Ammonia stripping of biologically treated liquid manure

A prerequisite for efficient ammonia removal in air stripping is that the pH of the liquid to be stripped is sufficiently high. Swine manure pH is usually around 7. At pH 7 (at 20°C), only 0.4% of ammonium is in ammonia form, and it is necessary to raise the pH of swine slurry to achieve efficient ammonia removal. Because manure has a very high buffering capacity, large amounts of chemicals are needed to change the slurry pH. The present study showed that efficient air stripping of manure can be achieved with a small amount of chemicals and without strong bases like NaOH. Slurry was subjected to aerobic biological treatment to raise pH before stripping. This facilitated 8 to 32% ammonia removal without chemical treatment. The slurry was further subjected to repeated cycles of stripping with MgO and Ca(OH)(2) additions after the first and second strippings, respectively, to raise slurry pH in between the stripping cycles. After three consecutive stripping cycles, 59 to 86% of the original ammonium had been removed. It was shown that the reduction in buffer capacity of the slurry was due to ammonia and carbonate removal during the stripping cycles.     

Recycling of gneiss rock waste in the manufacture of vitrified floor tiles

The present study focuses on the recycling of gneiss rock waste generated by the ornamental rock industry for manufacturing vitrified floor tile products. The gneiss rock waste came from a rock-cutting plant located in Santo Antônio de Pádua-RJ, Brazil. Initially the waste sample was characterized for chemical composition, X-ray diffraction, particle size, morphology, and pollution potential. Floor tiles containing up to 47.5 wt.% waste were prepared. The tiles were tested to determine their physical-mechanical properties (linear shrinkage, water absorption, apparent density, and flexural strength). Microstructural evolution was carried out by scanning electron microscopy. The results indicate that the gneiss rock waste could be used for vitrified floor tile production, resulting in a new possibility for recycling this waste and conserving natural resources.     

COMPREHENSIVE FLOOD PLAIN STUDIES USING SPATIAL DATA MANAGEMENT TECHNIQUES1

ABSTRACT: A pilot study undertaken to develop and test analytical methodologies for application in comprehensive flood plain information studies is described. The methodology permits and encourages comprehensive, systematic, practical assessments of present and alternative future basin-wide development patterns as reflected by alternative land use patterns and physical works in terms of flood hazard, economic damage potential and selected environmental consequences. The analysis methodologies are centered about integrated use of computerized spatial, gridded geographic and resource data files. A family of special purpose utility computer programs access the data file and extract appropriate variables and interpret and format the data into specific analytical parameters that are subsequently formatted for input to traditional modeling computer programs. An example application to Trail Creek in Clarke County, Georgia, is described.     

Prediction of odor from pig production based on chemical odorants

The present work was performed to investigate the use of odorant measurements for prediction of odor concentration in facilities with growing-finishing pigs and to analyze the odorant composition in facilities with different floor and ventilation systems. Air was sampled in Nalophan bags, odor concentrations were measured by dilution-to-threshold olfactometry, and concentrations of odorants were measured by proton-transfer-reaction mass spectrometry (PTR-MS). Olfactometry and chemical analyses were synchronized to take place at identical time intervals after sampling. A principal component analysis revealed that different facilities for growing-finishing pigs can be distinguished based on the odorants. Pit ventilation comprising a small amount of the total ventilation air (10-20%) in facilities with both room and pit ventilation can be used to concentrate odorants, whereas the room ventilation contains lower concentrations of most odorants. A partial least squares regression model demonstrated that prediction of the odor concentration based on odorants measured by PTR-MS is feasible. Hydrogen sulfide, methanethiol, trimethylamine, and 4-methylphenol were identified as the compounds having the largest influence on the prediction of odor concentration, whereas carboxylic acids had no significant influence. In conclusion, chemical measurement of odorants by PTR-MS is an alternative for expressing the odor concentration in facilities with growing-finishing pigs that can be used to increase the understanding of odor from different types of facilities and improve the development of odor reduction technologies.     

