The Climate Value of Cycling

The reduction of CO₂ emissions constitutes one of the largest challenges of the current era. Sustainable transportation, and especially cycling, can contribute to the mitigation of CO₂ emissions since cycling possesses an intrinsic zero‐emission value. Few studies have been conducted that appraise the CO₂ reduction potential of cycling. Opportunity costs enable the estimation of avoided CO₂ emissions resulting from bicycle trips. The methodology developed in this research allows the attribution of a climate value to cycling by substituting bicycle trips with their most likely alternative transportation modes and calculating the resulting additional CO₂ emissions. The methodology uses data on the current modal shares of cycling mobility, the competition of cycling with other transportation modes, and CO₂ emission factors to calculate the climate value of cycling. When it is assumed that the avoided CO₂ emissions of cycling mobility could be traded on financial carbon markets, the climate value of cycling represents a monetary value. Application of the methodology to the case of Bogotá, Colombia — a city with a current bicycle modal share of 3.3% on a total of 10 million daily trips — results in a climate value of cycling of 55,115 tons of CO₂ per year, corresponding to an economic value of between 1 and 7 million US dollars when traded on the carbon market.     

Carbon flows and carbon use in the German anthroposphere: An inventory

Today, global climate change is one of the most urgent environmental problems. The atmospheric concentration of carbon dioxide (CO₂) has to be stabilised by significant reductions of CO₂ emissions in the next decades to keep the expected temperature rise within tolerable borders. Efforts exceeding the implemented measures to reduce CO₂ emissions in Germany are desirable. An important pre-condition for such measures is a scientific-based inventory of the sources, sinks, and use of carbon.In this paper, we present CarboMoG, i.e. Carbon Flow Model of Germany. CarboMoG is a carbon flow model covering carbon flows, carbon sources and sinks in Germany and the German anthroposphere, showing concurrent energy and non-energy use of carbon sources.The model consists of seven modules in German anthroposphere following the German classification of economic sectors. Carbon flows to and from atmosphere and lithosphere as well as imports and exports were included into the model. The model comprises roughly 220 material flows determined based on material flow procedures for the base year 2000.Main sources of carbon are fossil energy carriers from lithosphere and uptake of CO₂ by crops (52% resp. 48% of all carbon sources). The model calculations show that import of energy carriers dominates total carbon import to Germany (82%). Total non-energy use of carbon in Germany is significantly higher than energy use (386 Mt C and 230 Mt C, resp.). Carbon throughput of Industry is greatest (about 224 Mt C input), followed by Energy (about 129 Mt C input). Agriculture and Forestry & Industry show the highest figure for non-energy use of carbon, energy use of carbon is largest in the Energy sector. Emissions of CO₂ to atmosphere account for 94% of all carbon flows to sinks in Germany. Carbon accumulates in German anthroposphere 5 Mt C in 2000.     

Toward sustainable use of natural resources: Nexus between resource rents,affluence, energy intensity and carbon emissions in developing and transition economies

Sustainable use of natural resources would entail ensuring that derived economic benefits today do not undermine the welfare of generations to come. On this basis, this study examines the nexus between natural resource rents and carbon dioxide (CO₂) emissions disaggregated into production and consumption-based (i.e., trade-adjusted) CO₂ emissions for a selected panel of 45 developing and transition economies over the period 1995–2017. The empirical model also incorporates the impacts of population, affluence, and energy intensity. The results show that affluence increases production-based CO₂ emissions by 1.407%, with the EKC's predicted inverted U-shaped curve only explaining consumption-based CO₂ emissions. Economic reliance on natural resource rents and energy intensification contribute 0.022% and 0.766%, respectively, to CO₂ emissions embedded in territorial production inventories and 0.035% and 0.583%, respectively, to CO₂ emissions embedded in consumption inventories. The bootstrap non-causality test shows that historical data on each variable has significant predictive power for future CO₂ emissions from both sources. The historical information about natural resource rents has significant predictive power over the future levels of affluence and energy intensity. Clearly, the results show that the environmental impact of natural resource rents is stronger when CO₂ emissions are adjusted for trade and varies among the countries, with Bangladesh, Guinea, India, Malaysia, Mexico, Nigeria, Pakistan, Saudi Arabia, Vietnam, and Zimbabwe among the most affected countries. Overall, this study provides motivation for policies to keep the use of natural resources within sustainable limits.     

