Risk assessment near uncontrolled hazardous waste sites: Role of monitoring data

The traditional approach of coupling estimates of human exposures to individual chemicals with laboratory studies of the toxicity of the chemicals as the basis for quantitative assessments of risk is not adequate when considering problems near hazardous waste sites. For example, there are (a) too many chemicals and mixtures involved, (b) containment uncertainties, and (c) future exposure problems associated with groundwater and soil contamination. Among the items to be considered in expanding the dimensions of risk assessment methodologies of the past are (a) identification of chemical groups or of dominant toxic chemicals of principal concern and the likely man-made as well as natural pathways for environmental migration, (b) the role of biological monitoring in addition to traditional monitoring approaches, and (c) the coupling of monitoring data with past, current, and future population activity patterns and with epidemiological and other health data.Monitoring data is a key in risk assessments since there is little likelihood that materials balances or modelling will provide authoritative information concerning exposure levels. The use of monitoring data from control areas and from nationwide baseline surveys in developing comparative risk assessments is particularly important. Finally, recent experience provides us with a number of practical guidelines for designing and carrying out monitoring programs that will provide authoritative and useful data. *** DIRECT SUPPORT *** AZ802019 00002     

Decision support methods for the environmental assessment of contamination at mining sites

Polluting mine accidents and widespread environmental contamination associated with historic mining in Europe and elsewhere has triggered the improvement of related environmental legislation and of the environmental assessment and management methods for the mining industry. Mining has some unique features such as natural background pollution associated with natural mineral deposits, industrial activities and contamination located in the three-dimensional sub-surface space, the problem of long-term remediation after mine closure, problem of secondary contaminated areas around mine sites and abandoned mines in historic regions like Europe. These mining-specific problems require special tools to address the complexity of the environmental problems of mining-related contamination. The objective of this paper is to review and evaluate some of the decision support methods that have been developed and applied to mining contamination. In this paper, only those methods that are both efficient decision support tools and provide a ‘holistic’ approach to the complex problem as well are considered. These tools are (1) landscape ecology, (2) industrial ecology, (3) landscape geochemistry, (4) geo-environmental models, (5) environmental impact assessment, (6) environmental risk assessment, (7) material flow analysis and (8) life cycle assessment. This unique inter-disciplinary study should enable both the researcher and the practitioner to obtain broad view on the state-of-the-art of decision support methods for the environmental assessment of contamination at mine sites. Documented examples and abundant references are also provided.     

An evaluation of a risk-based environmental regulation in Brazil: Limitations to risk management of hazardous installations

The environmental regulation of hazardous projects with risk-based decision-making processes can lead to a deficient management of human exposure to technological hazards. Such an approach for regulation is criticized for simplifying the complexity of decisions involving the economic, social, and environmental aspects of the installation and operation of hazardous facilities in urban areas. Results of a Brazilian case study indicate that oil and gas transmission pipelines may represent a threat to diverse communities if the relationship between such linear projects and human populations is overlooked by regulatory bodies. Results also corroborate known challenges to the implementation of EIA processes and outline limitations to an effective environmental and risk management. Two preliminary topics are discussed to strengthen similar regulatory practices. Firstly, an effective integration between social impact assessment and risk assessment in EIA processes to have a more comprehensive understanding of the social fabric. Secondly, the advancement of traditional management practices for hazardous installations to pursue a strong transition from assessment and evaluation to management and control and to promote an effective interaction between land-use planning and environmental regulation.     

Application of the IPCC Waste Model to solid waste disposal sites in tropical countries: case study of Thailand

Measurements of landfill methane emission were performed at nine solid waste disposal sites in Thailand, including five managed sanitary landfills (four deep and one shallow landfills) and four unmanaged landfills (three deep and one shallow dumpsites). It was found that methane emissions during the rainy season were about five to six times higher than those during the winter and summer seasons in the case of managed landfills and two to five times higher in the case of unmanaged landfills. Methane emission estimate using the Intergovernmental Panel on Climate Change (IPCC) Waste Model was compared with the actual field measurement from the studied disposal sites with methane correction factors and methane oxidation factors that were obtained by error function analysis with default values of half-life parameters. The methane emissions from the first-order decay model from the IPCC Waste Model yielded fair results compared to field measurements. The best fitting values of methane correction factor were 0.65, 0.20, 0.15, and 0.1 for deep landfills, shallow landfills, deep dumpsites, and shallow dumpsites, respectively. Using these key parameters in the case of Thailand, it was estimated that 89.22 Gg of methane were released from solid waste disposal sites into the atmosphere in 2006.     