Nutrient-Balance Modeling as a Tool for Environmental Management in Aquaculture: The Case of Trout Farming in France

The control and prevention of nutrient pollution from fish farming plays an essential role in the French regulatory framework. Assessing nutrient emissions from fish farms is important in terms of farm authorization, taxation, and monitoring. Currently employed strategies involve both water sampling and empirical modeling. This article reports the work and outcomes of an expert panel that evaluated existing methodologies and their possible alternatives. The development and evaluation of a nutrient-balance approach was assessed as a potential alternative to currently used methodologies. A previously described nutrient-balance model was suggested and parameterized using expert choice, and its validity and applicability were assessed. The results stress that the nutrient-balance model provides more robust and relatively conservative waste estimates compared to the currently used methodologies. Sensitivity of the approach to the uneven data quality available at farm level, difficulties of on-farm measurements, as well as model requirements and limitations are discussed.     

Multiyear nutrient removal performance of three constructed wetlands intercepting tile drain flows from grazed pastures

Subsurface tile drain flows can be a major s ource of nurient loss from agricultural landscapes. This study quantifies flows and nitrogen and phosphorus yields from tile drains at three intensively grazed dairy pasture sites over 3- to 5-yr periods and evaluates the capacity of constructed wetlands occupying 0.66 to 1.6% of the drained catchments too reduce nutrient loads. Continuous flow records are combined with automated flow-proportional sampling of nutrient concentrations to calculate tile drain nutrient yields and wetland mass removal rates. Annual drainage water yields rangedfrom 193 to 564 mm (16-51% of rainfall) at two rain-fed sites and from 827 to 853 mm (43-51% of rainfall + irrigation) at an irrigated site. Annually, the tile drains exported 14 to 109 kg ha(-1) of total N (TN), of which 58 to 90% was nitrate-N. Constructed wetlands intercepting these flows removed 30 to 369 gTN m(-2) (7-63%) of influent loadings annually. Seasonal percentage nitrate-N and TN removal were negatively associated with wetland N mass loadings. Wetland P removal was poor in all wetlands, with 12 to 115% more total P exported annually overall than received. Annually, the tile drains exported 0.12 to 1.38 kg ha of total P, of which 15 to 93% was dissolved reactive P. Additional measures are required to reduce these losses or provide supplementary P removal. Wetland N removal performance could be improved by modifying drainage systems to release flows more gradually and improving irrigation practices to reduce drainage losses.     

Medical waste management in Korea

The management of medical waste is of great importance due to its potential environmental hazards and public health risks. In the past medical waste was often mixed with municipal solid waste and disposed of in residential waste landfills or improper treatment facilities (e.g. inadequately controlled incinerators) in Korea. In recent years, many efforts have been made by environmental regulatory agencies and waste generators to better manage the waste from healthcare facilities. This paper presents an overview of the current management practices of medical waste in Korea. Information regarding generation, composition, segregation, transportation, and disposal of medical wastes is provided and discussed. Medical waste incineration is identified as the most preferred disposal method and will be the only available treatment option in late 2005. Faced with increased regulations over toxic air emissions (e.g. dioxins and furans), all existing small incineration facilities that do not have air pollution control devices will cease operation in the next few years. Large-scale medical waste incinerators would be responsible for the treatment of medical waste generated by most healthcare facilities in Korea. It is important to point out that there is a great potential to emit air toxic pollutants from such incinerators if improperly operated and managed, because medical waste typically contains a variety of plastic materials such as polyvinyl chloride (PVC). Waste minimization and recycling, control of toxic air emissions at medical waste incinerators, and alternative treatment methods to incineration are regarded to be the major challenges in the future.     

