Chemistry of lakes in designated wilderness areas in the western United States

A synoptic survey of 719 lakes representing an estimated 10,393 lakes in mountainous areas of the western United States was conducted in autumn 1985. Nearly two-thirds of the study lakes were located in wilderness areas or national parks and were sampled by ground access. The results of a comparability study of 45 wilderness lakes accessed by helicopter and ground crews indicated that the data were generally indistinguishable, making it possible to use data from lakes sampled by ground crews without modification. Wilderness lakes had lower acid neutralizing capacity (ANC), base cations, sulfate, and dissolved organic carbon than nonwilderness lakes throughout the West. The highest estimated number (849) and percentage (42.1) of low ANC (50 eq L^-1) wilderness lakes were located in California; the lowest number (66) was located in the Southern Rockies. The Sierra Nevada contained an estimated 808 low ANC lakes, representing the largest subpopulation of low ANC lakes associated with an individual mountain range in the West. Wilderness lakes in selected geographic areas of the Rocky Mountains generally contained higher concentrations of major ions than lakes in the far West and the concentrations generally increased from the Northern to the Southern Rockies. Comparison of wilderness lakes in the West with lakes in the Adirondack Park, New York, and the Boundary Waters Canoe Area/Voyagers National Park in Northeastern Minnesota showed that western lakes are highly sensitive resources that currently exhibit little evidence of anthropogenic acidification. Although wilderness lakes do not exhibit symptoms of chronic acidification, short-term depression of pH and ANC from snowmelt and thunderstorms occur and episodic acidification influenced by anthropogenic sources cannot be discounted on the basis of this survey.Contribution from Fourth World Wilderness Congress-Acid Rain Symposium, Denver (Estes Park), Colorado, September 11–18, 1987.     

Residues of organochlorine pesticides and polychloribiphenyls in starlings (Sturnus vulgaris), from the continental United States, 1982

Starlings were collected from 129 sites throughout the contiguous United States in the fall of 1982 and analyzed for organochlorine compounds as part of a nationwide monitoring program. Residues of 14 organochlorine compounds were found. Only DDE, polychlorobiphenyls (PCB), dieldrin, and heptachlor epoxide occurred in more than 50% of the 10-starling pools. Geographical variation in the occurrence of seven organochlorine compounds was noted. Mean DDE levels were higher in the southwestern United States. Mean PCB levels were higher in the eastern United States. The occurrence frequency of most organochlorines in 1982 was similar to that which was reported in the previous nationwide study in 1979. A slight increase in occurrence was noted for trans-nonachlor. Mean DDE level in 1982 was similar to that of 1979. Mean PCB level in 1982 was lower than the 1979 mean, but this change may not reflect a decrease in environmental PCB levels.     

Land use effects on macrobenthic communities in southeastern United States tidal creeks

Runoff from impervious land cover has a major impact on headwater tidal creek ecosystems resulting from ever increasing development along the coastline. Tidal creek habitats can serve as "early warning systems" for anthropogenic stressors due to their proximity to the uplands. In this study, the macrobenthic community was sampled along the longitudinal gradient of tidal creeks (i.e., first order, second order, and third order) in North Carolina, South Carolina, and Georgia which varied in their levels of watershed development (salt marsh, forested, suburban, and urban). This study was designed to assess the condition of macrobenthic communities in tidal creek ecosystems under varying levels of anthropogenic stressors and test whether the conclusions of a previous study in South Carolina (Holland et al., J Exp Mar Biol Ecol 298:151-178, 2004) could be generalized to the southeastern USA. Metrics of community-level and species-specific response within tidal creeks draining watersheds of varying degrees of impervious cover suggest the macrobenthic community may be a useful indicator of development in tidal creeks ecosystems. The differences observed when data from all three states were pooled was consistent with previous findings in South Carolina tidal creeks which illustrates that macrobenthic communities in tidal creeks may react to watershed development in similar patterns along the southeastern coast of the USA.     