Integrating adaptation to climate change in regional plans and programmes: The role of strategic environmental assessment

Climate changes exert negative impacts on the global environments and the human beings. They imply more frequent extreme weather events, which are responsible of sea level rise, coastal erosion, flooding, droughts, and desertification. Mitigation and adaptation represent intertwined strategies for counteracting climate changes. Mitigation is associated to the lessening of the causes of climate changes and includes actions reducing greenhouse gas emissions. Adaptation is a proactive concept addressing how humans can adapt and benefit from climate change. The mainstreaming and integration of adaptation to climate change into routine practice can be favored by Strategic Environmental Assessment (SEA) of regional policies, plans and programmes. In this study, we aim at scrutinizing a set of SEA reports of regional plans and programmes adopted in Sardinia (Italy), to investigate if -and to what extent- adaptation to climate change has characterized planning and programming tools. Evidence shows that the integration of adaptation-driven issues into regional planning is still in its infancy but presents the signs of promising expansion.     

Signal-transfer modeling for regional assessment of forest responses to environmental changes in the southeastern United States

Stochastic transfer of information in a hierarchy of simulators is offered as a conceptual approach for assessing forest responses to changing climate and air quality across 13 southeastern states of the USA. This assessment approach combines geographic information system and Monte Carlo capabilities with several scales of computer modeling for southern pine species and eastern deciduous forests. Outputs, such as forest production, evapotranspiration and carbon pools, may be compared statistically for alternative equilibrium or transient scenarios providing a statistical basis for decision making in regional assessments. This revised version was published online in July 2006 with corrections to the Cover Date.     

Soil microbial characteristics at the monitoring plots on windthrow areas of the Tatra National Park (Slovakia): their assessment as environmental indicators

This study focused on the responses of soil microorganisms to different management regimes on disturbed windthrow areas. Microbial parameters potentially serving as indicators of environmental changes within a long-term monitoring of forest development after large-scale disturbance events were assessed. Basal and substrate-induced respiration, N mineralisation, catalase activity, microbial biomass as well as functional diversity based on Biolog assay were determined in soil samples from three disturbed plots and an undisturbed reference plot in the Tatra National Park (Slovakia) since 2006. A relative congruence of inter-annual trends of microbial activity indicators at all plots results from a common response of microbiota to changes of climate at the landscape level after forest stands were destroyed. While catalase activity and functional diversity proved to be useful indicators of temporal trends, microbial biomass seems to reflect different management regimes at the disturbed plots.     

Seasonal variation for the ratio of BaP to BeP at different sites in Great Xiamen Bay

From March 2008 to February 2009, PM(10) samples were collected and analyzed for polycyclic aromatic hydrocarbons (PAHs) at eight sampling sites in Great Xiamen Bay, China. Analyses of the seasonal and spatial variations of these compounds revealed the following results. Significantly high levels of PAHs were found in the winter compared to the summer, sometimes exceeding 100 ng m(-3), and the spatial variations were influenced most by the sampling site surroundings. Composition profiles of PAHs of an urban and a rural site were shown to be very similar with a positive correlation coefficient larger than 0.9 at the 0.01 level of significance for the same season. Diagnostic ratios, together with principal component and multiple linear regression analysis, showed that more PAHs were from grass/wood/coal combustion in winter than in other seasons. The ratios of benzo[a]pyrene to benzo[e]pyrene (BaP-BeP) in winter and fall were 0.6-1.7 times higher than those in spring and summer, suggesting the importance of local emissions of PAHs. The BaP-BeP ratios in Kinmen were generally lower than those in Xiamen, indicating that the aging degree of PAHs was higher in Kinmen than in Xiamen. The external input of PAHs from upwind urban and industrial areas was one of the key factors causing high levels of PAHs in PM(10) in Great Xiamen Bay in winter.     

Theory and practice to integrating health in environmental assessment: Synthesis of an experience with stakeholders to deliver a national HIA guideline

Private or public developers, including local authorities and government agencies, have limited operational guidance to include case-relevant health information in environmental reports. In Italy, the absence of technical indications prompted the Ministry of Health to construct a new model of Health Impact Assessment (HIA) for health integration in Environmental Assessment (EA) processes. A coordinating committee set within an inter-institutional working group was assisted by public and private key stakeholders to deliver guidance on HIA. The three research stages of framing, production and delivery were carried out to: (1) frame the context for HIA guidance implementation; (2) produce the operational guideline and tools; (3) train and disclose the guideline to final users. The guideline and the operational procedures were informed by core criteria to achieve a health standard in environmental reporting. The procedures guide the user to carry out a comprehensive assessment of the population health based on the broad determinants. The environmental reporting integrates health through functional components, divided into levels and supported by related flowcharts and checklists. HIA knowledge and skills were provided to facilitate the guideline utilization within the health departments. The guideline embedded the existing EA national legacy, normative and technical. The entire decisional cycle, from strategic planning to project development was covered in the guideline including the screen of proposals. The experience triggered the definition of an environmental health collaborative platform under the Ministry of Health coordination to fill gaps in competence building, sector operational tools development, methodologies harmonization on the national territory.     

