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1.
ABSTRACT

Renewable and sustainable fuels for diesel engine applications provide energy protection, overseas exchange saving and address atmospheric and socio-economic concerns. This study presents the investigational work carried out on a single cylinder, four-stroke, direct injection diesel engine operated in dual fuel (DF) mode using renewable and sustainable fuels. In the first phase, a Y-shaped mixing chamber or venture was developed with varied angle facility for gas entry at 30°, 45° and 60°, respectively, to enable homogeneous air and gas mixing. Further effect of different gas and air mixture entry on the DF engine performance was studied. In the next phase of the work, hydrogen flow rate influence on the combustion and emission characteristics of a compression ignition (CI) engine operated in DF mode using diesel, neem oil methyl ester (NeOME) and producer gas has been investigated. During experimentation, hydrogen was mixed in different proportions varied from 3 to 12 l/min (lpm) in step of 3 lpm along with air-producer gas and the mixtures were directly inducted into engine cylinder during suction stroke. Experimental investigation showed that 45° Y-shaped mixing chamber resulted in improved performance with acceptable emission levels. Further, it is observed that investigation showed that at maximum operating conditions and hydrogen flow rate of 9 lpm, Diesel–producer gas and NeOME–producer gas combination showed increased thermal efficiency by 13.2% and 3.8%, respectively, compared to the DF operation without hydrogen addition. Further, it is noticed that hydrogen-enriched producer gas lowers the power derating by 5–10% and increases nitric oxide (NOx) emissions. However, increased hydrogen addition beyond the 12 lpm leads to sever knocking.

Abbreviations: NeOME: Neem oil methyl ester; BTE: brake thermal efficiency; CI: compression ignition; ITE: indicated thermal efficiency; PG: producer gas; CA: crank angle; K: Kelvin; BP: brake power; IP: indicated power; H2: hydrogen; HC: unburnt hydrocarbon; CO: carbon dioxide; CO2: carbon dioxide; NOx: nitric oxide; HRR: heat release rate; %: percentage; PPM: parts per million; CMFIS: conventional mechanical fuel injection system.  相似文献   

2.
The economic marketability of a brachiopod, Lingula was studied at three coastal mangrove sites, specifically based on socioeconomic parameters from 10 villages that utilized Lingula along Pearl Bay, Beilun Estuary Marine Nature Reserve, China. The significantly highest density of Lingula was at Jiao Dong (48.2 ± 35.14 individual/m2) whereas the biomass of Lingula was highest (0.76 ± 0.22 g/individual) at Gui Lao Bu. The shell size of the largest specimen was still less than that in other references. The socioeconomic study of the population related to Lingula involved a small group, and no relationship could be determined among the parameters of age range, education level, occupation, and financial status. The total economic value (320,927.4 Yuan) was based on the value of consumption whereas the value from sales was very low as recorded from Shan Xin over a three-month season. Analysis of the results to determine strengths, weaknesses, opportunities, and threats was undertaken to identify the potential of Lingula sp. to be promoted and supported in the market as a novel source of income for the local community who are associated with mangrove resources; and also to examine its potential as a new food source for the rapidly growing population of China.  相似文献   

3.
We estimated carbon dioxide (CO2) and methane (CH4) emissions by diffusion, ebullition, and degassing in turbines from a semi-arid hydropower reservoir in northeastern Brazil. Sampling sites were allocated within the littoral and deeper waters of one embayment, the main-stream, and at turbines. Annual carbon emissions were estimated at 2.3?×?105?±?7.45?×?104 t C year?1, or in CO2-equivalents (CO2-eq) at 1.33?×?106?±?4.5?×?105 t CO2-eq year?1. Diffusion across the water surface was the main pathway accounting for 96% of total carbon emissions. Ebullition was limited to littoral areas. A slight accumulation of CO2, but not of CH4, in bottom waters close to the turbines inlet led to degassing emissions about 8?×?103 t C year?1. Emissions in littoral areas were higher than in main-stream and contribute to 40% of the total carbon. Carbon (C) emissions per electricity generated, at 60% of installed capacity, is 0.05 t C-CO2-eq MWh?1. The ratio increases to 0.09 t C-CO2 MWh?1, equating 80% of the emissions from natural gas and 40% of diesel or coal power plants. Retention time and benthic metabolism were identified as main drivers for carbon emissions in littoral areas, while water column mixing and rapid water flow are important factors preventing CH4 accumulation and loss by degassing. Our results indicate that Itaparica Reservoir, located in the semi-arid region of Northeastern Brazil, acts as a source of GHGs. Management measurements are needed to prevent emissions to raise in the future.  相似文献   

