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1.
To reveal clearly the effects of particle thermal characteristics on flame microstructures during organic dust explosions, three long-chain monobasic alcohols, solid at room temperature and similar in physical-chemical properties, were chosen to conduct experiments in a half-closed chamber. In the experiments, the dust materials were dispersed into the chamber by air to form dust clouds and the hybrids were ignited by an electrical spark. A high-speed optical schlieren system was used to record the flame propagation behaviors. A fine thermocouple and an ion current probe were respectively used to measure the flame temperature profile and the reaction behaviors of the combustion zone. Based on the experimental results, combustion behaviors and flame microstructures in dust clouds with different thermal characteristics were analyzed in detail. As a result, it was found that the dust flame surfaces were completely covered by cellular structures that significantly increased the flame frontal areas. Flame propagated more quickly and the number of the cellular cells increased as increasing the volatility of the particles. On the contrary, maximum temperature and the thickness of the preheated zone decreased as increasing the volatility of the particles. According to the ion current profile, the particles in the preheat zone were pyrolyzed to intermediate radicals and the radicals' fraction in the higher volatile dust flame was higher than that in the lower volatile dust flame.  相似文献   

2.
The prevention of dust explosions is still a challenge for the process industry. Ignition, in particular, is a phenomenon that is still not completely understood. As a consequence, safety conditions pertaining to ignition suppression are rarely identified to an adequate level. It is well known that, in general, the ignition attitude of a dust depends on several factors, such as the nature of the chemical, the particle size, moisture content, etc., but there is still a lack of knowledge on the effect of the single variables.This paper has the aim of providing data on the Minimum Ignition Temperatures of dust mixtures obtained from a mixing of a combustible dust (flour, lactose, sucrose, sulphur) and an inert dust (limestone, extinguishing powders) as well as from the mixing of two different combustible dusts. Various mixtures with different weight ratios have been tested in a Godbert Greenwald (GG) furnace and on a hot plate in order to measure the effect of mixture composition on the Minimum Ignition Temperature (MITL) of the layer and on the Minimum Ignition Temperature (MITC) of the cloud. In order to further verify the effects of inert dust particle size, inerts sieved to different size ranges have been tested separately. Generally, both MITL and MITC increase as the inert content is increased. MITC is poorly affected by inert particle size when limestone is used. The MITL of pure flour is higher than the MITL of mixtures containing up to 40% of 32–75 μm of limestone. This was probably due to the behaviour of pure flour during the test, which demonstrated strong tendency to produce char, cracks in the layer and detachment from the hot plate.  相似文献   

3.
随着现代工业的发展,粉尘爆炸事故发生的频率也逐年增加,因此,对粉尘云点火敏感程度进行测量和计算就变得十分重要。粉尘云最小点火能是粉尘爆炸重要的特性参数之一,是采取粉尘爆炸防护的基础。最小点火能在测量的过程中受到多个敏感条件的影响,其中湍流则是最复杂的影响因素之一。文中对实验过程中粉尘云的湍流进行了定义,并分析了湍流对粉尘云最小点火能影响的内在原因;同时对通过数值模拟计算粉尘云最小点火能过程中的湍流计算给出了数学模型。从实验和数学模型两个方向对湍流进行了全面描述,对粉尘云电火花点火过程中湍流影响的分析结论,可有效的指导实验。  相似文献   

4.
To reveal the effects of particle characteristics on the mechanisms of flame propagation during organic dust explosions clearly, three long chain monobasic alcohols which are solids at room temperature and have similar physical–chemical properties were chosen to carry out experiments in a half-closed small chamber. A high-speed video camera was used to record the flame propagation process and to obtain the direct light emission photographs. Flame temperature was detected by a fine thermocouple. Based on the experimental results above, analysis was conducted on flame propagation characteristics and temperature profiles of organic particle cloud. As a result, it was found that the particle materials, especially volatility, strongly affected the flame propagation behavior. Particle concentration also affects the combustion zone propagation process significantly. With increasing the particle concentration, the maximum temperature of the combustion zone increases at the lower concentration, reaches a maximum value, and then decreases at the higher concentration. The propagation velocity of the combustion zone has a linear relationship with the maximum temperature, which implies conductive heat transfer is dominant in the flame propagation process of the three different volatile dusts.  相似文献   