Comparison and application of different component municipal solid wastes based carbon on adsorption of carbon dioxide

The prepared different components municipal solid wastes based carbons were used to investigate the adsorption of CO₂. The optimum conditions for CO₂ adsorption were investigated firstly. And then, the CO₂ adsorption performance of different components based carbon adsorbents were compared with each other under the optimum parameters. The results illustrated that the triple components (pinewood, acrylic textile, and tire) based carbon exhibited the best adsorption performance, which is 1.522 mmol/g and its physical prosperity was also conducted to interpret the adsorption mechanism. Besides, to further approach to the actual gas, the influence of additional O₂ and SO₂ on CO₂ adsorption properties of ternary-component-based carbon was investigated. The results illustrate that O₂ concentration exerts little effect on adsorption capacity. SO₂ plays the dominated role in the competitive adsorption effect.     

Energy technology modelling of major carbon abatement options

The International Energy Agency Energy Technologies Perspectives (ETP) model is used to assess the prospects for carbon abatement options, including carbon capture and storage, up to 2050. Three main scenarios are considered: a Baseline scenario with current energy policies, an accelerated technology scenario that seeks to return energy-related CO₂ emissions in 2050 to their level in 2005, and a scenario for which CO₂ emissions are reduced at 50% of current levels by 2050. To reach these emissions reduction targets, annual global CO₂ emissions in the year 2050 must be reduced by 35 GtCO₂ to 48 GtCO₂ compared to the Baseline scenario. The analysis presented here shows that a broad portfolio of emissions reducing technologies will need to be deployed across all economic sectors of the global economy to reach these targets. Carbon dioxide capture and storage (CCS) is one of the suite of technologies employed across the globe to reach these targets. CCS adoption occurs in many aspects of the global economy and accounts for 14–19% of all emissions reductions. The total amount of CO₂ captured and stored in deep geologic reservoirs up to 2050 ranges between 5.1 GtCO₂ and 10.4 GtCO₂ in these two climate policy scenarios. Up to 2030, more than half of total CCS deployment takes place in OECD countries. After 2035, emerging economies account for more than half of total CCS use. This paper also demonstrates that as the climate policy becomes more stringent it will be necessary for CCS to deploy more extensively in many different industries outside of the electric power sector which often receives the most attention in discussions of CCS's role in addressing climate change.     

Assessing the current practice and policy with recommendations for emission control strategy for coal‐fired thermal power plants under Indian regulatory framework emphasizing the roles of R&D

On December 7, 2015, the Ministry of Environment, Forest and Climate Change (MoEFCC), Government of India (GoI), promulgated stack emission standards for sulfur dioxide (SO₂), oxides of nitrogen (NO_x), and mercury (Hg) from coal‐fired thermal power plants (TPPs). These standards were promulgated in addition to tightening the emission standard for particulate matter. Thus far, the GoI and a non‐governmental organization (NGO) have recommended the use of limestone‐based flue‐gas desulfurization (FGD) technology for removing only SO₂ emissions, which would then require the application of additional technologies to remove the other regulated pollutants. A single technology, such as the Multi‐pollutants Control Technology (MPCT), which was recently developed elsewhere in the world and can remove all of the pollutants from the TPP, could be more economical than introducing separate technologies for the removal of each pollutant. Furthermore, unlike the limestone‐based FGD technology, which generates carbon dioxide (CO₂) during the desulfurization process, the MPCT does not increase power plant CO₂ emissions. Water consumption is also lower in MPCT than with the limestone‐based FGD technology. Thus, MPCT offers a lower carbon footprint as well as a lower water footprint than the limestone‐based FGD technology in accordance with the United Nations Environmental Programme's Sustainable Development Goals. In light of these observations, this article aims to assess current practices and policies and offers policy recommendations for Indian TPPs with the goal of providing a cogent technological solution that also strengthens the Decision Support System for the holistic protection of the Indian environment.     

Evaluation of different CHP options for refinery integration in the context of a low carbon future

This study presents a comparison of different concepts for delivering combined heat and power (CHP) to a refinery in Norway. A reference case of producing high pressure steam from natural gas in boilers and electricity in a combined cycle power plant, is compared to a: (1) natural gas fueled CHP without any CO₂ capture; (2) hydrogen fueled CHP with hydrogen produced from steam methane reforming (SMR); (3) hydrogen fueled CHP with hydrogen produced from autothermal reforming (ATR); and finally (4) natural gas fueled CHP with postcombustion CO₂ removal. The options are compared on the basis of first law efficiency, emissions of CO₂ and a simplified cash flow evaluation. Results show that in terms of efficiency the standard natural gas fueled CHP performs better than the reference case as well as the options with carbon capture. The low carbon options in turn offer lower emissions of greenhouse gases while maintaining the same efficiency as the reference case. The cash flow analysis shows that for any option, a certain mix of prices is required to produce a positive cash flow. As expected, the relationship between natural gas price and electricity price affects all options. Also the value of heat and CO₂ emissions plays an important role.     

