Geologic vs. geographic constraints on cement resources

This study evaluates the importance of geologic and geographic factors in constraining the location of limestone mining operations for the production of cement in the Great Lakes region of the United States. Cities and their infrastructure require abundant cement, which is manufactured from limestone and other quarry products, but expansion of cities limits the locations of these operations. Possible locations of limestone and cement operations are controlled by geologic factors including distribution and mineralogy of geologic formations as well as depth of overburden, and geographic factors including location of wetlands, cities, and other surface features that preclude development of quarries and manufacturing operations. Overlay analysis was used to evaluate the importance of these factors. Results show that, although limestone underlies about a third of the region, almost 50 percent of this limestone is unavailable for quarrying due to coverage by the built environment, protected natural areas, or excessive overburden thickness. When characteristics such as limestone quality are also accounted for, accessible resources shrink to as little as 2 percent of the total land area. Although the remaining 2 percent of land area may supply local needs for some years, geologic factors clearly must be included in long-term regional land use planning.     

浅析电石渣的综合利用

本文对电石渣在建材、环保、化工等多个行业中的应用情况进行了分析，并着重介绍了电石渣替代石灰石生产水泥的工艺。     

Utilisation of high volumes of limestone quarry wastes in concrete industry (self-compacting concrete case)

In limestone quarries, considerable amounts of limestone powders are being produced as by-products of stone crushers. High amounts of powders are being collected and utilisation of this by-product is a big problem from the aspects of disposal, environmental pollution and health hazards. In conventional concrete, the introduction of high volumes of limestone quarry dust to concrete mixes is limited due to its negative effects on water demand and strength of concrete. However, these fines can be efficiently utilised as viscosity enhancer particularly in special concrete (like self-compacting concrete—SCC) applications. Thus, the successful utilisation of this quarry dust in SCC could turn this material into a valuable resource.In this paper the usability of a quarry dust limestone powder in self-compacting paste and concrete applications was investigated. In the first part, the physical and mechanical properties of cement pastes incorporating quarry waste limestone powder (QLP) and a powder produced by direct grinding of limestone (PLP) were compared. In the second part, the performance of quarry waste limestone powder in SCC applications were tested and discussed. Results showed that, it is possible to successfully utilise high amounts of quarry waste limestone powder in producing normal-strength SCCs. Among its observed mechanical advantages, employment of quarry waste limestone powders improved the economical feasibility of SCC production.     

Utilisation of high volumes of limestone quarry wastes in concrete industry (self-compacting concrete case)

In limestone quarries, considerable amounts of limestone powders are being produced as by-products of stone crushers. High amounts of powders are being collected and utilisation of this by-product is a big problem from the aspects of disposal, environmental pollution and health hazards. In conventional concrete, the introduction of high volumes of limestone quarry dust to concrete mixes is limited due to its negative effects on water demand and strength of concrete. However, these fines can be efficiently utilised as viscosity enhancer particularly in special concrete (like self-compacting concrete—SCC) applications. Thus, the successful utilisation of this quarry dust in SCC could turn this material into a valuable resource.In this paper the usability of a quarry dust limestone powder in self-compacting paste and concrete applications was investigated. In the first part, the physical and mechanical properties of cement pastes incorporating quarry waste limestone powder (QLP) and a powder produced by direct grinding of limestone (PLP) were compared. In the second part, the performance of quarry waste limestone powder in SCC applications were tested and discussed. Results showed that, it is possible to successfully utilise high amounts of quarry waste limestone powder in producing normal-strength SCCs. Among its observed mechanical advantages, employment of quarry waste limestone powders improved the economical feasibility of SCC production.     

