膜分离技术在水处理中的应用研究

介绍了膜分离技术及其特点，对膜分离技术进行了分类，同时阐述了渗透、电渗析、反渗透、超滤、微滤和纳滤这些常规膜分离技术的研究和应用情况，在此基础上介绍了近年来发展起来的液膜、气态膜、双极膜、膜萃取和膜蒸馏这些新型膜分离技术。提出了膜分离技术存在的一些问题、研究方向、展示了膜分离技术的应用前景。     

应用于水处理的反渗透浓缩液处理和资源化技术综述

在反渗透技术中,浓缩液的处理是最关键的问题之一。随着反渗透技术在水处理上的广泛使用,浓缩液的处理和资源化利用已经成为急需解决的大问题。介绍了目前国内外处理浓缩液的方法,包括Fenton法、混凝—吸附法、膜法、蒸发法、浓缩液回灌和海水淡化浓缩液再利用。     

挑战水资源环境问题的最新反渗透膜技术

近年,在对污水和废水进行处理及再利用的技术领域里,反渗透法受到广泛的关注。自2004年起中国大陆已超越北美成为全球最大的反渗透膜市场,而与之不相适应的是,我国市场上95％以上所用的反渗透膜产品需要进口,各行各业对国外反渗透膜形成了严重的依赖。我国是全球最大的发展中国家,面对日益紧迫的环境压力,节能减排成为可持续发展的必然选择,实践证明,反渗透技术在污水回用深度处理方面已非常成熟。     

沸石负载型TiO2处理炼化反渗透浓缩水的研究

利用沸石负载型二氧化钛对炼化企业的反渗透浓缩水进行研究,考察了催化剂对浓缩水的处理效果及影响降解的因素。由实验结果可知:沸石负载型二氧化钛对反渗透浓缩水TOC降解率达到67.4%,降解浓缩水的最佳条件为:pH值为4～6,温度30～40℃,光照时间2.5h,催化剂投加量为1.5g/L。实验为浓缩水处理技术的发展提供了新的依据。     

膜分离技术在电镀废水处理中的应用现状

膜分离技术作为一种新型分离技术,具有分离效率高、过程能耗低等特点,被广泛应用于废水处理领域。由于电镀废水污染物种．是多样,纳滤、反渗透、聚合物强化超滤、电渗析等膜分离过程作为电镀废水的处理与资源化技术被深入研究,纳滤、反渗透及其组合工艺等被应用于电镀废水的处理及其资源化,有着良好的应用前景。     

反渗透膜法海水淡化技术在大连石化公司的应用

大连石化公司采用反渗透膜法海水淡化工艺为生产装置提供淡水资源,其用水取自炼化装置冷却换热后的海水,不额外增加海水的取用量,降低了成本。装置采用常规预处理加三级反渗透膜分离技术,同时配备了能量回收装置,将反渗透高压"浓水"的能量转换到低压的原海水中,使得能耗大大降低。文章介绍了该工艺的流程及其技术特点,该装置节能、节水,其产品水质量达到甚至超过了中压锅炉补给水的要求。工程运行稳定,对沿海同类企业有借鉴意义。     

双膜法对钢铁废水脱盐处理的应用研究

本文依托某钢铁企业的综合污水膜处理工程项目，对超滤-反渗透双膜法在钢铁工业综合污水处理回收中的应用进行了研究。     

反渗透装置处理炼油污水的优化运行

通过对反渗透装置初次化学清洗时进水水质、运行情况、反渗透系统进水端和浓水端情况、保安过滤器滤芯情况分析,确定造成膜污染的主要原因,并针对这些原因采取化学清洗、运行管理等一定措施。措施实施后:反渗透运行周期均有所增加,特别是1#反渗透装置,运行周期增至2 414h,达到健康运行要求。     

应用反渗透技术处理垃圾填埋场渗滤液

垃圾填埋场渗滤液属于高浓度氨氮废水,其水量、水质特性变化大,成分复杂,因此较难处理。反渗透分离技术能有效截留垃圾渗滤液中溶解态的有机和无机污染物。采用三级反渗透处理垃圾渗滤液工艺处理后的出水水质,能够满足《生活垃圾填埋污染控制标准》（DB16889-2008）要求,并把渗滤液浓缩液回灌于填埋场。     

碟管式反渗透(DT-RO)渗滤液处理系统

该技术由玻尔过滤器（北京）有限公司和北京天地人环保科技有限公司共同开发. 主要技术内容 一.工艺路线 采用两级反渗透处理渗滤液.垃圾渗滤液排入调节池.     

