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1.
Jordan has witnessed a rapid increase in healthcare facilities during the last two decades. As a consequence, the amount of generated medical waste have been increased rapidly and a proper management system is indeed needed to eliminate the environmental and health hazards resulted from such waste. An approved medical waste treatment facility is the incinerator located at the northern region of Jordan which serves the four northern governorates. Two trucks are used to pickup waste from the hospitals in these governorates to be treated at the incinerator. In this paper, a route scheduling model is proposed to minimize the total travel distance which in turn minimizes transportation cost and reduces emissions. The proposed model takes into account the capacity of trucks, number of visits per week, timing between visits along with the service level required by the hospitals. An optimal routing schedule was found and verified. Compared to current routing schedule, a saving of 102 km per week was achieved.  相似文献   

2.
During recent decades heathlands havechanged into grasslands in regions with high atmosphericnitrogen deposition. In regions with intermediatedeposition level (e.g., Denmark) changes have been lesspronounced which may be due to delay or decrease inresponse of the ecosystem. The mor layer (O horizon) mayplay an important role for this delay due to high sinkstrength for N. In this study, the capacity for netNH4 + immobilization and mineralization wasstudied during short- and long-term incubations (2–36 days)of mor samples from Danish dry inland heaths. High short-term capacity for net NH4 + immobilization wasfound to be a general characteristic of Danish heath morlayers both under heather (Calluna vulgaris) andcrowberry (Empetrum nigrum ssp nigrum), the latterdominating late stages in heathland succession. The netNH4 + immobilization was higher under youngcompared to old or dead vegetation, and higher on lessnutrient poor soils than on extremely nutrient poor soils.The addition of N, P and C stimulated CO2 productionand net NH4 + immobilization, but not net Nmineralization. The immobilization of 15NH4 +caused release of dissolved organic N, increased N anddecreased C/N ratio in the microbial biomass, and indicatedgrowth of microorganisms with other metabolic abilitiesthan the indigenous population. No evidence was obtained ofstabilization of immobilized 15NH4 + intosoil organic matter during the experiment. On background ofthe results and current knowledge it was concluded that therecognition of the high capacity for net NH4 +immobilization in mor layers does not allow for a raiseof critical loads for N for northern dry inland heaths.  相似文献   

3.
The rising popularity of incineration of municipal solid waste (MSW) calls for detailed mathematical modeling and accurate prediction of pollutant emissions. In this paper, mathematical modeling methods for both solid and gaseous phases were employed to simulate the operation of a 450 t/d MSW-burning incinerator to obtain detailed information on the flow and combustion characteristics in the furnace and to predict the amount of pollutant emissions. The predicted data were compared to on-site measurements of gas temperature, gas composition and SNCR de-NOX system. The major operating conditions considered in this paper were grate speed and oxygen concentration. A suitable grate speed ensures complete waste combustion. The predictions are as follows: volatile release increases with increasing grate speed, and the maximal value is within the range of 700–800 kg/m2 h; slow grate speeds result in incomplete combustion of fixed carbon; the gas temperature at slow grate speeds is higher due to adequate oxygenation for fixed carbon combustion, and the deviation reaches 200 K; NOX emission decreases, but CO emission and O2 concentrations increase, and the deviation is 63%, 34% and 35%, respectively. Oxygen-enriched atmospheres promote the destruction of most pollutants due to the high oxygen partial pressure and temperature. The furnace temperature, NO production and CO emission increase as the oxygen concentration increases, and the deviation of furnace exit temperature, NO and CO concentration is 38.26%, 58.43% and 86.67%, respectively. Finally, oxygen concentration is limited to below 35% to prevent excessive CO and NOX emission without compromising plant performance. The current work greatly helps to understand the operating characteristics of large-scale MSW-burning plants.  相似文献   

