Kraft mill residues effects on Monterey pine growth and soil microbial activity

The production of bleached Kraft pulp generates inorganic and organic residues that are usually deposited on the soil surface or land-filled. Studies conducted to address the impact of these wastes on the environment are scarce. In this work, Monterey pine (Pinus radiata D. Don), an important tree for pulping, was evaluated for germination and development under greenhouse conditions in forest soils exposed to solid residues of the cellulose industry using the Kraft process. Soils exposed to 10 to 60% ashes, 10 to 70% fly ashes, or 10 to 30% dregs allowed substantial seed germination and seedling growth. In contrast, soils exposed to low proportions of brown rejects, grits, or a mixture of all these residues were detrimental for germination, plant growth, or both. The strongest negative effect (no germination) was observed with as low as 10% grits. The changes in pH and/or water content caused by solid wastes did not correlate with detrimental effects observed in various soil-residue combinations. No significant changes in the microbial community of soils exposed to these solid residues were observed by determination of culturable counts, or by terminal-restriction fragment length polymorphism analysis of the microbial community DNA. The presence of organic residues did not affect the ability of the soil microbial community to remove typical pulp bleaching chloroaromatics. However, inorganic wastes strongly decreased the removal of such compounds.     

中药渣絮凝剂处理造纸废水的研究

本文介绍了一种天然高分子絮凝剂中药渣的制备,并用于处理造纸废水。结果表明,中药渣对造纸废水有良好的絮凝效果。适宜ｐＨ值为６．５～９．５;最佳絮凝剂投加量为０．２５０ｇ／ｌ。     

水解-气浮-接触氧化处理草浆造纸废水

本文介绍了采用水解-气浮-接触氧化法对某草浆造纸废水原有废水处理工艺改造，经过一年多的运行监测，结果表明：处理后出水COD、BODs、SS等各项指标均优于《造纸工业污染物排放标准》（GWPB2-199）的要求。     

碱回收技术在棉浆粕行业废水治理中的应用

结合国内棉浆粕行业废水治理的现状,对碱回收技术的原理、工艺进行了介绍分析,并结合工程实例,对碱回收工艺在棉浆粕行业废水治理中的应用进行了探讨。     

CO2-free paper?

Black liquor gasification–combined cycle (BLGCC) is a new technology that has the potential to increase electricity production of a chemical pulping mill. Increased electricity generation in combination with the potential to use biomass (e.g. bark, hog fuel) more efficiently can result in increased power output compared to the conventional Tomlinson-boiler. Because the BLGCC enables an integrated pulp and paper mill to produce excess power, it can offset electricity produced by power plants. This may lead to reduction of the net-CO₂ emissions. The impact of BLGCC to offset CO₂ emissions from the pulp and paper industry is studied. We focus on two different plant designs and compare the situation in Sweden and the US. The CO₂ emissions are studied as function of the share of recycled fibre used to make the paper. The study shows that under specific conditions the production of “CO₂-free paper” is possible. First, energy efficiency in pulp and paper mills needs to be improved to allow the export of sufficient power to offset emissions from fossil fuels used in boilers and other equipment. Secondly, the net-CO₂ emission per ton of paper depends strongly on the emission reduction credits for electricity export, and hence on the country or grid to which the paper mill is connected. Thirdly, supplemental use of biomass to replace fossil fuel inputs is important to reduce the overall emissions of the pulp and paper industry.     

