OCCURRENCE OF TOTAL DISSOLVED PHOSPHORUS IN UNCONSOLIDATED AQUIFERS AND AQUITARDS IN IOWA1

ABSTRACT: Seven sets of ground water samples from 103 observation wells were analyzed for total dissolved phosphorus (TDP) in four areas and five materials including loess and loess derived alluvium in the Deep Loess Hills of western Iowa, outwash and fractured till adjacent to Clear Lake in north central Iowa, fractured till in central Iowa, and a sand and gravel aquifer in northwest Iowa. Land use in ground water recharge zones in all four areas is dominated by crop or animal production or both. Concentrations of TDP exceeding the minimum laboratory detection limit of 20 μg/l as P were found in all areas and in all materials sampled. Samples from the outwash deposits associated with Clear Lake contained significantly larger concentrations than all other areas and materials with a median of 160 μg/l. Water from fractured till in three areas produced the smallest range of concentrations with a median of 40 μg/l. The mean value of TDP in all sample sets exceeded 50 μg/l, an important ecological threshold that causes increased productivity in lakes and perennial streams and one being considered as a surface water nutrient standard by regulatory agencies. These results clearly show that ground water in essentially all near‐surface aquifers and aquitards discharging to Iowa's streams and lakes is capable of sustaining P concentrations of 50 to 100 μg/l in streams, lakes, and reservoirs. Consequently, even if point discharges and sediment sources of P are substantially reduced, ground‐water discharge to surface water may exceed critical thresholds under most conditions.     

HYDROLOGICAL EFFECTS OF AN UNCONTROLLED FLOWING WELL,RED RIVER VALLEY,NORTH DAKOTA,USA1

ABSTRACT: In areas of the Red River Valley that overlie permeable Paleozoic sediments, wetlands and salinization have developed where unregulated flowing wells discharge brackish water. Field data were collected to assess the fate of water and salt from a well 25 km northwest of Grand Forks. Drilled during the drought of the 1930s, discharge was used to replenish water in a small oxbow pond used by livestock. The unregulated well discharges about 56 m³/day, measured since 1993. This discharge exceeds ground water flow from the site, thereby forming a ground water mound with a maximum height of 1 m and a diameter of about 300 m. Most soil and underlying sediments near the well have a hydraulic conductivity of 0.3 m³/day. Flow net analysis suggests that less than 25 percent infiltrates, with the remaining water lost to surface flow and evapotranspiration (ET). Evapotranspiration and slow infiltration has led to increased salinization, with shallow soils exhibiting EC to 500 milliSiemens/m. The most pronounced soil salinization occurs along the margins of the oxbow pond and meander scars. Wetland vegetation with low diversity comprises three zones, with species associations similar to those of closed basin prairie potholes to the west.     

Discharge From the Edwards Aquifer Through the Leona River Floodplain,Uvalde, Texas1

Abstract: Analysis of results from an electrical resistivity survey, a magnetic survey, and an aquifer test performed on the Leona River floodplain in south‐central Texas indicates that ground‐water discharge from the Edwards Aquifer through the Leona River floodplain may be as great as 91.7 Mm³/year. When combined with an estimate of 8.8 Mm³/year for surface flow in the Leona River, as much as 100.5 Mm³/year could be discharged from the Edwards Aquifer through the Leona River floodplain. A value of 11,200 acre‐ft/year (13.82 Mm³/year) has been used as the calibration target in existing ground‐water models for total discharge from Leona Springs and the Leona River. Including ground water or underflow discharge would significantly increase the calibration target in future models. This refinement would improve the conceptualization of ground‐water flow in the western portion of the San Antonio segment of the Edwards Aquifer and would thereby allow for more accurate assessment and management of the ground‐water resources provided by the Edwards Aquifer.     