5.
In order to explore flame propagation characteristics during wood dust explosions in a semi-closed tube, a high-speed camera, a thermal infrared imaging device and a pressure sensor were used in the study. Poplar dusts with different particle size distributions (0–50, 50–96 and 96–180 μm) were respectively placed in a Hartmann tube to mimic dust cloud explosions, and flame propagation behaviors such as flame propagation velocity, flame temperature and explosion pressure were detected and analyzed. According to the changes of flame shapes, flame propagations in wood dust explosions were divided into three stages including ignition, vertical propagation and free diffusion. Flame propagations for the two smaller particles were dominated by homogeneous combustion, while flame propagation for the largest particles was controlled by heterogeneous combustion, which had been confirmed by individual Damköhler number. All flame propagation velocities for different groups of wood particles in dust explosions were increased at first and then decreased with the augmentation of mass concentration. Flame temperatures and explosion pressures were almost similarly changed. Dust explosions in 50–96 μm wood particles were more intense than in the other two particles, of which the most severe explosion appeared at a mass concentration of 750 g/m3. Meanwhile, flame propagation velocity, flame propagation temperature and explosion pressure reached to the maximum values of 10.45 m/s, 1373 °C and 0.41 MPa. In addition, sensitive concentrations corresponding to the three groups of particles from small to large were 500, 750 and 1000 g/m3, separately, indicating that sensitive concentration in dust explosions of wood particles was elevated with the increase of particle size. Taken together, the finding demonstrated that particle size and mass concentration of wood dusts affected the occurrence and severity of dust explosions, which could provide guidance and reference for the identification, assessment and industrial safety management of wood dust explosions.  相似文献   

6.
Bisphenol A is one of the basic compounds used in a synthesis of polycarbonates and epoxy resins. Its dust can create an explosive mixture with air under specific circumstances. Therefore, the main goal of this research was to determine explosion characteristics and flammability behaviour of this compound. The complete flammability characteristic requires the determination of the basic parameters of Bisphenol A under fire conditions including Heat Release Rate, speed of combustion, ability to ignite and the temperature of the decomposition range. To establish those parameters, a cone calorimeter was used. The explosion characteristics were tested in a 20-L spherical vessel. Minimum Ignition Energy was tested on MINOR II Apparatus which is a modified Hartman's Tube. In order to identify hazardous substances generated during a fire involving Bisphenol A, a simultaneous thermal analysis that combines thermogravimetry and differential scanning calorimetry was used. The substances obtained from the thermal degradation were analyzed by infrared spectroscope with Fourier transformation. Furthermore, the application of a Purser furnace and gas chromatography with mass spectrometry facilitated the identification of gaseous substances formed during the thermal degradation of Bisphenol A samples.  相似文献   

7.
A dispersion of fine particles in the air is needed for a dust explosion to occur since an explosion is the fast combustion of particles in the air. When particles are poorly dispersed, agglomerated, or their concentration is low, the combustion velocity decreases, and deflagration would not occur. The combustion rate is strictly related to dust concentration. Therefore, the maximum explosion pressure rise occurs at dust concentration close to stoichiometric. Conversely, Minimum Explosion Concentration (MEC) is the lower limit at which self-sustained combustion and a pressure rise are possible. Dust explosion tests are designed to reproduce the dispersion and generation of dust clouds in industrial ambiences by using dispersion devices activated by pressurised air pulses. The resulting dust cloud, which has a marked transient character, is considered representative of real clouds by current standards. Over time, several studies have been carried out to optimise these devices (e.g. to reduce the inhomogeneity of the cloud in the 20 L sphere). The Minimum Ignition Energy (MIE) of dust is measured using the Mike3 modified Hartmann tube, where the ignition attempt is made 60–180 ms after dust dispersion regardless of dust characteristics.This work investigates the dust clouds’ actual behaviour inside the modified Hartmann tube before ignition using high-velocity video movies and a new image post-treatment method called Image Subtraction Method (ISM). Movies are recorded with high-speed cameras at a framerate of 2000 fps and elaborated with an on-purpose developed LabVIEW® code. Concentration (mass per volume) and dispersion pressure are varied to evaluate their effect on dust clouds. Maise starch, iron powder and silica powder are chosen to investigate the effect of particle density and size on the cloud structure and turbulence. This approach will help to investigate the structure of the dust cloud, the shape and size of the particle lumps and the change in dust concentration over time. In addition, information on the actual concentration and cloud turbulence at the ignition location and delay time were obtained, which may help identify the local turbulence scale and widen the characterisation of the cloud generated in the Hartmann tube.  相似文献   

