Evaluation of spatial and temporal variation in Karun River water quality during five decades (1968–2014)

In the present study, the multivariate statistical technique cluster analysis (CA) is used to evaluate the spatial and temporal variations in the water quality data for the Karun River, which was gathered during 46 years of monitoring (from 1968 to 2014). The data recorded electrical conductivity (EC) in the river at six water monitoring stations along its course. The mean of EC was 972.05 ± 365.466 micromhos per centimeter (μmhos/cm) at the most upstream station and showed an increase to 1458.41 ± 675.048 μmhos/cm at the most downstream of the stations. By using hierarchical CA, the six sampling stations were grouped into three clusters of similar characteristics, which may be a result of different land uses in proximity to the stations. Furthermore, two‐way analysis of variance showed that EC had a significant correlation (p < 0.001) with the season, and the mean of the pollution depended on the level of the cluster and the season (spring, summer, autumn, and winter).     

Climatic Controls on Watershed Reference Evapotranspiration Varied during 1961–2012 in Southern China

Reference evapotranspiration (ET_o) is an important hydrometeorological term widely used in understanding and projecting the hydrological effects of future climate and land use change. We conducted a case study in the Qinhuai River Basin that is dominated by a humid subtropical climate and mixed land uses in southern China. Long‐term (1961–2012) meteorological data were used to estimate ET_o by the FAO‐56 Penman–Monteith model. The individual contribution from each meteorological variable to the trend of ET_o was quantified. We found basin‐wide annual ET_o decreased significantly (p < 0.05) by 3.82 mm/yr during 1961–1987, due to decreased wind speed, solar radiation, vapor pressure deficit (VPD), and increased relative humidity (RH). However, due to the increased VPD and decreased RH, the ET_o increased significantly (p < 0.05) in spring, autumn, and annually at a rate of 2.55, 0.56, and 3.16 mm/yr during 1988–2012, respectively. The aerodynamic term was a dominant factor controlling ET_o variation in both two periods. We concluded the key climatic controls on ET_o have shifted as a result of global climate change during 1961–2012. The atmospheric demand, instead of air temperature alone, was a major control on ET_o. Models for accurately predicting ET_o and hydrological change under a changing climate must include VPD in the study region. The shifts of climatic control on the hydrological cycles should be considered in future water resource management in humid regions.     

2014~2016年成都地区空气污染气象要素分型研究

为研究成都地区发生不同程度空气污染时,地面气象要素的搭配类型特征,基于成都地区2014~2016年多个逐日气象要素值(气温、气压、湿度等)和逐日AQI资料,对2014~2016年成都地区空气质量状况进行特征分析,并且通过TSI天气分型方法,并结合同期逐日空气质量资料探讨了四季不同天气类型下空气质量特征,主要结果为:(1)2014~2016年成都市总体空气质量夏秋季空气质量最佳,春季次之,冬季最差。(2)不同天气类型空气质量状况差异较大。春季3型和4型容易发生轻度污染;夏季1型和4型容易发生轻度污染;秋季3型容易出现轻度污染;冬季4型和5型天气下容易发生轻度污染以上的空气污染状况。研究为成都地区空气污染气象研究提供参考依据,也为空气污染预报提供一些借鉴意义。     

Municipal solid waste production and composition in Finland—Changes in the period 1960–2002 and prospects until 2020

Waste reduction was recognised as the main goal of waste management policy in the EU in the 1990s. Although knowledge of past waste generation is essential for effective waste reduction policy there are no comprehensive statistics on the past development of municipal solid waste (MSW) production. MSW management is currently under turmoil in many EU countries as the requirements of the EC landfill directive (1999/31/EC) are set into force. In this study, the production and composition of MSW in Finland between 1960 and 2002 is presented using historical data. The impact of population, affluence and technology on MSW production are analysed using the IPAT equation and three scenarios are constructed until year 2020. The results are compared with national future targets on MSW production. Production of MSW increased in Finland until 1990, declined to year 1997, increased to 2000 and then declined again. The share of organic and plastic waste increased over the study period while the share of paper and cardboard declined. The results suggest that so far national targets on MSW reduction have been set fairly low. Moreover, our scenarios depict a wide range of future MSW production, even though the time horizon is not longer than 15 years into the future. In order to narrow this range, continuous improvement of the statistics of MSW is essential.     

Effect of Light on Biodegradation of Estrone, 17β‐Estradiol,and 17α‐Ethinylestradiol in Stream Sediment