Estimating Nitrogen Loading to Ground Water and Assessing Vulnerability to Nitrate Contamination in a Large Karstic Springs Basin,Florida1

Abstract: A nitrogen (N) mass‐balance budget was developed to assess the sources of N affecting increasing ground‐water nitrate concentrations in the 960‐km² karstic Ichetucknee Springs basin. This budget included direct measurements of N species in rainfall, ground water, and spring waters, along with estimates of N loading from fertilizers, septic tanks, animal wastes, and the land application of treated municipal wastewater and residual solids. Based on a range of N leaching estimates, N loads to ground water ranged from 262,000 to 1.3 million kg/year; and were similar to N export from the basin in spring waters (266,000 kg/year) when 80‐90% N losses were assumed. Fertilizers applied to cropland, lawns, and pine stands contributed about 51% of the estimated total annual N load to ground water in the basin. Other sources contributed the following percentages of total N load to ground water: animal wastes, 27%; septic tanks, 12%; atmospheric deposition, 8%; and the land application of treated wastewater and biosolids, 2%. Due to below normal rainfall (97.3 cm) during the 12‐month rainfall collection period, N inputs from rainfall likely were about 30% lower than estimates for normal annual rainfall (136 cm). Low N‐isotope values for six spring waters (δ¹⁵N‐NO₃ = 3.3 to 6.3‰) and elevated potassium concentrations in ground water and spring waters were consistent with the large N contribution from fertilizers. Given ground‐water residence times on the order of decades for spring waters, possible sinks for excess N inputs to the basin include N storage in the unsaturated zone and parts of the aquifer with relatively sluggish ground‐water movement and denitrification. A geographical‐based model of spatial loading from fertilizers indicated that areas most vulnerable to nitrate contamination were located in closed depressions containing sinkholes and other dissolution features in the southern half of the basin.     

HYDROLOGIC RESPONSE TO PUMPING AND CONTAMINANT ADVECTION IN A FRACTURED ROCK ENVIRONMENT1

ABSTRACT: Ground water flow and supply at the Whiteshell Research Area (WRA) in southeastern Manitoba and the advective movement of contaminants from a hypothetical nuclear fuel waste disposal vault to the adjacent biosphere and a nearby ground water supply well are simulated using finite-element modeling and numerical particle-tracking technique. The hypothetical vault is located at a depth of 500 m, below the water table, in low-permeability plutonic rock of the Canadian Shield. The rock mass is intersected by high-permeability fracture zones (aquifers), which also act as conduits for vault contaminants to migrate to the ground surface. The ground water resource is, therefore, limited in quantity and quality and should be explored with care. A 30 m deep well, which pumps water at a rate of 120 m³/yr from a low-dipping fracture zone, LD1, reduces natural discharge from the system to augment natural recharge. At this pumping rate, a 100 m or 200 m deep well neither reduces discharge nor induces recharge into the system. Thus, at the WRA, a 30 m deep domestic water supply well best meets the water requirements of a one-person household at the rate of 120 m³/yr. The 100 m and 200 m wells best meet the requirements of a family of six and a family of six with light irrigation, respectively, without capturing contaminants’pathways from the vault to the ground surface. By virtue of the proximity of the 200 m well intake to the hypothetical vault, this well performs best as a purge well at pumping rates of 0,000 m³/yr and greater. Finite-element modeling is useful in evaluating the water supply potential of a fractured rock environment in which a nuclear waste disposal vault is proposed to be sited.     