河南省水泥生产过程中CO2排放量估算

水泥是重要的建筑材料,水泥工业的快速发展有力地支撑了我国经济的高速增长。但水泥生产过程中石灰石分解产生的CO2已成为重要的CO2排放源。根据2006年IPCC提供的水泥生产过程碳排放估算方法,采用全国吨水泥熟料比推算河南水泥熟料产量,对1990--2010年河南水泥生产过程CO2的排放量进行了估算,其结果可为河南省节能减排政策的制定提供科学依据。     

Experimental investigation of wellbore integrity and CO2–brine flow along the casing–cement microannulus

Wellbore integrity is one of the key performance criteria in the geological storage of CO₂. It is significant in any proposed storage site but may be critical to the suitability of depleted oil and gas reservoirs that may have 10’s to 1000’s of abandoned wells. Much previous work has focused on Portland cement which is the primary material used to seal wellbore systems. This work has emphasized the potential dissolution of Portland cement. However, an increasing number of field studies (e.g., Carey et al., 2007), experimental studies (e.g., Kutchko et al., 2006) and theoretical considerations indicate that the most significant leakage mechanism is likely to be flow of CO₂ along the casing–cement microannulus, cement–cement fractures, or the cement–caprock interface.In this study, we investigate the casing–cement microannulus through core-flood experiments. The experiments were conducted on a synthetic wellbore system consisting of a 5-cm diameter sample of cement that was cured with an embedded rectangular length of steel casing that had grooves to accommodate fluid flow. The experiments were conducted at 40 $°$ C and 14 MPa pore pressure for 394 h. During the experiment, 6.2 l of a 50:50 mixture of supercritical CO₂ and 30,000 ppm NaCl-rich brine flowed through 10-cm of limestone before flowing through the 6-cm length cement–casing wellbore system. Approximately 59,000 pore volumes of fluid moved through the casing–cement grooves. Scanning electron microscopy revealed that the CO₂–brine mixture impacted both the casing and the cement. The Portland cement was carbonated to depths of 50–250 $\mu$m by a diffusion-dominated process. There was very little evidence for mass loss or erosion of the Portland cement. By contrast, the steel casing reacted to form abundant precipitates of mixed calcium and iron carbonate that lined the channels and in one case almost completely filled a channel. The depth of steel corroded was estimated at 25– $30\mu$m and was similar in value to results obtained with a simplified corrosion model.The experimental results were applied to field observations of carbonated wellbore cement by Carey et al. (2007) and Crow et al. (2009) to show that carbonation of the field samples was not accompanied by significant CO₂–brine flow at the casing–cement interface. The sensitivity of standard-grade steel casing to corrosion suggests that relatively straight-forward wireline logging of external casing corrosion could be used as a useful indicator of flow behind casing. These experiments also reinforce other studies that indicate rates of Portland cement deterioration are slow, even in the high-flux CO₂–brine experiments reported here.     

我国袋式除尘行业2008年发展综述

综述了2008年我国袋式除尘行业的发展概况;分析了袋式除尘技术在水泥、钢铁与有色冶金、电力、垃圾焚烧等行业的开发应用情况;针对袋式除尘行业在发展过程中存在的主要问题提出了对策建议,并对行业的发展趋势进行了展望。     

Trends and development of steel demand in China: A bottom–up analysis

With economic development, the Chinese steel industry has rapidly expanded over the past three decades. However, this expansion has resulted in many problems, such as increasing energy consumption and excessive environmental pollution. Therefore, it is important to analyze the future steel demand in China. This study presents changes in steel production and apparent steel consumption in the years 1998–2010. Steel is mainly consumed by construction, machinery, automobiles, shipbuilding, railways, petroleum, household appliances and containers, and these nine industries are analyzed separately using stock based models. The study suggests steel demand in China will rise from 600 million t in 2010 to a peak of 753 million t in 2025, and then gradually decrease to 510 million t in 2050. The construction industry is the largest steel consumer, although its share of total steel demand will decrease in the future. Steel demand in automobile manufacturing, by contrast, will increase rapidly before 2035, and its share will increase from 6.0% in 2010 to 19.0% in 2050. Sensitivity analysis on the four major impact factors such as saturation levels, lifetime distributions, GDP and urbanization rate shows that saturation levels of different products greatly affect long-term and short-term steel demands, while GDP and lifetime distributions, especially the lifetime distribution of buildings, mainly affect the short-term and long-term steel demands, respectively.     