Phosphorus runoff from two water sources on a calcareous soil

Phosphorus (P) in irrigation runoff may enrich offsite water bodies and streams and be influenced by irrigation water quality and antecedent soil surface conditions. Runoff, soil loss, and P fractions in runoff using reverse osmosis (RO) water or mixed RO and well water (RO/ Tap) were studied in a laboratory sprinkler study to evaluate water source effects on P transport. A top- or subsoil Portneuf silt loam (coarse-silty, mixed, superactive, mesic Durinodic Xeric Haplocalcid), either amended or not amended with manure and/or with cheese whey, with Olsen P from 20 to 141 mg kg(-1) and lime from 108 to 243 g kg(-1), was placed in 1.5 x 1.2 x 0.2-m-deep containers with 2.4% slope and irrigated three times from a 3-m height for 15 min, applying 20 mm of water. The first irrigation was on a dry loose surface, the second on a wet surface, and the third on a dry crusted surface. Surface (ca. 2 cm) soil samples, prior to the first irrigation, were analyzed for Olsen P, water-soluble P (Pws), and iron-oxide impregnated paper-extractable P (FeO-P) analyses. Following each irrigation we determined runoff, sediment, dissolved reactive phosphorus (DRP) in a 0.45-microm filtered sample, and FeO-P and total P in unfiltered samples. Soil surface conditions had no effect on P runoff relationships. Water source had no significant effect on the relationship between DRP or FeO-P runoff and soil test P, except for DRP in RO runoff versus water-soluble soil P (r2 = 0.90). Total P in RO runoff versus soil P were not related; but weakly correlated for RO/Tap (r2 < 0.50). Water source and soil surface conditions had little or no effect on P runoff from this calcareous soil.     

炼油污水回用处理RO系统的稳定运行及维护

文章介绍了兰州石化公司炼油污水深度处理反渗透(RO)系统的工艺流程及维护。通过进出水电导率、产水回收率等变化情况,分析了RO系统的运行状况。得知:运用此系统,反渗透系统产水回收率达到65%～70%,系统脱盐率在99%以上,产水可以满足一级除盐水要求,实现了装置稳定运行的目标。     

Comparison of different pre-treatment methods for enriching hydrogen-producing bacteria from intertidal sludge

Batch tests of cultivations were conducted to analyze influences of pre-treatment methods (heat–shock, acid, and alkaline) on hydrogen production. The hydrogen yields of the pre-treated samples were significantly higher than those without pre-treatment. Heat–shock pre-treatment yielded maximum hydrogen (75.5 ± 4.0 mL/g sucrose_removed), and had the highest sucrose removal efficiency (81.20 ± 1.23%). Heat–shock pre-treatment produced more ethanol and acetate (80.44 ± 0.55% of the total soluble metabolites), which belonged to ethanol-type fermentation. Denaturing gradient gel electrophoresis (DGGE) profiles showed that pre-treatment methods affected the composition of microbial communities. The results showed that pre-treatment methods play a key role in the hydrogen production process of marine hydrogen-producing microflora.     

