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1.
Over a period of 21 months, we composted food refuse from a student restaurant in Hokkaido University using a commercially available composting machine. The machine had two reactors, each with a working volume of 250 l. The refuse was mixed with sawdust in a ratio of 5 l sawdust to 10 kg refuse, and this mixture was fed into the machine daily. We studied the characteristics of the refuse, the composting mixture, and the finished compost in an effort to optimize the operating parameters. We also evaluated the effectiveness of the composting process by determining the decomposition rates of the composting materials. The optimum moisture content of the composting mixture was between 30% wet basis (wb) and 40% wb in this machine. The composting machine worked well when the first reactor was filled with composting mixture and 0.5 kg lime was added once per week. The mass of the materials supplied was reduced by 84% over the study period. The decomposition rate of the volatile matter in all composting materials was 66%. The mass of the food refuse supplied was 14.8 kg/day on average, and the moisture content of the refuse was 77% wb on average. Received: October 4, 1999 / Accepted: April 4, 2000  相似文献   

2.
The safe and economical disposal of poultry litter is becoming a major problem for the USA poultry industry. Current disposal methods such as land application and feeding to cattle are now under pressure because of pollution of water resources due to leaching, runoffs and concern for mad cow disease contamination of the food chain. Incineration or combustion is potentially applicable to large scale operations, but for small scale growers and EPA non-attainment areas, this is not a suitable option because of the high cost of operation. Thus, there is a need for developing appropriate technologies to dispose poultry litter.Poultry litters from broiler chicken and turkey houses, as well as bedding material were converted into biocrude oil in a fast pyrolysis fluidized bed reactor. The biocrude oil yields were relatively low ranging from 36 wt% to 50 wt% depending on the age and bedding material content of the litter. The bedding material (which was mostly hardwood shavings) biocrude oil yield was 63 wt%. The higher heating value (HHV) of the poultry litter biocrude oils ranged from 26 MJ/kg to 29 MJ/kg while that of the bedding material was 24 MJ/kg. The oils had relatively high nitrogen content ranging from 4 wt% to 8 wt%, very low sulfur (<1 wt%) content and high viscosity. The viscosities of the oils appeared to be a function of both the source of litter and the pyrolysis temperature. The biochar yield ranged from 27 wt% to 40 wt% depending on the source, age and composition of the poultry litter. The biochar ash content ranged from 24 wt% to 54 wt% and was very rich in inorganic components such as potassium and phosphorous.  相似文献   

3.
The high-temperature thermal destruction of poultry derived wastes (e.g., manure and bedding) for energy recovery is viable in Australia when considering resource availability and equivalent commercial-scale experience in the UK. In this work, we identified and examined the opportunities and risks associated with common thermal destruction techniques, including: volume of waste, costs, technological risks and environmental impacts. Typical poultry waste streams were characterised based on compositional analysis, thermodynamic equilibrium modelling and non-isothermal thermogravimetric analysis coupled with mass spectrometry (TG–MS). Poultry waste is highly variable but otherwise comparable with other biomass fuels. The major technical and operating challenges are associated with this variability in terms of: moisture content, presence of inorganic species and type of litter. This variability is subject to a range of parameters including: type and age of bird, and geographical and seasonal inconsistencies. There are environmental and health considerations associated with combustion and gasification due to the formation of: NOX, SOX, H2S and HCl gas. Mitigation of these emissions is achievable through correct plant design and operation, however, with significant economic penalty. Based on our analysis and literature data, we present cost estimates for generic poultry-waste-fired power plants with throughputs of 2 and 8 tonnes/h.  相似文献   

4.
The objective of the present study was to evaluate the viability of reducing landfill requirements to satisfy EC Landfill Directive requirements by applying composting/bioremediation techniques to the construction and demolition (C&D) industry waste stream at laboratory scale. The experimental study was carried out in nine test rigs to examine different wood mixtures; untreated timber, creosote treated timber and chromated copper arsenate (CCA) treated timber. Several experimental variables affecting the process were characterised and optimised. These include the best nitrogen additive and optimum moisture content required for composting. Poultry manure was found to be the best nitrogen additive. The optimum moisture content was decreased after the addition of poultry manure. The composting/bioremediation process was evaluated through monitoring the microbial activity, carbon dioxide emissions and toxicity examination of the composted product. A typical temperature profile suggested that untreated and CCA treated mix could be classified as hot composting whereas creosote treated mix could be classified as cold composting. The paper reports on the results obtained during this investigation.  相似文献   

