质较差的主要原因是有机类污染导致富营养化。整个"十一五"期间,内城河对Ⅴ类水质隶属度逐年减小,说明水质总体趋于好转。     

苏州古城区水体污染时空分异特征及污染源解析

利用2012年苏州古城区30个监测断面的11个水质指标数据,综合运用水质指数模型(WQI)、层次聚类(HCA)、后退式判别(DA)、因子分析(FA)、绝对主成分多元线性回归(APCS-MLR)及GIS平台系统分析了旅游城市苏州古城区河网水体污染物时空分异特征及污染源解析.结果表明:①苏州古城区内城河及外围河道水体的CCME WQI值介于40~74之间,其中,66.67%的监测点水环境遭到严重破坏,主要集中在内城河河道;②系统聚类分析将采样时间分为1—3月、11月及4—6月、7—10月3个时段;将采样点分为2类,从空间上反映了古城区内城河与外围河道的污染程度;③采样时间和采样点聚类分析结果的判别分析交叉验证,正确率分别达到88.1%和78.5%;表征时间差异性用了7个指标,分别为总氮(TN)、总磷(TP)、溶解氧(DO)、水温(T)、高锰酸盐指数(COD Mn)、藻密度(Algae density)、叶绿素(Chl),表征空间差异性用了5个指标,分别为总氮(TN)、氨氮(NH3-N)、溶解氧(DO)、浊度(Turb)、水温(T);显著性指标的时空差异性比较明显;④古城区内城河河道在1—3月、11月及4—6月、7—10月3个时段内的因子分析分别提取4、3和4个因子,累积解释方差分别为83.64%、72.67%和77.98%;古城区外围河道在全年内的因子分析提取了3个因子,累积解释了62.28%的总方差;因子分析表明,古城区内城河及外围河道主要为氮、磷等营养物质污染及夏季藻类爆发的问题,与古城区外围河道相比内城河河道的污染更为严重,应优先开展治理;内城河氮、磷污染除了有来自生活、餐饮旅游等第三产业的污染外,还受到降雨地表径流及河道底泥释放的非点源污染影响;⑤绝对主成分多元线性回归(APCS-MLR)表明,总氮(TN)、氨氮(NH3-N)、总磷(TP)和高锰酸盐指数(COD Mn)主要来自城市生活及餐饮旅游等第三产业污水.研究结果可为苏州古城区河道水环境改善治理提供参考.     

淮河入海道滨海枢纽工程沿线水环境质量调查

简述淮河人海道滨海枢纽工程开挖前后，其沿线水系及工业污染源结构的变化，并对沿线水环境质量变化作了具体分析。工程沿线水环境质量的变化主要受水系的改变和污染源结构变化的综合影响。提出在加入工业污染源治理力度的同时，还应注意相关水系范围内的农业、生活等方面产生的面源污染。建议水利部门在规划水建工程时，应对水环境质量和周边生态进行全面、客观地评价；内城河船闸在不影响几主要功能的情况下，应保持开启状态，让优质的中山河水补给内城河，从根本上改善内城河的水质。     

沭阳县水质监控预警体系建立

主要分析了沭阳县2009年和2010年水质自动监测数据、饮用水源监测数据以及内城河监测数据,参照GB 3838-2002《地面水环境质量标准》做评价分析,综合多方面因素,从自动监测到例行监测,从饮用水源监测到内城河流监测,全面研究了沭阳县环境保护部门对于水源监测体系建立成效,为以后城市经济建设和水源保护奠定了基础.     