Hydrochemistry of drinking water sources and water purifiers in relation to epidemiological study in Hisar,North-West India

The concern related to the drinking of reverse osmosis (RO) water containing low levels of minerals is growing day by day. This study involves the analysis of water samples from various drinking water sources in a rural site, Mirchpur village, an Indus Valley civilization site (grid location: 29° 18′ 42.3″ N, 76° 10′ 33.0″ E) of Hisar, India, along with the health survey of human subjects. The hydrochemistry of water collected from hand pumps, river canals, tube wells, submersibles, and the RO systems installed in various homes was explored for pH, EC, TH, TDS, turbidity, cations (Na⁺, Ca²⁺, Mg²⁺), anions (CO₃²⁻, HCO₃⁻, Cl⁻, SO₄²⁻, NO₃⁻, F⁻), and elements (Fe, Pb, Se) employing the ion chromatography, flame photometry, and ICP-AES techniques. Lead (Pb) and Selenium (Se) were detected in trace amounts (0.30–2.6 μg L⁻¹; 0.10–4.1 μg L⁻¹, respectively) in all the samples, including the samples collected from RO purifiers, but Iron (Fe) was not detected in RO samples even in trace amounts. The F-levels in hand pump water (HPW) and submersible water (SW) (1.9  and 1.7 mg L⁻¹, respectively) and TDS levels in SW (3048 mg L⁻¹) were found to be above WHO and BIS safe limits. TDS levels in the river canal (900 mg L⁻¹), tube well (1104 mg L⁻¹), hand pump (1170 mg L⁻¹), and submersible samples (3048 mg L⁻¹) were found significantly higher as compared to the RO personal water (ROPW; 216 mg L⁻¹) and RO supply water (ROSW; 90 mg L⁻¹). The collected epidemiological data reveals that 21%, 19%, 13%, and 12% of natives reported skin, kidney, hair fall, liver, and stomach issues, respectively, suspecting the crucial role of high TDS and fluoride levels in the area. This study also provides a comparison between the quality of RO and the direct supply water, along with correlation matrices for different parameters, which gives a rationale for the limitations of drinking direct supply water without any purification and RO water containing low mineral content.     

ANALYSIS OF STREAMFLOW TRENDS AND THE EFFECTS OF CLIMATE IN PENNSYLVANIA, 1971 TO 20011

An understanding of temporal trends in total stream‐flow (TSF), base flow (BF), and storm runoff (RO) can help in the development of water management plans for watersheds and local communities. In this study, 47 streams across Pennsylvania that were unregulated and unaffected by karst environments or coal mining were studied for flow trends and their relationships to selected climate parameters for the period 1971 to 2001. LOWESS curves for annual flow showed that almost all of the selected streams in Pennsylvania had downward trends in total TSF, BF, and RO. Using a seasonal Mann‐Kendall analysis, downward trends were significant at an α= 0.05 level for 68, percent 70 percent, and 62 percent of the streams and at an α= 0.10 level for another 19, 17, and 13 percent of the streams for TSF, BF, and RO, respectively. The ratio of BF to TSF (RBS) had significant upward trends for 34 percent of the streams at an α= 0.05 level and for another 9 percent of the streams at an α= 0.10 level, indicating that TSF decreased relative to BF for more than 40 percent of the streams during the previous 30 years. Downward trends in TSF, BF, and RO were most common for the months of June, July, and December. Trend analyses using monthly and annual total precipitation and mean temperature showed some association between climate and the streamflow trends, but Spearman's correlation and partial Mann‐Kendall analyses revealed that the trends in TSF, BF, and RO could not be explained by trends in precipitation and temperature alone, and thus urbanization and development may have played a role.     

实验用水对总氮检测结果的影响

用RO纯水与超纯水分别作为实验用水,通过标准曲线及空白、标准样品、水样等总氮测定对比实验,发现两种实验用水的标准曲线及空白值、标准样品的检测均受控,但两种纯水对比实验显示相对于超纯水而言,RO纯水中有一定浓度的总氮,同时在水样检测中用RO纯水作实验用水测定值明显低于用超纯水作实验用水的测定值,其差值与RO纯水中总氮值相符。实验结果表明总氮检测中不能只以标准曲线、空白值和标准样品测定值作为受控标准,要考虑实验用水中硝酸根离子的影响。     

Comparing Contaminant Removal Costs for Aquifer Recharge with Wastewater with Water Supply Benefits