5.
Co-combustion of poultry wastes with natural gas in an advanced Swirling Fluidized Bed Combustor (SFBC) has been carried out to investigate the performance of poultry wastes combustion. Wastes burnt were poultry litter, poultry manure and sawdust. This paper presents the effect of three different wastes, excess air ratio, and secondary/total air ratio on the combustion characteristics. These characteristics include temperature distributions, carbon combustion efficiency, major gaseous pollutants emissions and heat recovery efficiency. The results indicate that, with the given moisture and ash contents in wastes, the excess air and the secondary air play important roles in achieving stable combustion. The carbon combustion efficiency could increase by 8-10% when the excess air is increased to 25% with the secondary air being at 20% and having a low injection height. However, the carbon combustion efficiency for the sawdust, which is 92% on average, is much higher than that of the poultry litter and manure, which is 81% and 76% on average, respectively. Differences regarding temperature distribution and pollutants emission were also observed with different combinations of the excess air, the secondary air and the secondary air injection height. The NO(x) emission was very low even though the materials contain high levels of nitrogen. In addition, the heat recovery efficiency aiming at the commercial use of the SFBC system for the farm industries was also evaluated.  相似文献   

6.
In Ireland, conversion of biodegradable farm wastes such as pig manure spent mushroom compost and poultry litter wastes to pelletised fertilisers is a desirable option for farmers. In this paper, results obtained from the composting of pig waste solids (20% w/w) blended with other locally available biodegradable wastes comprising poultry litter (26% w/w), spent mushroom compost (26% w/w), cocoa husks (18% w/w) and moistened shredded paper (10% w/w) are presented. The resulting 6-mo old 'mature' composts had a nutrient content of 2.3% total N, 1.6% P and 3.1% K, too 'low' for direct use as an agricultural fertiliser. Formulations incorporating dried blood or feather meal amendments enriched the organic N-content, reduced the moisture in mature compost mixtures and aided the granulation process. Inclusion of mineral supplements viz., sulphate of ammonia, rock phosphate and sulphate of potash, yielded slow release fertilisers with nutrient N:P:K ratios of 10:3:6 and 3:5:10 that were suited for amenity grasslands such as golf courses for spring or summer application and autumn dressing, respectively. Rigorous microbiological tests carried out throughout the composting, processing and pelletising phases indicated that the formulated organo-mineral fertilisers were free of vegetative bacterial pathogens.  相似文献   

7.
Physical parameters of 12 co-compost cover materials were experimentally determined and predicted variations in airflow characteristics were evaluated under varying moisture contents. Predicted air-filled porosity showed high correlation with measured air-filled porosity, facilitating development of a reliable model of air-filled porosity that makes it possible to predict the effect of varying moisture content and compost bed height on air-filled porosity and permeability. Predicted air-filled porosity decreased with increasing moisture content and compost depth for all materials. Air-filled porosity of corn stalks, oat straw, soybean straw, leaves, alfalfa hay, wheat straw, silage, wood shavings and sawdust was in the range of 38-99%. Turkey litter, soil compost blend and beef manure showed air-filled porosity values less than 30% near saturation and the bottom of pile. In concert with the findings of other researchers, effective particle size of all materials increased with increasing moisture content from 20% to 80% of water holding capacity (WHC). It increased dramatically near saturation. In general, permeability increased with increasing air-filled porosity and decreasing bulk density, but the relationship between permeability and moisture content is complex. Permeability is dependent on the balance between particle size and air-filled porosity. If the influence of aggregated particle size on the permeability is significant, it will compensate for the effect of reduced air-filled porosity caused by compaction and moisture content. In this case, permeability will increase; in the reverse case, it will decrease. Permeability decreased for corn stalks, oat straw, silage, wood shavings, soybean straw, sawdust, turkey litter and wheat straw with increasing moisture content from 20% WHC to 50% WHC, regardless of the depth of the compost bed. But the permeability increased with increasing moisture level from 50% to 80% WHC at moderate to shallow simulated bed depths. The soil compost blend and leaves showed the permeability increasing when the moisture increased not only from 50% to 80% WHC but also from 20% to 50% WHC. Permeability of alfalfa hay and beef manure always decreased with increasing moisture levels and pile depth. In this study the maximum wet bulk density and mechanical strength decreased with increasing the moisture content. The method described for determining physical properties under varying moisture contents and compost bed depths will be very useful for designing and modeling airflow characteristics of a mortality composting process with a variety of materials.  相似文献   

