Optimization of biodiesel production from the waste cooking oil using response surface methodology

In this research, transesterification of the waste cooking oil has been studied. Response surface methodology (RSM) based on Box–Behnken design was used to investigate the effects of the main operating parameters, including the methanol to oil molar ratio, catalyst concentration, and reaction temperature, on the biodiesel yield. The results revealed that the catalyst concentration is the most important parameter. The maximum biodiesel yield under the optimized conditions was 99.38 wt.%. Thermogravimetric analysis (TGA) was used for the determination of biodiesel conversion and the results were compared with that of gas chromatography (GC) analysis, showing a very small difference. Furthermore, an empirical quadratic equation has been presented to show the relation between biodiesel conversion and product viscosity.     

Optimization of novel pyrazolium ionic liquid catalysts for transesterification of bitter apple oil

In the present study, 4 different functionalized pyrazoliums based on sulfoalkyl-pyrazolium hydrogensulfate and alkylsulfo-alakylpyrazolium hydrogensulfate were explored to catalyze biodiesel production from bitter apple oil (BAO). The results demonstrated that a longer chains catalyst of 2-(4-sulfobutyl) pyrazolium hydrogensulfate (SBPHSO₄) exhibited the highest catalytic activity, which is attributed to its strong acidity. The highest yield of esters was up to 89.5% when the reaction was carried out under the conditions of 5.2 wt% of SBPHSO₄, molar ratio of methanol to BAO of 15:1, 170 °C, and 800 rpm for 6 h. These results demonstrated that ionic liquids offer a promising new type of pyrazolium catalyst for biodiesel production. The use of clean ionic liquids in preparing clean biodiesel could solve the drawbacks associated with using the old conventional catalysts and might be employed as an efficient catalyst for such relevance.     

Studies on design of heterogeneous catalysts for biodiesel production

The production of biodiesel is gaining momentum with the ever increasing demand of the fuel. Presently, limited literature is available with respect to well designed solid heterogeneous catalyst for biodiesel production considering all the characteristics, process and operation parameters. Hence, a study was conducted to design effective heterogeneous catalyst for biodiesel production. Further, the significant impact of different catalysts, different feed stock, various reaction conditions such as temperature, methanol oil molar ratio, catalyst concentrations and stability/inactivation of the catalysts, are detailed out for transesterification process of biodiesel production. Based on the studies it can be concluded that well designed heterogeneous catalyst can yield high throughput of biodiesel.     

Performance evaluation of biodiesel from used domestic waste oils: A review

Global warming, high-energy demand and availability of new technologies are among the factors catalyzing the search for alternative sources of energy. Currently, there is renewed interest in obtaining energy from wastes hitherto meant for disposal. Increased costs of disposal and their attendant problems of heavy environmental loading are some aspects making the disposal option unattractive. These wastes are sources of energy and among the several sources of generating this energy are the waste-to-energy (WTE) categories with potentials for useable fuel production. The WTE materials are mainly used domestic waste oils (UDWOs), municipal solid waste (MSW), agricultural and industrial wastes. However, the latter wastes are not attractive as they consist of innumerable hazardous contaminants. The UDWOs are arguably a safe and cost effective source of useable fuel. Their conversion offers the merits of a reduction in greenhouse gas emission (GHG), enhancing fuel diversification and a qualitatively comparable energy output to fossil diesel fuels. Thus, UDWOs could significantly contribute towards achieving the 2020 and 2030 goals of substituting approximately 20% and 30% of petro-diesel with biofuels in US and EU, respectively. Moreover, attaining the forecasted annual production rate of 227 billion liters of biofuel by most active stakeholders in the biodiesel industry could be easily achieved.This review aims to analyze the performance of biodiesel fuels obtained from UDWO and to demonstrate the suitability of applying these fuels as substitutes to mineral diesel in various industries. Benefits of UDWO as a biodiesel feedstock were as well highlighted.     