4.
Outotec open cycle (OOC) is a new low-energy process linking together production of hydrogen and sulfuric acid. While sulfuric acid is the world’s most widely produced chemical by mass at approximately 200 Mt/a, the OOC gives the potential for making 4 Mt/a of hydrogen gas as a by-product. H2SO4 manufacture requires a source of sulfur dioxide. 30% of world production of H2SO4 is from the SO2 by-product of pyrometallurgical processing of sulfur containing concentrates of metals such as copper, nickel and zinc. SO2 can also be made by direct combustion of sulfur. In OOC, a divided electrochemical cell is used for SO2-depolarized electrolysis of water. SO2 is fed to the anolyte and converted to H2SO4, while hydrogen gas is produced at the cathode. On the industrial scale, the equipment will be in the form of a membrane electrolyzer assembly or stack. A case is described where the OOC would be connected to a pyrometallurgical plant smelting 1 Mt/a of nickel and copper concentrate, producing 1 Mt/a of H2SO4 and 20 kt/a of hydrogen.  相似文献   

5.
The study reported here focuses on the environmental pressure exerted by large-scale eucalyptus-based kraft pulp industry in Thailand. The objective of this study was to identify the most important sources of greenhouse gases, acidifying and eutrophying compounds and tropospheric ozone precursors, human toxicity compounds and solid waste associated with the kraft pulp industry. To this end, we performed an environmental systems analysis of the kraft pulp industry system in which we distinguished between two subsystems: the eucalyptus forestry subsystem and the kraft pulp production subsystem. The results indicate that the environmental pressure is caused by the kraft pulp production subsystem rather than by the eucalyptus forestry one. The chemical recovery unit was found to be the most important source of carbon dioxide (CO2) and sulfur dioxide (SO2) and responsible for more than one-half of the emissions of greenhouse gases and acidifying compounds from eucalyptus-based kraft pulp production in Thailand. Biomass combustion in the energy gene ration unit is an important source of nitrogen oxide (NO x ) and carbon monoxide (CO) which in turn are responsible for over 50% of the emissions of tropospheric ozone precursors. About 73% of the eutrophication is caused by biological aerobic wastewater treatment emitting phosphorus (P). With respect to the eucalyptus forestry, only fertilizer use in eucalyptus plantations is a relevant source of pollution through the emission of nitrous oxide (N2O) and phosphate (PO 4 3− ).  相似文献   

6.
Ultrafiltration membranes were prepared using cellulose acetate (CA) as a polymer, LiCl and CaCl2 as porogens and methyl-(S)-lactate as a solvent. CA, methyl lactate and the porogens used in this work are obtained from renewable resources; they are biodegradable, non-toxic and non-volatile organic compounds. Flat sheet ultrafiltration membranes were prepared by the phase inversion technique. A molecular weight cut-off between 15 and 35 kDa (polyethylene glycol) and pure water permeability between 13 and 177 litres h? 1m? 2 bar? 1 were obtained. These parameters are in the ideal range for water treatment industry. Improvement of pollutant degree and ecotoxicity of the process was evaluated by ‘green’ metrics by the P (pollutants, persistent and bioaccumulative) and E (ecotoxicity) parameters. Both of these variables were recorded as zero using our method. This study represents a step ahead towards the production of ultrafiltration polymeric membranes by a ‘greener’ process than current methods.  相似文献   