8.
Moisture affects the physical and biological properties of compost and other solid-state fermentation matrices. Aerobic microbial systems experience different respiration rates (oxygen uptake and CO2 evolution) as a function of moisture content and material type. In this study the microbial respiration rates of 12 mortality composting envelope materials were measured by a pressure sensor method at six different moisture levels. A wide range of respiration (1.6-94.2mg O2/g VS-day) rates were observed for different materials, with alfalfa hay, silage, oat straw, and turkey litter having the highest values. These four envelope materials may be particularly suitable for improving internal temperature and pathogen destruction rates for disease-related mortality composting. Optimum moisture content was determined based on measurements across a range that spans the maximum respiration rate. The optimum moisture content of each material was observed near water holding capacity, which ranged from near 60% to over 80% on a wet basis for all materials except a highly stabilized soil compost blend (optimum around 25% w.b.). The implications of the results for moisture management and process control strategies during mortality composting are discussed.  相似文献   

9.
For safe and sustainable management of poultry litter, it is important to evaluate and understand the chemical forms and concentrations of their constituent trace elements during treatment for disposal. This experiment was carried out to compare changes in metal (Cu, Mn, Zn, Pb and Ni) fractions in chicken and duck litter after incineration at temperatures ranging from 200 to 900 degrees C. The metals were stepwise fractionated into exchangeable, adsorbed, organically bound, carbonate precipitated and residual forms by extracting with 0.5M KNO3, de-ionized water, 0.5M NaOH, 0.05M Na2 EDTA and 4M HNO3, respectively. The content of total metal and other elements (i.e., Ca, Mg and K) were was also determined. Results showed an increasing trend in the total concentrations of metals with increasing temperature with higher amounts in chicken litter ash (CLA) than duck litter ash (DLA). Higher temperatures significantly reduced the levels of H2O-soluble Mn, Zn and Ni and enhanced those of Cu and Pb. The metal fractions extracted by EDTA and HNO3 increased directly with increasing temperature while the fraction extracted with KNO3 and NaOH decreased with ashing. For Cu, Mn, Pb and Ni, the amount extracted varied in the order EDTA>HNO3>NaOH>KNO3>H2O, but the absolute amounts differed between CLA and DLA. Peak concentrations of the total metals were achieved at the highest burning temperature. The amount of H2O soluble Ca and Mg decreased and K increased in both CLA and DLA with temperature. Total and exchangeable forms of cations increased with increasing temperature. Total Ca was highest in DLA, whereas total Mg and K were higher in CLA. This study indicated that incinerating poultry litter before soil application may have mixed effects on the vulnerable metal fractions by increasing or decreasing some fractions, depending on poultry type.  相似文献   

10.
The unstable nature of biocrude oils produced from conventional pyrolysis of biomass is one of the properties that limits its application. In the disposal of poultry litter via pyrolysis technology, the biocrude oil produced as a value-added product can be used for on farm applications. In this study, we investigated the influence of bedding material (wood shavings) on the storage stability of biocrude oils produced from the fast pyrolysis of poultry litter. The biocrude oils produced from manure, wood (pine and oak), and mixtures of manure and wood in proportions (75:25 50:50, and 25:75 w/w%) were stored under ambient conditions in sealed glass vials for a period of 6 months and their stability were monitored by measuring the changes in viscosity over time. The manure oil had the lowest rate of viscosity change and thus was relatively the most stable and the oils from the 50:50 w/w% litter mixtures were the least stable. The rate of viscosity change of the manure biocrude oil was 1.33 cP/day and that of the 50/50 litter mixture was 7.6 cP/day for pine and 4.17 cP/day for oak.The spectrometric analyses of the biocrude oils showed that the presence of highly reactive oxygenated functionalities in the oil were responsible for the instability characteristic of the litter biocrude oils. The poor stability of the biocrude oil from the 50:50 w/w% litter mixtures was attributed to reactions between nitrogenous compounds (amides) from protein degradation and oxygenated compounds from the decomposition of polysaccharides and lignin. The addition of 10% methanol and 10% ethanol to the oil from 50% manure and 50% pine reduced the initial viscosity of the oil and was also beneficial in slowing down the rate of viscosity change during storage.  相似文献   

