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气相色谱法测定水中有机磷农药 总被引:3,自引:0,他引:3
本方法研究了水样中DDVP、地亚农、乐果、甲基对硫磷、内吸磷、马拉硫磷、水胺硫磷、乙硫磷和乙基谷硫磷等九种有机磷农药的气相色谱分析方法。该方法用三氯甲烷提取水中的有机磷农药,毛细管柱分离,程序升温,FPD测定。方法操作简单,测定水中有机磷农药的最低检出浓度在2.8ng/L至0.029mg/L之间,加标回收率在70.0%~120%。方法适用于地表水、地下水和废水中痕量有机磷农药的测定。 相似文献
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采用吹扫捕集与快速气相色谱-飞行时间质谱联用,建立测定水中10种石化行业常见挥发性有机物(VOCs)的吹扫捕集-快速气相色谱-飞行时间质谱的分析方法。通过质谱定性,选定目标物的特征离子,运用内标法定量,采用DN-624(20m×0.18mm×1μm)快速毛细管色谱柱,在10min内完成对水中10种VOCs的分析,在保证各目标物灵敏度和分辨率不受影响的同时,分析时间从标准方法的17min降至10min。该方法的线性、精密度与检出限满足标准方法 HJ 639—2012《水质挥发性有机物的测定吹扫捕集/气相色谱-质谱法》要求,通过实验验证,能够广泛应用于石化行业环境监测与应急监测。 相似文献
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巯基棉富集气相色谱法测定水中微量甲基汞 总被引:12,自引:0,他引:12
根据在一定的酸度条件下,巯基棉能定量吸附甲基汞的原理,采用多只巯基棉吸附串接富集,并两次浓缩的方法,用气相色谱法测定水中微量甲基汞。 相似文献
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测定水中阴离子表面活性剂(简称AS)最常用的方法是以Longwell-Maniece为代表的亚甲基兰(methvlene blue)法(MB法),而MB法却是一个繁琐和灵敏度低的方法,不适于饮用水、自来水和天然水中微量AS测定。该法选择性差,所测结果通常称为MB活性物浓度。尚有一些其它的方法,如原子吸收间接测定法、气相色谱法、红外光谱法、高速液相色谱法、火焰分光光度间接测量法等。本文采用一种新的AS分光光度测定法:以乙基紫作阳离子染料,使痕迹量的阴离子表面恬性剂被选 相似文献
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气相色谱法测定蔬菜中菊酯类农药残留 总被引:3,自引:0,他引:3
用等量体积混合的丙酮和石油醚作提出剂,弹性石英毛细管柱分离,电子捕获检测器,气相色谱法测定蔬菜中3种菊酯类农药残留。方法检出限(3S/N)为0.010mg/L~0.023 mg/L,相对标准偏差均〈7%,样品加标回收率在78%~91%范围内。方法简便快速,可满足蔬菜安全卫生的监督检测。 相似文献
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Gabriele Villarini Enrico Scoccimarro Kathleen D. White Jeffrey R. Arnold Keith E. Schilling Joyee Ghosh 《Journal of the American Water Resources Association》2015,51(5):1361-1371
Our improved capability to adapt to the future changes in discharge is linked to our capability to predict the magnitude or at least the direction of these changes. For the agricultural United States Midwest, too much or too little water has severe socioeconomic impacts. Here, we focus on the Raccoon River at Van Meter, Iowa, and use a statistical approach to examine projected changes in discharge. We build on statistical models using rainfall and harvested corn and soybean acreage to explain the observed discharge variability. We then use projections of these two predictors to examine the projected discharge response. Results are based on seven global climate models part of the Coupled Model Intercomparison Project Phase 5 and two representative concentration pathways (RCPs 4.5 and 8.5). There is not a strong signal of change in the discharge projections under the RCP 4.5. However, the results for the RCP 8.5 point to a stronger changing signal related to larger projected increases in rainfall, resulting in increased trends, in particular, in the upper part of the discharge distribution (i.e., 60th percentile and above). Examination of two hypothetical agricultural scenarios indicates that these increasing trends could be alleviated by decreasing the extent of the agricultural production. We also discuss how the methodology presented in this study represents a viable approach to move forward with the concept of return period for engineering design and management in a nonstationary world. 相似文献
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Rainfall samples were collected during the 2003 and 2004 growing seasons at four agricultural locales across the USA in Maryland, Indiana, Nebraska, and California. The samples were analyzed for 21 insecticides, 18 herbicides, three fungicides, and 40 pesticide degradates. Data from all sites combined show that 7 of the 10 most frequently detected pesticides were herbicides, with atrazine (70%) and metolachlor (83%) detected at every site. Dacthal, acetochlor, simazine, alachlor, and pendimethalin were detected in more than 50% of the samples. Chlorpyrifos, carbaryl, and diazinon were the only insecticides among the 10 most frequently detected compounds. Of the remaining pesticide parent compounds, 18 were detected in fewer than 30% of the samples, and 13 were not detected. The most frequently detected degradates were deethylatrazine; the oxygen analogs (OAs) of the organophosphorus insecticides chlorpyrifos, diazinon, and malathion; and 1-napthol (degradate of carbaryl). Deethylatrazine was detected in nearly 70% of the samples collected in Maryland, Indiana, and Nebraska but was detected only once in California. The OAs of chlorpyrifos and diazinon were detected primarily in California. Degradates of the acetanilide herbicides were rarely detected in rain, indicating that they are not formed in the atmosphere or readily volatilized from soils. Herbicides accounted for 91 to 98% of the total pesticide mass deposited by rain except in California, where insecticides accounted for 61% in 2004. The mass of pesticides deposited by rainfall was estimated to be less than 2% of the total applied in these agricultural areas. 相似文献
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Brian W. Walker 《The Environmentalist》1986,6(1):9-13
Summary The author analyses the problems currently faced by the African continent, recognises six factors which he believes are important in influencing the analysis, and argues that the only secure, renewable asset any country or continent has, is its people. He maintains that people development, rather than the classical economic forms of encouraging development, offers Africa a viable way forward. He then identifies a number of specific issues within such a strategy of investment in human capital.Brian Walker is the President of the International Institute for Environment and Development (IIED), and this address was given at the inaugural meeting of the International Year of Shelter for the Homeless, in London, on 18th April, 1985. A second, earlier, associated address was published inThe Environmentalist 5(3) 167–170. 相似文献
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Environmental assessment in countries in transition: evolution in a changing context 总被引:1,自引:0,他引:1
Cherp A 《Journal of environmental management》2001,62(4):357-374