In situ bioreactors and deep drain-pipe installation to reduce nitrate losses in artificially drained fields

Nitrate in water removed from fields by subsurface drain ('tile') systems is often at concentrations exceeding the 10 mg N L(-1) maximum contaminant level (MCL) set by the USEPA for drinking water and has been implicated in contributing to the hypoxia problem within the northern Gulf of Mexico. Because previous research shows that N fertilizer management alone is not sufficient for reducing NO(3) concentrations in subsurface drainage below the MCL, additional approaches are needed. In this field study, we compared the NO(3) losses in tile drainage from a conventional drainage system (CN) consisting of a free-flowing pipe installed 1.2 m below the soil surface to losses in tile drainage from two alternative drainage designs. The alternative treatments were a deep tile (DT), where the tile drain was installed 0.6 m deeper than the conventional tile depth, but with the outlet maintained at 1.2 m, and a denitrification wall (DW), where trenches excavated parallel to the tile and filled with woodchips serve as additional carbon sources to increase denitrification. Four replicate 30.5- by 42.7-m field plots were installed for each treatment in 1999 and a corn-soybean rotation initiated in 2000. Over 5 yr (2001-2005) the tile flow from the DW treatment had annual average NO(3) concentrations significantly lower than the CN treatment (8.8 vs. 22.1 mg N L(-1)). This represented an annual reduction in NO(3) mass loss of 29 kg N ha(-1) or a 55% reduction in nitrate mass lost in tile drainage for the DW treatment. The DT treatment did not consistently lower NO(3) concentrations, nor reduce the annual NO(3) mass loss in drainage. The DT treatment did exhibit lower NO(3) concentrations in tile drainage than the CN treatment during late summer when tile flow rates were minimal. There was no difference in crop yields for any of the treatments. Thus, denitrification walls are able to substantially reduce NO(3) concentrations in tile drainage for at least 5 yr.     

Evaluation of alternative water sources for commercial buildings: A case study in Brisbane,Australia

Commercial buildings are central to cities and contribute significantly to the urban demand for natural resources, including freshwater. Green building benchmarking tools include more efficient water use as key indicator of sustainability. This paper explores options for substituting mains drinking water with an alternative, non-potable water source on a fit for purpose basis. The research findings are based on a monitoring study of a commercial building in Brisbane, Australia that is harvesting rainwater for meeting non-potable water demand. The results demonstrated that the system is only achieving moderate reliability in meeting demand due to operational problems. The case study analysis has highlighted the need to include validation and monitoring to ensure the system is operating as per design intent. The paper also investigates the potential of other local, non-potable water sources for high-rise commercial buildings, in particular air conditioning condensate and groundwater inflow to a basement wet well. The paper concludes by comparing the advantages and disadvantages of different local water sources which highlights the need to undertake a site specific investigation to identify a suitable alternative water source, which considers O&M complexity and the capacity of facilities management.     

Estimation of Nonpoint Source Nitrate Concentrations in Indiana Rivers Based on Agricultural Drainage in the Watershed

Subsurface tile‐drained agricultural fields are known to be important contributors to nitrate in surface water in the Midwest, but the effect of these fields on nitrate at the watershed scale is difficult to quantify. Data for 25 watersheds monitored by the Indiana Department of Environmental Management and located near a U.S. Geological Survey stream gage were used to investigate the relationship between flow‐weighted mean concentration (FWMC) of nitrate‐N and the subsurface tile‐drained area (DA) of the watershed. The tile DA was estimated from soil drainage class, land use, and slope. Nitrate loads from point sources were estimated based on reported flows of major permitted facilities with mean nitrate‐N concentrations from published sources. Linear regression models exhibited a statistically significant relationship between annual/monthly nonpoint source (NPS) nitrate‐N and DA percentage. The annual model explained 71% of the variation in FWMC of nitrate‐N. The annual and monthly models were tested in 10 additional watersheds, most with absolute errors within 1 mg/l in the predicted FWMC. These models can be used to estimate NPS nitrate for unmonitored watersheds in similar areas, especially for drained agricultural areas where model performance was strongest, and to predict the nitrate reduction when various tile drainage management techniques are employed.     