Biomass use in chemical and mechanical pulping with biomass-based energy supply

The pulp and paper industry is energy intensive and consumes large amounts of wood. Biomass is a limited resource and its efficient use is therefore important. In this study, the total amount of biomass used for pulp and for energy is estimated for the production of several woodfree (containing only chemical pulp) and mechanical (containing mechanical pulp) printing paper products, under Swedish conditions. Chemical pulp mills today are largely self-sufficient in energy while mechanical pulp mills depend on large amounts of external electricity. Technically, all energy used in pulp- and papermaking can be biomass based. Here, we assume that all energy used, including external electricity and motor fuels, is based on forest biomass. The whole cradle-to-gate chain is included in the analyses. The results indicate that the total amount of biomass required per tonne paper is slightly lower for woodfree than for mechanical paper. For the biomass use per paper area, the paper grammage is decisive. If the grammage can be lowered by increasing the proportion of mechanical pulp, this may lower the biomass use per paper area, despite the higher biomass use per unit mass in mechanical paper. In the production of woodfree paper, energy recovery from residues in the mill accounts for most of the biomass use, while external electricity production accounts for the largest part for mechanical paper. Motor fuel production accounts for 5–7% of the biomass use. The biomass contained in the final paper product is 21–42% of the total biomass use, indicating that waste paper recovery is important. The biomass use was found to be about 15–17% lower for modelled, modern mills compared with mills representative of today's average technology.     

Ink and dirt behavior in pulping after artificial aging of cold-set offset printed newspapers in different humidity conditions

Although moisture has a decisive role in the permanence of cellulose and unprinted paper, its role in ink release from the surface of printed recovered papers remains unclear. This work aimed to determine whether various relative humidity levels in the artificial aging test affect ink release from the surface of the paper and its fibers when pulping cold-set offset printed newspapers in alkaline pulping conditions. The results showed that relative humidity variations from 30% to 70% negligibly affected ink release at 60 °C. However, compared with these lower humidity levels, exposure to 90% relative humidity for at least 25 h resulted in a higher ink content bound to fibers, a greater formation of visible dirt specks after pulping and a smaller formation of microscopic ink particles. In practical applications, the accurate estimation of climate effects during the storage and the transportation of recycled papers requires that humidity conditions are taken into account while performing artificial aging tests with paper products.     

Deinking of recycled pulps using column flotation: energy and environmental benefits

Deinking of recycled pulps is an important operation intended to provide pulps appropriate for making paper and paperboard products from recycled wastepaper. Conventionally, deinking of recycled pulp is conducted in a flotation cell equipped with an agitator. We have investigated the applicability of a new flotation cell based on a column without an agitator present to accomplish the deinking of typical wastepaper feedstocks and also a feedstock consisting of rejects from a conventional deinking cell. Experimental results on the deinking operation indicate that it is possible to achieve deinking of a mixture of photocopier and laserprinted paper in the column flotation cell. The performance of the column, as measured by the resultant pulp’s brightness and ink particle size distributions, is comparable to that of a conventional laboratory cell which incorporates severe agitation regimens. Thus, it is found that the agitator can be eliminated by using the column flotation design which could yield significant electrical energy savings in addition to savings in capital costs and other operational and maintenance costs. A series of deinking experiments were also performed on a feedstock consisting of rejected waste obtained from a conventional cell in a pilot plant. We found that deinking of the rejected waste could yield significant usable fiber. This indicates the potential of the column flotation technique in enhancing the reuse of a waste component thus reducing the volume of deinking waste rejected into the environment.     

碱法草浆造纸黑液厌氧生物降解研究

采用中温(34±2℃)全混合式厌氧反应器处理蒽酸和硫化烧碱草浆造纸黑液。对比厌氧发酵结合物化前或后处理两种方法进行试验,厌氧生物降解COD_(er)去除率分别为61.2～75.3％和34.9～46.2％,COD_(er)总去除率分别为80.0～87.6％和68.4～75.8％。在厌氧发酵稳态运行条件下,对发酵污泥中主要微生物类群和数量进行了研究。     

Constraints to improved energy efficiency in agricultural pumpsets: the case of India

Supply to electrical pumpsets for irrigation purposes accounts for about 25% of the total electricity sold in India. The number of electrical pumpsets is expected to increase from 8.5 million in 1989–90 to 10.5 million in 1994–95. Low load factors (10–12%) and low densities (1–4 pumpsets/km²) mean large investments for the electric utility in order to supply electricity for irrigation. It is reported that there exists a potential to save at least 10% of the electricity supplied to this sector by means of simple retrofit measures. However, conditions in the field pose constraints to such retrofits. Some of those constraints are highlighted in this paper. It is also suggested that immediate attempts be made to ensure that all new connections are energy efficient. This paper suggests that the additional cost incurred to ensure new energy efficient connections and to maintain retrofit energy efficient pumpsets must be looked on as a necessary cost for energy efficiency.     