The environmental life cycle assessment of agricultural sector in Thailand: EIO‐LCA approach

Agriculture is one of the major sectors in Thailand, with more than half of the population employed in agriculture‐related occupations. This study evaluated energy consumption and greenhouse gas (GHG) emissions of the Thai agricultural sector by applying the economic input–output life cycle assessment (EIO‐LCA) approach. The model evaluates the entire agricultural sector supply chain. Based on one million Thai baht (approximately $27,800 U.S. dollars) final demand of the rice paddy sector, the carbon dioxide (CO₂) emissions from the electricity sector are responsible for 27% (1,246 kilograms [kg] CO₂) of the total CO₂ emissions, whereas the emissions from paddy activities associated with the fertilizers and pesticides sector account for 16% (760 kg CO₂) and 11% (513 kg CO₂), respectively. The top three largest GHG emissions from the total agricultural sector supply chain are associated with the oil palm, the coffee and tea, and the fruit sectors. The government should promote and encourage sustainable agriculture by reducing the use of fertilizers and pesticides and by utilizing energy‐saving technologies.     

减污降碳协同增效的关键路径与政策研究

全面推动实现减污降碳协同增效是新发展阶段我国兑现碳达峰碳中和庄严承诺、深入打好污染防治攻坚战、建设美丽中国的必然要求。环境污染物与二氧化碳排放的高度同源性是实现减污降碳协同增效的理论基础。本文首先就目标指标、管控区域、控制对象、措施任务、政策工具五个方面的协同性系统讨论了减污降碳协同增效的基本内涵。其次，着眼于当前大气环境治理与碳减排在中国的重要性，本文在国家层面讨论了二者的中长期协同控制路线图，阐述了重点协同区域的识别方法和重点部门的协同治理思路，系统提出了大气环境治理与碳减排的协同路径。再次，本文还就“无废城市”建设和生态保护这两个领域与碳减排的协同治理思路展开分析讨论。最后，针对减污降碳协同治理对政策体系的需求，提出了统筹优化减污降碳协同目标、建立协同法规标准、建立减污降碳协同管理制度三个方面的建议。本研究将有助于厘清各方对减污降碳协同增效的认识，对各级政府后续推进减污降碳协同治理工作提供理论和科学基础。     

A statistical analysis of the carbon dioxide capture process

Post combustion carbon dioxide (CO₂) capture is one of the most commonly adopted technologies for reducing industrial CO₂ emissions, which is now an important goal given the widespread concern over global warming. Research on amine-based CO₂ capture has mainly focused on improving effectiveness and efficiency of the CO₂ capture process. Our research work focuses on studying the relationships among the significant parameters influencing CO₂ production because an enhanced understanding of the intricate relationships among the parameters involved in the process is critical for improving efficiency of the CO₂ capture process. This paper presents a statistical study that explores the relationships among parameters involved in the amine-based post combustion CO₂ capture process at the International Centre for CO₂ Capture (ITC) located in Regina, Saskatchewan of Canada. A multiple regression technique has been applied for analysis of data collected at the CO₂ capture pilot plant at ITC. The parameters have been carefully selected to avoid issues of multicollinearity, and four mathematical models among the key parameters identified have been developed. The models have been tested, and accuracy of the models is found to be satisfactory. The models developed in this study describe part of the CO₂ capture process and can help to predict performance of the CO₂ capture process at ITC under different conditions. Some results from a preliminary validation process will also be presented.     