苏州水网城市暴雨径流污染的研究

“苏州市水污染综合防治规划研究”总课题的要求,需要探索苏州内城暴雨径流所产生的非点源污染,即从内城河各出口输出至外城河的流量及其相应的有机污染负荷量。目前解决这一类都市雨水排水问题一般采用概念模型和水动力学模型两种途径。我们根据苏州实际情况,建立了苏州暴雨径流     

陈塘热电“煤改气”指标国际先进、国内领先——记天津陈塘热电煤改气工程

<正>本刊讯:为优化能源结构,促进绿色发展,加快大气污染治理,改善中心城区居民生活环境,提高供热和供电能力,满足城市长远发展要求,2010年,按照天津市政府"进一步拓展城市发展空间.提升中心城区生态环境,改善群众生活条件,扩大热电联产供应能力"要求,天津陈塘热电有限公司开始实施"煤改气"搬迁工程。工程的设计采用了先进可行的节电、节水及节     

异龙湖及主要入湖河流(含湿地)水质监测与评价

介绍了异龙湖基本情况,对异龙湖主要入湖河流(含湿地)进行现状监测,结果显示,按照Ⅲ类水质标准评价,大水河入湖口、城河入湖口水质均不达标.若按《异龙湖流域水环境保护治理"十三五"规划(2016—2020年)》确定的Ⅴ类水质目标评价,大水河入湖口水质达标,城河入湖口水质不达标.提出了对策建议.     

雾霾污染的空间外溢与治理政策的检验分析

以2006~2016年城市层面数据为样本,结合空间扩散效应深入探究雾霾污染的影响机理,并对已出台治霾政策的治理效果和传导机制进行识别.研究发现：考察期内我国雾霾污染具有一定时滞性、空间相关性和时空“警示作用”;以往环境规制由于诱发污染产业地区间就近转移对减霾贡献并未达到预期效果.“大气十条”的治霾效果明显,到2016年该政策的实施使重点关注的三大经济带PM_2.5显著降低约7.1%,其中,中部和东部区域政策实施城市治理效果最为显著;政策实施以来各地区环保部门通过对重污染企业的限产整治取得了降霾的短期治理效果,但对重污染企业的创新激励传导作用并不显著.因此,未来雾霾治理政策更需注重如何通过激发企业绿色技术创新从而建立根治雾霾污染的长效机制.     

城市环境污水治理的探析与研究

针对如何搞好城市环境污水的治理探析问题,介绍了中国城市污水治理的现状,同时介绍了城市污水处理的方法,如城市利用活性污泥处理污水方法、利用生物膜处理污水方法、利用氧化处理污水方法,并探讨了如何对城市环境污水进行治理的探究,文中介绍了增强城市污水集中处理的力度、如何加强污水管网的配套建设、如何对城市污水分散处理回用和采用新的污水处理工艺及提高污水再生效率.只有这样才能加快城市的发展,有利于搞好城市环境污水的治理目标.     

城市大气污染的治理方法探讨

城市大气污染是目前比较严重的一个问题,直接影响了人们的生活质量。近年来,我国城市化建设日益加强,居民的生活环境也受到很大的影响,如何有效改善居民的生活环境,治理城市的大气污染成为当前城市建设的主要问题之一。本文主要是在大气污染的情况下,通过分析城市大气污染现象形成原因,找出治理城市大气污染的主要措施。     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Removal of heavy metals from sewage sludge by low costing chemical method and recycling in agriculture

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Isolation and preliminary characterization of a 3-chlorobenzoate degrading bacteria

A study was conducted to compare the diversity of 2-, 3-, and 4-chlorobenzoate degraders in two pristine soils and one contaminated sewage sludge. These samples contained strikingly different populations of mono-chlorobenzoate degraders. Although fewer cultures were isolated in the uncontaminated soils than contaminated one, the ability of microbial populations to mineralize chlorobenzoate was widespread. The 3- and 4-chlorobenzoate degraders were more diverse than the 2-chlorobenzoate degraders. One of the strains isolated from the sewage sludge was obtained. Based on its phenotype, chemotaxonomic properties and 16S rRNA gene, the organism S-7 was classified as Rhodococcus erythropolis. The strain can grow at temperature from 4 to 37℃. It can utilize several （halo）aromatic compounds. Moreover, strain S-7 can grow and use 3-chlorobenzoate as sole carbon source in a temperatures range of 10-30℃ with stoichiometric release of chloride ions. The psychrotolerant ability was significant for bioremediation in low temperature regions. Catechol and chlorocatechol 1,2-dioxygenase activities were present in cell free extracts of the strain, but no （chloro）catechol 2,3- dioxygenase activities was detected. Spectral conversion assays with extracts from R. erythropolis S-7 showed accumulation of a compound with a similar UV spectrum as chloro-cis,cis-muconate from 3-chlorobenzoate. On the basis of these results, we proposed that S-7 degraded 3-chlorobenzoate through the modified ortho-cleave pathway.     