Municipal hotlines and automated weather stations as a tool for monitoring bad odour dispersion: the northern Negev case

Bad odours are often dispersed from chemical industries, waste dumps, sewer plants, and other facilities. They are indicative of pollution emissions from these sites and cause discomfort, apprehension, and sometimes signal the presence of health hazards. Monitoring the pollution by direct means, such as chemical analysis of ambient air, is obviously the most reliable mechanism to acquire data regarding pollution. However, this is not always possible. In this paper we report on the value of local government hotlines that record information provided by the public regarding bad odours. These data can alert the authorities to the existence of pollution and should be regarded as potentially useful when collected in conjunction with information from automated weather stations. An analysis of data from the Be'er Sheva municipality and the Ramat Negev regional council hotlines is provided. Complaints recorded by these systems were correlated with weather data from local automatic weather stations to indicate the sources of the bad odours. Wind direction was found to be highly correlated with bad odour and pollution sources, revealing consistent patterns in terms of the time of day and weather conditions.     

Contaminant Retention Potential of Forested Filter Strips Established as SMZs in the Piedmont of Georgia1

Abstract: It is common practice in the United States and elsewhere to maintain vegetated filter strips adjacent to streams to retain contaminants in surface runoff. Most research has evaluated contaminant retention in managed agricultural field strips, while relatively few studies have quantified retention in forested filter strips, particularly for dissolved contaminants. Plot‐scale overland flow experiments were conducted to evaluate the efficiency of natural forested filter strips established as streamside management zones (SMZs) for retaining phosphorus (P), atrazine, and picloram transported in runoff. Retention was evaluated for five different slope classes: 1‐2, 5‐7, 10‐12, 15‐17, and 20‐22%; two cover conditions: undisturbed forest floor (O horizon intact) and forest floor removed by raking; and two periods with contrasting soil moisture conditions: summer‐dry and winter‐wet season. Surface flow was collected at 0, 2, 4, 6, and 10 m within the filter strip to evaluate changes in solution concentration as it moved through the O horizon and the surface soil horizon mixing zone. On average, a 10 m length of forested SMZ with an undisturbed forest floor reduced initial solution concentration of total dissolved P by 51%, orthophosphate P by 49%, atrazine by 28%, and picloram by 5%. Percentages of mass retention through infiltration of water plus concentration reductions in runoff were 64% for total dissolved P, 62% for orthophosphate P, 47% for atrazine, and 28% for picloram for undisturbed forest floor conditions. Lower retention occurred following forest floor removal, particularly for P. Average dissolved P retention was 16% lower following forest floor removal. For undisturbed sites, differences in retention were more closely related to forest floor depth than to slope or antecedent soil moisture. These results indicate that forested SMZ filter strips provide a significant measure of surface water protection from dissolved P and herbicide delivery to surface water.     

Sectoral sustainability and sustainability assessment methodologies: A review of methodology in light of collaboration with the UK oil and gas sector

This paper discusses methodologies that have been employed to give insights into business performance in relation to sustainable development, both at a sectoral and corporate level. From consideration of different sectoral sustainable development methodologies, some key issues and good practice related to their derivation are elaborated. These issues are then further illustrated by a detailed comparison between three sustainable development methodologies that have been used in the UK offshore oil and gas industry. The methodologies chiefly differ in terms of how they address the problem of comparing different impacts across potentially non-commensurable dimensions, one proceeding through explicit monetary valuation, another through implicit valuation of different options and another through presentation of an unaggregated framework of indicators. The paper concludes by identifying the different situations in which use of these different methodologies is appropriate.     