Capture-ready coal plants—Options,technologies and economics

This paper summarizes the spectrum of options that can be employed during the initial design and construction of pulverized coal (PC), and integrated gasification and combined cycle (IGCC) plants to reduce the capital costs and energy losses associated with retrofitting for CO₂ capture at some later time in the future. It also estimates lifetime (40 year) net present value (NPV) costs of plants with differing levels of pre-investment for CO₂ capture under a wide range of CO₂ price scenarios. Three scenarios are evaluated—a baseline supercritical PC plant, a baseline IGCC plant and an IGCC plant with pre-investment for capture. This analysis evaluates each technology option under a range of CO₂ price scenarios and determines the optimum year of retrofit, if any. The results of the analysis show that a baseline PC plant is the most economical choice under low CO₂ prices, and IGCC plants are preferable at higher CO₂ prices (e.g., an initial price of about $22/t CO₂ starting in 2015 and growing at 2%/year). Little difference is seen in the lifetime NPV costs between the IGCC plants with and without pre-investment for CO₂ capture. This paper also examines the impact of technology choice on lifetime CO₂ emissions. The difference in lifetime emissions become significant only under mid-estimate CO₂ price scenarios (roughly between $20 and 40/t CO₂) where IGCC plants will retrofit sooner than a PC plant.     

A targeted social marketing approach for community pro-environmental behavioural change

Community-level initiatives will play a key role in meeting greenhouse gas reduction targets. This paper examines the experience gained in applying a targeted social marketing approach to foster local-scale community pro-environmental behavioural change in the City of York, UK. This involved determining the neighbourhood carbon footprint, identifying residents that had access to appropriate infrastructure and were receptive to green issues. Six community teams were recruited from the selected neighbourhoods and provided with information, advice and mentoring on how to reduce their carbon footprint over a six-month period. A statistically significant reduction in carbon emissions was achieved. Each participant achieved a mean reduction in their carbon footprint of 2.0 tonnes of CO₂e/year. The largest reductions were achieved in the areas of shopping and home energy. In addition, it helped to foster community spirit. Based on the experience gained from implementing this approach, a cost-effective model of community engagement is proposed.     

Processing of Straw/Corn Stover: Comparison of Life Cycle Emissions

The LCA emissions from four renewable energy routes that convert straw/corn stover into usable energy are examined. The conversion options studied are ethanol by fermentation, syndiesel by oxygen gasification followed by Fischer Tropsch synthesis, and electricity by either direct combustion or biomass integrated gasification and combined cycle (BIGCC). The greenhouse gas (GHG) emissions of these four options are evaluated, drawing on a range of studies, and compared to the conventional technology they would replace in a western North American setting. The net avoided GHG emissions for the four energy conversion processes calculated relative to a “business as usual” case are 830 g CO₂e/kWh for direct combustion, 839 g CO₂e/kWh for BIGCC, 2,060 g CO₂e/L for ethanol production, and 2,440 g CO₂e/L for FT synthesis of syndiesel. The largest impact on avoided emissions arises from substitution of biomass for fossil fuel. Relative to this, the impact of emissions from processing of fossil fuel, e.g., refining of oil to produce gasoline or diesel, and processing of biomass to produce electricity or transportation fuels, is minor.     

A well to wire LCA model development and sensitivity analysis for carbon footprint of combined cycle power plants in Iranian electricity network

The present research introduces a well to wire pseudo comprehensive carbon footprint model for combined cycle power plants. The mentioned model integrates land use change model, operational model and transmission and distribution model into one comprehensive model. The parameters which their effects are considered in the integrated model are: fuel type, fuel transmission type, emission for fuel extraction and processing, own consumption of the plant, degradation, site ambient condition, transmission and distribution losses. For quantifying the effectiveness of each parameter, sensitivity analyses based on different life cycle scenarios are performed. The result shows that the effect of land use change is negligible. The carbon footprint of electrical energy produced in combined cycle plant until it is delivered to the end users varies from 321 to 522 g CO₂ eq/kWh.     

Intermediate storage of carbon dioxide in geological formations: A technical perspective