4.
The remediation of per‐ and polyfluoroalkyl substances by injection of colloidal activated carbon (CAC) at a contaminated site in Central Canada was evaluated using various visualization and modeling methods. Radial diagrams were used to illustrate spatial and temporal trends in perfluoroalkyl acid (PFAA) concentrations, as well as various redox indicators. To assess the CAC adsorption capacity for perfluorooctane sulfonate (PFOS), laboratory Freundlich isotherms were derived for PFOS mixed with CAC in two solutions: (1) PFOS in a pH 7.5 synthetic water that was buffered by 1 millimolar NaHCO3 (Kf = 142,800 mg1‐a La/kg and = 0.59); and (2) a groundwater sample (pH = 7.4) containing PFOS among other PFAS from a former fire‐training area in the United States (Kf = 4,900 mg1‐a La/kg and a = 0.24). A mass balance approach was derived to facilitate the numerical modeling of mass redistribution after CAC injection, when mass transitions from a two‐phase system (aqueous and sorbed to organic matter) to a three‐phase system that also includes mass sorbed to CAC. An equilibrium mixing model of mass accumulation over time was developed using a finite‐difference solution and was verified by intermodel comparison for prediction of CAC longevity in the center of a source area. A three‐dimensional reactive transport model (ISR‐MT3DMS) was used to indicate that the CAC remedy implemented at the site is likely to be effective for PFOS remediation for decades. Model results are used to recommend remedial design and monitoring alternatives that account for the uncertainty in long‐term performance predictions.  相似文献   

5.
We used the Québec forest monitoring network (`Réseaud'Étude et de Surveillance des Écosystèmes Forestiers' or RESEF)along with its atmospheric monitoring stations to assess criticalS and N loads and their combined soil acidification exceedancesfor natural ecosystems of the northern hardwood and borealconiferous forests in Québec, Canada. Critical loads (CL) forforest soil acidification were calculated using the simple mass-balance (SMB) approach and with the steady-state PROFILE model.Atmospheric deposition rates for water, S, N, Ca, Mg, Na, and K,for the years 1989–1993, and detailed, plot-specific forest andsoil characteristics were used as input. The SMB model alsorequired information regarding nutrient uptake and storage in theaboveground woody biomass. The CL calculations indicated that,from the 31 RESEF plots, 18 received atmospheric acidic inputs inexcess of their CL (55 and 61% of the hardwood and coniferousplots, respectively). The range of CL exceedance varied from 60to 470 eq ha-1 yr-1 for the hardwood stands, and from 10to 590 eq ha-1 yr-1 for the coniferous stands. The standswith CL exceedance were mainly located in the western and centralpart of the province. Stand growth associated with exceedanceclass of acidity was determined using the RESEF plots along withselected permanent forest survey plots having similar sitecharacteristics, but for which longer growth records wereavailable. We found a significant negative correlation betweenforest growth rates and critical soil acidification exceedancefor both the northern hardwood and the boreal conifer sites.Specifically, plots with critical load exceedances were found tohave a growth reduction of about 30% during the 1974–1982 andthe 1972–1990 measurement (plots with no soil acidificationexceedance served as a control). While this correlation is notnecessarily causal, it is nevertheless consistent with theexpectation that increased losses of soil base cations on accountof increased soil acidification should and could lead todeteriorating forest health conditions.  相似文献   

6.
In this study we describe the development of an alternative methodology for hazard characterization of waste materials. Such an alternative methodology for hazard assessment of complex waste materials is urgently needed, because the lack of a validated instrument leads to arbitrary hazard classification of such complex waste materials. False classification can lead to human and environmental health risks and also has important financial consequences for the waste owner. The Hazardous Waste Directive (HWD) describes the methodology for hazard classification of waste materials. For mirror entries the HWD classification is based upon the hazardous properties (H1–15) of the waste which can be assessed from the hazardous properties of individual identified waste compounds or – if not all compounds are identified – from test results of hazard assessment tests performed on the waste material itself. For the latter the HWD recommends toxicity tests that were initially designed for risk assessment of chemicals in consumer products (pharmaceuticals, cosmetics, biocides, food, etc.). These tests (often using mammals) are not designed nor suitable for the hazard characterization of waste materials. With the present study we want to contribute to the development of an alternative and transparent test strategy for hazard assessment of complex wastes that is in line with the HWD principles for waste classification. It is necessary to cope with this important shortcoming in hazardous waste classification and to demonstrate that alternative methods are available that can be used for hazard assessment of waste materials. Next, by describing the pros and cons of the available methods, and by identifying the needs for additional or further development of test methods, we hope to stimulate research efforts and development in this direction. In this paper we describe promising techniques and argument on the test selection for the pilot study that we have performed on different types of waste materials. Test results are presented in a second paper.As the application of many of the proposed test methods is new in the field of waste management, the principles of the tests are described. The selected tests tackle important hazardous properties but refinement of the test battery is needed to fulfil the a priori conditions.  相似文献   