Over the last fifteen years, Environmental Assessment systems of transitional societies of Central and Eastern Europe and Central Asia have undergone dramatic change from appraisals integrated into centrally planned economies to formal procedures aimed to ensure interdisciplinary analysis of environmental impacts and linked to publicly accountable decision-making. In most Central European nations, EA systems have been radically reformed to approximate the procedures used in developed countries, particularly in the European Union. In contrast, EA in most of the former Soviet republics has been reformed more gradually and is still based on the so-called State Environmental Review procedure inherited from the USSR and substantially different from 'Western' EA. About one-third of the transitional countries (in the Balkans, the Caucasus and Central Asia) have, so far, failed to establish functioning EA systems. Throughout the region, there has been a gap between EA legislation and practice, especially concerning interdisciplinary analysis of environmental impacts, public participation, and utilisation of EA findings in decision-making. A key driving force in the reform of EA systems has been the change in their societal context, the so-called 'process of transition'. Three main policy agendas--environmental protection, reforms of decision-making, and conforming to international requirements--along with the institutional context of EA regulations and practice have influenced both the change of EA systems over time and the regional variations in the patterns of their evolution. This study suggests that an effective reform of an EA system should be context-sensitive, or be 'in gear' with the political and economic transition. Future EA research should consider their changing societal contexts and focused on practical effects of applying EA procedures. 相似文献
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As a result of Structural Adjustment Programme from the 1980s, many developing countries have experienced an increase in resource extraction activities by international and transnational corporations. The work reported here examines the perceived impacts of gold mining at the community level in the Wassa West District of Ghana, Africa and discusses those perceived impacts in the context of globalization processes and growing multinational corporate interest in Corporate Social Responsibility (CSR). Interview data compared community members' perceptions with those of company representatives in three communities. The results indicate that communities held companies responsible for a series of economic, social, and environmental changes. While recognizing some of the benefits brought by the mines, communities felt that the companies did not live up to their responsibility to support local development. Companies responded by denying, dismissing concerns, or shifting blame. Findings from this work show that lack of engagement and action by government agencies at all levels resulted in companies acting in a surrogate governmental capacity. In such situations, managing expectations is key to community-company relations. 相似文献
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Zbigniew Bochniarz 《Natural resources forum》1992,16(1):55-63
Ambitious programmes of reform in Central and Eastern Europe (CEE) are threatened by a serious deterioration of the environment. Large-scale damage of the natural environment in many forms, including water pollution has created development barriers which adversely affect the living conditions of current and future generations. Despite similar patterns of environmental policy in the CEE countries compared with their Western counterparts, neither environmental legislation nor economic incentives have produced any significant improvement in water quality over the last 10–20 years. For that very reason in the transition period, it is necessary to identify existing deficiencies in the system and to build up a mixed system of new institutions of water management, more realistic legislation with a strong enforcement system, and market based incentives for water conservation and protection against pollution. 相似文献
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Xinzhi Yu 《Journal of Environmental Planning and Management》2019,62(6):939-959
The preparation of strategic environmental assessment (SEA) inclusive sustainability appraisals (SAs) for neighbourhood plans (NPs) in England may be required when significant environmental effects are expected to arise from an NP. In this paper, we report on the result of a Ph.D. project, conducted between 2012 and 2015, in which all 15 NP SEA inclusive SAs that had been completed at the time were evaluated. In this context, the quality of SA practice was found to differ substantially. SAs were prepared either ‘in-house’ (i.e. by neighbourhood planning steering groups) or by consultants. The quality of SAs was found to be associated with their overall perceived degree of influence on the underlying NPs. Whilst the focus of this paper is on practice in England, findings are expected to be of interest to a wider international audience, in particular to those experimenting with voluntary neighbourhood/local level plan SA/SEA. 相似文献
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Yuriko Sakairi 《Natural resources forum》2000,24(4):313-323
This article presents a case study from Mozambique of the electrification of two selected towns under a World Bank financed project. Low-cost electricity services were extended to the two isolated areas after an enabling framework had been created for private sector participation. The World Bank project also demonstrates that the private sector can be attracted to participate in rural electrification schemes even in a poor country. The example shown in this article is one of the few of its kind in SubSaharan Africa. 相似文献