8.
In the last decade, the use of renewable resources has increased significantly in order to reduce the energetic dependence on fossil fuels, as they have an important contribution to the global warning and greenhouse gasses effect. Because of that, research on biofuels has been increased in the last years as its characteristics of use match those of the conventional fuel's: solid biomass can be used instead of coals, and biodiesel could replace diesel. Research on solid biomass ignition properties has been considerably developed because of the amount of industrial accidents related to the treatment and use of solid biomass (self-ignition, dust explosions, etc.). On the other hand, thermogravimetric analysis (TGA) is becoming and important characterization technique as it can be used to determine a wide spectrum of properties, such as kinetics, composition, proximate analysis, etc. This research aims to combine thermal analysis and ignition properties, by using the TGA to obtain the elemental composition of lignocellulosic biomass and compare those results to Minimum Ignition Energy (MIE) values test output, so a relation between composition and MIE can be found.To achieve this aim, biomass samples from different origins have been used: oil palm wastes (empty fruit bunches, mesocarp fiber and palm kernel shell), agricultural wastes (straw chops) and forestry wastes (wood chips and wood powder). Also, raw materials and torrefied biomass were compared. The hemicellulose/cellulose ratio was calculated and compared to different flammability properties, finding out that the greater the ratio and the lower the onset temperature (temperature at which the pyrolysis reaction accelerates), the lower was the minimum ignition energy. From this basis it was possible to define “tendency areas” that grouped the samples whose MIE values were similar. Three tendency areas were found: high minimum ignition energy, medium minimum ignition energy, and low ignition energy.  相似文献   

9.
An investigation of ignition of dust clouds by the use of electric spark discharges triggered by the explosive dust cloud itself has been conducted. This method of triggering capacitive sparks probably represents a realistic mechanism for initiating accidental dust explosions in industrial practice. Unlike the conventional method for determining the minimum ignition energy (MIE) in the laboratory, the delay between dust dispersion and spark discharge is not a degree of freedom. In stead, the transient dust cloud itself is used to initiate spark breakdown between electrodes set at a high voltage lower than breakdown in pure air. In the present study, different kinds of dusts were tested as ‘spark triggers’, and they exhibited quite different abilities to trigger breakdown. Large particles were found to initiate breakdown at lower voltages than smaller ones. In general, conductive particles were not found to initiate breakdown at lower voltages than dielectric ones when using the same dust concentration.Minimum ignition energies (MIE) of three dusts (Lycopodium clavatum, sulphur and maize starch) were determined using the authors' method of study. The MIEs were somewhat higher than those obtained using conventional methods, but relatively close to the values obtained through conventional methods.  相似文献   

10.
In this work, the explosion and combustion characteristics of aluminum and some aluminum alloys AlSi7Mg0.6, AlSi10Mg, AlMg5 under powders conditioning were studied. The idea was to compare the combustion of pure aluminum and aluminum alloys. The Minimum Ignition Energy (MIE) and explosion severity ΔPmax and (dP/dt)max which represents the dust explosion parameters were measured for all powders using Hartman tube and 20 L spherical bomb. The particles temperature and flame temperature were determined by using IR pyrometer and spectroscopy respectively. The results showed that pure aluminum was more sensitive and severe than its alloys. MIE were: 4 mJ for pure aluminum, 13–23 mJ for aluminum alloys. For severity parameters, the overpressure ΔPmax were around 7–8 bars with maximum rate of pressure rise at 1170 bar/s for aluminum and 5–7 bars with 250–360 bar/s for alloys. However, it has been observed that flame temperatures were similar for aluminum and alloys and vary around 2800–3300 K as a function of concentration.  相似文献   