The use of waters of impaired quality has been suggested as a means to expand available water resources supply for water‐limited communities. An ongoing concern is the safety of supplies that use wastewater because of the potential for introduction of emerging contaminants such as pharmaceuticals into drinking water supplies. Prior research into contaminants of emerging concerns (CECs) have included a variety of methods, but the only consistent removal is with reverse osmosis (RO) membranes, ultraviolet light (UV), and advanced oxidation processes (AOP). However, few of these prior studies have measurable quantities of these contaminants in the influent wastewater, so determining actual removal percentages is difficult. This project was designed to evaluate the removal of CECs to verify that a 3‐log removal of common constituents was realized. Spike testing was used to compare to prior research and to evaluate whether the project costs were competitive with other forms of reuse or other water supplies. The combination of RO/UV/AOP was effective at obtaining a 3‐log removal of CECs, but the RO and UV/AOP processes alone were not capable of removing all substances. However, despite the extensive treatment, the proposed process was both competitive cost‐wise and met the water quality goals.     

低营养低温条件下双膜法水处理系统的改进

膜分离技术中的MBR与RO组合工艺具有出水水质好、占地面积小、便于自动控制、运行稳定等优点。但在运行过程中,膜会发生不同程度的污堵,如何减缓膜污染的发生及让系统稳定高效的运行是膜法水处理技术面临的主要问题。通过优化生化系统的菌群结构,提高生化出水水质,可有效减缓MBR膜污染的发生,从而使生化＋ MBR系统的整体运行效果大大增强;通过在MBR和RO之间增设汽水换热系统,可克服冬季低温对RO系统运行的影响,提高MBR ＋ RO组合工艺的产水率,节省运行能耗。     

Improving anaerobic sewage sludge digestion by implementation of a hyper-thermophilic prehydrolysis step

The present study focuses on a two-step process for treatment and stabilisation of primary sludge. The process consists of a hyper-thermophilic hydrolysis step operated at 70 degrees C and a hydraulic retention time (HRT) of 2 days followed by a thermophilic (55 degrees C) anaerobic digestion step at a HRT of 13 days. A one-step anaerobic digester operated at 55 degrees C and 15 days HRT was used as a reference process. The two-step process was characterized by a 12% higher organic suspended solids removal efficiency and better pathogen reduction effect than the conventional one-step digestion. The microbial community of the digester fed with pre-treated sludge was characterised by a higher activity compared to that of the digester treating raw sludge. Moreover, the pre-treatment of the primary sludge resulted up to 48% increase of the methane potential (20.09 and 13.56mmolCH(4)g(-)VS(-1) with and without pre-treatment, respectively) and up to 115% increase of the methane production rate. Finally it was shown that the extra energy requirements for the operation of a pre-treatment step would be covered by the energy produced from the extra methane production and in addition there would be a significant energy surplus of 2.17kJd(-1) for the system tested.     

COST EFFECTIVE ARSENIC REDUCTIONS IN PRIVATE WELL WATER IN MAINE1

ABSTRACT: This study was undertaken to investigate the cost effectiveness of selected arsenic avoidance methods. Annual costs of reverse osmosis (RO), activated alumina (AA), bottled water, and rented and purchased water coolers for various household sizes in Maine were compared. Relative ranking of systems shows that RO ($411 annually) is the most cost effective, followed by AA ($518) and one‐gallon jugs of water ($321 to $1,285), respectively, for households larger than one person. One‐gallon jugs ($321) followed by 2.5‐gallon jugs ($358) of water were found to be the most cost effective for households of one person or for households with arsenic III concentrations of 0.02 to 0.06 mg/L and arsenic V concentrations of 0.08 to 1.0 mg/L. Point‐of‐entry systems and water coolers were not found to be cost effective under any of the study's conditions. The research reported here will help states make more definitive treatment recommendations to households regarding the cost effectiveness of alternative treatment systems to reduce arsenic concentrations below 0.01 mg/L. While arsenic removal technologies are improving, which enhances removal rates and reduces costs, the major insights from this analysis appear to be reinforced by technological improvements.