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1.
Several theoretical models have been proposed to explain the new heavy mesons discovered in 1974, among them the charm model and the color model. Recent experiments strongly support the charm model. Following the historical development from isospin-symmetry SU(2) over isospin-strangeness-symmetry SU(3) to isospin-strangeness-charm-symmetry SU(4), the present article discusses the basic assumptions of the model and its predictions concerning the production and decay of charmed particles. In a second article the current status of the model's experimental verification is reviewed.  相似文献   

2.
The effects of indoor radon decay product behavior on overall concentrations have generally been characterized using uniformly-mixed models, mathematical formulations based on steady-state macroscopic mass-balances, assuming uniform concentrations within the enclosure. The uniformly-mixed model parameterizes the deposition process as a constant volumetric removal rate, given different values for the free and attached progeny. The model requires prior knowledge of the deposition rates, and assumes them to be constant, independent of environmental conditions, and identical for all decay products. There has generally been little agreement regarding the actual values of the deposition rates, and the uncertainty in these required values presents an important limitation.In response to the limitations of existing mass-balance models, an indoor radon mass-transport model, RADTRAN, was developed using a microscopic mass-balance. Deposition by molecular diffusion is accounted for through boundary conditions, and deposition velocity is calculated based on the concentration distribution near the wall. Parametric sensitivity studies using RADTRAN examined the sensitivity of the deposition of radon decay products to several factors: the size of the free progeny (measured by its diffusivity, Df), particle concentration (using the attachment rate, X), and air motion. Deposition is described in terms of the deposition velocities of the free and attached progeny, uf and ua. The development of RADTRAN is described in a companion paper. This paper presents the results of the parametric sensitivity studies examining the influence of environmental conditions on radon progeny deposition. Results primarily focus on the influence on the free mode of the first radon decay product, 218Po. RADTRAN is also used to examine the variations of deposition velocity between the decay products.  相似文献   

3.
Commonly used mathematical models of indoor radon decay product behavior are based on macroscopic mass-balances, often referred to as ‘uniformly-mixed models’. The uniformly-mixed model's applicability is limited by its inability to track the movement of pollutants from their sources to other areas within the enclosure, to permit spatial- or time-dependent sources, or to take proper account of interactions with macroscopic surfaces. Although the uniformly-mixed model parameterizes the deposition process as a constant volumetric removal rate, in reality the deposition process is actually a surface phenomenon and is strongly affected by environmental conditions.This paper describes the development of RADTRAN, a two-dimensional radon progeny transport model that begins with the differential conservation equations describing the motion of air and the transport of reactive pollutants, introduces appropriate boundary conditions to represent surface deposition, and then calculates the concentration distribution of radon progeny throughout the entire region of interest. Knowing the concentration gradient near the surface, a local mass-transfer coefficient (the deposition velocity) can be determined as a function of environmental conditions. RADTRAN simulations have been based on several flow conditions: buoyancy-driven recirculating enclosure flows, free and forced-convection boundary layer flows, and one-dimensional diffusion. Free progeny diffusivity, Df, and attachment rate, X, were varied over representative ranges. For these conditions, RADTRAN calculated free deposition velocities of uf = 0.014–0.079 cm s−1, for 218Po. RADTRAN predictions are compared to a range of experimental measurements. It was found that the predicted range of deposition velocities is in rough agreement with findings from experiments conducted in flow conditions similar to the simplified flows used in RADTRAN.  相似文献   

4.
Formic acid was used for the nitrate reduction as a reductant in the presence of Pd:Cu/γ-alumina catalysts. The surface characteristics of the bimetallic catalyst synthesized by wet impregnation were investigated by SEM, TEM-EDS. The metals were not distributed homogeneously on the surface of catalyst, although the total contents of both metals in particles agreed well with the theoretical values. Formic acid decomposition on the catalyst surface, its influence on solution pH and nitrate removal efficacy was investigated. The best removal of nitrate (50 ppm) was obtained under the condition of 0.75 g/L catalyst with Pd:Cu ratio (4:1) and two fold excess of formic acid. Formic acid decay patterns resembled those of nitrate removal, showing a linear relationship between kf (formic acid decay) and k (nitrate removal). Negligible amount of ammonia was detected, and no nitrite was detected, possibly due to buffering effect of bicarbonate that is in situ produced by the decomposition of formic acid, and due to the sustained release of H2 gas.  相似文献   