An intergrated waste survey and environmental effects of COGIDO, a bleached pulp and paper mill in Vietnam, on the receiving waterbody

An integrated investigation on wastewater characterization and the environmental effects from the COGIDO pulp and paper mill in Bien Hoa Industrial Estate, Vietnam, a chlorine bleached soda integrated pulp and paper mill operating without a chemical recovery system, on the receiving water body was conducted during the rainy and dry seasons in 1993 and 1995. The pollution load from the mill was very high in terms of BOD, COD and SS (COD_m: 58.7 t/d; BOD: 33.3 t/d and SS: 25.1 t/d). The effluent toxicity was determined using four toxicity tests: the green micro-alga, Selenastrum capricornutum, Microtox (marine bacteria: Photobacterium phosphoreum), the duckweed, Lemna aequinoctialis, and fish (silver barb: Puntius gonionotus, and Tilapia: Tilapia nilotica). Selenastrum capricornutum was the most sensitive among the tested organisms. The mill toxicity emission rate (TER) was as high as 338 610 (Selenastrum test). The bleaching-pulp and semi-chemical pulp plants which contributed the largest pollution load to the total COGIDO effluent, therefore, were targeted for abatement measures. Physico-chemical parameters as well as qualitative and quantitative aquatic organism composition for the river water were established. The BOD₅ and COD values exceeded the potable surface water standard by a factor of 2 to 4. The species diversity and abundance of the phytoplankton, zooplankton and zoobenthos were found to be lower (20–40%) than that of unpolluted rivers in Vietnam, whereas pollution-indicator species increased up to four times during the dry season 1995.     

电除尘器节能优化控制系统在电厂的应用

介绍了电除尘器节能的基本原理及一种新型电除尘器节能优化控制系统,以及该节能技术在电厂的应用实例。     

超滤技术处理造纸废水的研究与应用

介绍了超滤技术及其优点,其在制浆废液、漂白废水、纸机白水的处理中的研究应用进展;分析了超滤技术处理造纸废水中的膜污染;指出了影响超滤技术处理造纸废水应用的因素,最后提出了今后的研究方向。     

新型节能电源控制技术在电除尘器上的应用

对当前电除尘器的主流节能技术进行了综合分析和论证,指出应通过先进的电源控制产品优化除尘器运行方式来实现除尘器的节能高效运行,利用高频电源技术达到电除尘器节能减排的目的。     

污泥厌氧消化预处理技术综述

全球环境问题已成为国际社会关注的焦点,围绕全球气候变化,降低温室气体排放,寻求再生能源,节能减排已成为目前国际科技发展的方向。通过"十一五"污水处理厂的建设,每年污泥产量已接近3000万吨(含水率80%脱水污泥计)以上,且以每年10%的速度递增。其处理与处置是制约社会经济发展的重要问题。但是,城市污泥蕴含有大量生物质能,通过借鉴国外先进技术与经验,开发城市污泥生物质能提取和利用技术,对我国节能减排具有重要战略意义。由于细胞壁的存在,使得污泥水解成为限制厌氧消化效率的重要瓶颈,而污泥强化预处理可有效提高污泥细胞壁的破坏,溶出胞内有机物,最大化回收剩余污泥中的有机能源。目前,预处理技术较多,如超声波预处理、热处理、微波预处理、碱解处理、臭氧预处理等,本文从物理、化学等角度分析了不同预处理对厌氧消化技术的影响。     

Paper and biomass for energy?: The impact of paper recycling on energy and CO2 emissions