Biodegradation of [A‐ring ¹⁴C] Estrone (E1), 17β‐estradiol (E2), and 17α‐ethinylestradiol (EE2) to ¹⁴CO₂ was investigated under light and dark conditions in microcosms containing epilithon or sediment collected from Boulder Creek, Colorado. Mineralization of the estrogen A‐ring was observed in all sediment treatments, but not epilithon treatments. No difference in net mineralization between light and dark treatments was observed for ¹⁴C‐E2. Net mineralization of ¹⁴C‐E1 and ¹⁴C‐EE2 was enhanced in light treatments. Extents of ¹⁴CO₂ accumulation and rates of mineralization were significantly greater for E2 than E1 under dark conditions, but were comparable under light conditions. These results indicate substantial differences in the uptake and metabolism of E1 and E2 in the environment and suggest biorecalcitrance of E1 relative to E2 in light‐limited environments. The extent of ¹⁴CO₂ accumulation and rate of mineralization for EE2 in dark treatments were less than half of that observed for E2 and generally lower than for E1, consistent with previous reports of EE2 biorecalcitrance. However, ¹⁴CO₂ accumulation and rates of mineralization were comparable for EE2, E2, and E1 under light conditions. These results indicate photoactivation and/or phototransformation/photodegradation processes can substantially enhance heterotrophic biodegradation of estrogens in sunlit environments and may play an important role in estrogen transport and attenuation.     

Assessment of the Extreme Rainfall Event at Nashville,TN and the Surrounding Region on May 1–3, 2010

This paper analyzes the May 1–3, 2010 rainfall event that affected the south‐central United States, including parts of Mississippi, Tennessee, and Kentucky. The storm is evaluated in terms of its synoptic setting, along with the temporal distributions, and spatial patterns of the rainfall. In addition, the recurrence interval of the storm is assessed and the implications for hydrologic structure designs are discussed. The event was associated with an upper‐level trough and stationary frontal boundary to the west of the rainfall region, which remained quasi‐stationary for a period of 48 h. Heavy rainfall was produced by two slow‐moving mesoscale convective complexes, combined with abundant atmospheric moisture. Storm totals exceeding 330 mm occurred within a large elongated area extending from Memphis to Nashville. Isolated rainfall totals over 480 mm were reported in some areas, with NEXRAD weather radar rainfall estimates up to 501 mm. An extreme value analysis was performed for one‐ and two‐day rainfall totals at Nashville and Brownsville, Tennessee, as well as for gridded rainfall estimates for the entire region using the Storm Precipitation Analysis System. Results suggest maximum rainfall totals for some durations during the May 1–3, 2010 event exceeded the 1,000‐year rainfall values from National Oceanic and Atmospheric Administration Atlas 14 for a large portion of the region and reached up to 80% of the probable maximum precipitation values for some area sizes and durations.     

Spatiotemporal Variability of Snow Depletion Curves Derived from SNODAS for the Conterminous United States, 2004‐2013

Assessment of water resources at a national scale is critical for understanding their vulnerability to future change in policy and climate. Representation of the spatiotemporal variability in snowmelt processes in continental‐scale hydrologic models is critical for assessment of water resource response to continued climate change. Continental‐extent hydrologic models such as the U.S. Geological Survey National Hydrologic Model (NHM) represent snowmelt processes through the application of snow depletion curves (SDCs). SDCs relate normalized snow water equivalent (SWE) to normalized snow covered area (SCA) over a snowmelt season for a given modeling unit. SDCs were derived using output from the operational Snow Data Assimilation System (SNODAS) snow model as daily 1‐km gridded SWE over the conterminous United States. Daily SNODAS output were aggregated to a predefined watershed‐scale geospatial fabric and used to also calculate SCA from October 1, 2004 to September 30, 2013. The spatiotemporal variability in SNODAS output at the watershed scale was evaluated through the spatial distribution of the median and standard deviation for the time period. Representative SDCs for each watershed‐scale modeling unit over the conterminous United States (n = 54,104) were selected using a consistent methodology and used to create categories of snowmelt based on SDC shape. The relation of SDC categories to the topographic and climatic variables allow for national‐scale categorization of snowmelt processes.     

Effects of Land‐Use and Land‐Cover Change on Evapotranspiration and Water Yield in China During 1900‐20001

Abstract: China has experienced a rapid land‐use/cover change (LUCC) during the 20th Century, and this process is expected to continue in the future. How LUCC has affected water resources across China, however, remains uncertain due to the complexity of LUCC‐water interactions. In this study, we used an integrated Dynamic Land Ecosystem Model (DLEM) in conjunction with spatial data of LUCC to estimate the LUCC effects on the magnitude, spatial and temporal variations of evapotranspiration (ET), runoff, and water yield across China. Through comparisons of DLEM results with other model simulations, field observations, and river discharge data, we found that DLEM model can adequately catch the spatial and seasonal patterns of hydrological processes. Our simulation results demonstrate that LUCC led to substantial changes in ET, runoff, and water yield in most of the China’s river basins during the 20th Century. The temporal and spatial patterns varied significantly across China. The largest change occurred during the second half century when almost all of the river basins had a decreasing trend in ET and an increasing trend in water yield and runoff, in contrast to the inclinations of ET and declinations of water yield in major river basins, such as Pearl river basin, Yangtze river basin, and Yellow river basin during the first half century. The increased water yield and runoff indicated alleviated water deficiency in China in the late 20th Century, but the increased peak flow might make the runoff difficult to be held by reservoirs. The continuously increasing ET and decreasing water yield in Continental river basin, Southwest river basin, and Songhua and Liaohe river basin implied regional water deficiency. Our study in China indicates that deforestation averagely increased ET by 138 mm/year but decreased water yield by the same amount and that reforestation averagely decreased ET by 422 mm/year since most of deforested land was converted to paddy land or irrigated cropland. In China, cropland‐related land transformation is the dominant anthropogenic force affecting water resources during the 20th Century. On national average, cropland expansion was estimated to increase ET by 182 mm/year while cropland abandonment decreased ET by 379 mm/year. Our simulation results indicate that urban sprawl generally decreased ET and increased water yield. Cropland managements (fertilization and irrigation) significantly increased ET by 98 mm/year. To better understand LUCC effects on China’s water resources, it is needed to take into account the interactions of LUCC with other environmental changes such as climate and atmospheric composition.     