5.
基于2011年7月藻类培养实验期间的实测数据,研究了强壮前沟藻生消过程中水体的散射特性.结果表明,强壮前沟藻本次培养周期共21d,前15 d为生长期,之后进入消亡期;生消过程中水体散射光谱变化明显,叶绿素浓度较低时,散射系数随波长增加近似呈幂函数衰减,而叶绿素浓度较高时,蓝绿光波段散射系数随波长增加呈现近似线性增大趋势,红光波段叶绿素强吸收造成的散射谷更明显;生长期和消亡期时,散射系数与叶绿素浓度幂函数回归的可决系数均随波长增加逐渐增大,750 nm波段达到最大值,R2分别为0.95、0.97;生长期时,蓝光波段散射占总散射量的比例逐渐减小,而红光波段逐渐增大,绿光波段变化较小,但基本呈现增大趋势,水色由蓝绿色逐渐变为红褐色,消亡期时,恰恰相反;生长期和消亡期的绿蓝、红蓝、红绿波段散射比与叶绿素浓度均存在正相关关系,说明随叶绿素浓度增加水色逐渐趋近于长波颜色.  相似文献   

6.
Submersed macrophytes decay is an important natural process and has important role in mass and energy flow in aquatic ecosystems. However, little is known about the dynamical changes in nutrients release and bacterial community during submersed macrophyte decay in natural environment. In this study, a field observation was conducted in a wetland dominated with Hydrilla verticillata for 36 days. Increase of H2O2 and malondialdehyde (MDA) content and decrease of soluble proteins concentration were detected in leaves during H. verticillata decay. Meanwhile, ammonium-N, soluble microbial products (SMP) and TOC concentration increased in overlying water. According to bacterial 16S rRNA Illumina sequencing analysis, the Shannon values were lower in epiphytic biofilms than deciduous layer sediments. The relative abundances of Proteobacteria, Cyanobacteria and Actinobacteria were higher in epiphytic biofilms than in deciduous layer sediments (P < 0.05). Co-occurrence network analyses showed that a total of 578 and 845 pairs of correlations (|r| > 0.6) were identified from 122 and 112 genera in epiphytic biofilms and deciduous layer sediments, respectively. According to co-occurrence patterns, eight hubs were mainly from phyla Proteobacteria, Acidobacteria and Parcubacteria in epiphytic biofilms; while 37 hubs from the 14 phyla (Proteobacteria, Bacteroidetes, Acidobacteria, Chloroflexi, et al.) were detected in deciduous layer sediments. Our results indicate that bacterial community in deciduous layer sediments was more susceptible than in epiphytic biofilms during decay process. These data highlight the role of microbial community in deciduous layer sediments on nutrients removal during H. verticillata decay and will provide useful information for wetland management.  相似文献   

7.
Disinfection by low-pressure monochromatic ultraviolet (UVC) radiation (253.7 nm) became an important technique to sanitize drinking water and also wastewater in tertiary treatments. In order to prevent the transmission of waterborne viral diseases, the analysis of the disinfection kinetics and the quantification of infectious viral pathogens and indicators are highly relevant and need to be addressed. The families Adenoviridae and Polyomaviridae comprise human and animal pathogenic viruses that have been also proposed as indicators of fecal contamination in water and as Microbial Source Tracking tools. While it has been previously suggested that dsDNA viruses may be highly resistant to UVC radiation compared to other viruses or bacteria, no information is available on the stability of polyomavirus toward UV irradiation. Here, the inactivation of dsDNA (HAdV2 and JCPyV) and ssRNA (MS2 bacteriophage) viruses was analyzed at increasing UVC fluences. A minor decay of 2-logs was achieved for both infectious JC polyomaviruses (JCPyV) and human adenoviruses 2 (HAdV2) exposed to a UVC fluence of 1,400 J/m2, while a decay of 4-log was observed for MS2 bacteriophages (ssRNA). The present study reveals the high UVC resistance of dsDNA viruses, and the UV fluences needed to efficiently inactivate JCPyV and HAdV2 are predicted. Furthermore, we show that in conjunction with appropriate mathematical models, qPCR data may be used to accurately estimate virus infectivity.  相似文献   