The implementation of wood waste ash as a partial cement replacement material in the production of structural grade concrete and mortar: An overview

The timber manufacturing and power generation industry is gradually shifting towards the use of biomass such as timber processing waste for fuel and energy production and to help supplement the electrical energy demand of national electric gridlines. Though timber processing waste is a sustainable and renewable source of fuel for energy production, the thermal process of converting the aforementioned biomass into heat energy produces significant amounts of fine wood waste ash as a by-product material which, if not managed properly, may result in serious environmental and health problems. Several current researches had been carried out to incorporate wood waste ash as a cement replacement material in the production of greener concrete material and also as a sustainable means of disposal for wood waste ash. Results of the researches have indicated that wood waste ash can be effectively used as a cement replacement material for the production of structural grade concrete of acceptable strength and durability performances. This paper presents an overview of the work carried out by the use of wood waste ash as a partial replacement of cement in mortar and concrete mixes. Several aspects such as the physical and chemical properties of wood waste ash, properties of wood waste ash/OPC blended cement pastes, rheological, mechanical and the durability properties of wood waste ash/OPC concrete mix are detailed in this paper.     

我国袋式除尘行业2009年发展综述

综述了2009年我国袋式除尘行业的发展概况;分析了袋式除尘技术在水泥、钢铁与有色冶金、电力、垃圾焚烧等行业的开发应用情况,针对袋式除尘行业在发展过程中存在的主要问题提出了对策和建议,并对行业的发展趋势进行了展望。     

Seaborne iron ore trade in the 1990s

This paper discusses how world steel production and seaborne iron ore trade have grown since 1950. The role of steel production forecasts in determining investment in the iron ore industry is examined. Forecasts for world steel production and the demand and supply of seaborne iron ore in the 1990s are presented. It is predicted that world steel production will increase by 64 million tons between 1991 and 2000. This increase will be located principally in the developing countries and China. The corresponding increase in seaborne iron ore trade will be approximately 55 million tons. Expansion projects will be located mainly in Australia and Brazil, but no greenfield iron ore projects will be undertaken. By the end of the decade, the demand for seaborne iron ore will be equal to its supply.     

Size and performance of anoxic limestone drains to neutralize acidic mine drainage

Acidic mine drainage (AMD) can be neutralized effectively in underground, anoxic limestone drains (ALDs). Owing to reaction between the AMD and limestone (CaCO3), the pH and concentrations of alkalinity and calcium increase asymptotically with detention time in the ALD, while concentrations of sulfate, ferrous iron, and manganese typically are unaffected. This paper introduces a method to predict the alkalinity produced within an ALD and to estimate the mass of limestone required for its construction on the basis of data from short-term, closed-container (cubitainer) tests. The cubitainer tests, which used an initial mass of 4 kg crushed limestone completely inundated with 2.8 L AMD, were conducted for 11 to 16 d and provided estimates for the initial and maximum alkalinities and corresponding rates of alkalinity production and limestone dissolution. Long-term (5-11 yr) data for alkalinity and CaCO3 flux at the Howe Bridge, Morrison, and Buck Mountain ALDs in Pennsylvania, USA, indicate that rates of alkalinity production and limestone dissolution under field conditions were comparable with those in cubitainers filled with limestone and AMD from each site. The alkalinity of effluent and intermediate samples along the flow path through the ALDs and long-term trends in the residual mass of limestone and the effluent alkalinity were estimated as a function of the computed detention time within the ALD and second-order dissolution rate models for cubitainer tests. Thus, cubitainer tests can be a useful tool for designing ALDs and predicting their performance.     