7.
The impacts of climate change on crop yield have increasingly been of concern. In this study, we investigated the impacts of trends in sunshine duration (S) and maximum temperature (T max) on rice yields in Jiangsu Province at both the provincial and county level during the period from 1980 to 2008. The results showed that although S and T max both were positively correlated with rice yields, the combined impacts of the decreasing trend of S (0.37 h/decade) and the increasing trend of T max (0.34 °C/decade) in August caused a reduction of 0.16 t ha?1 in rice yields (approximately 1.8 %) in Jiangsu Province, and the trend of S had played a dominant role in the yield losses. Further analyses suggest that the increasing concentration of aerosols from rapid economic development in Jiangsu Province has caused a significant solar dimming at least since 1960, making mitigations and adaptation measurements on regional haze impact imperative. Our study provides a prototype for detecting negative feedback on agricultural production caused by intensified anthropogenic activities that aim only to create rapid economic development.  相似文献   

8.
ABSTRACT

Poultry skin waste is considered to be a promising source of biodiesel. However, this source presents an environmental threat as it is being discharged into landfills without any treatment. We studied the feasibility of biodiesel production from poultry skin waste. Two-step extraction of lipids from chicken’s skin was developed and gave 97.5% yield using the optimum time and temperature. Esterification was then optimised to remove free fatty acids (FFA) where the ideal parameters were 65 °C during 30min with a molar ratio of methanol to oil of (1:3) and 1% of H2SO4. The third step was the transesterification which was performed using 60 °C and 300–600 rpm agitation for 1 h, with 1% basic catalyst and 1:3 (molar ratio) of methanol to oil. The biodiesel (FAME), was characterised using gas chromatography coupled with mass spectrometry (GC-MS) followed by chemical and physical analyses such as iodine number, acid number, flash point and cetane number. The total conversion was obtained using above conditions and most of the studied proprieties of produced biodiesel meet the EN14214 standard. This is an extremely encouraging result, offering a good source of biodiesel by valuing poultry skin waste.  相似文献   

9.
Microalgae has been considered potential biofuel source from the last decade owing to its versatile perspectives such as excellent capability of CO2 capture and sequestration, water treatment, prolific growth rate and enormous energy content. Thus, energy research on microalgae is being harnessed to mitigate CO2 and meet future energy demands. This study investigated the bioenergy potential of native blue-green microalgae consortium as initial energy research on microalgae in Brunei Darussalam. The local species of microalgae were assembled from rainwater drains, the species were identified as Stigonematales sp. and physical properties were characterised. Sundried biomass with moisture content ranging from 6.5% to 7.37% was measured to be used to determine the net and gross calorific value and they were 7.98 MJ/kg-8.57 MJ/kg and 8.70 MJ/kg-9.45 MJ/kg, respectively. Besides that, the hydrogen content, ash content, volatile matter, and bulk density were also experimented and they were 2.56%-3.15%, 43.6%-36.71%, 57–38%-63.29% and 661.2 kg/m3-673.07 kg/m3, respectively. Apart from experimental values, other physical bioenergy parameters were simulated and they were biomass characteristic index 61,822.29 kg/m3-62,341.3 kg/m3, energy density 5.27 GJ/m3-5.76G J/m3 and fuel value index 86.19–88.54. With these experimental results, microalgae manifested itself a potential source of biofuel feedstock for heat and electricity generation, a key tool to bring down the escalated atmospheric greenhouse gases and an alternation for fossil fuel.  相似文献   

10.
The production of energy crops in Germany is a growing agronomic sector and is expected to occupy a substantial share of farmland in the near future. At the same time, there are concerns that energy crops might cause increased nitrogen pollution of soil water, surface water and groundwater. Therefore, the Federal State of Saxony, Germany, funded a study on potential effects of an intensified cultivation of energy crops. In frame of this study, we used the Web GIS-based model STOFFBILANZ to simulate N leaching from the rooting zone and N loads of surface water for a reference scenario and an energy crop scenario. For the reference scenario, we used data representing the crop cultivation for the year 2005 at municipality level. We found that the total loads for N leaching from the rooting zone of cropland are highest for the loess region (8,067 t year?1), followed by mountainous region (6,797 t year?1) and lowland (5,443 t year?1). However, highest N fluxes in the leachate from rooting zones have been simulated for lowland (40.6 kg ha?1 year?1) and mountainous region (37.1 kg ha?1 year?1), while nitrate concentrations of leachate were highest for the lowland (101.8 mg l?1). In terms of diffuse N input into surface water, the mountainous region is the most important source area (total N load 6,380 t year?1, flux 34.6 kg ha?1 year?1). Retention by in-stream processes accounts for 15 % (3,784 t year?1) of the total N load leaving the study area (25,136 t year?1). In the 2020 energy crop scenario, shares of rape and silage maize (id., ensiled corn) were limited for each municipality to a maximum of 25 and 33 %, respectively. The conversion of grasslands to crop farming was not allowed. Under these conditions, we found slight to substantial reductions of nitrogen loads for leachate from the rooting zone and for surface waters. The simulated reduction depends strongly on local conditions. Only small reductions (ca. 4–8 %) were found for the lowlands and mountainous regions of Saxony, while reductions for the loess region were substantial (ca. 22 %). A major outcome of our study is that the cultivation of energy crops might reduce N loss if certain preconditions are assumed, for example, without conversion of grasslands to crop farming. However, effects might vary widely depending on local conditions.  相似文献   