11.
The effects of a polymeric chain extender on the properties of bioplastic film made from blends of plasticized polylactic acid (p-PLA) and thermoplastic starch (TPS) were studied. Joncryl? ADR 4370S, a polymeric chain extender, was blended with TPS and p-PLA at a level of 1% (w/w). A co-rotating twin-screw extrusion process was used to prepare films with various ratios of TPS and p-PLA. Mechanical and physical properties of films, including film tensile properties, surface energy, moisture content, hydrophilicity, moisture sorption behaviour and thermal mechanical properties were determined. During extrusion, films enhanced by 1% Joncryl addition demonstrated more desirable and consistent qualities, such as smoother film edge and surface. Addition of Joncryl significantly improved film tensile strength, 0.2% offset yield strength, and elongation, especially evident with the 250% elongation of 70/30 (TPS/p-PLA) film. Total surface energy of films was not significantly influenced by addition of Joncryl. However, the polar contribution to the total surface energy of 70/30 (TPS/p-PLA) film increased after the addition of Joncryl. The study showed that blending TPS with p-PLA transformed TPS film from being highly hydrophilic to highly hydrophobic. On the other hand, addition of Joncryl had limited effects on moisture content, water solubility, glass transition temperature and moisture sorption behaviour of TPS/p-PLA blend films.  相似文献   

12.
Poultry litter generated on the Delmarva Peninsula is from phytase-modified bird diet and bisulfate amendment. To establish agronomic application rates in conservation tillage systems, bisulfate-amended phytase-diet poultry litter was investigated for its nutrient release kinetics and supply capacity under simulated weathering conditions. Delmarva poultry litter was packed in PVC columns (15 cm i.d. × 25 cm height) to a depth of 5 cm and leached intermittently with 600 mm of water for 190 days. Concentrations of various nutrients in leachate were analyzed and nutrient release kinetics were modelled. Poultry litter leachate contained high contents of dissolved organic carbon (DOC, 35–11,800 mg L?1), nitrogen (N 6–2690 mg L?1), phosphorus (P 45–225 mg L?1), potassium (K 20–6060 mg L?1), and other nutrients. Release of the nutrients occurred primarily in the starting 5 weeks and mostly followed a first order Exponential-Rise-to-Maximum model. Under the specified conditions, the poultry litter demonstrated a nutrient supply capacity of 11.7 kg N Mg?1, 5.4 kg P Mg?1, and 36.8 kg K Mg?1. Release of the potentially plant-available N and K was nearly finalized within 190 days of leaching/weathering, but it would require two years for full release of the leachable P. The results indicate that with consideration of field conditions, surface application of bisulfate-amended phytase-diet Delmarva poultry litter at recommended 6.6 Mg ha?1 to conservation tillage systems would largely provide P 25.0 kg ha?1, N 106.6 kg ha?1, and K 245.5 kg ha?1 to seasonal crops.  相似文献   

13.
The high availability of large quantities of turkey manure generated from turkey production makes it an attractive feedstock for carbon production. Pelletized samples of turkey litter and cake were converted to granular activated carbons (GACs) by steam activation. Water flow rate and activation time were changed to produce a range of activation conditions. The GACs were characterized for select physical (yield, surface area, bulk density, attrition), chemical (pH, surface charge) and adsorptive properties (copper ion uptake). Carbon physical and adsorptive properties were dependent on activation time and quantity of steam used as activant. Yields varied from 23% to 37%, surface area varied from 248 to 472 m(2)/g and copper ion adsorption varied from 0.72 to 1.86 mmol Cu(2+)/g carbon. Copper ion adsorption greatly exceeded the values for two commercial GACs. GACs from turkey litter and cake show considerable potential to remove metal ions from water.  相似文献   