7.
This paper discusses actions aimed at sustainable management of healthcare wastes (HCW) in China, taking into account the current national situation in this field, as well as the requirements deriving from the Stockholm Convention on Persistent Organic Pollutants and the WHO recommendations. By the end of 2005, there were 149 low-standard HCW disposal facilities in operation in China, distributed throughout different areas. According to the National Hazardous Waste and Healthcare Waste Disposal Facility Construction Plan, 331 modern, high-standard, centralized facilities will be built up in China in municipal level cities. Although incineration is still the main technical option for HCW disposal in China, it is expected that, especially for medium and small size facilities, non-incineration technologies will develop quickly and will soon become the main technical option. The basic management needs – both from the point of view of pollution control and final disposal – have been defined, and a system of technical and environmental standards has been formulated and implemented; however, there are still some shortages. This is particularly true when considering the best available techniques and best environmental practices developed under the Stockholm Convention, with which the present technological and managing situations are not completely compliant. In this framework, the lifecycle (from generation to final disposal of wastes) of HCW and holistic approaches (technology verification, facilities operation, environmental supervision, environmental monitoring, training system, financial mechanism, etc.) towards HCW management are the most important criteria for the sustainable and reliable management of HCW in China.  相似文献   

8.
In order to understand the fate of anthropogenic lead (Pb)pollution in boreal forest soils, and to predict future trends, it is important to know where in the soil the pollution Pb is accumulated and how large the pollution and natural Pb inventories are in different soil horizons. We combined stable Pb isotope (206Pb/207Pb ratios) and concentration analyses to study Pb in podzol profiles and mor samples from old-growth forest stands at seven sites distributed from southern to northern Sweden. Additional samples were taken from managed forests, and from an agricultural field, to give some idea of the effects of land-use. Pb concentrations are typically 60–100 g g-1 dry mass in the mor layer in southern Sweden and about 30 g g-1 in northern Sweden. Pb isotope analyses show that virtually all of this Pb is pollution Pb. The isotope composition also shows that pollution Pb has penetrated downwards between 20–60 cm in the forest soils. The total pollution Pb inventories vary between 0.7–3.0 g m-2 ground surface, with larger inventories in southern compared to northern Sweden. Although the highest Pb concentrations occur in the mor layer, the largest inventories of pollution Pb are found in the Bs-horizon. The limited investigation of Pb distribution and inventories in soils from managed forests did not point to any major difference compared to the old-growth forests. The agricultural field revealed, however, a completely deviating Pb profile with all pollution Pb evenly distributed in the 20 cm thick top-soil.  相似文献   

9.
Although intra-European trade of combustible waste has grown strongly in the last decade, incineration and landfill taxes remain disparate within Europe. The paper proposes a more coherent taxation approach for Europe that is based on the principle of Pigovian taxation, i.e. the internalization of environmental damage costs. The approach aims to create a level playing field between European regions while reinforcing incentives for sustainable management of combustible waste. Three important policy recommendations emerge. First, integrating waste incineration into the European Emissions Trading System for greenhouse gases (EU ETS) reduces the risk of tax competition between regions. Second, because taxation of every single air pollutant from waste incineration is cumbersome, a differentiated waste incineration tax based on NOx emissions can serve as a second-best instrument. Finally, in order to strengthen incentives for ash treatment, a landfill tax should apply for landfilled incineration residues. An example illustrates the coherence of the policy recommendations for incineration technologies with diverse environmental effects.  相似文献   