A REEVALUATION OF THE GROUND WATER BUDGET FOR LAS VEGAS VALLEY,NEVADA, WITH EMPHASIS ON GROUND WATER DISCHARGE1

ABSTRACT: An essential component to the ground water budget for the Las Vegas Valley (LVV) in southern Nevada is discharge from the ground water system. Discharge for the LW has been based on estimates made more than 50 years ago of 35,524,224 m3 per year as evapotranspiration (ET) and 0 m³ per year as subsurface outflow. Newly published values for recharge based on a more robust data set (70,308,360 m³) indicate a large imbalance associated with the earlier discharge estimates, providing the basis for the reevaluation conducted in this study. ET estimates in this study, as opposed to previous studies, were assigned a range in values that included an approach that assigned higher weight to the unique soil, plant, water, and climatic conditions that existed in predevelopment (1905) LW. The earlier discharge estimates also assumed that the basin was hydrologically closed; however, based on our evaluation, a range in yearly discharge by subsurface outflow from 1,480,176 m³ to 19,735,680 m³ could be assigned. Likewise, a range in yearly ET from 20,475,768 m³ to 78,819,372 m³ could be assigned. Based on newly published recharge values, closure can only occur if higher values are assigned to both the subsurface outflow and/or ET components of ground water discharge. We cannot provide a complete water balance closure with our ground water discharge estimate of 64,140,960 m³. However our reevaluation gives support to the higher recharge estimates and provides the rationale for future studies to be conducted based on a more rigorous scientific assessment.     

SIMULATION OF REGIONAL GROUND WATER FLOW IN BEDROCK,SOUTHWESTERN NEW YORK-NORTHWESTERN PENNSYLVANIA1

ABSTRACT: This paper presents the results of steady-state three-dimensional computer simulations to determine the hydrogeologic setting of formation water in the hydrocarbon producing formations of southwestern New York and northwestern Pennsylvania. Recharge areas for the regional ground water flow systems in the study area are the Valley Heads Moraine and Allegheny uplands; discharge areas are Lakes Erie and Ontario to the north and the northern margin of the Appalachian basin to the south. Simulated ground water flow in all model layers moves north from the ground water divide on the Valley Heads Moraine towards Lake Erie at a rate from 10^?-⁶ to 10^?-³ ft/day. South of the divide intermediate-scale and local-scale flow systems occur in the upper 4000 feet of the stratigraphic section and the directions of ground water flow diverge towards major rivers and other topographically low areas.     

Comparison of 85Kr and 3H Apparent Ground‐Water Ages for Source Water Vulnerability in the Collyer River Catchment,Maine1

Abstract: Apparent ground‐water ages as determined by the noble gas isotope ⁸⁵Kr and the water isotope ³H are compared. Refined gas extraction methodology at the wellhead permits efficient collection of Kr for ⁸⁵Kr isotope enrichment. ⁸⁵Kr isochrones elucidate areas of much younger ground‐water ages than ³H. Declining ³H activities in the catchment prevent its correlation with the youngest measured ⁸⁵Kr ages. Source water for most drinking water supplies in the Collyer River catchment is recharged within 40 years BP (2004). Mean‐age (τ) transport modeling suggests uncertainty of ground‐water ages is greatest in the central basin area.     

EDWARDS AQUIFER EVALUATION: KINNEY COUNTY,TEXAS1

ABSTRACT: The Edwards Aquifer is one of the most studied and most prolific aquifers in the United States. The aquifer is a heavily fractured and faulted carbonate aquifer with transmissivities in excess of 100 ft²/s. The City of San Antonio relies upon the Edwards Aquifer as its sole source for water. Much work has been done on quantifying recharge to the aquifer and discharge from wells and acquiring aquifer characteristics from pumping tests, specific capacity tests, and geophysical logs. Although the aquifer has been well studied in Bexar County, much less is known about the Edwards Aquifer in Kinney County. This is partly due to the lower population within the county (approximately 3,500 people) relative to the eastern counties (Uvalde, Medina, Bexar, Comal, and Hays) and the great distance of Kinney County from high profile discharge areas such as the City of San Antonio and Comal and San Marcos Springs. Three key products resulted from this study: (1) exploratory well drilling and the largest aquifer test in the county that were conducted to evaluate the well yields within a 10,000 acre study area in which a drawdown of 2.5 ft approximately 1.2 miles away was observed while pumping at approximately 4,600 gpm; (2) a recharge estimate for the Edwards Aquifer within Kinney County of approximately 71,382 ac‐ft/yr; and (3) locating the Brackettville Groundwater Divide from an evaluation of ground water flow direction and hydrograph analysis. These results help evaluate the complex hydraulics occurring within Kinney County and aid in development of ground water modeling that will be used in managing the Edwards Aquifer.     