Enhanced oil recovery (EOR) through CO₂ flooding has been practiced on a commercial basis for the last 35 years and continues today at several sites, currently injecting in total over 30 million tons of CO₂ annually. This practice is currently exclusively for economic gain, but can potentially contribute to the reduction of emissions of greenhouse gases provided it is implemented on a large scale. Optimal operations in distributing CO₂ to CO₂-EOR or enhanced gas recovery (EGR) projects (referred to here collectively as CO₂-EHR) on a large scale and long time span imply that intermediate storage of CO₂ in geological formations may be a key component. Intermediate storage is defined as the storage of CO₂ in geological media for a limited time span such that the CO₂ can be sufficiently reproduced for later use in CO₂-EHR. This paper investigates the technical aspects, key individual parameters and possibilities of intermediate storage of CO₂ in geological formations aiming at large scale implementation of carbon dioxide capture and storage (CCS) for deep emission reduction. The main parameters are thus the depth of injection and density, CO₂ flow and transport processes, storage mechanisms, reservoir heterogeneity, the presence of impurities, the type of the reservoirs and the duration of intermediate storage. Structural traps with no flow of formation water combined with proper injection planning such as gas-phase injection favour intermediate storage in deep saline aquifers. In depleted oil and gas fields, high permeability, homogeneous reservoirs with structural traps (e.g. anticlinal structures) are good candidates for intermediate CO₂ storage. Intuitively, depleted natural gas reservoirs can be potential candidates for intermediate storage of carbon dioxide due to similarity in storage characteristics.     

Life cycle assessment of natural gas combined cycle power plant with post-combustion carbon capture,transport and storage

Hybrid life cycle assessment has been used to assess the environmental impacts of natural gas combined cycle (NGCC) electricity generation with carbon dioxide capture and storage (CCS). The CCS chain modeled in this study consists of carbon dioxide (CO₂) capture from flue gas using monoethanolamine (MEA), pipeline transport and storage in a saline aquifer.Results show that the sequestration of 90% CO₂ from the flue gas results in avoiding 70% of CO₂ emissions to the atmosphere per kWh and reduces global warming potential (GWP) by 64%. Calculation of other environmental impacts shows the trade-offs: an increase of 43% in acidification, 35% in eutrophication, and 120–170% in various toxicity impacts. Given the assumptions employed in this analysis, emissions of MEA and formaldehyde during capture process and generation of reclaimer wastes contributes to various toxicity potentials and cause many-fold increase in the on-site direct freshwater ecotoxicity and terrestrial ecotoxicity impacts. NO_x from fuel combustion is still the dominant contributor to most direct impacts, other than toxicity potentials and GWP. It is found that the direct emission of MEA contribute little to human toxicity (HT < 1%), however it makes 16% of terrestrial ecotoxicity impact. Hazardous reclaimer waste causes significant freshwater and marine ecotoxicity impacts. Most increases in impact are due to increased fuel requirements or increased investments and operating inputs.The reductions in GWP range from 58% to 68% for the worst-case to best-case CCS system. Acidification, eutrophication and toxicity potentials show an even large range of variation in the sensitivity analysis. Decreases in energy use and solvent degradation will significantly reduce the impact in all categories.     

Integration of CO2 capture unit using single- and blended-amines into supercritical coal-fired power plants: Implications for emission and energy management

This work provides the essential information and approaches for integration of carbon dioxide (CO₂) capture units into power plants, particularly the supercritical type, so that energy utilization and CO₂ emissions can be well managed in the subject power plants. An in-house model, developed at the University of Regina, Canada, was successfully used for simulating a 500 MW supercritical coal-fired power plant with a post-combustion CO₂ capture unit. The simulations enabled sensitivity and parametric study of the net efficiency of the power plant, the coal consumption rate, and the amounts of CO₂ captured and avoided. The parameters of interest include CO₂ capture efficiency, type of coal, flue gas delivery scheme, type of amine used in the capture unit, and steam pressure supplied to the capture unit for solvent regeneration. The results show that the advancement of MEA-based CO₂ capture units through uses of blended monoethanolamine–methyldiethanolamine (MEA–MDEA) and split flow configuration can potentially make the integration of power plant and CO₂ capture unit less energy intensive. Despite the increase in energy penalty, it may be worth capturing CO₂ at a higher efficiency to achieve greater CO₂ emissions avoided. The flue gas delivery scheme and the steam pressure drawn from the power plant to the CO₂ capture unit should be considered for process integration.     

Planning implications from the interactions between renewable energy programs and carbon regulation

Complex relationships exist between programs to reduce carbon dioxide (CO₂) from the electricity sector and programs to promote renewable electricity generation. Simulation modeling of three scenarios in the UK electricity sector are used to identify potential interactions between these programs. A strict CO₂ cap can result in a renewable electricity requirement being easily met. Conversely, the renewables quota could be required under low natural gas prices to keep electricity suppliers from switching from coal to gas. Similarly, CO₂ trading can reduce renewables deployment levels because purchased CO₂ allowances replace renewables. Therefore, both programs are required to ensure CO₂ and renewables goals. The planning implications for administrative procedures and renewables subsidies are also discussed.