我国城市可持续发展能力的评价

应用社会、经济、资源、环境四大类系统的２４个指标，分别采用数理统计、加权迭加、系统聚类等数学分析方法，对我国３０个大城市的可持续发展能力进行了综合分析与评价，并且选用协调度与综合评价值双重指标对各类城市发展战备进行分类指导与科学决策。     

晋冀鲁豫接壤区“经济─环境”系统协调状态研究

本文用协调度中的发展协调度方法对晋冀鲁豫接壤区区域“经济──环境”系统的协调状态及调控进行了研究。在经济快速增长（GNP＞8％）的前提下，用2个权重相等的子系统，即生态环境质量综合评价值Sp和发展经济的投资环境综合评价值Tp所组成的协调度综合评价值Zp的计算值判断了该区域的“经济──环境”系统的协调状态为基本不协调状态，即随着经济的快速增长，生态环境有所恶化。从2个子系统的单项指标分析了生态环境有所恶化的原因并用环境经济学中的环境管理规划的基本原理从可持续发展的角度讨论了环境和经济发展的调控对策。     

上海市可持续交通指标体系的建立及评价方法研究

以城市交通的可持续发展为出发点，运用层次分析法（AHP），采用塔式结构，构成一个以目标层．系统层．状态层及要素层所组成的递阶层次结构的上海市可持续交通指标体系，包括48项指标。采用Expert Choice Model模型，通过应用层次分析法对各类指标进行权重的计算：利用隶属函数及线性加权法进行综合指数的计算，从而对城市交通可持续发展状况进行评价。根据综合指数的大小将交通可持续发展状况分为4个等级及相应的特征描述。对指标的选择及评价过程提出了一些问题和建议。     

城市可持续发展状况评价体系探讨

应用经济、社会、资源、环境四大类系统的24个指标,分别采用数理统计、加权迭加、系统聚类等数学分析方法,选取我国30个城市为样本,进行可持续发展状况的综合评价和分析,对城市可持续发展状况的评价体系进行探讨。     

生态示范区可持续发展指标体系的实例研究

本文以长沙市芙蓉区为研究对象,采用定性与定量分析相结合的方法,对城区可持续发展水平的综合评价进行了探讨.在运用主成分分析中,设计了评价城市可持续发展的两个综合评价系数:城市可持续发展指数和城市可持续发展协调系数.从资源、经济、社会、环境、体制管理发展的制约因素五个方面对芙蓉区可持续发展进行详细说明.     

重庆高新区可持续发展水平评价与对策研究

提出了建立重庆高新区可持续发展评价指标体系的6项基本原则，从经济高效、社会文明、环境舒适（ESE）3方面设计了包括3个高层指标、8个中层指标、45个单项指标的指标体系。采用特尔斐法、层次分析法和线性加权法，对评价指数进行了量化计算和整合，据此评价重庆高新区的可持续发展水平，并对照发展性质相似的苏州高新区、深圳高新区，指出重庆高新区在发展中存在的问题，并提出可持续发展的若干对策。     

区域可持续发展能力的AHP综合评价

从经济可持续、社会可持续和生态可持续三个角度出发,建立区域可持续发展评价的指标体系,根据山东省1996年、2000年及2004年可持续发展调查数据,建立多目标线性加权函数对该可持续发展体系进行了综合评价模型,运用层次分析法(AHP)计算评价体系中各单项指标、领域层及子系统层的评价权重,分析结果表明山东省的可持续发展呈现逐步上升的态势,但与建立"和谐山东"的发展目标仍存在很大差距.该评价模型原理简单,可操作性强,对于政府管理及宏观决策部门有一定的应用价值.     

工业园区清洁生产审核重点企业筛选方法

针对工业园区清洁生产审核方法学不完善问题,以工业园区清洁生产审核重点作为研究对象,构建了普适性强的园区审核重点企业筛选评价指标,该指标体系包括目标层1个指标,准则层7个指标和指标层36个指标,同时建立了综合评价模型:利用主客观组合赋权结合指标合成,对园区企业进行综合评价得分优劣排序,筛选得分低于均值的企业为园区清洁生产审核重点企业,建立指标贡献百分比数学模型,对审核重点企业进行清洁生产潜力挖掘,有针对性地提出清洁生产方案。并以东北某工业园区进行实际案例验证,在此基础上对方案实施后的园区进行环境和经济效益评估。该成果可为工业园区实施清洁生产提供参考。     

资源环境经济综合指数及其应用探讨

工业现代化的发展需要体现可持续发展的指导思想。文章综合考虑环境、资源和经济因素对产业结构的影响,采用环境污染类因子、资源消耗类因子和经济类因子构建资源环境经济综合指数模型,并对2013年中国工业产业结构合理性进行了评价。研究表明:1资源环境经济综合指数建模简单,可将各类影响因子纳入模型中。将该指数用于产业结构合理性评价,评价结果可靠。22013年中国工业各行业中,金属冶炼及压延加工业、电力、热力生产和供应业、造纸及纸制品业、石油加工业、化学原料和化学制品业等5个行业属于增长粗放型行业,应对其进行限制和约束,其余行业增长的集约化程度较高,应给予鼓励和支持。     

陕北能源重化工基地社会经济与环境协调发展研究——以榆林市为例

分析了陕北能源重化工基地社会经济与环境发展的矛盾，指出环境与社会经济的协调发展是实现可持续发展的前提和基础。文章分析了环境与社会经济协调发展的含义，建立了社会经济系统与环境系统评价的指标体系，采用主成分分析与回归分析相结合的综合评价方法，以榆林市为例，借助SPSS分析软件，对陕北能源重化工基地建设中的社会经济与环境协调发展进行定量评价。根据评价得出了榆林市社会经济系统与环境系统发展协调度不高的结论，并对其社会经济系统与环境系统协调发展状况进行了讨论，最后提出了实现两系统协调发展的建议。     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Removal of heavy metals from sewage sludge by low costing chemical method and recycling in agriculture

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