10.
The production of hydrogen through Anaerobic Digestion (AD) has been investigated to verify the efficacy of several pretreatment processes. Three types of waste with different carbon structures have been tested to obtain an extensive representation of the behavior of the materials present in Organic Waste (OW). The following types of waste were selected: Sweet Product Residue (SPR), i.e., confectionary residue removed from the market after the expiration date, Organic Waste Market (OWM) refuse from a local fruit and vegetable market, and Coffee Seed Skin (CSS) waste from a coffee production plant. Several pretreatment processes have been applied, including physical, chemical, thermal, and ultrasonic processes and a combination of these processes. Two methods have been used for the SPR to remove the packaging, manual (SPR) and mechanical (SPRex). A pilot plant that is able to extrude the refuse to 200 atm was utilized. Two parameters have been used to score the different pretreatment processes: efficiency (ξ), which takes into account the amount of energy produced in the form of hydrogen compared with the available energy embedded in the refuse, and efficacy (η), which compares the efficiency obtained using the pretreated refuse with that obtained using the untreated refuse. The best result obtained for the SPR was the basic pretreatment, with η = 6.4, whereas the thermal basic pretreatment gave the highest value, η = 17.0 for SPRex. The best result for the OWM was obtained through a combination of basic/thermal pretreatments with η = 9.9; lastly, the CSS residue with ultrasonic pretreatment produced the highest quantity of hydrogen, η = 5.2.  相似文献   

11.
Providing an accurate estimate of the dry component of N deposition to low N background, semi-natural habitats, such as bogs and upland moors dominated by Calluna vulgaris is difficult, but essential to relate nitrogen deposition to effects in these communities. To quantify the effects of NH3 inputs to moorland vegetation growing on a bog at a field scale, a field release NH3 fumigation system was established at Whim Moss (Scottish Borders) in 2002. Gaseous NH3 from a line source was released along of a 60 m transect, when meteorological conditions (wind speed >2.5 m s?1 and wind direction in the sector 180–215°) were met, thereby providing a profile of decreasing NH3 concentration with distance from the source. In a complementary study, using a NH3 flux chamber system, the relationships between NH3 concentrations and cuticular resistances were quantified for a range of NH3 concentrations and micrometeorological conditions for moorland vegetation. Cuticular resistances increased with NH3 concentration from 11 s m?1 at 3.0 μg m?3 to 30 s m?1 at 30 μg m?3. The NH3 concentration data and the concentration-dependent canopy resistance are used to calculate NH3 deposition taking into account leaf surface wetness. The implications of using an NH3 concentration-dependent cuticular resistance and the importance for refining critical loads are discussed.  相似文献   

12.
To establish an empirical model for predicting a lower heating value (LHV) easily and economically by multiple regression analysis. A wet-based physical components model (WBPCM) was developed and based on physical component analysis without dewatering. Based on 497 samples of municipal solid waste (MSW) gathered from 14 incinerators in western parts of Taiwan from 2002 to 2009. The proposed model was verified by independent samples from other incinerators through parameters multiple correlation coefficients (R), relative percentage deviation (RPD) and mean absolute percentage error (MAPE). Experimental results indicated that R, RPD and MAPE were 0.976, 17.1 and 17.7, respectively. This finding implies that LHV predicted by the WBPCM could well explain the LHV characteristics of MSW. The WBPCM was also compared with existing prediction models of LHV on a dry basis. While more accurately predicting LHV predicting than those models based on proximate analysis, the WBPCM was comparable with models based on physical component analysis in term of RPD and MAPE. Experimental results further indicated that the prediction accuracy of the WBPCM varied with MSW moisture parabolically. No specific relation was observed in the results of the previous prediction model. The accuracy of the WBPCM was almost approached to that of ultimate analysis in moisture ranging from 40% to 55%. The model was applicable within this moisture range. We conclude that the WBPCM is a faster and more economical model for LHV predictions with comparable accuracy than those models based on physical component analysis. The proposed WBPCM is highly promising for use in designing and operating incinerators.  相似文献   