Single and joint effects of pesticides and mercury on soil urease

The influence of two pesticides including chlorimuron-ethyl and furadan and mercury （Hg） on urease activity in 4 soils （meadow burozem and phaeozem） was investigated. The soils were exposed to various concentrations of the two pesticides and Hg individually and simultaneously. Results showed that there was a close relationship between urease activity and organic matter content in soil. Chlorimuron-ethyl and furadan could both activate urease in the 4 soils. The maximum increment of urease activity by chlorimuronethyl was up to 14%-18%. There was almost an equal increase （up to 13%-21%） in the urease activity by furadan. On the contrary, Hg markedly inhibited soil urease activity. A logarithmic equation was used to describe the relationship （P〈0.05） between the concentration of Hg and the activity of soil urease in the 4 tested soils. Semi-effect dose （ED50） values by the stress of Hg based on the inhibition of soil urease in the 4 soils were 88, 5.5, 24 and 20 mg/kg, respectively, according to the calculation of the corresponding equations. The interactive effect of chlorimuron-ethyl or furadan with metal Hg on soil urease was mainly synergic at the highest tested concentrations.     

Organochlorine pesticides in soils under different land usage in the Taihu Lake region, China

A field study was conducted in the Taihu Lake region, China in 2004 to reveal the organochlorine pesticide concentrations in soils after the ban of these substances in the year 1983. Thirteen organochlorine pesticides (OCPs) were analyzed in soils from paddy field, tree land and fallow land. Total organochlorine pesticide residues were higher in agricultural soils than in uncultivated fallow land soils. Among all the pesticides, ΣDDX (DDD, DDE and DDT) had the highest concentration for all the soil samples, ranging from 3.10 ng/g to 166.55 ng/g with a mean value of 57.04 ng/g and followed by ΣHCH, ranging from 0.73 ng/g to 60.97 ng/g with a mean value of 24.06 ng/g. Dieldrin, endrin, HCB and α-endosulfan were also found in soils with less than 15 ng/g. Ratios of p,p'-(DDD DDE)/DDT in soils under three land usages were: paddy field ＞ tree land ＞ fallow land, indicating that land usage inlfuenced the degradation of DDT in soils. Ratios of p,p'-(DDD DDE)/DDT ＞1, showing aged residues of DDTs in soils of the Taihu Lake region. The results were discussed with data from a former study that showed very low actual concentrations of HCH and DDT in soils in the Taihu Lake region, but according to the chemical half-lives and their concentrations in soils in 1980s, the concentration of DDT in soils seemed to be underestimated. In any case our data show that the ban on the use of HCH and DDT resulted in a tremendous reduction of these pesticide residues in soils, but there are still high amounts of pesticide residues in soils, which need more remediation processes.     

Alterations of organ histopathology and metallolhionein mRNA expression in silver barb, Puntius gonionotus during subchronic cadmium exposure

Common silver barb,Puntius gonionotus,exposed to the nominal concentration of 0.06 mg/L Cd for 60 d,were assessed for histopathological alterations(gills,liver and kidney),metal accumulation,and metallothionein(MT)mRNA expression.Fish exhibited pathological symptoms such as hypertrophy and hyperplasia of primary and secondary gill lamellae,vacuolization in hepatocytes,and prominent tubular and glomerular damage in the kidney.In addition,kidney accumulated the highest content of cadmium,more than gills and liver.Expression of MT mRNA was increased in both liver and kidney of treated fish.Hepatic MT levels remained high after fish were removed to Cd-free water.In contrast,MT expression in kidney was peaked after 28 d of treatment and drastically dropped when fish were removed to Cd-free water.The high concentrations of Cd in hepatic tissues indicated an accumulation site or permanent damage on this tissue.