14.
The use of flat gas-permeable membranes was investigated as components of a new process to capture and recover ammonia (NH3) in poultry houses. This process includes the passage of gaseous NH3 through a microporous hydrophobic membrane, capture with a circulating dilute acid on the other side of the membrane, and production of a concentrated ammonium (NH4) salt. Bench- and pilot-scale prototype systems using flat expanded polytetrafluoroethylene (ePTFE) membranes and a sulfuric acid solution consistently reduced headspace NH3 concentrations from 70% to 97% and recovered 88% to 100% of the NH3 volatilized from poultry litter. The potential benefits of this technology include cleaner air inside poultry houses, reduced ventilation costs, and a concentrated liquid ammonium salt that can be used as a plant nutrient solution.  相似文献   

15.
In this study, co-composting of food waste and green waste at low initial carbon to nitrogen (C/N) ratios was investigated using an in-vessel lab-scale composting reactor. The central composite design (CCD) and response surface method (RSM) were applied to obtain the optimal operating conditions over a range of preselected moisture contents (45–75%) and C/N ratios (13.9–19.6). The results indicate that the optimal moisture content for co-composting of food waste and green waste is 60%, and the substrate at a C/N ratio of 19.6 can be decomposed effectively to reduce 33% of total volatile solids (TVS) in 12 days. The TVS reduction can be modeled by using a second-order equation with a good fit. In addition, the compost passes the standard germination index of white radish seed indicating that it can be used as soil amendment.  相似文献   

16.
This paper presents the results of a laboratory investigation to determine the geotechnical properties of fresh municipal solid waste (MSW) collected from the working phase of Orchard Hills Landfill located in Davis Junction (Illinois, USA). Laboratory testing was conducted on shredded MSW to determine the compaction, hydraulic conductivity, compressibility, and shear strength properties at in-situ gravimetric moisture content of 44%. In addition, the effect of increased moisture content during leachate recirculation on compressibility and shear strength of MSW was also investigated by testing samples with variable gravimetric moisture contents ranging from 44% to 100%. Based on Standard Proctor tests, a maximum dry density of 420 kg/m(3) was observed at 70% optimum moisture content. The hydraulic conductivity varied in a wide range of 10(-8)-10(-4)m/s and decreased with increase in dry density. Compression ratio values varied in a close range of 0.24-0.33 with no specific trend with the increase in moisture content. Based on direct shear tests, drained cohesion varied from 31 to 64 kPa and the drained friction angle ranged from 26 to 30 degrees. Neither cohesion nor friction angle demonstrated any correlation with the moisture content, within the range of moisture contents tested. The consolidated undrained triaxial shear tests on saturated MSW showed the total strength parameters (c and phi) to be 32 kPa and 12 degrees, and the effective strength parameters (c' and phi') to be 38 kPa and 16 degrees. The angle of friction (phi) decreased and cohesion (c) value increased with the increase in strain. The effective cohesion (c') increased with increase in strain; however, the effective angle of friction (phi') decreased first and then increased with the increase in strain. Such strain-dependent shear strength properties should be properly accounted in the stability analysis of bioreactor landfills.  相似文献   

17.
Poultry litter from broilers and turkeys are a mixture of manure, feathers, feed and wood shavings, thus pyrolysis oils produced from this material are influenced by the individual components. In order to determine the influence of wood shavings that are used as bedding material, we investigated the pyrolysis of pine wood shavings and poultry manure. Because manure from layer chickens are usually not contaminated with wood shavings, we made mixtures of layer manure and pine wood shavings in the following manure to wood ratios, 100:0, 75:25, 50:50, 25:75, and 0:100 w/w and pyrolyzed them in a fluidized bed reactor at 450 °C. The total liquid yield ranged from 43.3 to 62.7 wt.%. The layer manure oil had a HHV of 29.7 MJ/kg and pH of 5.89 compared to pine wood oil which had HHV of 25.6 MJ/kg and pH of 3.04. The addition of wood shavings to manure clearly influenced the physical properties of the oil, resulting in a decrease in pH and HHV and an increase in density. The oils had relatively high nitrogen content ranging from 1.36 to 5.88 wt.%. The ash (<0.07 wt.%) and sulfur (<0.28 wt.%) contents were very low. FTIR, 13C NMR and 1H NMR spectrometric analysis of the oils showed that manure oil was rich in hydrocarbons and nitrogenous compounds such as primary, secondary amides, aromatic amines and N-heterocyclic. The properties of the oils were strongly influenced by the amount of wood in the mixture.  相似文献   