13.
The carbon emissions trading market has created a need for standard methods for the determination of biogenic content (χB) in solid recovered fuels (SRF). We compare the manual sorting (MSM) and selective dissolution methods (SDM), as amended by recent research, for a range of process streams from a mechanical–biological treatment (MBT) plant. The two methods provide statistically different biogenic content values, as expressed on a dry mass basis, uncorrected for ash content. However, they correlate well (r2 > 0.9) and the relative difference between them was <5% for χB between 21% w/wd and 72% w/wd (uncorrected for ash content). This range includes the average SRF biogenic content of ca. 68% w/wd. Methodological improvements are discussed in light of recent studies. The repeatability of the SDM is characterised by relative standard deviations on triplicates of <2.5% for the studied population.  相似文献   

14.
Used batteries contain numerous metals in high concentrations and if not disposed of with proper care, they can negatively affect our environment. These metals represent 83% of all spent batteries and therefore it is important to recover metals such as Zn and Mn, and reuse them for the production of new batteries. The recovery of Zn and Mn from used batteries, in particular from Zn–C and alkaline ones has been researched using hydrometallurgical methods. After comminution and classification of elemental components, the electrode paste resulting from these processes was treated by chemical leaching. Prior to the leaching process the electrode paste has been subjected to two washing steps, in order to remove the potassium, which is an inconvenient element in this type of processes. To simultaneously extract Zn and Mn from this paste, the leaching method in alkaline medium (NaOH solution) and acid medium (sulphuric acid solution) was used. Also, to determine the efficiency of extraction of Zn and Mn from used batteries, the following variables were studied: reagents concentration, S/L ratio, temperature, time. The best results for extraction yield of Zn and Mn were obtained under acid leaching conditions (2 M H2SO4, 1 h, 80 °C).  相似文献   

15.
The paper is concerned with biohydrometallurgical methods of cadmium recovery from spent Ni–Cd batteries. Cd leaching efficiency from electrode material in different media (H2SO4 and Fe2(SO4)3 solutions), at different Fe(III) concentrations and using the bacteria Acidithiobacillus ferrooxidans were investigated. The main aim of this study was to understand which from the bioleaching products (sulphuric acid or ferric sulphate) play a main role in the bioleaching process of Cd recovery. The influence of Fe ions on Cd leachability was confirmed. The best leaching efficiency of Cd (100%) was reached by bioleaching and also by leaching in Fe2(SO4)3 solution. The results of X-ray diffraction confirmed that no cadmium was present in solid residuum obtained after the Cd bioleaching as well as Cd leaching using solely ferric iron. The use of H2SO4 solution resulted in the lowest efficiency of Cd leachability, the presence of hydroxides in electrode materials caused neutralization of the leaching solution and inhibition of Cd leaching.  相似文献   

16.
On-site sanitation solutions have gained much interest in recent years. One such solution is the urine diverting vermicomposting toilet (UDVT). This study evaluated the hygienic quality of the composted material in six UDVTs in operation in France. Samples were taken from three sampling positions in each toilet, with increasing distance from the fresh material. The concentration of Salmonella spp., Enterococcus spp., thermotolarent coliforms and coliphages were analysed and plotted against a number of variables. The variables found to have the greatest impact was the pH (for Enterococcus spp. and thermotolarent coliforms (TTC)) and time since last maintenance (coliphages). The pH was found to correlate with the material maturity. The current practise of maintenance can cause recontamination of the stabilised material and increase the risk of regrowth of pathogenic microorganisms. A modification in the maintenance procedure, in which a fourth maturation point is introduced, would eliminate this risk. UDVTs were found to be a good on-site sanitation option as the maintenance requirement is small and the system effectively reduced odour and concentration of pathogen and indicator organisms in human waste while keeping the accumulation of material down to a minimum. If the vermicompost is to be used for crops consumed raw, an additional sanitisation step is recommended.  相似文献   