Biodiesel production from waste oil feedstocks by solid acid catalysis

Biodiesel is a non-toxic and biodegradable substitute for petroleum-based diesel. However, it is impractical to use refined edible oils to produce biodiesel due to its high cost and priority for food products, especially in China, while waste oils with high free fatty acids (FFAs) can be considered as the raw materials. In the present work, a solid acid catalyst comprising SO₄²⁻/TiO₂–SiO₂ was prepared, characterized and studied for its activity for the production of biodiesel from several low cost feedstocks with high FFAs. The solid acid catalyst can be recycled, easily removed and can simultaneously catalyze esterification and transesterification. The influence of reaction parameters was studied, and the optimized reaction parameters are reaction temperature 200 °C, molar ratio of methanol to oil 9:1 and catalyst concentration 3 wt.%. The catalyst showed good stability. A continuous process for biodiesel production from cheap raw feedstocks was proposed, and a 10,000-tonnes/year biodiesel production demonstration plant has been built.     

Improving the sustainability of the production of biodiesel from oilseed rape in the UK

Owing to concerns about energy security and because of increased environmental awareness, the biofuel industry is expanding worldwide. It is therefore extremely important to be able to quantify the sustainability of biofuels in order to determine their benefits over using conventional fossil fuel derived transport fuels. This study investigates the total energy requirement and global warming potential (GWP) of the production of biodiesel from oilseed rape in the UK, using life cycle analyses. Large- and small-scale productions are compared and the sensitivity of these environmental impacts to production variables investigated. Possible changes to the processes are considered, with a view to reduce the energy requirement and global warming potential.This research shows that the scale of the production of biodiesel from oilseed rape in the UK, and the transport involved in the various stages of manufacture, has little effect on its global warming potential. It is also shown that if the rape meal and glycerol were combusted in combined heat and power plants, and the rate of application of nitrogenous fertiliser were reduced from 211 kg/ha to 100 kg/ha, the energy requirement and global warming potential savings from using biodiesel rather than ultra low sulphur diesel would increase dramatically, to 170% and 120%, respectively, on a basis of equivalent net energy content.     

某采油队推行HSE管理的经验

通过对采油 12队 (HSE)管理体系进行调查 ,总结、分析了该队在推行HSE管理体系中的一些成功做法和存在问题 ,为其他油气生产单位的生产经营提供了良好借鉴     

火炸药废水处理技术综述

火炸药废水问题已经成为世界性的环境污染问题.火炸药废水的处理技术主要包括物理技术、化学技术、生物技术以及各类技术的综合应用.根据国内外文献报道对各类技术进行了分类整理,分析了各类技术的优缺点及应用现状,推论出多种技术联合应用将是火炸药废水处理技术的发展趋势,并提出具体方案,为火炸药废水处理工艺的选择提供一定参考依据.     

Integration of safety instrumented system with automated HAZOP analysis: An application for continuous biodiesel production

Integration of a human-machine interface (HMI) with hazard and operability (HAZOP) analysis is proposed in this work. This concept can potentially lead to the identification of some unexpected deviations, and radically decreases the time necessary for hazard identification. A continuous biodiesel production was simulated. This can be divided into two cases, covering both conventional and reactive distillation. Soybean oil (trioleic, trilinoleic and tripalmitic) at 1000 kg/h as raw material is converted to 99 wt% pure biodiesel. The HMI was designed to improve these processes by combining automatic HAZOP analysis. With this approach, users can receive sufficient information from the simulation to analyze the optimum operation and safety. Severity levels are also provided to classify the actions in the process. Severity levels 1 and 2 are concerned with operating conditions, which are 58-64 °C, and 50-150 kPa. If the analysis shows severity level 3, the safety instrumented system (SIS) will automatically manage the operation in order to reduce/restrain the amount of damage at this level. This proposed system could minimize the damage and also improve the overall quality of the process.     