8.
Distinctive cues are predicted to evolve when the benefits obtained by the recognition process overcome its costs. When individual recognition is particularly beneficial for both senders and receivers, the expression of strongly distinctive signals is predicted to evolve. On the other hand, it could be predicted that each individual should show a very stable individual signature. In the same perspective, a great stability of the individual signatures could be expected. Lemur catta is the first non-human primate in which olfactory individual recognition has been demonstrated on the basis of the specialized brachial gland secretions. In this paper, I performed gas chromatograph analyses of right and left gland samples collected in two different periods (breeding and non-breeding seasons) from seven males. The aim was to verify if a diversification in such cues, already demonstrated at the inter-individual level, also occurs at the intra-individual level between left and right glands. I verified, by discriminant analysis and chemical distance comparisons, that each gland of each lemur has its particular signature that is maintained through time. Moreover, such diversification resulted so marked to make the overall intra-individual chemical differences similar to/as strong as the inter-individual ones. Since in rodents several odors from different glands may be integrated in individual recognition, I suggest that bilateral diversification in L. catta scents may offer an enhanced distinctiveness that could provide benefits in mate choice and social relationships.  相似文献   

9.
This paper describes the results of combining several simple models to assess the changes in plant sensitivity to direct effects of gaseous air pollutants that result from changes in climatic conditions. This research has been carried out within the framework of a project on the integrated assessment of regional air pollution and climate change in Europe (AIR-CLIM). The modulation of plant sensitivity to gaseous pollutants has been studied using a model of stomatal conductance that simulates the flow of water vapor from the atmosphere to the plant interior through the stomata. The model has been applied to Norway spruce (Picea abies L.) and European beech (Fagus sylvatica L.). The critical atmospheric concentration levels for SO2 and NOx adopted in international environmental norms have been modified to maintain in different climate scenarios a concentration level inside the plant equivalent to the critical limit in 1990. These simulated critical concentrations are compared with the predicted atmospheric concentrations. Our work indicates that the response can be very different for the two types of forests and in different regions. In general, climate change sensitivity increases in boreal areas and decreases in temperate areas due to temperature and water stress. If the air pollution levels are in the predicted ranges, the problems are less severe now than in 1990, but the cumulative stress will still be significant.  相似文献   

10.
DGT技术一直以固态结合相原位采集和测量水体、土壤或沉积物中有效态重金属,液态结合相的DGT主要应用于现场水体中金属离子的检测.本研究分别采用固态结合相梯度扩散薄膜(chelex100-DGT)装置和改进的液态结合相梯度薄膜扩散(CDM-PAAS-DGT)装置,对广西甘蔗田土壤中有效态Cd进行了测定.结果表明,2种装置提取的土壤有效态Cd含量与甘蔗(根、茎、叶)体内Cd含量都呈极显著正相关,改进的CDM-PAAS-DGT装置对土壤中有效态Cd的提取能力更强;融合土壤pH、阳离子交换量(CEC)、有机质(OM%)和土壤颗粒组成等理化指标影响,运用多元统计分析,提取出2种主成分因子,建立了多元回归模型.液态结合相DGT技术能较好地预测甘蔗田土壤中Cd的生物有效性,拓展了其应用范围.  相似文献   