Integrating ecosystem services in spatial planning and strategic environmental assessment: The role of the cascade model

Over the last decade, the ecosystem service (ES) approach has gained increasing attention because it offers important advantages for enhancing decision-making. However, a key and remaining challenge is how to implement this approach in real-world decision problems. This challenge is particularly relevant for governance and policy instruments, such as spatial planning and strategic environmental assessment (SEA), where including the ES approach is recognized as a great opportunity for achieving sustainable development goals. Consequently, this opinion paper proposes the use of the ES cascade model, as the basis to develop a framework that makes explicit the links among development objectives, sustainability goals, and the overall dependency on the ES supply. The main reflections address the need for a collaborative work between policy and science as a cross-cutting aspect for an interactive, participative and transparent research process that allows 1) the development of spatial indicators of ecosystem structures, 2) valuation and spatial modeling of ES, 3) identification of benefits and networks of actors, 4) the definition of values and, 5) generation of scenarios for a trade-off assessment of development alternatives. Finally, in addition to the information and knowledge generation regarding multi-scale relationships of the different components of the ES cascade, real-world evidence is urgently needed.     

On the indiscriminate use of imported emission factors in environmental impact assessment: A case study in Chile

Environmental Impact Assessment (EIA) aims to determine if the environmental effect of an activity or project complies with standards and regulations. A primary component of the environment to evaluate is air and the effect that various activities can have on its quality. To this end, emission factors (EFs), which are empirical coefficients or mathematical relationships, are normally used. The present research critically analyzes the implications and consequences of using imported EFs in environmental impact studies (EISs), taking as case of study the situation in Chile. Among the main results, the widespread use of EFs in EISs in the country and the lack of assessments of their actual applicability stand out. In addition, the official guidelines related to emissions estimation that are used for EIA in the country mostly include EFs derived elsewhere, without considering the recommendations or restrictions that the original sources indicate for their use. Finally, the broad use of default values defined for the Metropolitan Region in Central Chile, is highly questionable for a country that extends north-south along more than 35° of latitude, with wide variability in climate, traffic conditions, population, soil types, etc. Finally, it is very likely that situations similar to those observed in the present work occurs in other countries with young environmental impact assessment systems, and therefore, that the results herein presented should be of general interest and relevance.     

Human health risk assessment of environmental and dietary exposure to natural radionuclides in the Catalan stretch of the Ebro River, Spain

This study was aimed at assessing the levels of ²¹⁰Pb and ²¹⁰Po concentrations as well as gross alpha and beta activities in environmental monitors from the Catalan stretch of the Ebro River (Spain), potentially influenced by the presence of sediments with high concentrations of ²³⁸U and its decay chain daughters in the Flix reservoir. The chronic daily intake of ²¹⁰Pb and ²¹⁰Po through ingestion and inhalation of soils was evaluated, and the derived non-carcinogenic and carcinogenic risks were characterized. The low concentration of radioisotopes in soils resulted in a negligible annual effective dose. The levels of ²¹⁰Pb and ²¹⁰Po were determined in various groups of highly consumed food (fish and seafood, vegetables, fruits, and rice), and their dietary intake was calculated. The annual effective dose for the adult people from food intake was estimated in 3.3 × 10^???2 mSv, mostly due to ²¹⁰Po. Overall, the current radioactivity levels in the Catalan stretch of the Ebro River should not mean any additional health risk for the population living nearby. However, an integral assessment of the risks derived from exposure to other pollutants (e.g., metals and organochlorine compounds) jointly with radionuclides could be of great interest.     

Cross-sensitivities of electrochemical detectors used to monitor worker exposures to airborne contaminants: false positive responses in the absence of target analytes

Ideally, the response of electrochemical detectors is proportional to the concentration of targeted airborne chemicals and is not be affected by concomitantly present substances. Manufacturers provide a limited list of cross-sensitivities but end-users have anecdotally reported unexpected interferences by other substances. Electrochemical detectors designed to measure airborne levels of CO, H(2)S, NO, NO(2), or SO(2), were challenged with potentially interfering substances in the absence of target analytes. Cross-sensitivities undocumented by the manufacturers were observed and were found to vary between different models of instruments for the same challenge chemical.