The pulp and paper industry is placed in a unique position as biomass used as feedstock is now in increasingly high demand from the energy sector. Increased demand for biomass increases pressure on the availability of this resource, which might strengthen the need for recycling of paper. In this study, we calculate the energy use and carbon dioxide emissions for paper production from three pulp types. Increased recycling enables an increase in biomass availability and reduces life-cycle energy use and carbon dioxide emissions. Recovered paper as feedstock leads to lowest energy use (22 GJ/t) and CO₂ emissions (−1100 kg CO₂/t) when biomass not used for paper production is assumed to be converted into bio-energy. Large differences exist between paper grades in e.g. electricity and heat use during production, fibre furnish, filler content and recyclability. We found large variation in energy use over the life-cycle of different grades. However, in all paper grades, life-cycle energy use decreases with increased recycling rates and increased use of recovered fibres. The average life-cycle energy use of the paper mix produced in The Netherlands, where the recycling rate is approximately 75%, is about 14 GJ/t. This equals CO₂ savings of about 1 t CO₂/t paper if no recycled fibres would be used.     

四川省制浆造纸行业可持续发展建议

造纸业是与民生关联度极高的行业.为改变国内造纸行业污染局面、整合企业规模、合理原料结构、提高技术装备、改革落后生产工艺,国家先后出台了多项政策规定.特别是2008年新的<制浆造纸工业水污染物排放标准>(GB3544)颁布后,四川省制浆造纸行业面临巨大的整改压力.如何抓住产业调整机遇,加快产品结构调整和生产方式转变,努力...     

Biosolids-derived nitrogen mineralization and transformation in forest soils

Utilization of biosolids through land application is becoming increasingly popular among wastewater managers. To minimize the potential contamination of receiving waters from biosolids-derived nitrogen (N), it is important to understand the availability of N after land application of biosolids. In this study, four secondary biosolids (two municipal and two pulp and paper industrial biosolids) were used in a laboratory incubation experiment to simulate N mineralization and transformation after land application. Municipal biosolids were from either aerobically or anaerobically digested sources, while pulp and paper industrial biosolids were from aerated wastewater stabilization lagoons. These biosolids were mixed with two New Zealand forest soils (top 100 mm of a volcanic soil and a brown soil) and incubated at two temperatures (10 and 20 degrees C) for 26 wk. During incubation, mineralized N was periodically leached from the soil-biosolids mixture with 0.01 M CaCl2 solution and concentrations of NH4 and NO3 in leachate were determined. Mineralization of N from aerobically digested municipal biosolids (32.1%) was significantly more than that from anaerobically digested biosolids (15.2%). Among the two pulp and paper industrial biosolids, little N leached from one, while as much as 18.0% of total organic N was leached from the other. As expected, mineralization of N was significantly greater at 20 degrees C (average 22.8%) than at 10 degrees C (average 9.7%). It was observed that more N in municipal biosolids was mineralized in the brown soil, whereas more N in pulp and paper industrial biosolids mineralized in the volcanic soil. Transformation of NH4 to NO3 was affected by soil type and temperature.     

Resource conservation in the pulp and paper industries—rational-use-of-energy approach

Sharp rises in energy prices have generated an interest in the pulp and paper industries in cogeneration and heat pump applications. However, the institutional and industry-specific barriers to their implementation, despite economic viability, indicate the inadequacies of the energy conservation and energy saving approaches to minimise energy costs. A systems approach, referred to as rational-use-of-energy, is proposed to overcome some of the barriers and to highlight the conservation potential of other resources, such as chemicals and water at appreciably low effluent loads.     

Evaluation of energy savings by using high efficiency motors in a thermal power station

This paper presents potential energy savings by installing high-efficiency motors instead of existing ones and their impact on greenhouse gases emissions reductions. This research study of the energy efficiency of electric motors has been performed in a typical thermal power plant. In the literature, the focus has been mainly on separate and away electric motors from operating facilities. The important advantage of this paper over other studies is that it uses the actual motors’ efficiency in the evaluation. The gains both in terms of electrical energy savings and in terms of financial economy by using high-efficiency motors have been discussed. As a result, the energy saving can be expected as 12.6% at the operating rate. This excellent result also reduces greenhouse gas emission by 1,423 tons every year. The analysis of the data provided an overview on energy losses often generated by the degradation and rewinding of electrical motors. This study represents very encouraging results that will help energy managers of industrial plants to become more involved in energy efficiency strategies.