11.
Stringent environmental policies and the ever increasing demand for energy have triggered interest in novel combustion technologies that use alternative fuels as energy sources. Of these, pilot-ignited compressed natural gas (CNG) engines that employ small biodiesel pilot to ignite a premixed natural gas–air mixture have received considerable attention. This paper discusses the effect of mixing chamber venturi, injection timing, compression ratio and exhaust gas recirculation (EGR) on the performance of dual-fuel engine operated on biodiesel derived from honge oil and is called honge oil methyl ester (HOME) and CNG. The proposed study mainly focuses on the manifold induction of CNG along with HOME injection. However, CNG can also be injected using port or direct gas injector (Lakshmanan and Nagarajan 2010, Energy 35, pp. 3172–3178). The future study will involve these methods of CNG injection. From this study, it is concluded that an advanced injection timing and an increased compression ratio resulted in increased brake thermal efficiency and reduced smoke, hydrocarbons and carbon monoxide emissions. However, nitrogen oxides (NO x ) emission increased significantly. The increased NO x emission was effectively reduced with EGR method. A mixing chamber venturi of 3 mm size, injection timing of 27° before top dead centre (BTDC), compression ratio of 17.5 and 10% EGR were found to be optimum for the modified compression ignition engine that was operated on CNG–HOME dual-fuel mode.  相似文献   

12.
The objective of this paper is to analyse the impacts of climate change on a pine forest stand in Central Siberia (Zotino) to assess benefits and risks for such forests in the future. We use the regional statistical climate model STARS to develop a set of climate change scenarios assuming a temperature increase by mid-century of 1, 2, 3 and 4 K. The process-based forest growth model 4C is applied to a 200-year-old pine forest to analyse impacts on carbon and water balance as well as the risk of fire under these climate change scenarios. The climate scenarios indicate precipitation increases mainly during winter and decreases during summer with increasing temperature trend. They cause rising forest productivity up to about 20 % in spite of increasing respiration losses. At the same time, the water-use efficiency increases slightly from 2.0 g C l?1 H2O under current climate to 2.1 g C l?1 H2O under 4 K scenario indicating that higher water losses from increasing evapotranspiration do not appear to lead to water limitations for the productivity at this site. The simulated actual evaporation increases by up to 32 %, but the climatic water balance decreases by up to 20 % with increasing temperature trend. In contrast, the risk of fire indicated by the Nesterov index clearly increases. Our analysis confirms increasing productivity of the boreal pine stand but also highlights increasing drought stress and risks from abiotic disturbances which could cancel out productivity gains.  相似文献   

13.
This study was conducted to examine perceptions of the farmers and key informants on the use of low-quality irrigation water for vegetable production in urban and peri-urban areas in Morogoro, Tanzania. The methods used to collect data were farmer surveys (n = 60), focus group discussions (n = 4) and key informants interviews (n = 15). The results showed that the respondents had a positive perception on using low-quality irrigation water for vegetable production. The reported benefits include availability of water throughout the year, highest soil and crop nutrients in irrigation water, less costs of buying commercial fertilizers, vegetable production all year round, sustainable income generation from selling vegetables and also jobs creation in the community among farmers and vegetable sellers. Findings from Mann–Whitney U test and Kruskal–Wallis test score on farmers perception scales indicate an association between the source of low-quality water used and the respondents’ sex. Accordingly, female farmers had higher positive perception on the benefits of low-quality water compared to male farmers. Higher perception score was also observed among farmers who used polluted river water in irrigation vegetable production compared to farmers who used wastewater. Since low-quality irrigation water is a good strategy of coping with scarcity of freshwater for communities which have no alternative source of irrigation water, the study recommends multi-sectorial agencies across the country to be involved in formulating policies and creating health promotion awareness for safe use of low-quality water for benefit maximization and health risk reduction.  相似文献   

