WATER QUALITY ANALYSIS OF THE HALIFAX RIVER,FLORIDA1

ABSTRACT: An application of the receiving water block of the EPA Storm Water management Model (SWMM) is presented to quantify water quality impacts and evaluated control alternatives for a 208 areawide waste water management plan in Volusia Country, Florida. The water quality impact analyses were conducted for dry-and wet-weather conditions to simulate dissolved oxygen (DO), chlorides, total nitrogen (TN), and total phosphorus (TP) in the Halifax Rivers, Florida, a 40-kilometer-long tidal estuary located on the Atlantic coast of Florida near Daytona Beach. Dry-weather analysis was performed using conventional 7-day, 10-year low flow conditions to determine a set of unit transfer coefficients which estimate the pollutant concentration transferred to any point in the estuary from a constant unit discharge of pollutants at the existing waste water treatment plant outfall locations. Wet-weather analysis was performed by continuous simulation of a typical three-month summer wet season in Florida. Three-month cumulative duration curves of DO, TN and TP concentrations were constructed to estimate the relative value of controlling urban runoff of waste water treatment plant effluent on the Halifax River. The three-month continuous simulation indicated that the greatest change in DO, TN, and TP duration curves is possible by abatement of waste water treatment plant pollution.     

GEOMETRIC VARIATIONS IN RESERVOIR WATER QUALITY1

ABSTRACT: In developing water quality models for lakes and reservoirs, the assumptions of one-dimensionality (i.e., water quality changes are significant only in one dimension – usually depth), as well as two-dimensionality (considering the length and depth of the water body), have been utilized to predict water quality. In both caws, the assumption of lateral homogeneity is made. A field study was undertaken to determine the change of water quality in the lateral dimension. The main study reservoir was Center Hill Lake in Middle Tennessee. Data were also obtained for Cherokee Lake in East Tennessee. Several water quality parameters (temperature, dissolved oxygen, pH, conductivity, and oxidation reduction potential) were analyzed over the length, breadth, and depth of these reservoirs from pre-stratification through post-stratification. The statistical and theoretical three-dimensional analysis showed the expected variation for each water quality parameter in each direction. The influence of the lateral dimension on water quality management and modeling was found to be negligible.     

THE STABILITY IN WATER OF A NEW CHLORAMINE DISINFECTANT AS A FUNCTION OF pH,TEMPERATURE, AND WATER QUALITY1

The stabilities in water and dry storage of two solid-state disinfectants (3-chloro-4, 4-dimethyl-2-oxazolidinone, agent I, and calcium hypochlorite) have been compared under a variety of conditions. Variables in the study included pH, temperature, and water quality. Agent I is considerably more stable in dry storage and in water, especially at pH 4.5 and 7.0, than is calcium hypochlorite. This is true for solutions of the two compounds in sterile, distilled, deionized, demandfree water or in a synthetic water containing heavy organic load. Prior work in these laboratories concerning use of agent I as a disinfectant for lake water in a laboratory-scale treatment plant had suggested that agent I has considerable potential for use as an alternative to cholorine gas for water disinfection. The present work suggests that agent I is of sufficient stability to be of use as a solid-state disinfectant for swimming pools and for potable water for remote areas.     

AN ASSESSMENT OF SEDIMENT PHOSPHORUS INACTWATION,KEZAR LAKE,NEW HAMPSHIRE1

ABSTRACT: Aluminum sulfate and sodium aluminate were utilized as sediment phosphorus inactivants to improve the water quality of a northeastern eutrophic lake. A four-year monitoring program has provided an extensive lake-database utilized to evaluate the short-and long-term effectiveness of sediment phosphorus inactivation as a lake restoration technique. An immediate impact of treatment was marked by a reduction in hypolimnetic BOD and dissolved oxygen deficit, lower chlorophyll-a and phosphorus concentrations, improved transparency, and the elimination of obnoxious blue-green phyto-plankton blooms. For two to three years after treatment, these pa-rameters continued to exhibit both less variability and improved values over the pre-treatment conditions. The improved water quality conditions warranted an upgrade of the lake trophic status from eutrophic to mesotrophic. Four years after the treatment, the mean hypolimnetic total phosphoru.s and chlorophyll-a have increased and transparency has decreased from initial post-treatment levels. Although long-term trends show water quality decreasing since the treatment, the water quality has stabilized at a level suitable for recreation. A major benefit is an increase in the average attendance at the lake by almost 2,000 people per summer.     