Evaluation of Ground‐Water and Surface‐Water Exchanges Using Streamflow Difference Analyses1

Abstract: In the karstic lower Flint River Basin, limestone fracturing, jointing, and subsequent dissolution have resulted in the development of extensive secondary permeability and created a system of major conduits that facilitate the exchange of water between the Upper Floridan aquifer and Flint River. Historical streamflow data from U.S. Geological Survey gaging stations located in Albany and Newton, Georgia, were used to quantify ground‐water and surface‐water exchanges within a 55.3 km section of the Flint River. Using data from 2001, we compared estimates of ground‐water flux using a time adjustment method to a water balance equation and found that these independent approaches yielded similar results. The associated error was relatively large during high streamflow when unsteady conditions prevail, but much lower during droughts. Flow reversals were identified by negative streamflow differences and verified with in situ data from temperature sensors placed inside large spring conduits. Long‐term (13 years) analysis showed negative streamflow differentials (i.e., a losing stream condition) coincided with high river stages and indicated that streamflow intrusion into the aquifer could potentially exceed 150 m³/s. Although frequent negative flow differentials were evident, the Flint River was typically a gaining stream and showed a large net increase in flow between the two gages when examined over the period 1989‐2003. Ground‐water contributions to this stream section averaged 2‐42 m³/s with a mean of 13 m³/s. The highest rate of ground‐water discharge to the Flint River occurred during the spring when regional ground‐water levels peaked following heavy winter and spring rains and corresponding rates of evapotranspiration were low. During periods of extreme drought, ground‐water contributions to the Flint River declined.     

Relative Effects of Climate and Water Use on Base‐Flow Trends in the Lower Klamath Basin1

Abstract: Since the 1940s, snow water equivalent (SWE) has decreased throughout the Pacific Northwest, while water use has increased. Climate has been proposed as the primary cause of base‐flow decline in the Scott River, an important coho salmon rearing tributary in the Klamath Basin. We took a comparative‐basin approach to estimating the relative contributions of climatic and non‐climatic factors to this decline. We used permutation tests to compare discharge in 5 streams and 16 snow courses between “historic” (1942‐1976) and “modern” (1977‐2005) time periods, defined by cool and warm phases, respectively, of the Pacific Decadal Oscillation. April 1 SWE decreased significantly at most snow courses lower than 1,800 m in elevation and increased slightly at higher elevations. Correspondingly, base flow decreased significantly in the two streams with the lowest latitude‐adjusted elevation and increased slightly in two higher‐elevation streams. Base‐flow decline in the Scott River, the only study stream heavily utilized for irrigation, was larger than that in all other streams and larger than predicted by elevation. Based on comparison with a neighboring stream draining wilderness, we estimate that 39% of the observed 10 Mm³ decline in July 1‐October 22 discharge in the Scott River is explained by regional‐scale climatic factors. The remainder of the decline is attributable to local factors, which include an increase in irrigation withdrawal from 48 to 103 Mm³/year since the 1950s.     

Pesticide and Transformation Product Detections and Age‐Dating Relations from Till and Sand Deposits1

Abstract:  Pesticide and transformation product concentrations and frequencies in ground water from areas of similar crop and pesticide applications may vary substantially with differing lithologies. Pesticide analysis data for atrazine, metolachlor, alachlor, acetochlor, and cyanazine and their pesticide transformation products were collected at 69 monitoring wells in Illinois and northern Indiana to document occurrence of pesticides and their transformation products in two agricultural areas of differing lithologies, till, and sand. The till is primarily tile drained and has preferential fractured flow, whereas the sand primarily has surface water drainage and primary porosity flow. Transformation products represent most of the agricultural pesticides in ground water regardless of aquifer material – till or sand. Transformation products were detected more frequently than parent pesticides in both the till and sand, with metolachlor ethane sulfonic acid being most frequently detected. Estimated ground‐water recharge dates for the sand were based on chlorofluorocarbon analyses. These age‐dating data indicate that ground water recharged prior to 1990 is more likely to have a detection of a pesticide or pesticide transformation product. Detections were twice as frequent in ground water recharged prior to 1990 (82%) than in ground water recharged on or after 1990 (33%). The highest concentrations of atrazine, alachlor, metolachlor, and their transformation products, also were detected in samples from ground water recharged prior to 1990. These age/pesticide detection relations are opposite of what would normally be expected, and may be the result of preferential flow and/or ground‐water mixing between aquifers and aquitards as evident by the detection of acetochlor transformation products in samples with estimated ground‐water ages predating initial pesticide application.     