11.
Analysis of the higher statistical moments of a hydraulic conductivity (K) and an intrinsic permeability (k) data set leads to the conclusion that the increments of the data and the logs of the data are not governed by Levy-stable or Gaussian distributions. The distribution tails appear to display a Pareto-like power-law decay (i.e. Prob(|x|>s|)∝s−α as s→∞), with α values of ≈2.5 and 3.6, respectively. Unlike the calculations of Liu and Molz (1997), α values were largely independent of lag size. These results suggest that the Levy model does not fit the tail behavior of the data well, even prior to the need for truncation in order to keep the statistical moments of simulated K distributions from becoming unrealistically large. It is suggested also that the fractional diffusion equation, based on an underlying Levy motion rather than the usual Brownian motion, might be better justified if porosity variations, as well as K variations, were considered. For the past 10 years, hydrologists and petroleum scientists have explored the use of non-stationary stochastic processes with stationary increments as models for log hydraulic conductivity distributions — the so-called scaling fractal models. Initially, Gaussian processes were used based on fractional Brownian motion. Later, a non-Gaussian model, fractional Levy motion, was suggested as a more realistic alternative. Even more recently, Levy multi-fractals have been proposed as direct models for K variations. In the on-going effort to arrive at the most practical and realistic model for K or log(K) increments, the present communication attempts to develop useful information by presenting a careful analysis of the tail behavior of K and log(K) data sets. It is concluded that although more realistic than the Gaussian model, the Levy model over-estimates the variability inherent in the two carefully measured data sets that were studied.  相似文献   

12.
铜、锌对小麦的联合毒性及其预测模型研究   总被引:1,自引:1,他引:0  
利用溶液培养实验,研究了不同Ca浓度和Cu/Zn配比下,Cu、Zn对小麦的联合毒性;基于毒性单位模型(TU)和生物配体模型(BLM),建立了Cu-Zn对小麦的联合毒性预测模型TUfmix-BLM.结果表明,随着溶液中Ca浓度增加,单一Cu和Zn的毒性均明显减弱.不同Ca浓度、不同Cu/Zn浓度配比下(1∶50、1∶200、1∶800),Cu-Zn联合毒性均表现为加和作用.基于Cu、Zn单一毒性的BLM络合常数,结合TU模型,预测了CuZn对小麦的联合毒性.与单独利用TU模型相比,TUfmix-BLM预测的RMSE从13.06减小到10.01,R2从0.89增加到0.94,表明TUfmix-BLM模型可以很好地预测Cu-Zn的联合毒性.  相似文献   

13.
Although pharmaceuticals have been detected in the environment only in the range from ng/L to g/L, it has been demonstrated that they can adversely affect the health status of aquatic organisms. Lysosomal membrane stability (LMS) has previously been applied as an indicator of cellular well-being to determine health status in bivalve mussels. The objective of this study is to evaluate LMS in Ruditapes philippinarum haemolymph using the neutral red retention assay (NRRA). Clams were exposed in laboratory conditions to caffeine (0.1, 5, 15, 50 μg/L), ibuprofen (0.1, 5, 10, 50 μg/L), carbamazepine and novobiocin (both at 0.1, 1, 10, 50 μg/L) for 35 days. Results show a dose-dependent effect of the pharmaceuticals. The neutral red retention time measured at the end of the bioassay was significantly reduced by 50% after exposure to environmental concentrations (p < 0.05) (caffeine = 15 μg/L; ibuprofen = 10 μg/L; carbamazepine = 1 μg/L and novobiocin = 1 μg/L), compared to controls. Clams exposed to these pharmaceuticals were considered to present a diminished health status (retention time < 45 min), significantly worse than controls (96 min) (p < 0.05). The predicted no environmental effect concentration (PNEC) results showed that these pharmaceuticals are very toxic at the environmental concentrations tested. Measurement of the alteration of LMS has been found to be a sensitive technique that enables evaluation of the health status of clams after exposure to pharmaceuticals under laboratory conditions, thus representing a robust Tier-1 screening biomarker.  相似文献   

14.
The effect of cyanobacterial bloom decay on water quality and the complete degradation of cyanobacterial blooms in a short period were examined by an enclosure experiment in Gonghu Bay of Lake Taihu,China.Water quality parameters as well as taste and odor compounds during the breakdown of cyanobacterial blooms were measured.Results showed that the decay of cyanobacterial blooms caused anoxic water conditions,decreased pH,and increased nutrient loading to the lake water.The highest concentrations of dimethyl sulfide (DMS),dimethyl trisulfide (DMTS),and β-cyclocitral were observed in the anoxic water,at 62331.8,12413.3,and 1374.9 ng/L,respectively.2-Methylisoborneol was dominant during the live growth phase of cyanobacterial blooms,whereas DMS and DMTS were dominant during the decomposition phase.Dissolved oxygen,pH,and chlorophyll a were negatively correlated with DMS,DMTS,and β-cyclocitral,whereas total phosphorus,total nitrogen,and ammonium (NH4+-N) were positively correlated with DMS,DMTS,β-cyclocitral,and β-ionone.The experimental results suggested that preventing the anaerobic decomposition of cyanobacterial blooms is an important strategy against the recurrence of a malodor crisis in Lake Taihu.  相似文献   