A summary of the available technologies for biodiesel production based on a comparison of different feedstock's properties

Biodiesel production is mainly done by carrying on the transesterification reaction while using refined oil, methanol and a homogeneous base catalyst. When using refined oil, a competition between oil for food and oil for fuel is then presented. Even more, the conventional technology has the disadvantage that the raw material has to be very pure, with no traces of other impurities. Otherwise, undesirable products will be produced decreasing the productivity of the process and making a large amount of waste treatment.Because of this, other technologies appear as possible sources for biodiesel production, mainly from refined oil, but also allowing less pure raw material to be used, such as waste oil, frying oil, soapstocks, and animal fats.In this work, a comparison of all these different raw materials, their physicochemical properties and how they can have an influence, and the magnitude of this phenomenon, in the biodiesel production will be presented and compared. Based on the previous analysis, a short summary of the technological possibilities to produce good quality biodiesel from low price raw material will be discussed with the aim of showing their advantages and disadvantages when using different feedstocks.     

采油矿场安全多功能采暖炉的研究

介绍了采油矿场安全多功能采暖炉的原理和主要技术参数，叙述了安装和安全操作及注意事项，分析了推广应用前景。     

采油队安全巡视管理系统的试验与应用

介绍了采油队安全生产巡视管理系统的组成、系统配置与工作过程，叙述了试验与应用情况，分析了其经济效益和社会效益与推广应用前景。     

Optimization of gas detector placement considering scenario probability and detector reliability in oil refinery installation

Gas detection system is a critical layer of protection in process safety. Leak scenario probability and detector reliability are two key factors in the optimization of gas detector placement. However, they are easily neglected in previous studies, which may lead to an inaccurate evaluation of the optimization solutions. In this study, a stochastic programming (SP) optimization method is proposed considering these two factors. In order to quantitatively represent the probability of leak scenarios, a complete accident scenario set (CASS) is built combining leak sources and wind fields. Then, the computational fluid dynamics (CFD) method is adopted for consequence modeling of gas dispersion. The Markov model is developed to predict the detector reliability. With the objective of minimal cumulative detection time (MCDT), the SP formulation considering scenario probability and detector reliability (MCDT-SPR) is proposed. By introducing the particle swarm optimization (PSO) algorithm, the optimization formulations can be solved. A case study is investigated on a diesel hydrogenation refining unit. Results validate this approach is promising to improve the detection efficiency. This method is more practical and matching with the actual industrial environment, where the leak scenarios and the detector reliability can change dynamically in real process setting.     

浅谈油气田生产企业职业病危害防治体系的建立

采油采气过程中普遍存在噪声、毒物等职业病危害因素,对员工的健康安全具有很大的危害,也是造成职业病的根源。本文详细阐述了石油上游企业存在的职业病危害现状,分析了建立职业健康监管体系的方法,并对职业病防治措施进行了研究。     

PTG测定油脂与高压氧气的反应

介绍说明几起氧气瓶内附油脂充氧过程中爆炸事故。介绍高压氧气与油脂的反应,论述了空压机润滑油燃烧基本特性,采用热重天平进行了空压机润滑油在不同压力的气体氛围内的燃烧试验,建立起空压机润滑油的热重和微商热重曲线,得到空压机润滑油在不同压力的氧气氛围内的自燃点。放入加压热重分析仪内的润滑油,接触高压氧气后迅速被氧化,氧气压力越高,氧化程度越深。随着氧气压力的升高,润滑油的着火点降低。这表明氧气瓶中油脂,随着充氧压力的增加,着火点降低,即压力越大,油脂越容易自燃,释放热量,导致爆炸。提出安全措施。     

最优指标法在环境监测优化布点中的应用

采用最优指标法对郑州市17个大气环境采样点的监测数据进行优选,得到的优化点位基本能反映城市空气质量的总体情况,可以达到环境监测优化布点的目的.     