11.
Deflagration explosions of coal dust clouds and flammable gases are a major safety concern in coal mining industry. Accidental fire and explosion caused by coal dust cloud can impose substantial losses and damages to people and properties in underground coal mines. Hybrid mixtures of methane and coal dust have the potential to reduce the minimum activation energy of a combustion reaction. In this study the Minimum Explosion Concentration (MEC), Over Pressure Rise (OPR), deflagration index for gas and dust hybrid mixtures (Kst) and explosive region of hybrid fuel mixtures present in Ventilation Air Methane (VAM) were investigated. Experiments were carried out according to the ASTM E1226-12 guideline utilising a 20 L spherical shape apparatus specifically designed for this purpose.Resultsobtained from this study have shown that the presence of methane significantly affects explosion characteristics of coal dust clouds. Dilute concentrations of methane, 0.75–1.25%, resulted in coal dust clouds OPR increasing from 0.3 bar to 2.2 bar and boosting the Kst value from 10 bar m s−1 to 25 bar m s−1. The explosion characteristics were also affected by the ignitors’ energy; for instance, for a coal dust cloud concentration of 50 g m−3 the OPR recorded was 0.09 bar when a 1 kJ chemical ignitor was used, while, 0.75 bar (OPR) was recorded when a 10 kJ chemical ignitor was used.For the first time, new explosion regions were identified for diluted methane-coal dust cloud mixtures when using 1, 5 and 10 kJ ignitors. Finally, the Le-Chatelier mixing rule was modified to predict the lower explosion limit of methane-coal dust cloud hybrid mixtures considering the energy of the ignitors.  相似文献   

12.
The knowledge of the ignition behavior of dust–air mixtures due to electrical sparks (MIE, Minimum Ignition Energy) and hot surfaces (MIT, Minimum Ignition Temperature) is important for risk assessments in chemical production plants. The ignition behavior determines the extent and hence the cost of preventive protection measures.This paper describes the use of the minimum ignition energy and minimum ignition temperature as very important safety indexes in practice.  相似文献   

13.
The majority of powders that are used in the processing industries are combustible (also referred to as flammable, explosible). An explosion will occur if the concentration of the combustible dust that is suspended in air is sufficient to propagate flame when ignited by a sufficiently energetic ignition source.A systematic approach to identifying dust cloud explosion safety against their consequences generally involves:-Identification of locations where combustible dust cloud atmospheres could be present-Understanding of the explosion characteristics of the dust(s)-Identification of potential ignition sources that could be present under normal and abnormal conditions-Proper process and facility design to eliminate and/or minimize the occurrence of dust explosions and protect people and facilities against their consequences-Adequate maintenance of facilities to prevent ignition sources and minimize dust releaseThis presentation will discuss the conditions that are required for dust cloud explosions to occur and presents a well-tried approach to identify, assess, and eliminate/control dust explosion hazards in facilities.  相似文献   

14.
Powdered materials are widely used in industrial processes, chemical processing, and nanoscience. Because most flammable powders and chemicals are not pure substances, their flammability and self-heating characteristics cannot be accurately identified using safety data sheets. Therefore, site staff can easily underestimate the risks they pose. Flammable dust accidents are frequent and force industrial process managers to pay attention to the characteristics of flammable powders and create inherently safer designs.This study verified that although the flammable powders used by petrochemical plants have been tested, some powders have different minimum ignition energies (MIEs) before and after drying, whereas some of the powders are released of flammable gases. These hazard characteristics are usually neglected, leading to the neglect of preventive parameters for fires and explosions, such as dust particle size specified by NFPA-654, MIE, the minimum ignition temperature of the dust cloud, the minimum ignition temperature of the dust layer, and limiting oxygen concentration. Unless these parameters are fully integrated into process hazard analysis and process safety management, the risks cannot be fully identified, and the reliability of process hazard analysis cannot be improved to facilitate the development of appropriate countermeasures. Preventing the underestimation of process risk severity due to the fire and explosion parameters of unknown flammable dusts and overestimation of existing safety measures is crucial for effective accident prevention.  相似文献   