ISOTOPE HYDROLOGY DYNAMICS OF RIVERINE WETLANDS IN THE KANKAKEE WATERSHED,INDIANA1

ABSTRACT: Wetland restoration activities may disturb shallow ground‐water flow dynamics. There may be unintentional sources of water flowing into a constructed wetland that could compromise the long‐term viability of a wetland function. Measurement of naturally‐occurring isotopes in the hydrosphere can provide an indication of provenance, flow paths or components, and residence times or ages of wetland ground‐water flow systems. Hydraulic head measurements may not provide sufficient detail of shallow flow disturbances and can be complemented by analyzing isotopes in waters flowing through the wetland. Two north‐central Indiana wetlands in the Kankakee watershed are being studied to determine the adequacy of wetland restoration activities. The native LaSalle wetland and the restored Hog Marsh wetland have contrasting ground‐water flow regimes. The conservative water isotopes ¹⁸O, ²H, and ³H, and selected solute isotopes ¹³C, ¹⁴C, ¹⁵N, ³⁴S, ⁸⁷Sr, and 206–208Pb, demonstrate the complexity of ground‐water flow in Hog Marsh compared to the established flow regime at the LaSalle wetland.     

Sensitivity and Uncertainty of Ground‐Water Discharge Estimates for Semiarid Shrublands1

Abstract: We proposed a step‐by‐step approach to quantify the sensitivity of ground‐water discharge by evapotranspiration (ET) to three categories of independent input variables. To illustrate the approach, we adopt a basic ground‐water discharge estimation model, in which the volume of ground water lost to ET was computed as the product of the ground‐water discharge rate and the associated area. The ground‐water discharge rate was assumed to equal the ET rate minus local precipitation. The objective of this study is to outline a step‐by‐step procedure to quantify the contributions from individual independent variable uncertainties to the uncertainty of total ground‐water discharge estimates; the independent variables include ET rates of individual ET units, areas associated with the ET units, and precipitation in each subbasin. The specific goal is to guide future characterization efforts by better targeting data collection for those variables most responsible for uncertainty in ground‐water discharge estimates. The influential independent variables to be included in the sensitivity analysis are first selected based on the physical characteristics and model structure. Both regression coefficients and standardized regression coefficients for the selected independent variables are calculated using the results from sampling‐based Monte Carlo simulations. Results illustrate that, while as many as 630 independent variables potentially contribute to the calculation of the total annual ground‐water discharge for the case study area, a selection of seven independent variables could be used to develop an accurate regression model, accounting for more than 96% of the total variance in ground‐water discharge. Results indicate that the variability of ET rate for moderately dense desert shrubland contributes to about 75% of the variance in the total ground‐water discharge estimates. These results point to a need to better quantify ET rates for moderately dense shrubland to reduce overall uncertainty in estimates of ground‐water discharge. While the approach proposed here uses a basic ground‐water discharge model taken from an earlier study, the procedure of quantifying uncertainty and sensitivity can be generalized to handle other types of environmental models involving large numbers of independent variables.     