Seasonal characteristics of haze observed by continuous visibility monitoring in the urban atmosphere of Kwangju, Korea

Continuous visibility monitoring has been carried out inKwangju, Korea since May 1999. The total light extinctioncoefficient b _ext measured by a transmissometer andreveals seasonal trends in urban visual air quality,especially under hazy conditions with a visual range of lessthan 15 km. Seasonal atmospheric visibility under lowrelative humidity during the winter was observed to be betterthan during any other seasons. Summertime visibility wasseverely degraded due to highly increased light scattering byhygroscopic particles under high humidity atmosphericconditions. Visibility during spring and fall was alsomoderate. However, yellow sand in spring caused the lowestvisibility conditions over the measurement area for a fewdays. With continuous monitoring using the transmissometer,the daily average seasonal visual range was measured to be13.1, 9.2, 11.0, and 13.9 km in spring, summer, falland winter, respectively. Under the atmospheric humiditycondition less than 60%, visual range was observed tobe 16.1, 13.9, 15.1, and 16.6 km in spring, summer,fall, and winter, respectively. The mean light extinctionbudget by sulfate and nitrate aerosols was determined to bethe highest value of 63.71% during the summer and thelowest value of 27.08% during spring. During the `yellow sand dust' period, a mean light extinction budget by soil particles was estimated to be at an unusually high value of 44.22%.     

The response of hydrophobic organics and potential toxicity in streams to urbanization of watersheds in six metropolitan areas of the United States

Semipermeable membrane devices (SPMDs) were deployed in streams along a gradient of urban land-use intensity in and around six metropolitan areas: Atlanta, Georgia; Raleigh-Durham, North Carolina; and Denver-Fort Collins, Colorado, in 2003; and Dallas-Fort Worth, Texas; Milwaukee-Green Bay, Wisconsin; and Portland, Oregon, in 2004 to examine relations between percent urban land cover in watersheds and the occurrence, concentrations, and potential toxicity of hydrophobic compounds. Of the 142 endpoints measured in SPMD dialysates, 30 were significantly (alpha = 0.05) related to the percent of urban land cover in the watersheds in at least one metropolitan area. These 30 endpoints included the aggregated measures of the total number of compounds detected and relative toxicity (Microtox(R) and P450RGS assays), in addition to the concentrations of 27 individual hydrophobic compounds. The number of compounds detected, P450RGS assay values, and the concentrations of pyrogenic polycyclic aromatic hydrocarbons (PAHs) were significantly related to percent urban land cover in all six metropolitan areas. Pentachloroanisole, the most frequently detected compound, was significantly related to urban land cover in all metropolitan areas except Dallas-Fort Worth. Petrogenic PAHs and dibenzofurans were positively related to percent urban land cover in Atlanta, Raleigh-Durham, Denver, and Milwaukee-Green Bay. Results for other endpoints were much more variable. The number of endpoints significantly related to urban land cover ranged from 6 in Portland to 21 Raleigh-Durham. Based on differences in the number and suite of endpoints related to urban intensity, these results provide evidence of differences in factors governing source strength, transport, and/or fate of hydrophobic compounds in the six metropolitan areas studied. The most consistent and significant results were that bioavailable, aryl hydrocarbon receptor agonists increase in streams as basins become urbanized. Potential toxicity mediated by this metabolic pathway is indicated as an important factor in the response of aquatic biota to urbanization.     

Forest Health Monitoring in the United States: First Four Years

To address the need for more effective methods for evaluating and assessing forest ecosystem health, the USDA-Forest Service and the US Environmental Protection Agency through its Environmental Monitoring and Assessment Program developed the Forest Health Monitoring program. The program was initiated in 1990 and by 1994 was present in the major areas of the United States. This paper presents an overview of the program, the indicators and methods developed for the program, and some of the results after four years of monitoring and research.     

Government policy influences on rangeland conditions in the United States: A case example

Since the early 1970s the Bureau of Land Management (BLM) and the Forest Service have emphasized the monitoring approach in managing their rangelands. After a 5-year period of intensive monitoring, stocking rate and other management actions are typically adjusted, depending on whether a definite downward or upward trend in range condition is observed. Examining the Afton Allotment on BLM land in southcentral New Mexico, we demonstrate serious flaws in the monitoring approach and other BLM grazing policies. Monitoring reflects past management but does not consider the future. Perverse incentives for permittees to maximize permit value rather than sustain the forage base still remain in place. The Range Reform '94 proposals by the U.S. Department of the Interior do not address these incentives and other flaws in public land policy. We would reform federal grazing land policy by coupling grazing fees to grazing intensity. Ranchers choosing conservative sustainable grazing intensities would pay low fees, whereas those choosing heavy grazing intensities would be charged higher rates. We would also implement other reforms: making livestock grazing permits transferable to other uses, discontinuing subsidies, eliminating restrictions on nonuse, offering incentives for public land investment, and establishing a biodiversity fund.This paper was supported by the New Mexico Agricultural Experiment Station, Las Cruces and was part of project 1-5-27417.     