15.
In fossilised vertebrates, the presence of soft tissues is the most obvious way to determine aspects of anatomy and functional morphology; however, occurrences are rare and other lines of evidence must be sought to indicate its extent and strength. For example, pterosaurs possessed a large wing membrane that enabled powered flight but other tissues are not widely preserved. A semi-quantitative analysis comparing skeletal articulation and completeness of the pterodactyloid Pterodactylus and non-pterodactyloid pterosaur Rhamphorhynchus from Solnhofen-type deposits implies there were anatomical differences between soft-tissue structure and attachments articulating skeletal joints of each. Typically, skeletons of Pterodactylus disarticulate to a greater extent than those of Rhamphorhynchus, which in turn suggests decay progressed to more advanced states in the former. However, this generalisation masks a mosaic of differences between different body parts, for example Rhamphorhynchus tends to lose the wings as complete units but retains a complete and still articulated tail in a greater number of specimens than Pterodactylus.  相似文献   

16.
Some statistical characteristics of concentration (C) and wet deposition (D) for sulfate and nitres in rain water per rain event are described in relation to rainfall amount (R), using the data obtained at Shobara in Japan. The lognormal distributions may be appropriate for C of sulfate and nitrate, and R. In addition, logC of these two compositions has significant correlations with logR. Consequently, the bivariate distribution of C and R is assumed, then, the regression model of logC on logR and that of logD on logR are presented. It is shown that the expectation of logC, given R = r, corresponding to the regression function of logC on logR, is linear to logR, whereas its variance does not depend on r. Similarly, the regression function of logD on logR is linear to logr and its variance is also the same as that of logC on logR. Based on these results, the relationship: β′ = β + 1 (ϱ ≠ 0) is obtained, where β′, β and ϱ are the coefficient of slope of logD on logR, that of logC on logR, and population correlation coefficient between logC and logR, respectively. The values of β are −0.476 for sulfate and −0.479 for nitrate. From this result, concentrations of sulfate and nitrate are approximately predicted from rainfall amount by the inverse half-power relationships.  相似文献   

17.
Mechanistic cloud deposition models are very useful in the routine quantification of cloudwater deposition to forest canopies. In order to test, in a natural field situation, several assumptions in these models, a passive string cloudwater collector, a small artificial tree, and a living Norway spruce were exposed to cloudwater on a raised platform at the summit (elevation, 1686 m) of Whitetop Mountain, Virginia over a 5 month period. Cloudwater collection rates by these three collectors were used to examine relationships between these rates and measured values for two important meteorological variables in the models, liquid water content and wind speed, the product of which is the horizontal cloudwater flux. Collection rates for all three collectors were predicted moderately well by horizontal cloudwater flux (R2 ranged from 0.54 to 0.73; p<0.0001) across all hours of observation, but were least strongly related when liquid water content was low, probably because of various measurement uncertainties under this condition. For all three collectors, simple linear regressions using the horizontal water flux to predict collection rates were not appreciably improved by inclusion of a cloudwater collection efficiency term or by conversion to binomial or curvilinear models. Cloudwater collection efficiency for all three collectors was related to the logarithm of horizontal water flux, as predicted by the models, only when this relationship was analyzed within individual cloud events. Between individual cloud events, collection efficiency varied across a wide range (0.12–0.50 for the spruce tree), with efficiencies much higher during events of short duration. Cloudwater collection efficiency was often lower than predicted by cloud deposition models, possibly because the models use wind speed measurements which do not take into account reductions in wind speed occurring within needle clusters on branches. Collection rates for all three collectors correlated highly with each other (R2 ranged from 0.72 to 0.88; p<0.0001), as well as with a mature red spruce canopy. It was concluded that either the string collector or an artificial tree such as the one used in this study would serve as a good surrogate collector for living spruce tree crowns.  相似文献   