14.
The topic of carbon sequestration in plants has received much attention recently due to concerns about global climate change, which is being exacerbated by deforestation. In the early days of the global bioenergy boom, the private sector and non-government organizations enthusiastically promoted the planting of Jatropha curcas L. as a key candidate shrub species for the production of bioenergy in West Africa. This study investigates the aboveground biomass production and carbon sequestration potential of J. curcas, which is already widely cultivated for the production of oil seeds, biodiesel and biokerosene. The specific objective is to use a destructive method to develop allometric prediction equations of the aboveground biomass production of J. curcas plantations. 38 J. curcas shrubs were harvested and weighed in order to estimate biomass production. These data were used to develop allometric equations for the estimation of wood, leaf and total aboveground biomass production. The best-fit models found for estimating shrub component biomass and total aboveground biomass production were of the power form. All of the regression equations relating the prediction of leaf biomass, wood biomass and total aboveground biomass with J. curcas diameter at 20 cm above the ground (D) were statistically significant (p < 0.001) and also presented the highest goodness of fit (high R 2). The aboveground biomass carbon content was estimated using the ash method. Carbon content in leaves and wood was, respectively, 48 and 54 %. The current established allometric equations can be helpful to provide a rapid estimation of the aboveground biomass and C stock for J. curcas biofuel projects in semi-arid conditions.  相似文献   

15.
The Welsh Government is committed to reduce greenhouse gas (GHG) emissions from agricultural systems and combat the effects of future climate change. In this study, the ECOSSE model was applied spatially to estimate GHG and soil organic carbon (SOC) fluxes from three major land uses (grass, arable and forest) in Wales. The aims of the simulations were: (1) to estimate the annual net GHG balance for Wales; (2) to investigate the efficiency of the reduced nitrogen (N) fertilizer goal of the sustainable land management scheme (Glastir), through which the Welsh Government offers financial support to farmers and land managers on GHG flux reduction; and (3) to investigate the effects of future climate change on the emissions of GHG and plant net primary production (NPP). Three climate scenarios were studied: baseline (1961–1990) and low and high emission climate scenarios (2015–2050). Results reveal that grassland and cropland are the major nitrous oxide (N2O) emitters and consequently emit more GHG to the atmosphere than forests. The overall average simulated annual net GHG balance for Wales under baseline climate (1961–1990) is equivalent to 0.2 t CO2e ha?1 y?1 which gives an estimate of total annual net flux for Wales of 0.34 Mt CO2e y?1. Reducing N fertilizer by 20 and 40 % could reduce annual net GHG fluxes by 7 and 25 %, respectively. If the current N fertilizer application rate continues, predicted climate change by the year 2050 would not significantly affect GHG emissions or NPP from soils in Wales.  相似文献   

16.
The UK Climate Change Act (CCA) mandates an 80 % reduction in CO2 emissions by 2050. It is estimated that 3.2 M tonnes pa CO2 results from travel-related NHS business. The acquisition of an electric bicycle to replace a car for both commuting and home visits allowed comparison of fuel use and CO2 emissions over a 4-year period. The switch to the use of the electric bicycle reduced the average annual petrol use by 329 l, the energy consumption by 3,140 kWh and the CO2 released by 748 kg a year. Wider adoption of electric bicycles in urban General Practice will contribute to the requirements of the CCA though to have a significant effect on the current estimated commuting-related carbon footprint of the NHS (0.76 MT pa) would require two-thirds of the workforce to abandon their cars in favour of electric bicycles.  相似文献   