CHARACTERIZATION OF GROUND WATER FLOW FROM SPRING DISCHARGE IN A CRYSTALLINE ROCK ENVIRONMENT1

ABSTRACT: Recent investigations describing the hydrogeology of the Blue Ridge Province of Virginia suggest the occurrence of multiple aquifers and flow paths that may be responsible for the variable flow behavior of springs and seeps appearing throughout the region. Deep, confined aquifers associated with ubiquitous faults and shallow, variably confined saprolite aquifers may contribute water to spring outlets resulting in significantly different quantities of discharge and water quality. Multiple analyses are required to adequately identify the flow paths to springs. In this investigation, hydrograph analyses, surface electrical resistivity surveys, aquifer tests, and nitrate concentrations are used in conjunction with previously reported analyses from borehole logs and age dating of ground water to identify two distinct flow paths. Results indicate that base flow occurs from a deep fault zone aquifer and such discharge can be maintained even during prolonged periods of drought, while increased discharge identified on hydrograph peaks suggests the occurrence of rapid flow through the saprolite aquifer within a radius of about 25 meters of the spring orifice. Springflow hydrograph analysis is suitable for rapid characterization of flow paths leading to spring outlets. Rapid characterization is important for evaluation of potential water quality problems arising from contamination of shallow and deep aquifers and for evaluation of water resource susceptibility to drought. The techniques evaluated here are suitable for use in other locations in fractured crystalline rock environments.     

Urban Land Use,Channel Incision,and Water Table Decline Along Coastal Plain Streams,North Carolina1

Abstract: This study evaluates the effects of urban land use on stream channels and riparian ground‐water levels along low‐order Inner Coastal Plain streams in North Carolina. Six sites with stream catchments of similar size (1.19‐3.46 km²) within the Tar River Basin were selected across an urban land use gradient, as quantified by a range of catchment total impervious area (TIA; 3.8‐36.7%). Stream stage and ground‐water levels within three floodplain monitoring wells were measured manually and using pressure transducers from May 2006‐June 2007. Channel incision ratio (CIR), the ratio of bank height to bankfull height, was also measured at each monitoring site and along stream reaches within the study area (12 urban and 12 rural sites). Riparian ground‐water levels were inversely related to catchment TIA (%). As TIA (%) and stormwater runoff increased, the degree of stream channel incision increased and riparian ground‐water tables declined. In urban floodplains (>15% TIA), the median ground‐water level was 0.84 m deeper than for the rural settings (<15% TIA). This has resulted in a shift to drier conditions in the urban riparian zones, particularly during the summer months. CIR was found to be a reliable surface indicator of “riparian hydrologic drought” in these settings.     

EXAMPLES OF LANDFILL-GENERATED PLUMES IN LOW-RELIEF AREAS,SOUTHEAST FLORIDA1

ABSTRACT: Areas of low topographic relief have low water-table gradients and make the direction of movement of contaminants from land fills in the ground water difficult to predict from regional gradients alone. The landfill, nearby free-flowing ditches or canals, variations in hydraulic conductivity, and the influence of nearby pumping wells can all affect the direction of flow. In low-gradient areas the concepts of “upgradient” and “downgradient” are less useful in planning the location of monitoring wells than in areas of higher relief. Low-relief areas also may be affected by the discharge of mineralized water from deeper aquifers, naturally or through irrigation, which can mask geochemical surveys intended to detect landfill leachate. Examples of effects of low topographic relief are noted in southeast Florida where water-table gradients are 7×10^?-⁴ to 5×10^?-⁴ feet per foot. Water-table mounding beneath the landfill and the drainage effects of nearby ditches and well have created multiple leachate plumes in Stuart where one plume migrated in a direction opposite to the apparent regional gradient. In Coral Springs analysis suggests a bifurcating plume migrating along two narrow zones. In Fort Pierce it was difficult to detect leachate because of mineralized irrigation water and fertilizer runoff from an adjacent citrus grove.     