18.
水中细菌内毒素污染特性及检测方法研究进展   总被引:3,自引:2,他引:1  
张灿  刘文君  张明露  田芳  杨毅  安代志 《环境科学》2014,35(4):1597-1601
细菌内毒素是革兰氏阴性菌和某些蓝藻细胞壁的脂多糖复合物,主要由菌体死亡解体后释放,是常见的外源性致热原,具有强免疫刺激能力,与人类多种疾病密切相关.内毒素分子的耐受力好,耐热性强,不易被常规方法去除.饮用水和水环境中的内毒素可通过多种暴露途径导致机体潜在的健康风险,成为近年来研究的热点.本文概述了细菌内毒素的理化特性和生物活性,综述了细菌内毒素多种检测方法的研究进展,并对细菌内毒素的法定检测方法——鲎试验用于检测水体环境样品的干扰问题和排除方法进行分析.  相似文献   

19.
The photochemical box model (PBM) developed in the present study is based on the principle of mass conservation. It has a horizontal domain of the size of a typical city and a vertical dimension defined by the mixed-layer height. The concentration of any pollutant is determined by horizontal advection, vertical entrainment, source emissions and chemical reactions. A one-dimensional high resolution boundary layer model by Blackadar (Preprints, Third Symp. on Atmospheric Turbulence, Diffusion, and Air Quality, Raleigh, Am. Met. Soc., pp. 443–447, 1976; Advances in Environmental Sciences and Engineering, Vol. 1, No. 1 (edited by Pfafflin J. and Ziegler E.), pp. 50–85. Gordon and Breach, New York, 1979) has been incorporated in the PBM and further developed to consider the effect of urban heat islands in the simulation of mixed layer height. The predicted mixed-layer heights compare very well with observations. The gas phase chemical kinetic mechanism used in the Regional Acid Deposition Model II (RADM2) and that of an earlier version of PBM have been used to calculate the contributions of chemical reactions to the changes of pollutant concentrations. Detailed analysis and comparisons of the two chemical mechanisms have been made. The simulated pollutant concentrations using both chemical mechanisms are in very good agreement with available observations for CO, NO, NO2 and O3. A radiative transfer model developed by Madronich (J. geophys. Res.92, 9740–9752, 1987) has been incorporated in the PBM for the calculation of actinic flux and photolytic rate constants. Height-averaged and radiation-corrected photolytic rate constants are used for the photochemical reactions. Budget analyses conducted for CO, NO, NO2 and O3 have enhanced our understanding of the relative contributions of horizontal advection, vertical entrainment, source emissions and chemical reactions to the overall rate of change of their concentrations. Model predictions are not sensitive to the large number of peroxy radical-peroxy radical reactions in the RADM2 chemical mechanism under urban conditions.  相似文献   

20.
The Kyoto Protocol entering into force on 16 February 2005 continues to spur interest in development of carbon trading mechanisms internationally and domestically. Critical to the development of a carbon trading effort is verification that carbon has been sequestered, and field level measurement of C change is likely cost prohibitive. Estimating C change based on agricultural management practices related to carbon sequestration seems more realistic, and analysis of satellite imagery could be used to monitor and verify these practices over large areas. We examined using Landsat imagery to verify crop rotations and quantify crop residue biomass in north central Montana. Field data were collected using a survey of farms. Standard classification tree analysis (CTA) and boosted classification and regression tree analysis (BCTA) were used to classify crop types. Linear regression (LM), regression tree analysis (RTA), and stochastic gradient boosting (SGB) were used to estimate crop residue. Six crop types were classified with 97% accuracy (BCTA) with class accuracies of 88–99%. Paired t-tests were used to compare the difference between known and predicted mean crop residue biomass. The difference between known and predicted mean residues using SGB was not different than 0 (p-value = 0.99); however root mean square error (RMSE) was large (1981 kg ha−1), implying that SGB accurately predicted regional crop residue biomass but not local predictions (i.e., field or farm level). The results of this study, and previous research classifying tillage practices and estimating soil disturbance, supports using satellite imagery as an effective tool for monitoring and verifying agricultural management practices related to carbon sequestration over large areas.  相似文献   

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