IMPACTS OF AGRICULTURAL DRAINAGE WELL CLOSURE ON CROP PRODUCTION: A WATERSHED CASE STUDY1

ABSTRACT: Much of north-central Iowa is characterized by flat topography, shallow depressions, and poor natural surface drainage. Land drainage systems comprising of tile drains and agricultural drainage wells (ADWs) are used as outlets for subsurface drainage of cropland under corn and soybean production. Studies have shown that these drainage systems, mainly the ADWs, are potential routes for agricultural chemicals to underground aquifers. To protect the region's vital groundwater resource, researchers are evaluating alternative outlets ranging from complete closure of existing ADWs (and creation of wetlands) to continued use of ADWs and chemical management in a comprehensive policy framework. This paper presents the results of a study designed to provide government jurisdictions, farmers, and land managers information for assessing the impact of closing ADWs on crop production. The study couples a geographic information systems database for a 471-hectare watershed in Humboldt County, Iowa, with a groundwater flow model (MODFLOW) and an empirical crop yield loss model to predict long-term effects of complete closure of ADWs on crop production. The cropland areas inundated and the relative crop yield loss due to ADW closure are determined as a function of long-term climatic data. The results indicate that elimination of drainage outlets in the watershed could result in ponding of low-lying areas and poorly drained soils, making them unsuitable for crop production. Such wetness also decreases the efficiency of production in the no-ponding areas by isolating fields, and the crop yield loss can be reduced by an annual average of about 18 percent.     

Source characterization of nervous system active pharmaceutical ingredients in healthcare facility wastewaters

Nervous system active pharmaceutical ingredients (APIs), including anti-depressants and opioids, are important clinically administered pharmaceuticals within healthcare facilities. This study provides source characterization data describing the composition and magnitude of nervous system APIs present in healthcare facility wastewaters. Concentrations and mass loadings of ten nervous system APIs and three nervous system API metabolites are reported for wastewaters from a hospital, nursing, assisted living, and independent living facility within a single municipality. Concentrations of nervous system APIs ranged from non-detectable levels for alprazolam in all four facility wastewaters to a high of 290 ng/L amitriptyline in nursing facility wastewater. The summed mean concentration of all thirteen analytes ranged from 402 ng/L in independent living facility wastewater to 624 ng/L in assisted living facility wastewater. Wastewater flow rates from each facility were combined with concentration data to estimate the daily mass loading of nervous system APIs leaving each facility through wastewater discharge to the municipal sewer system. The total mass loading of all thirteen analytes for the hospital, nursing, assisted living, and independent living facility was 228, 44, 29.5, and 28.1 mg/day, respectively. The total mass loading of nervous system APIs contributed to the municipality's wastewater from all four facilities was 330 mg/day.     

Diuron in surface runoff and tile drainage from two grass-seed fields

The typical method of cool-season grass-seed production in Mediterranean climates briefly exposes surface waters to potentially high concentrations of the herbicide diuron [3-(3,4-dichlorophenyl)-1,1-dimethyl urea] during the initial season of growth. To better understand the process, and the degree, of diuron transport from agricultural fields, two grass-seed fields in the Willamette Valley of Oregon were monitored for diuron loss in surface runoff and tile drainage during the first wet season after planting. Initial diuron concentrations in surface runoff were high (>1000 microg L(-1) in one field and >100 microg L(-1) in the other), though they decreased by two orders of magnitude by the end of the season. Concentrations in the tile drains were as much as 1000 times lower than in the surface runoff during the first few weeks of runoff events, and they remained lower than surface water concentrations throughout the season. Total losses in surface runoff were between 1.3 and 3% of the amount applied-much higher than losses via the tile drains. It is also shown by means of a simple first-order decay model that, when little information is available, it may be best to describe diuron depletion in runoff water as a function of cumulative rainfall during the wet season.     