Evaluation of the temporal variations of air quality in Taipei City, Taiwan, from 1994 to 2003

Data collected from the five air-quality monitoring stations established by the Taiwan Environmental Protection Administration in Taipei City from 1994 to 2003 are analyzed to assess the temporal variations of air quality. Principal component analysis (PCA) is adopted to convert the original measuring pollutants into fewer independent components through linear combinations while still retaining the majority of the variance of the original data set. Two principal components (PCs) are retained together explaining 82.73% of the total variance. PC1, which represents primary pollutants such as CO, NO(x), and SO(2), shows an obvious decrease over the last 10 years. PC2, which represents secondary pollutants such as ozone, displays a yearly increase over the time period when a reduction of primary pollutants is obvious. In order to track down the control measures put forth by the authorities, 47 days of high PM(10) concentrations caused by transboundary transport have been eliminated in analyzing the long-term trend of PM(10) in Taipei City. The temporal variations over the past 10 years show that the moderate peak in O(3) demonstrates a significant upward trend even when the local primary pollutants have been well under control. Monthly variations of PC scores demonstrate that primary pollution is significant from January to April, while ozone increases from April to August. The results of the yearly variations of PC scores show that PM(10) has gradually shifted from a strong correlation with PC1 during the early years to become more related to PC2 in recent years. This implies that after a reduction of primary pollutants, the proportion of secondary aerosols in PM(10) may increase. Thus, reducing the precursor concentrations of secondary aerosols will be an effective way to lower PM(10) concentrations.     

甘肃民勤湖区水资源的合理利用

本文基于民勤湖区水资源贫乏、生态环境严重恶化的情况,提出了水资源合理分配利用的具罚函数 LP-DP 模型。模型解算结果表明,在维持一定粮食产量的条件下,发展林牧业可充分利用土地资源,提高经济效益,促进生态环境良性循环和可得到现有水资源的保证。     

Copper and copper alloys in the UK : Consumption and losses, 1920–1970

The authors consider consumption of copper in the UK using data from 1920 to 1970. They draw up an overall balance sheet which, it is hoped, provides a firm foundation on which to base the total availability of copper and against which could be balanced the scrap which was recycled.     

Trends in Pesticide Concentrations in Streamsof the Western United States, 1993‐20051

Johnson, Henry M., Joseph L. Domagalski, and Dina K. Saleh, 2010. Trends in Pesticide Concentrations in Streams of the Western United States, 1993‐2005. Journal of the American Water Resources Association (JAWRA) 00(0):1‐22. DOI: 10.1111/j.1752‐1688.2010.00507.x Abstract: Trends in pesticide concentrations for 15 streams in California, Oregon, Washington, and Idaho were determined for the organophosphate insecticides chlorpyrifos and diazinon and the herbicides atrazine, s‐ethyl diproplythiocarbamate (EPTC), metolachlor, simazine, and trifluralin. A parametric regression model was used to account for flow, seasonality, and antecedent hydrologic conditions and thereby estimate trends in pesticide concentrations in streams arising from changes in use amount and application method in their associated catchments. Decreasing trends most often were observed for diazinon, and reflect the shift to alternative pesticides by farmers, commercial applicators, and homeowners because of use restrictions and product cancelation. Consistent trends were observed for several herbicides, including upward trends in simazine at urban‐influenced sites from 2000 to 2005, and downward trends in atrazine and EPTC at agricultural sites from the mid‐1990s to 2005. The model provided additional information about pesticide occurrence and transport in the modeled streams. Two examples are presented and briefly discussed: (1) timing of peak concentrations for individual compounds varied greatly across this geographic gradient because of different application periods and the effects of local rain patterns, irrigation, and soil drainage and (2) reconstructions of continuous diazinon concentrations at sites in California are used to evaluate compliance with total maximum daily load targets.     

The profitability of the buffer stocks operated under the International Tin Agreements,1956–77

In this paper estimates are made of the profitability of the tin buffer stocks operated under the International Tin Agreements. The issue of buffer stock profitability is important because under UNCTAD's Common Fund proposals some funds will be raised from money or capital markets and commercially competitive rates of interest must be paid. If a buffer stock fails to be commercially profitable, these interest payments will have to be subsidized from governmental contributions or elsewhere. Although it does seem that the International Tin Agreements have been broadly self- financing, the limited influence that they have had on market price fluctuations still leaves open the question of their usefulness.