15.
Current status and expected future trends in dust explosion research   总被引:4,自引:0,他引:4  
In spite of extensive research and development for more than 100 years to prevent and mitigate dust explosions in the process industries, this hazard continues to threaten industries that manufacture, use and/or handle powders and dusts of combustible materials. Lack of methods for predicting real dust cloud structures and flame propagation processes has been a major obstacle to prediction of course and consequences of dust explosions in practice. However, work at developing comprehensive numerical simulation models for solving these problems is now on its way. This requires detailed experimental and theoretical studies of the physics and chemistry of dust cloud generation and combustion. The present paper discusses how this kind of work will promote the development of means for prevention and mitigation of dust explosions in practice. However, progress in other areas will also be discussed, e.g. ignition prevention. The importance of using inherently safe process design, building on knowledge in powder science and technology, and of systematic education/training of personnel, is also emphasized.  相似文献   

16.
The explosivity of dust clouds is greatly influenced by several parameters which depend on the operating conditions, such as the initial turbulence, temperature or ignition energy, but obviously also on the materials composition. In the peculiar case of a mixture of two combustible powders, the physical and chemical properties of both dusts have an impact on the cloud flammability and on its explosivity. Nevertheless, no satisfactory ‘mixing laws’ predicting the mixture behavior are currently available and the composition variable to be considered for such models greatly depend on the safety parameters which have to be determined: from volume ratios for some thermal exchanges and ignition phenomena, to surface proportions for some heterogeneous reactions and molar contents for chemical reactions. This study is mainly focused on graphite/magnesium mixtures as they are encountered during the decommissioning activities of UNGG reactors (Natural Uranium Graphite Gas). Due to the different nature and reactivity of both powders, these mixtures offer a wide range of interests. Firstly, the rate-limiting steps for the combustion of graphite are distinct from those of metals (oxygen diffusion or metal vaporization). Secondly, the flame can be thickened by the presence of radiation during metal combustion, whereas this phenomenon is negligible for pure graphite. Finally, the turbulence of the initial dust cloud is modified by the addition of a second powder. In order to assess the explosivity of graphite/magnesium clouds, a parametric study of the effects of storage humidity, particle size distribution, ignition energy, and initial turbulence has been carried out. In particular, it was clearly demonstrated that the turbulence significantly influences the explosion severity by speeding up the rate of heat release on the one hand and the oxygen diffusion through the boundary layer surrounding particles on the other hand. Moreover, it modifies the mean particle size and the spatial dust distribution in the test vessel, impacting the uniformity of the dust cloud. Thus, the present work demonstrates that the procedures developed for standard tests are not sufficient to assess the dust explosivity in industrial conditions and that an extensive parametric study is relevant to figure out the explosive behavior of solid/solid mixtures subjected to variations of operating conditions.  相似文献   

17.
Suppression tests of oxyhydrogen gas explosions were performed in an explosion tube with five types of dry powder used as the suppressants. The experimental results showed that the powder with large dust cloud density and small radius has better suppression effect, which agrees well with previous correlative results. Moreover, our results also showed that particles with chemical activity and light material density, their suppression effect are more prominent than that of the inert particles with heavy density. To discover the detailed suppression process of dust powder, governing equations were developed based on the homogeneous reactive two-phase flow. The TVD scheme and the Lax–Wendroff–Rubin scheme were adopted to solve the reactive gas phase and particle phase, respectively. The time splitting technique was employed to handle the stiffness of the coupled equations. Our calculated results showed that the dust cloud has the suppression effect on the explosion of oxyhydrogen gas, and with the increase of dust cloud density or the decrease of particle diameter, its suppression effect become more evident, which is in good agreement with our experimental results, in addition, the numerical results showed that with the same particle diameter, the suppression performance is enhanced with the reduction in particle material density.  相似文献   