17.
Nitrogen fertilization (N) is commonly known as a main source of direct nitrous oxide (N2O) emission from agricultural soils. An area of 38 % of the total land surface of Poland was covered by agricultural soils in 2009. In this paper, we aimed at analyzing data regarding the land exploitation for 13 selected subareas of Poland between 1960 and 2009. Seven out of the 13 subareas studied are located in the West (area A), and six subareas are located in southeast of Poland (area B). The total area covered by large farms (>20 ha) differed largely, between area A (10.6 %) and area B (0.9 %) in 2009. Both areas varied in terms of the amount of fertilizers used annually, average crop yield and crop structure. Average direct emissions of N2O from agricultural soils were 1.66 ± 0.09 kg N2O–N ha?1 a?1 for area A, 1.39 ± 0.07 kg N2O–N ha?1 a?1 for area B and 1.46 ± 0.07 kg N2O–N ha?1 a?1 for the whole country between 1960 and 2009.  相似文献   

18.
This work aimed to utilize four low-cost materials, namely activated carbon (AC), activated carbon–nanoparticle composite, kaolin, and olive cake, for phosphate removal. Batch mode tests were used to evaluate the performance of the adsorbents. The parameters affecting the adsorption process such as pH, initial concentration, mixing time, dosage, and temperature were studied. The obtained results showed that the removal efficiency of the adsorbents followed the order of: activated carbon–nanosilica > activated carbon > kaolin > olive cake. The addition of silica nanoparticles significantly enhanced the removal efficiency of activated carbon by 18.1% reaching a removal efficiency of 98% at 15wt% nanosilica loading. The adsorption isotherm data fitted well with Langmuir and Redlich–Peterson models with a correlation coefficient of >0.98, which indicates a monolayer homogenous adsorption. The fitness of the kinetic models was ranked as: pseudo-second-order > pseudo-first-order > intraparticle model. The calculated values of ΔH° = 23.4 kJ/mole, ΔS° = 0.11 kJ/mole, and ΔG = ?7.4 to ?11.8 kJ/mole indicated the endothermic and spontaneous nature of adsorption. The positive value of activation energy (17.66 kJ/mole) and the very low value of the sticking probability (2.4 × 10?4) suggest high indefinite sticking of the phosphate ions to the adsorbent surface. The removal efficiency increased with time, dosage, and temperature, while it decreased with the increase in the initial concentration at an optimum pH of 7. The obtained results buttressed the benefit of using silica nanoparticles to enhance activated carbon capacity for phosphate removal, while kaolin and olive cake provided lower removal.  相似文献   

19.
The present study was undertaken in Pinus roxburghii forest along three different altitudes i.e., 1100, 1300 and 1500 meter above mean sea level of Garhwal Himalaya to understand the effect of altitudes on carbon stocks (live trees and soil) in Pinus roxburghii forest. Tree density of this forest ranged between 590 tree ha?1 (upper altitude) to 640 tree ha?1 (lower altitude). The highest total carbon density (TCD) of above and belowground carbon was 66.33 ± 29.92 Mg ha?1 at lower altitude followed by 57.64 ± 16.75 Mg ha?1 in middle altitude and 52.92 ± 6.52 Mg ha?1 in upper altitude. Soil organic carbon was highest (33.20 ± 2.77 Mg ha?1) at lower altitude followed by middle (22.61 ± 7.17 Mg ha?1) and upper altitude (12.65 ± 6.10 Mg ha?1). Total carbon stock (trees + soil) of Pinus roxburghii forest was maximum (99.53 Mg ha?1) at lower altitude and minimum (65.57 Mg ha?1) at upper altitude.  相似文献   

20.
Oxidation of hydrocarbon in asphalt binder leads to the production of carbon dioxide (CO2) during the production of hot mix asphalt. The objective of this laboratory study was to investigate the effects of the asphalt additive Sasobit®, asphalt content and mixing/placement temperature on CO2 emissions from binder with laboratory measurements. The isolated effects of Sasobit on asphalt absorption into the aggregate were also looked at. Temperature was found to be the only statistically significant factor on emissions. This would suggest that warm mix asphalt technology, which employs the use of Sasobit in asphalt mixtures, is a very effective way of lowering the industry's CO2 emission impact, both directly and by the use of less energy for heating. This work predicts that greater than 30% reduction of CO2 emissions is possible with typically used levels of Sasobit.  相似文献   

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