A LINEAR ANALYSIS OF AN URBAN WATER SUPPLY SYSTEM1

The use of linear programming as a planning tool for determining the optimal long-range development of an urban water supply system was explored. A stochastic trace of water demand was synthesized and used as an input to the model. This permitted evaluating the feasibility of imposing demand restrictions as an effective cost reduction mechanism. The City of Lincoln, Nebraska, was used as the urban model. The fundamental problem was to allocate limited water supplies from several sources to an urban load center to minimize costs and comply with system constraints. The study period covered twenty years, and findings indicate the planning direction for stage development during this period. Sensitivity analyses were performed on cost coefficients and demands. Thirteen sources were included in the initial computations. Conclusions were that linear programming and generated demand traces are useful tools for both short- and long-term urban water supply planning. Lowering peak demands results in long-range development of fewer sources of supply and more economic and efficient use of the supplies developed.     

我国脱硫脱硝行业2013年发展综述

综述了2013年我国脱硫脱硝行业的发展环境及发展概况;重点介绍了火电行业、钢铁行业、水泥行业脱硫脱硝产业发展现状;分析了行业市场特点及重要动态;针对行业发展中存在的主要问题提出了解决对策和建议.     

Water Supply Planning Considering Uncertainties in Future Water Demand and Climate: A Case Study in an Illinois Watershed

Ensuring an adequate, reliable, clean, and affordable water supply for citizens and industries requires informed, long-range water supply planning, which is critically important for water security. A balance between water supply and demand must be considered for a long-term plan. However, water demand projections are often highly uncertain. Climate change could impact the hydrologic processes, and consequently, threaten water supply. Thus, understanding the uncertainties in future water demand and climate is critical for developing a sound water supply plan. In Illinois, regional water supply planning attempts to explore the impacts of future water demand and climate on water supply using scenario analyses and hydrologic modeling. This study is aimed at developing a water supply planning framework that considers both future water demand and climate change impacts. This framework is based on the Soil and Water Assessment Tool to simulate the watershed hydrology and conduct scenario analyses that consider the uncertainties in both future water demand and climate as well as their impacts on water supply. The framework was applied to water supply planning efforts in the Kankakee River watershed. The Kankakee River watershed model was calibrated and validated to observed streamflow records at four long-term United States Geological Survey streamflow gages. Because of the many model parameters involved, the calibration process was automated and was followed by a manual refinement, resulting in good model performance. Long-range water demand projections were prepared by the Illinois State Water Survey. Six future water demand scenarios were established based on a suite of assumptions. Climate scenarios were obtained from the Coupled Model Intercomparison Projection Phase 5 datasets. Three representative concentration pathways (RCPs), RCP2.6, RCP4.5, and RCP8.5, are used in the study. The scenario simulation results demonstrated that climate change appears to have a greater impact on water availability in the study area than water demand. The framework developed in this study can also be used to explore the impacts of uncertainties of water demand and climate on water supply and can be extended to other regions and watersheds.     

CO2 emissions from Polish cement industry

The cement industry is one of the most significant sources of anthropogenic emissions of CO₂. It is connected with the specific character of the production processes, during which great quantities of CO₂ are produced. Basic actions to reduce CO₂ emissions recommended by the European Union's, Reference Document on Best Available Techniques in the Cement and Lime Manufacturing Industries, include: reduction of fuel consumption, selection of raw materials with low content of organic compounds and fuels with low coal contribution to heating value. All actions connected with the improvement of energy conversion efficiency of the cement production process cause CO₂ emissions reduction. The use of at most acceptable by the valid standards amounts of waste as raw materials and additives for cement production, also brings about the reduction of significant part of CO₂ emissions. These measures have been and continue to be pursued by the cement factories in Poland. This article describes the evolution of the cement industry in Poland over the period 1998–2008 and the resulting changes in CO₂ emissions and explores the drivers for these changes. The sources of CO₂ emissions in cement industry have been presented in this article as well as a discussion of potential ways to reduce Polish cement industry emissions even further.     