Freshwater Mussel Population Status and Habitat Quality in the Clinch River,Virginia and Tennessee,USA: A Featured Collection

The Clinch River of southwestern Virginia and northeastern Tennessee is arguably the most important river for freshwater mussel conservation in the United States. This featured collection presents investigations of mussel population status and habitat quality in the Clinch River. Analyses of historic water‐ and sediment‐quality data suggest that water column ammonia and water column and sediment metals, including Cu and Zn, may have contributed historically to declining densities and extirpations of mussels in the river's Virginia sections. These studies also reveal increasing temporal trends for dissolved solids concentrations throughout much of the river's extent. Current mussel abundance patterns do not correspond spatially with physical habitat quality, but they do correspond with specific conductance, dissolved major ions, and water column metals, suggesting these and/or associated constituents as factors contributing to mussel declines. Mussels are sensitive to metals. Native mussels and hatchery‐raised mussels held in cages in situ accumulated metals in their body tissues in river sections where mussels are declining. Organic compound and bed‐sediment contaminant analyses did not reveal spatial correspondences with mussel status metrics, although potentially toxic levels were found. Collectively, these studies identify major ions and metals as water‐ and sediment‐quality concerns for mussel conservation in the Clinch River.     

APPLICATION OF THE CONTINUOUS STORMWATER POLLUTION SIMULATION SYSTEM (CSPSS): PHILADELLPHIA CASE STUDY1

ABSTRACT: This paper describes the Continuous Stormwater Pollution Simulation System (CSPSS) as well as a site-specific application of CSPSS to the Philadelphia urban area and its receiving water, the Delaware Estuary. Conceptually, CSPSS simulates the quantity and quality or urban stormwater runoff, combined sewer overflow, municipal and industrial waste water effuent, and upstream flow on a continuous basis for each time step in the simulation period. In addition, receiving water dissolved oxygen, suspended solids, and lead concentrations resulting from these pollutant sources may be simulated. However, only rceiving water dissolved oxygen (DO) response is considered in this paper. The continuous Do receiving water response model was calibrated to existing conditions usinv observed data at Chester, Pennsylvnia, located on the Delaware Estuary approximately 10 miles down stream from the study area. Average annual pollutant loads to the receiving water were estimated for all major sources and receiving water quality improvements resulting from removal of various portions of these pollutant loads were estimated by application of the calibrated stimultion model. It was found that the removal of oxygen-demanding pollutants from combined sewer overflow and urban stormwater runoff would result in relatively minor improvements in the overall dissoved oxygen resources of the Delaware Estuary; whereas. removal of oxygen demanding pollutants from waste water treatment plant effluent would result in greater improvemens. The results of this investigation can be used along with appropriate economic techniques to identify the most cost-effective mix of point and nonpoint source pollution control measures.     

SITING OF A WATER POLLUTION CONTROL FACILITY AT JAMESTOWN,RHODE ISLAND1

ABSTRACT: The town of Jamestown, Rhode Island, located on Conanicut Island in Narragansett Bay, is constructing a secondary treatment plant in order to comply with NPDES regulations. Twelve candidate sites for the plant and marine outfall were initially proposed, and ability to meet State water quality standards at these sites was evaluated using an EPA buoyant plume model. A final outfall site, Taylor Point, was selected by the Town from among the sites considered acceptable. Taylor Point was then subjected to field hydrographic studies including drogue tracking, current recordings, and tracer dye surveys. Results of the measurement program served as input to a two-dimensional effluent dispersion model which predicted excess BOD, coliform, and suspended solids resulting from effluent discharge off Taylor Point. The model predictions demonstrated that State water quality standards can be maintained outside the initial discharge plume.     