18.
In this work, the influence of humidity on dust explosions of metallic (aluminium) and organic materials (icing sugar, polyethylene and magnesium stearate) has been studied. The impact of pre-humidification of powders on their ignition sensitivity, their volume resistivity and charge decay time has been assessed. The influence of humidity on explosion severity has also been studied by two methods: on the one hand, the dust sample was stored in a controlled workstation at constant relative humidity; on the other hand, the dry dust was dispersed in a humidity controlled atmosphere in the vessel.As expected, the effect of humidity strongly depends on the chemical nature of the particles. Experiments on powders volume resistivity and charge decay time have shown typical trends but have especially pointed out the inadequacy of some standards. Inhibition phenomena have been verified for polyethylene and magnesium stearate, whereas both inhibition and promotion have been observed for icing sugar and could be explained by an evolution of sucrose structure. Dry aluminium dust explosions in humid atmosphere show that water vapour inerts the explosion. However, when aluminium is stored at controlled humidity, the maximum rise of pressure rate increases with the water content, which is probably due to hydrogen generation.  相似文献   

19.
The hazards of dust explosions prevailing in plants are dependent on a large variety of factors that include process parameters, such as pressure, temperature and flow characteristics, as well as equipment properties, such as geometry layout, the presence of moving elements, dust explosion characteristics and mitigating measures. A good dust explosion risk assessment is a thorough method involving the identification of all hazards, their probability of occurrence and the severity of potential consequences. The consequences of dust explosions are described as consequences for personnel and equipment, taking into account consequences of both primary and secondary events.While certain standards cover all the basic elements of explosion prevention and protection, systematic risk assessments and area classifications are obligatory in Europe, as required by EU ATEX and Seveso II directives. In the United States, NFPA 654 requires that the design of the fire and explosion safety provisions shall be based on a process hazard analysis of the facility, process, and the associated fire or explosion hazards. In this paper, we will demonstrate how applying such techniques as SCRAM (short-cut risk analysis method) can help identify potentially hazardous conditions and provide valuable assistance in reducing high-risk areas. The likelihood of a dust explosion is based on the ignition probability and the probability of flammable dust clouds arising. While all possible ignition sources are reviewed, the most important ones include open flames, mechanical sparks, hot surfaces, electric equipment, smoldering combustion (self-ignition) and electrostatic sparks and discharges. The probability of dust clouds arising is closely related to both process and dust dispersion properties.Factors determining the consequences of dust explosions include how frequently personnel are present, the equipment strength, implemented consequence-reducing measures and housekeeping, as risk assessment techniques demonstrate the importance of good housekeeping especially due to the enormous consequences of secondary dust explosions (despite their relatively low probability). The ignitibility and explosibility of the potential dust clouds also play a crucial role in determining the overall risk.Classes describe both the likelihood of dust explosions and their consequences, ranging from low probabilities and limited local damage, to high probability of occurrence and catastrophic damage. Acceptance criteria are determined based on the likelihood and consequence of the events. The risk assessment techniques also allow for choosing adequate risk reducing measures: both preventive and protective. Techniques for mitigating identified explosions risks include the following: bursting disks and quenching tubes, explosion suppression systems, explosion isolating systems, inerting techniques and temperature control. Advanced CFD tools (DESC) can be used to not only assess dust explosion hazards, but also provide valuable insight into protective measures, including suppression and venting.  相似文献   

20.
The hybrid mixture of combustible dusts and flammable gases/vapours widely exist in various industries, including mining, petrochemical, metallurgical, textile and pharmaceutical. It may pose a higher explosion risk than gas/vapor or dust/mist explosions since the hybrid explosions can still be initiated even though both the gas and the dust concentration are lower than their lower explosion limit (LEL) values. Understanding the explosion threat of hybrid mixtures not only contributes to the inherent safety and sustainability of industrial process design, but promotes the efficiency of loss prevention and mitigation. To date, however, there is no test standard with reliable explosion criteria available to determine the safety parameters of all types of hybrid mixture explosions, nor the flame propagation and quenching mechanism or theoretical explanation behind these parameters. This review presents a state-of-the-art overview of the comprehensive understanding of hybrid mixture explosions mainly in an experimental study level; thereby, the main limitations and challenges to be faced are explored. The discussed main contents include the experimental measurement for the safety parameters of hybrid mixtures (i.e., explosion sensitivity and severity parameters) via typical test apparatuses, explosion regime and criterion of hybrid mixtures, the detailed flame propagation/quenching characteristics behind the explosion severities/sensitivities of hybrid mixtures. This work aims to summarize the essential basics of experimental studies, and to provide the perspectives based on the current research gaps to understand the explosion hazards of hybrid mixtures in-depth.  相似文献   

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