GROUND WATER/SURFACE WATER RESPONSES TO GLOBAL CLIMATE SIMULATIONS,SANTA CLARA‐CALLEGUAS BASIN,VENTURA, CALIFORNIA1

ABSTRACT: Climate variations can play an important, if not always crucial, role in successful conjunctive management of ground water and surface water resources. This will require accurate accounting of the links between variations in climate, recharge, and withdrawal from the resource systems, accurate projection or predictions of the climate variations, and accurate simulation of the responses of the resource systems. To assess linkages and predictability of climate influences on conjunctive management, global climate model (GCM) simulated precipitation rates were used to estimate inflows and outflows from a regional ground water model (RGWM) of the coastal aquifers of the Santa Clara‐Calleguas Basin at Ventura, California, for 1950 to 1993. Interannual to interdecadal time scales of the El Niño Southern Oscillation (ENSO) and Pacific Decadal Oscillation (PDO) climate variations are imparted to simulated precipitation variations in the Southern California area and are realistically imparted to the simulated ground water level variations through the climate‐driven recharge (and discharge) variations. For example, the simulated average ground water level response at a key observation well in the basin to ENSO variations of tropical Pacific sea surface temperatures is 1.2 m/°C, compared to 0.9 m/°C in observations. This close agreement shows that the GCM‐RGWM combination can translate global scale climate variations into realistic local ground water responses. Probability distributions of simulated ground water level excursions above a local water level threshold for potential seawater intrusion compare well to the corresponding distributions from observations and historical RGWM simulations, demonstrating the combination's potential usefulness for water management and planning. Thus the GCM‐RGWM combination could be used for planning purposes and — when the GCM forecast skills are adequate — for near term predictions.     

Variations in Base‐Flow Nitrate Flux in a First‐Order Stream and Riparian Zone1

Abstract: Nonpoint source pollution, which contributes to contamination of surface waters, is difficult to control. Some pollutants, particularly nitrate (), are predominantly transmitted through ground water. Riparian buffer zones have the potential to remove contaminants from ground water and reduce the amount of that enters surface water. This is a justification for setting aside vegetated buffer strips along waterways. Many riparian zone hydrologic models assume uniform ground‐water flow through organic‐rich soil under reducing conditions, leading to effective removal of ground‐water prior to discharge into a stream. However, in a small first‐order stream in the mid‐Atlantic coastal plain, base‐flow generation was highly variable (spatially and temporally). Average base‐flow loads were greater in winter than summer, and higher during a wetter year than in dryer years. Specific sections of the stream consistently received greater amounts of high ground water than others. Areas within the riparian zone responsible for most of the exported from the watershed are termed “critical areas.” Over this 5‐year study, most of the exported during base flow originated from a critical area comprising less than 10% of the total riparian zone land area. Allocation of resources to address and improve mitigation function in critical areas should be a priority for continued riparian zone research.     

STABLE HYDROGEN AND OXYGEN ISOTOPE COMPOSITION OF PRECIPITATION IN NORTHEASTERN COLORADO1

ABSTRACT: Where data are available, hydrologic studies may use precipitation's stable oxygen and hydrogen isotope composition to investigate streamflow, ground water/surface water interaction, and ground water recharge. Paleoclimate studies utilize the δ¹⁸O_{precipitation}‐T_air relationship, in conjunction with lake sediments, fossils, or old ground waters, for example, to estimate pale‐otemperatures. Ecological studies utilize precipitation and soil water isotope composition to track moisture uptake in plants, and to trace species migration patterns. Such studies require that the isotopic composition of precipitation be known. Oxygen‐18 (δ¹⁸O) and deuterium (δ²H) data for precipitation are lacking in the semi‐arid portion of the north‐central U.S. Great Plains, and thus there is a need to establish additional meteoric water lines as isotope input functions across the region, as well as to develop better understanding of the isotopic climate linkages that control oxygen and hydrogen isotope ratios in precipitation. This study determined the δ¹⁸O and δ²H composition of precipitation in the Pawnee Grasslands of northeastern Colorado from 1994 through 1998 using archived National Atmospheric Deposition Program samples. The resulting local water line follows the relationship δ²H = 7.86 δ¹⁸O‐7.66, and the data show a δ¹⁸O_weekly ‐ T_weekly relationship of δ¹⁸O = 0.560‐T (°C)‐18.8.