EFFECTS OF LIME-SLUDGE DISCHARGE ON AN ARCTIC RIVER1

ABSTRACT: The Fairbanks Water Treatment Plant in Fairbanks, Alaska, processes approximately 3 MGD of drinking water using lime softening. Approximately 0.3 MGD of lime-sludge from the treatment process is combined with effluent from a nearby power plant and discharged to the Chena River. There is little information available on the impact of water-treatment sludge discharges, and virtually no information on the impacts of such discharges in polar environments. Concern surrounding the discharge of water treatment sludges have centered on alum-sludge due to the potential toxic effects of aluminum. Because of the relatively benign composition of lime-sludge, very little research has been published. However, there is the possibility that discharge of solids will result in sedimentation, accumulation of solids, and subsequent impacts on benthic organisms. This paper reports on the results of a study to determine if lime-sludge discharge from the water treatment plant is adversely impacting the river environment. The results provide basic information on the important variables of concern in lime-discharges to rivers. Samples from the discharge of the water treatment plant and combined water treatment plant/power plant effluent were collected weekly over a one-year period, and in-stream benthic and water column samples were collected biweekly during the fall and spring. Sediment and water quality data indicate that while significant accumulation of sludge solids is found downstream of the water treatment plant outfall, they are flushed out of the system by spring flows, which are significantly increased by snow melt. This process is most likely repeated on a yearly cycle. Hence, the data suggest that the FMUS water treatment plant's discharge of lime-sludge is probably not adversely impacting the river. More generally, this may indicate that the natural flow variations and sediment-laden characteristics of Arctic, glacier-fed rivers may assimilate large quantities of nonputrescible solids without significant changes in the natural river environment. Further research in this area is required to verify this conclusion.     

STATISTICAL ANALYSIS OF GROUND WATER USE AND REPLENISHMENT1

A statistical technique which offers considerable promise in ground water studies is the fitting of polynomial trend-surfaces to ground water data and studying the variations in the surfaces and the residuals from these surfaces over a period of time. The application of trend-surface analysis to ground water study is based on the premise that the piezometric surface or water table can be approximated by a mathematically computed polynomial surface of the water levels of the wells in the aquifer. The evaluation of trend surface analysis application in ground water investigations was made up essentially of two considerations; a study of the relationship existing between the trend surfaces and the actual ground water surface and a study of the potential use of the residuals from the trend-surfaces to assist in the location of favorable sites for future development of ground water resources. The conclusions on aquifer behavior drawn from the trend surface analysis were compared with conclusions drawn from a concurrent survey of ground water conditions carried out independently of this investigation. This comparison provided the basis for the critical examination of the application of trend-surface analysis in ground water investigations.     

ELEMENTS OF A WATER QUALITY INFORMATION SYSTEM FOR THE STATE OF ILLINOIS1

ABSTRACT: A great deal of information can be derived from study of standard stream monitoring data, if these are properly ordered and organized. This information may then be used to make decisions about water quality management. Among critical information items are evaluation of performance to standards, determination of seasonality and time-trends of water quality conditions, and estimation of the effects on water quality to be expected from load reductions or standards modifications. Additional information on the magnitude of individual pollution sources is also critical to water quality management. Each of these items can be derived within the water quality information system which is currently under development for the State of Illinois.     

SIZING OF SURFACE WATER RUNOFF DETENTION PONDS FOR WATER QUALITY IMPROVEMENT1

ABSTRACT: Historically, storm water management programs and criteria have focused on quantity issues related to flooding and drainage system design. Traditional designs were based on large rainfall‐runoff events such as those having two‐year to 100‐year return periods. While these are key criteria for management and control of peak flows, detention basin designs based on these criteria may not provide optimal quality treatment of storm runoff. As evidenced by studies performed by numerous public and private organizations, the water quality impacts of storm water runoff are primarily a function of more frequent rainfall‐runoff events rather than the less frequent events that cause peak flooding. Prior to this study there had been no detailed investigations to characterize the variability of the more frequent rainfall events on Guam. Also, there was a need to develop some criteria that could be applied by designers, developers, and agency officials in order to reduce the impact of storm water runoff on the receiving bodies. The objectives of this paper were three‐fold: (1) characterize the hourly rainfall events with respect to volume, frequency, duration, and the time between storm events; (2) evaluate the rainfall‐runoff characteristics with respect to capture volume for water quality treatment; and (3) prepare criteria for sizing and designing of storm water quality management facilities. The rainfall characterization studies have provided insight into the characteristics of rainstorms that are likely to produce non‐point source pollution in storm water runoff. By far the most significant fmdings are the development of a series of design curves that can be used in the actual sizing of storm water detention and treatment facilities. If applied correctly, these design curves could lead to a reduction of non‐point source pollution to Guam's streams, estuaries, and coastal environments.     