Results from the NOAA National Status and Trends Program on distribution and effects of chemical contamination in the coastal and estuarine United States

The NOAA National Status and Trends (NS&T) Program has been monitoring chemical contamination in fish livers, and surface sediments since 1984 and in molluscan tissue and sediments since 1986. Data from fine-grained sediment at 175 sites are used to describe the spatial distribution of contamination throughout the coastal and estuarine United States. Highest levels are generally found in, and considered representative of, urban areas. It should be noted, however, that these levels are not as high as have been found near discharge pipes or in isolated industrial areas through other monitoring efforts. Dramatic biological responses, such as liver tumors in fish or apparently toxic contaminant levels in sediment, are found infrequently. Subtle biological changes, especially those that affect reproductive ability, are being sought. Data from three annual collections of mollusks have been used to identify early signals of temporal trends in contamination at NS&T sites.     

Atmospheric deposition of polybrominated dibenzo-p-dioxins and dibenzofurans in Guangzhou, China: seasonal variations and sources

The atmospheric deposition of polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) was investigated at four locations in different suburban and urban functional districts of Guangzhou City. The annual deposition fluxes of total PBDD/Fs (eight 2,3,7,8-substituted tetra- to hexa-BDD/Fs) were in the range of 36-51 (mean 46) pg m(-2) day(-1), and the corresponding TEQ fluxes were estimated to range between 7.9 and 11.3 (mean 10.3) pg I-TEQ m(-2) day(-1), indicating a noticeable pollution level. The deposition fluxes of PBDD/Fs during the wet season were 2-4 times as high as those during the dry season. Both rainfall and temperature positively correlated with PBDD/F deposition fluxes. Ambient gas/particle partition coefficients (K(p)) were predicted with SPARC. It appears seasonal variations of PBDD/F deposition fluxes were influenced by meteorological parameters and the local usage of brominated flame retardants (BFRs). The congener profiles of PBDD/Fs at four locations were similar either spatially or temporally, indicating that the main PBDD/F emission sources were similar to one another. Seasonal variations and congener patterns of PBDD/Fs indicated the possible sources included electronic waste recycling, industrial waste incinerators and products containing BFRs.     

Summer time haze characteristics of the urban atmosphere of Gwangju and the rural atmosphere of Anmyon, Korea

An extensive visibility monitoring was carried out simultaneously in the urban area of Gwangju and the rural area of Anmyon, Korea. This study examines patterns of visibility impairment and haze-forming pollutant concentrations on both sites resulting from natural and anthropogenic sources of gases and particles. Optical visibility measurements by a transmissometer, a nephelometer and an aethalometer provide aerosol light extinction, scattering, and absorption coefficients for both sites. In order to investigate the physico-chemical characteristics of atmospheric aerosols, aerosol samples were collected by various aerosol samplers at GJVMS (Gwangju Visibility Monitoring Station) and at KGAWO (Korea Global Atmosphere Watch Observatory), respectively. In addition, haze characteristics causing visibility impairment at those two sites were analyzed to obtain source contributions by regionally transported aerosols using grid analysis and display system (GrADS) from NECP reanalysis data. During the intensive monitoring period, ammonium sulfate was dominantly responsible for the fine particle mass loading at GJVMS, whereas organic carbon was the largest contributor at KGAWO. Light scattering by particles accounted for 52.8 to 81.3% of the range at the urban site, GJVMS and for 72.1 to 94.2% of the range at the rural site, KGAWO. Light absorption by the EC and NO₂ was between 14.5 and 34.8% at GJVMS, which was higher than the observed 1.1 ∼ 6.8% at KGAWO, respectively. Light scattering by aerosol was higher in the rural area than in the urban area. And organic carbon concentration was observed to be significantly higher than the concentration of elemental carbon at KGAWO. These haze-forming carbonaceous particles originate from anthropogenic pollutants at the urban atmosphere but they can be produced by natural environments such as marine and forest at the rural atmosphere.     