An integrated framework of safety performance evaluation for oil and gas production plants: Application to a petroleum transportation station

Safety performance evaluation is a significant way to ensure the safety of oil and gas production plants. Various evaluation methods have been proposed to make safety evaluation more consistent and scientific. However, a major concern is that many existing safety evaluation measurements are still subjective and are not easy to obtain in a uniform way, which can be attributed to the challenges that process plants faced such as people having different knowledge levels, equipment with dispersed locations and management with many processes. This paper aims to display the impact of risk factors on system safety level in a succinct and visual way that may be expected to overcome subjective opinions from experts and provide a more pertinent and practical safety strategies. To this end, an integrated framework is developed, which considers crucial risk factors from pipeline, static equipment, dynamic equipment and management. First, Fault tree analysis (FTA) is used to explicitly determine the crucial r risk factors. Then, a novel fuzzy cognitive map cooperating with relative degree analysis model (FCM-RDA) is proposed to deal with the weigh distribution opinions. Finally, considering the oil and gas production process is a complex system, a fuzzy comprehensive evaluation (FCE) is employed to calculate the overall safety level.     

Graduate recruitment in Britain: A survey of selection methods used by organizations

This investigation consisted of a questionnaire survey of the graduate selection methods used by 536 organizations in the U.K. The use of application forms for pre-selection purposes was widespread, although only a minority of organizations appeared to have approached this task in a systematic way. While references were also widely used, they were often taken up very late in the selection process, and only a minority of organizations sought specific information about job related abilities from referees. Interviews were universally used, both on their own, and as a component of an assessment centre. A total of 44 per cent of organizations used assessment centres as part of graduate recruitment. For most of those organizations using assessment centres, the interview was reported as being the most important component of the centre in determining final selection decisions. Most organizations provided some training for their selectors but this was typically general in nature, rather than being specific to graduate recruitment. The results are discussed in terms of their implications, both for practical application, and for future research.     

基于FLACS CFD的不同气油比油气混输管道泄漏火灾后果对比

不同气油比的油气混输管道泄漏后果危害形式和风险差异的准确判断对于管道泄漏应急处置至关重要。以中国西部某油田集输管道为研究对象,针对不同气油比管道泄漏的火灾危害进行了对比分析,构建了FLACS CFD模型,并研究了油气混输管道原油泄漏形成池火的火灾特征和影响范围,以及天然气泄漏形成喷射火的高温分布和影响规律。研究结果表明:应急处置应考虑不同气油比下池火与喷射火危害的差异。在油气混输管线泄漏10 min形成稳定火焰的场景中,气油比低于100 m3/t时,原油池火为火灾危险的主要影响因素;气油比高于200 m3/t时,天然气喷射火为主要影响因素;气油比超过250 m3/t,高温覆盖距离不再明显增加;40 m为此场景下混输油气泄漏喷射火致死距离上限,120 m为温度影响上限。     

Anaerobic co-digestion of fat,oil, and grease (FOG): A review of gas production and process limitations

The addition of readily available high strength organic wastes such as fats, oils, and grease (FOG) from restaurant grease abatement devices may substantially increase biogas production from anaerobic digesters at wastewater treatment facilities. This FOG addition may provide greater economic incentives for the use of excess biogas to generate electricity, thermal, or mechanical energy. Co-digestion of FOG with municipal biosolids at a rate of 10–30% FOG by volume of total digester feed caused a 30–80% increase in digester gas production in two full scale wastewater biosolids anaerobic digesters (Bailey, 2007, Muller et al., 2010). Laboratory and pilot scale anaerobic digesters have shown even larger increases in gas production. However, anaerobic digestion of high lipid wastes has been reported to cause inhibition of acetoclastic and methanogenic bacteria, substrate, and product transport limitation, sludge flotation, digester foaming, blockages of pipes and pumps, and clogging of gas collection and handling systems. This paper reviews the scientific literature on biogas production, inhibition, and optimal reactor configurations, and will highlight future research needed to improve the gas production and overall efficiency of anaerobic co-digestion of FOG with biosolids from municipal wastewater treatment.