THE DISCHARGE OF SEDIMENT IN CHANNELIZED ALLUVIAL STREAMS1

ABSTRACT: Approximately 400 million cubic feet of channel sediments have been delivered to the Mississippi River from the Obion-Forked Deer River system in the last 20 years. The discharge of sediment from these channelized networks in West Tennessee varies systematically with the stage of channel evolution. Variations in yields over time reflect the shifting dominance of fluvial and mass-wasting processes as the networks adjust to lower energy conditions. Maximum bed-material discharges occur during the initial phases of degradation (Stage III). In contrast, yields of suspended-sediment peak during the threshold stage (Stage 1V: large-scale mass wasting) as sediments are delivered from main-channel banks and tributary beds. Suspended-sediment yields then decrease as aggradation (Stage V) becomes the dominant trend in the main channels, but remains relatively high through restabiliza-tion (Stage VI) because of continued degradation and widening in the tributaries. Bed-material discharges decrease from the degradation stage (III) to Stage V, and increase again during restabiliza-tion (Stage VI) because secondary aggradation increases gradients and incipient meandering serves to rework bed sediments. This secondary maxima in bed-material discharge is analogous to those described previously as complex, or oscillatory, response. The trends of sediment production and transport described from these rejuvenated networks are in agreement with experimental and theoretical results of earlier investigations.     

Changes in Shallow Groundwater Quality Beneath Recently Urbanized Areas in the Memphis,Tennessee Area1

Barlow, Jeannie R.B., James A. Kingsbury, and Richard H. Coupe, 2012. Changes in Shallow Groundwater Quality Beneath Recently Urbanized Areas in the Memphis, Tennessee Area. Journal of the American Water Resources Association (JAWRA) 48(2): 336‐354. DOI: 10.1111/j.1752‐1688.2011.00616.x Abstract: Memphis, the largest city in the state of Tennessee, and its surrounding suburbs depend on a confined aquifer, the Memphis aquifer, for drinking water. Concern over the potential for downward movement of water from an overlying shallow aquifer to the underlying Memphis aquifer provided impetus for monitoring groundwater quality within the shallow aquifer. The occurrence of volatile organic compounds (VOCs), nitrate, and pesticides in samples from the shallow well network indicate a widespread affect on water quality from the overlying urban land use. Total pesticide concentration was generally higher in more recently recharged groundwater indicating that as the proportion of recent water increases, the occurrence of pesticides related to the current urban land use also increases. Groundwater samples with nitrate concentrations greater than 1.5 mg/l and detectable concentrations of the pesticides atrazine and simazine also had higher concentrations of chloroform, a VOC primarily associated with urban land use, than in other samples. The age of the water from these wells indicates that these concentrations are most likely not representative of past agricultural use, but of more recent urban use of these chemicals. Given that the median age of water represented by the shallow well network was 21 years, a lag time likely exists between changes in land use and the occurrence of constituents related to urbanization in shallow groundwater.     

THE IMPACT OF WATER QUALITY OBJECTIVES ON URBAN WATER SUPPLY PLANNING1

ABSTRACT: Optimal policies for supplying rapidly expanding urban centers with additional water supplies are shown to be dependent on water quality goals for the urban effluent. As effluents are required to meet increasingly stringent standards, the unit costs associated with adding capacity to existing wastewater treatment systems to renovate some waters for reuse are shown to substantially decrease. A nonlinear elimination algorithm is developed to delineate optimal policies. A model employing the technique was applied to the wastewater treatment system of a typical urban system and the water quality objectives varied. A comparison of costs with and without various levels of reuse were made and unit costs of reused water under these conditions determined.     

Recovery of Fish Communities in a Warm Water Stream Following Pollution Abatement

The long-term recovery process for fish communities in a warm water stream in East Tennessee was studied using quantitative measurements over 20 years. The stream receives effluents from a U. S. Department of Energy (DOE) facility, but since 1985 these effluents have been greatly reduced, eliminated, or diluted as part of a substantial long-term pollution abatement program. The resulting changes in water quantity and quality led to a recovery of the fish communities, evidenced by significant changes in species richness, abundance (density and biomass), and community composition (e.g., number of fish species sensitive to stress). The fish community changes occurred over a spatial gradient (downstream from the headwater release zone nearest the DOE facility) and temporally, at multiple sampling locations in the stream. Changes in measured parameters were associated with specific remedial actions and the intervening steps within the recovery process are discussed with regard to changes in treatment processes.     