17.
Emissions from open burning of military food waste and ration packaging compositions were characterized in response to health concerns from open burning disposal of waste, such as at military forward operating bases. Emissions from current and prototype Meals, Ready-to-Eat (MREs), and material options for their associated fiberboard packaging were quantified to assess contributions of the individual components. MREs account for 67–100% of the particulate matter (PM), volatile organic compounds (VOCs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated dibenzo-p-dioxins and -furans (PCDDs/PCDFs) emissions when burned in unison with the current fiberboard container and liner. The majority of the particles emitted from these burns are of median diameter 2.5 µm (PM2.5). Metal emission factors were similar regardless of waste composition. Measurements of VOCs and PAHs indicate that targeted replacement of MRE components may be more effective in reducing emissions than variation of fiberboard-packaging types. Despite MRE composition variation, equivalent emission factors for PM, PAH, VOC, and PCDD/PCDF were seen. Similarly, for fiberboard packaging, composition variations exhibited essentially equivalent PM, PAH, VOC, and PCDD/PCDF emission factors amongst themselves. This study demonstrated a composition-specific analysis of waste burn emissions, assessing the impact of waste component substitution using military rations.  相似文献   

18.
This research assesses the feasibility of degrading used disposable diapers, an important component (5-15% in weight) of urban solid waste in Mexico, by the activity of the fungus Pleurotus ostreatus, also known as oyster mushroom. Disposable diapers contain polyethylene, polypropylene and a super absorbent polymer. Nevertheless, its main component is cellulose, which degrades slowly. P. ostreatus has been utilized extensively to degrade cellulosic materials of agroindustrial sources, using in situ techniques. The practice has been extended to the commercial farming of the mushroom. This degradation capacity was assayed to reduce mass and volume of used disposable diapers. Pilot laboratory assays were performed to estimate the usefulness of the following variables on conditioning of used diapers before they act as substrate for P. ostreatus: (1) permanence vs removal of plastic cover; (2) shredding vs grinding; (3) addition of grape wastes to improve structure, nitrogen and trace elements content. Wheat straw was used as a positive control. After 68 days, decrease of the mass of diapers and productivity of fungus was measured. Weight and volume of degradable materials was reduced up to 90%. Cellulose content was diminished in 50% and lignine content in 47%. The highest efficiency for degradation of cellulosic materials corresponded to the substrates that showed highest biological efficiency, which varied from 0% to 34%. Harvested mushrooms had good appearance and protein content and were free of human disease pathogens. This research indicates that growing P. ostreatus on disposable diapers could be a good alternative for two current problems: reduction of urban solid waste and availability of high protein food sources.  相似文献   

19.
As a new member of the European Union (EU), Romania has to align its economy with that of other EU partners, including the addition of a proactive component to environmental protection. This requires the development of a transitive approach capable of overcoming the difficulties of implementing the sustainability paradigm within an emerging market-oriented economy, which despite its progress, is still not fully prepared to understand and accept sustainability. This paper describes such a transition, showing how INCD ECOIND (the main Romanian Research and Development entity in the field of industrial ecology) reshaped its policies to include in current projects developed with Romanian partners the following elements: the Integrated Pollution Prevention and Control (IPPC) Directive, components relating to the REACH Process; the Environmental Management Accounting (EMA) mainframe and assistance in cultivating Corporate Social Responsibility (CSR) as an intrinsic part of modern enterprise. Lessons learned from previous and current projects are presented, underlining the complexity of obstacles met and problem-solving procedures derived and verified in practice.  相似文献   

20.
Aspects of Langmuir circulation (Lc) which relate to the dispersion of floating material are reviewed. These include convergence, dispersion by advection (particularly of a plume of floating oil when wind and current are in different directions) and the spread and dispersion by cell instability or breakdown first described by Csanady. There are, however, processes which compete with Lc to diffuse floating material. In shallow tidally mixed seas, where the environmental impact of an oil spill may be greatest, cross-wind dispersion caused by Lc will dominate over that produced by bottom turbulence if the ratio of the wind speed, W, to current, U, is sufficiently large. Observations and rough estimates suggest a transition near W/U=15. A simple model is devised to estimate cross-wind dispersion in shallow unstratified waters when turbulence generated at a flat seabed dominates that produced by Lc, but when the effects of Lc are still evident in aligning filaments of oil, as may commonly be the case in moderate winds in coastal or continental shelf waters.  相似文献   

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