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Dolenec T Serafimovski T Tasev G Dobnikar M Dolenec M Rogan N 《Environmental geochemistry and health》2007,29(1):21-32
The objective of this study was to assess the bulk chemical composition as well as the extent and severity of heavy metal
contamination in the paddy soil of Kočani Field (eastern Macedonia). The results revealed that the paddy soil of the western
part of Kočani Field is severely contaminated with Pb, Zn, As and Cd in the vicinity of the Zletovska River due to irrigation
with riverine water that is severely affected by acid mine and tailing effluents from the Pb–Zn mine in Zletovo. The detected
total concentrations of these metals are far above the threshold values considered to be phytotoxically excessive for surface
soil. The paddy soil in the vicinity of the Zletovska River was also found to exhibit elevated levels of Ba, Th, U, V, W,
Mo, Cu, Sb, Bi, Ag, Au, Hg and Tl, with concentrations above their generally accepted median concentration values obtained
during this study. A correlation matrix revealed that the Mn and Fe oxides/hydroxides are the most important carrier phase
for several trace elements, with the exception of rare earth elements (REEs). These also represent a major sink for the observed
heavy metal pollution of the soil. REEs are mostly associated with two phases: light (L)REEs are bound to K-Al, while heavy
(H)REEs are bound to Mg-bearing minerals. Although there is no direct evidence of a health risk, the paddy soil in the vicinity
of Zletovska River needs further investigation and an assessment should be made of its suitability for agricultural use, particularly
in view of the highly elevated concentrations of Pb, Zn, As and Cd. 相似文献