A MANGANESE OXIDATION MODEL FOR RIVERS1

ABSTRACT: The presence of manganese in natural waters (>0.05 mg/L) degrades water-supply quality. A model was devised to predict the variation of manganese concentrations in river water released from an impoundment with the distance downstream. The model is one-dimensional and was calibrated using dissolved oxygen, biochemical oxygen demand, pH, manganese, and hydraulic data collected in the Duck River, Tennessee. The results indicated that the model can predict manganese levels under various conditions. The model was then applied to the Chattahoochee River, Georgia. Discrepancies between observed and predicted may be due to inadequate pH data, precipitation of sediment particles, unsteady flow conditions in the Chattahoochee River, inaccurate rate expressions for the low pH conditions, or their combinations.     

EFFECTS OF POTENTIAL WATER CONSERVATION EFFORTS IN EAST TENNESSEE1

ABSTRACT: The importance of water conservation was emphasized by a proposed National Water Policy which was established during the previous Carter Administration. This policy stressed water conservation on a national scale. Such a policy sought to apply one program to all water resources problems. Before implementation of this or another such policy, consideration must be given to those vast areas of the country which in reality do not have a shortage of water. One of these areas is the French-Broad River basin in Tennessee. This report was formulated in an effort to describe both the positive and negative effects of water policies which would bring about either a 10 percent or 30 percent reduction in water usage in this basically water rich area. The parameters used in the evaluation included selected economic, sociological, legal, and environmental impacts.     

A Simple Stream Monitoring Technique Based on Measurements of Semiconservative Propertiesof Water

Correlative relationships exist among conductivity, alkalinity, and hardness in streams due to natural geological and climatological controls, but the relationships among these three water-quality factors can be altered strongly by inputs of ion-rich wastewaters. The degree of alteration can be monitored conveniently by use of a simple chemical perturbation index, computed by subtracting the sum of rank pairwise correlations among the conductivity, alkalinity, and hardness (for observations on each of these variables, measured through time) from 3.0. The chemical perturbation index can be used to document or characterize spatiotemporal changes in stream water quality. This study explains the development of the index's concept and provides examples of its application in an extensive stream monitoring program used to assess ecological conditions in streams on the Department of Energy's Oak Ridge Reservation in east Tennessee, USA. The chemical perturbation index technique may be particularly useful in community-based stream monitoring programs because to its simplicity and low cost.     

ESTIMATION OF POTENTIAL REDUCTIONS IN RECREATIONAL BENEFITS DUE TO SEDIMENTATION1

ABSTRACT: A travel cost model is developed to estimate the potential reductions in recreational benefits from sedimentation in Reelfoot Lake in northwestern Tennessee. In addition to the consumer surplus estimates generated by the model, three other aspects of the study were significant. First, the study applied a relatively untested methodology for deriving the opportunity cost of travel time. The study resulted in a value that is less than one-half of the Water Resource Council's “one-third of the wage rate” rule-of-thumb. Second, water quality perceptions were unsuccessfully incorporated into the model as a demand shifter. This raised questions as to the appropriate manner in which perceptions could be included in a travel cost model. Finally, a simple methodology was outlined by which estimates of the recreational value of Reelfoot Lake could be used to suggest how much cost could be justified for soil erosion control on agricultural land surrounding the lake.     

NUTRIENT LOADS TO WISCONSIN LAKES: PART II. RELATIVE IMPORTANCE OF NUTRIENT SOURCES1

ABSTRACT: A comparison of municipal wastewater treatment plant (WWTP) and nonpoint source nutrient loads to Wisconsin's 14,927 inland lakes was performed. Only 65 of the 2,925 Wisconsin lakes having surface areas of at least eight ha and a maximum depth of at least 2.4 m had one or more WWTP's located within 40 km upstream; 99 of Wisconsin's 477 WWTP's were identified to be upstream of these 65 lakes. WWTP total nitrogen and total phosphorus loads to these 65 lakes were estimated using per capita influent loads and removal efficiencies based on wastewater treatment types. Nonpoint source nutrient loads were calculated utilizing nutrient export coefficients derived specifically for Wisconsin. Total nitrogen inputs to the lakes were dominated by nonpoint sources. The effectiveness of various phosphorus control programs to produce water quality improvements visible to the public was estimated to be as follows (going from most to least effective): municipal phosphorus removal and agricultural reductions, municipal phosphorus removal alone, agricultural reduction plus phosphate detergent ban, agricultural reductions alone, and phosphate detergent ban alone. The last option would not be expected to produce water quality improvement visible to the public in any Wisconsin lakes. The differences between the distributions in Wisconsin of population and inland lakes highlights the need to consider regional characteristics in any statewide water quality management plan.