The Environmental Implications of Soil Erosion in the United States

Soil erosion has both on-farm and off-farm impacts. Reductionof soil depth can impair the lands productivity, and thetransport of sediments can degrade streams, lakes, and estuaries. Since 1933, soil conservation policies have existedin the United States. Originally they focused on the on-farmbenefits of keeping soil on the land and increasing net farmincome. Beginning in the 1980s, however, policy goalsincreasingly included reductions in off-site impacts of erosion.As a consequence of conservation efforts associated withexplicit U.S. government policies, total soil erosion between1982 and 1992 was reduced by 32% and the sheet and rillerosion rate fell from an average of 4.1 tons per acre per yearin 1982 to 3.1 tons per acre in 1992 while the wind erosion ratefell from an average of 3.3 tons per acre per year to 2.4 tonsper acre per year over the same period. Still, soil erosion isimposing substantial social costs. These costs are estimated tobe about $37.6 billion annually. To further reduce soil erosionand thereby mitigate its social costs, there are a number ofpolicy options available to induce farmers to adopt conservationpractices including education and technical assistance, financial assistance, research and development, land retirement, andregulation and taxes.     

Passive ammonia monitoring in the United States: comparing three different sampling devices

The need for ambient gaseous ammonia (NH(3)) measurements has increased in the last decade as reactive NH(3) concentrations and deposition fluxes show little change even with tightening standards on nitrogen oxides (NO(x)) emissions. Currently, there are several networks developing methods for adding NH(3) measurements in the U.S. Gaseous NH(3) measurements will provide scientists and policymakers data which can be used to estimate ecosystem inputs, validate air quality models including trends and regional variability, and evaluate changes to the environment based on additional emission reduction requirements and estimates of critical nitrogen load exceedances. The passive samplers described in this paper were deployed in duplicate or triplicate and collocated with annular denuders or continuous instruments to determine their accuracy. The samplers assessed included the Adapted Low-Cost Passive High Absorption (ALPHA), Radiello(?), and Ogawa passive samplers. The median relative percent differences (MRPD) between the reference method and passive samplers for the ALPHA, Radiello(?) and Ogawa were -2.4%, -37% and -44%, respectively. The precision between duplicate samplers for the ALPHA and Ogawa samplers, was 7% and 6%, respectively. Triplicate Radiello(?) precision was assessed using the coefficient of variation (CV). The CV for the Radiello(?) samplers was 10%. This article discusses the statistical results from these studies.     

美国空气质量监测的经验与启示

2013年9月10日,国务院发布《大气污染防治行动计划》,为当前和今后一个时期全国大气污染防治工作提供行动指南。近年来,中国空气质量监测工作发展迅猛,但新的空气质量管理目标对空气质量监测水平提出了更高的要求。为了加强中国空气质量监测能力,文章总结了美国空气质量监测四十多年的发展历程,介绍了美国系统谋划监测战略、合理布设监测网络、严格控制数据质量、开展污染组分分析、科学应用监测结果、积极推动公众参与等方面的经验,为中国发展和完善空气质量监测体系提供参考,为切实改善空气质量提供技术支持。     

State of the Estuaries in the Mid-Atlantic Region of the United States

The U.S. EPA has prepared a State of the Region Report for Mid-Atlantic Estuaries to increase knowledge of environmental condition for improved environmental management. Sources of information included the National Estuary Programs, the Chesapeake Bay Program, the state monitoring programs in Delaware, Maryland, and Virginia, Federal programs such as National Status & Trends, National Shellfish Register, National Wetlands Inventory, the Environmental Monitoring and Assessment Program, and other primary literature sources. The state of the estuarine environment was summarized using indicators for water and sediment quality, habitat change, condition of living resources, and aesthetic quality. Each indicator was briefly discussed relative to its importance in understanding estuarine condition. Wherever possible, data from multiple programs were used to depict condition. Finally, an overall evaluation of estuarine condition in the region was determined. The usefulness of monitoring programs that collect consistent information with a well-defined sampling design cannot be overemphasized.     