18.
The blends of polylactic acid plasticized with acetyl tributyl citrate (P-PLA) and thermoplastic wheat starch (TPS) were prepared by a co-rotating twin screw extruder and the effect of maleic anhydride grafted PLA (PLA-g-MA) content as reactive compatibilizer on blends compatibility through morphological, rheological and tensile properties of the blends was investigated. Considerable improvement in properties of P-PLA/TPS (70/30 w/w) blend with incorporating the optimum PLA-g-MA content of 4 phr was achieved as this blend exhibited better morphological and rheological properties with an increase by 158 and 276% in tensile strength and elongation at break, respectively, compared to the uncompatibilized blend. Also the thermal stability and moisture sorption properties of the blends as effected by TPS content were studied. Decreasing in thermal stability and increasing in equilibrium moisture content of the blends were observed with progressively increasing of TPS content. For prediction the moisture sorption behaviour of blends with various TPS contents at different relative humidity, the moisture sorption isotherm data were modeled by GAB (Guggenheim–Anderson–de Boer) model.  相似文献   

19.
Currently, there is an environmental pollution problem generated in part by packaging materials produced from non-biodegradable synthetic polymers made from petroleum. However, these can be replaced with biodegradable materials made from cassava starch (CS) and natural rubber (NR). In the work described, a novel biopolymer film was obtained from the CS and NR using glycerol (GE) as a plasticizer in a water-based system. The physical properties of an 95/5 CS/NR blend films with the addition of NR and with varying GE contents were studied based on their swelling ratio, moisture content, moisture absorption, mechanical properties and biodegradability in soil. The results showed that the moisture content and moisture absorption tended to be directly proportional to the GE content, while the moisture content and moisture absorption of the sample decreased as a function of the NR content. The swelling ratio of the 95/5 CS/NR blend slightly decreased as a function of the NR and GE content. Surprisingly, the best swelling ratio of 350% was found at 10% NR. The elongation at break of the CS/NR blend was improved by the addition of GE. The contact angle of the 95/5 CS/NR blend decreased as a function of the GE. With increased NR in the composite, an increasing, trend in the contact angle was found. Further, the 95/5 CS/NR blend exhibited good transparency when it was applied as a coating to delay the ripening of bananas, the results were positive. Moreover, the film showed decomposition well in natural soil.  相似文献   

20.
Spain is one of the major producers of broilers and laying hens in the European Union, with an overall market share of around 12%. The poultry manure that is produced is usually employed as fertilizer on cropland, either directly or after a composting process. In some cases, however, this waste is transported over 120 km to be used as fertilizer, with the resulting high transport costs. In other countries, poultry manure is used as an alternative natural fuel source for power generation. In this study, poultry manure from all the laying hen farms in Asturias was characterized with a view to its possible use as an energy source. The Higher Heating Values on a dry basis (experimental) varies between 12,052 and 13,882 kJ/kg. Lower Heating Values (LHVs) on a wet basis range are much lower (mean values of 2664 kJ/kg) due to the high moisture content of poultry manure. Accordingly, the co-combustion of this waste with other types of waste such as forest and wood waste (LHV on a wet basis of 8044 and 15,830 kJ/kg, respectively) or municipal solid waste (LHV on a wet basis of 10,725 kJ/kg) should be considered as an alternative energy source. Chlorine and sulphur contents in dry matter vary around mean values of 0.64% and 0.11%, respectively. The waste also presents high amounts of Ca (4.84%) and K (2.38%).  相似文献   

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