Phosphorus removal with by-products in a flow-through setting

Phosphorus (P) losses to surface waters can result in eutrophication. Some industrial by-products have a strong affinity for dissolved P and may be useful in reducing nonpoint P pollution with landscape-scale runoff filters. Although appreciable research has been conducted on characterizing P sorption by industrial by-products via batch isotherms, less data are available on P sorption by these materials in a flow-through context integral to a landscape P filter. The objectives of this study were to evaluate several industrial by-products for P sorption in a flow-through setting, to determine material chemical properties that have the greatest impact on P sorption in a flow-through setting, and to explore how retention time (RT) and P concentration affect P removal. Twelve materials were characterized for chemical properties that typically influence P removal and subjected to flow-through P sorption experiments in which five different RTs and P concentrations were tested. The impact of RT and P concentrations on P removal varied based on material chemical properties, mainly as a function of oxalate-extractable aluminum (Al), iron (Fe), and water-soluble (WS) calcium (Ca). Statistical analysis showed that materials elevated in oxalate-extractable Al and Fe and WS Ca and that were highly buffered above pH 6 were able to remove the most P under flow-through conditions. Langmuir sorption maximum values from batch isotherms were poorly correlated with and overestimated P removal found under flow-through conditions. Within the conditions tested in this study, increases in RT and inflow P concentrations increased P removal among materials most likely to remove P via precipitation, whereas RT had little effect on materials likely to remove P via ligand exchange.     

Minimising the regeneration heat duty of post-combustion CO2 capture by wet chemical absorption: The misguided focus on low heat of absorption solvents

An ideal solvent for CO₂ capture by chemical absorption has to meet a number of requirements, such as high CO₂ capacity, high rate of reaction, low costs, low corrosive behaviour, low degradation and low vapour pressure; above all, it has to show a low regeneration heat duty. This heat can be approximated as the sum of three terms: the sensible heat to raise the solvent from absorber to desorber temperature, the heat of evaporation required to produce the stripping steam in the reboiler, and the heat necessary to desorb the CO₂ from the solution (heat of absorption).Many solvent screening studies focus almost exclusively on solvents that show a low heat of absorption. In these studies, the strong dependence of the three contributors to the overall regeneration heat duty on the chosen process parameters and on one another are often neglected.This work explains why the focus on solvents with a low heat of absorption, without considering the overall process, is not sufficient in quantifying the energy performance of alternative solvents. By using thermodynamic interrelations and underpinned by process simulations it is shown that operating parameters of the process, in particular the desorber pressure, must be taken into consideration in the evaluation of new solvents.     

Integrated Wastewater Management Reporting at Tourist Areas for Recycling Purposes, Including the Case Study of Hersonissos, Greece

Wastewater treatment facilities in tourist areas, in comparison to other municipal facilities, require specific configurations and additional management actions in order to achieve a reliable and cost-effective treatment. For example, the same facility operates during winter with minimum flows and in summer with peak flows. Moreover, careful effluent management is required to minimize environmental impact and health effects on tourists. In this study, effluent management data, including quantitative and qualitative effluent characteristics, reuse, and economic aspects of the Hersonissos Wastewater Treatment Plant (WTP) in Greece, are discussed. It has been designed to treat both municipal wastewater from the Hersonissos Municipality and septage from the wider area. Analysis of effluent quantitative data showed two flow peaks in the summer period and only one in winter. The WTP was found to provide a reliable level of treatment in terms of biochemical oxygen demand (95.9%), total suspended solids (97.2%), and total nitrogen (87.7%) removal, but increased numbers of fecal coliforms were measured at some peak flow periods, suggesting the need for additional management strategies. Effluent is reused mainly for agricultural irrigation; secondary uses include fire protection and landscape irrigation. Economic analysis showed that for each cubic meter treated, the total annual economic cost for treatment, filtration, and reuse infrastructure was 1.07 €, 0.05 €, and 0.08 €, respectively.     

Microwave-assisted stripping of oil contaminated drill cuttings

The application of microwave heating technology to conventional gas stripping processes has been investigated in the remediation of contaminated drill cuttings. The technical feasibility and limitations of nitrogen and steam stripping processes are demonstrated, and it is shown that the combination of microwave heating with the stripping process offers a step change in performance. Order of magnitude improvements in processing time are shown for the microwave-assisted processes, as well as greatly improved levels of remediation. The mechanisms of contaminant removal are discussed, along with the phenomena which occur with microwave heating processes. The energy requirements of each of pure gas and microwave-assisted processes are also discussed, and the potential applications of each technology are highlighted relative to the overall remediation requirements.