A GIS analysis of suitability for construction aggregate recycling sites using regional transportation network and population density features

Aggregate is used in road and building construction to provide bulk, strength, support, and wear resistance. Reclaimed asphalt pavement (RAP) and reclaimed Portland cement concrete (RPCC) are abundant and available sources of recycled aggregate. In this paper, current aggregate production operations in Virginia, Maryland, and the District of Columbia are used to develop spatial association models for the recycled aggregate industry with regional transportation network and population density features.The cost of construction aggregate to the end user is strongly influenced by the cost of transporting processed aggregate from the production site to the construction site. More than 60% of operations recycling aggregate in the mid-Atlantic study area are located within 4.8 km (3 miles) of an interstate highway. Transportation corridors provide both sites of likely road construction where aggregate is used and an efficient means to move both materials and on-site processing equipment back and forth from various work sites to the recycling operations.Urban and developing areas provide a high market demand for aggregate and a ready source of construction debris that may be processed into recycled aggregate. Most aggregate recycling operators in the study area are sited in counties with population densities exceeding 77 people/km² (200 people/mile²). No aggregate recycling operations are sited in counties with less than 19 people/km² (50 people/mile²), reflecting the lack of sufficient long-term sources of construction debris to be used as an aggregate source, as well as the lack of a sufficient market demand for aggregate in most rural areas to locate a recycling operation there or justify the required investment in the equipment to process and produce recycled aggregate.Weights of evidence analyses (WofE), measuring correlation on an area-normalized basis, and weighted logistic regression (WLR), are used to model the distribution of RAP and RPCC operations relative to transportation network and population distribution data. The models can be used on a regional scale to quickly map the relative site suitability for a RAP or RPCC aggregate recycling operation in a particular area based on transportation network and population parameters. The results can be used to identify general areas to be further evaluated on a site-specific basis using more detailed marketplace information. As transportation or population features change due to planning or actual development, the models can be easily revised to reflect these changes.     

基于三生空间生态服务供给和需求的国土空间规划效益评价研究

国土空间规划是统筹区域资源空间配置、开发管理和布局优化的总体方案,在引领区域协调发展上具有重要意义。国土空间规划必然导致土地利用类型及布局的改变,从而引起经济、社会、生态环境等方面的供给与需求变化。本研究从三生空间耦合协调的角度,通过生态系统服务和人类福祉需求的供需关系,揭示三生空间的供需连接与耦合关系。本研究借助 InVEST模型和生态服务价值当量法对生态系统服务供给与需求进行定量分析,同时引入耦合协调度模型与相对发展度模型,通过对生态系统服务供需变化进行耦合协调类型分析,探究国土空间用地结构调整所产生的供需间的协调关系,并用耦合协调状况对国土空间规划效益进行评价。研究发现,在规划期内宜宾市翠屏区生态系统服务供需总体耦合协调度呈现减小态势。2020-2035年耦合协调度从 0.60降低到 0.59,相对发展度由 1.05减小至 1.01。生态系统服务总体供给盈余明显,但由于供需分布空间差异,城镇地区为主要的供给赤字区域。影响生态系统服务需求的主要因素为环境净化需求,城市化指标对生态系统服务供需相对发展度具有较为普遍的负面影响。     

浅析宁夏水泥行业清洁生产水平现状及对策

水泥行业是宁夏自治区重要的经济支柱之一,同时也是一个污染极严重的产业,给当地环境质量带来了严重影响。通过对宁夏自治区内部分水泥企业进行清洁生产水平调研,从企业的生产规模、生产装备及资源能源利用情况等方面,与《清洁生产标准水泥工业》（HJ/T467-2009）进行对比分析,总结了区内水泥行业清洁水平存在的共性问题,并依此提出了相应的对策建议。