美国光化学污染监测的经验与启示

针对光化学污染的严峻形势,中国应尽快建立国家层面的光化学监测网络,完善光化学监测的技术体系与质量管理体系,为重点地区光化学污染防治工作提供监测数据支持。研究在总结美国光化学评估监测网络发展历程、运行及其监测目标、技术体系和质量管理体系的基础上,提出了明确光化学监测目标、制定优先监测VOCs名单、完善光化学监测技术体系和质量管理体系、建立光化学监测数据共享平台以及开展VOCs源解析等建设中国光化学监测网络的具体建议。     

The occurrence of acid precipitation on the west coast of the United States

Compilation of published and unpublished data shows acid precipitation to be more widespread in the Pacific coastal states than is generally recognized. Although information is scattered and discontinuous, precipitation is definitely acidic in the Los Angeles Basin and north-central california, and in the Puget Sound region in Washington. Acid rain occurrences have been observed in western and eastern Oregon, but data are inadequate for regional generalization. New stations currently being established in Washington and Oregon, largely in resposnse to the recently renewed activity of Mount St. Helens, will greatly facilitate assessment of precipitation acidity in the Northwest.     

基于激光雷达走航车的大气污染物探测技术及其应用

大气气溶胶对人体健康环境和全球气候都有一定的影响,是大气污染的主要来源。为了提升空气质量,大气污染防治刻不容缓。把气溶胶探测激光雷达和测风激光雷达集成在车辆上,进行走航和扫描探测可获得立体的大气气溶胶时空变化状态图。以合肥和芜湖等地大气气溶胶探测为例,基于激光雷达走航车的探测数据,获得大气气溶胶消光系数时空分布图,搜寻污染物排放源和估算颗粒物的PM_2.5输送通量。由此可知,激光雷达走航式探测技术是获得大气污染立体图像便捷的、有效的方法,可为大气污染防治提供精准的科学依据,具有重要的应用价值。     

Policy roots of land degradation in the arid region of the United States: An overview

The roots of land degradation in the arid region of the United States are set firmly in the era of open range conditions that led to the depletion of rangeland resources in the late 19th and early 20th centuries. Upon closure of the open range and establishment of the U.S. Forest Service and the Bureau of Land Management, public lands in the arid region were protected from the classic tragedy of the commons. Private lands, in turn, fell under the stewardship guidance of such organizations as the Soil Conservation Service, the Agricultural Stabilization and Conservation Service, and the Cooperative Extension Service. Despite these institutional protections, arid land degradation continues at an ecologically and socially unacceptable rate. The most likely explanation for this degradation resides in the institutions and public policies that shape and control livestock grazing. Flaws and disincentives endemic to the grazing permit system have encouraged destructive grazing. Federal subsidies to public- and private-land ranchers have encouraged rangeland stocking rates in excess of carrying capacity on economically and ecologically marginal lands and consistently favored unsound land management practices over superior ones. Policy-generated distortions of market forces have lead to unanticipated and environmentally undesirable land use outcomes. Land management, technical support, and educational institutions have also inadvertently contributed to land degradation in the arid region. Reversing the trend of land degradation in an advanced country like the United States demands that we understand the role of public policy in land use outcomes and that we structure future public policies in accordance with the lessons of recent history.     

Statistical Issues for Monitoring Ecological and Natural Resources in the United States

The United States funds a number of national monitoring programs to measure the status and trends of ecological and natural resources. Each of these programs has a unique focus; the scientific objectives are different as are the sample designs. However, individuals and committees, all well aware of the cost of ecological monitoring, have called for more effective monitoring programs. The objective of this paper is to summarize existing programs' statistical designs and discuss potential alternatives for improvement in national monitoring. Can we improve the current situation by providing an overall framework for the design or analysis of data from these disparate surveys? First, the paper summarizes the objectives of these surveys, compares and contrasts their survey designs as currently implemented, and determines what variables they collect. Through this process we identify commonalities and issues that impact our ability to combine information across one or more of the surveys. Three potential alternatives are presented, leading to comprehensive monitoring in the United States.     

中美环境监测体制之比较

对中美环境监测体制进行对比性评述,指出了中国环境监测行业存在的分析标准滞后、体制不完善、人员匮乏等问题,提出借鉴美国经验,完善法律体系,引入市场机制,逐步培育竞争有序、监管到位的环境监测行业的建议。