Calculated particle collection efficiencies of single droplets including inertial impaction,brownian diffusion,diffusiophoresis and thermophoresis

Particle collection efficiencies of a single 100 μm dia. water droplet were calculated with a Runge-Kutta numerical solution for the particle equation of motion. The bulk gas properties were held constant at 65°C and 100 per cent r.h. whereas the water droplet temperature ranged from 10°C (water vapor condensing on the droplet) to 82°C (water evaporating from droplet). Potential flow was assumed for the gas flow profile around the droplet moving at its settling velocity of 30.0 cm s⁻¹. The results show that over the 0.01–10μm particle dia. range, the calculated particle collection efficiency is significantly increased with colder water temperatures and decreased with warmer water temperatures. The calculated results for the case with both the water and gas temperature at 65°C (only inertial impaction and Brownian diffusion mechanisms) compares reasonably with previous reports.     

大直径好氧颗粒污泥的培养及其特性

接种某城市污水处理厂的好氧颗粒污泥,采用较高的污泥负荷、高选择压和人工洗出絮状污泥的培养方式,促使好氧颗粒污泥直径迅速增长.考察了大直径好氧颗粒污泥的增长、破裂、稳定的变化过程.大直径好氧颗粒污泥最大直径可达9.6mm,最大沉淀速率为160 m/h,污泥指数(SVI)在32～60 mL/g左右.大直径颗粒污泥内部质地疏松有孔洞,外表层相对致密并由大量的丝状物质构成,且活性低于普通活性污泥.     

Predicting Cutoff Aerodynamic Diameter and Sharpness of Single Round-Nozzle Impactors with a Finite Impaction Plate Diameter

Abstract

This investigation numerically examined the cutoff aerodynamic diameter (da₅₀) and the sharpness (GSD) of the particle collection efficiency curve of impactors with a finite impaction plate diameter. Results revealed that the inertial impactors have a limited cutoff aerodynamic diameter at different air velocities. The extreme value of the cutoff aerodynamic diameter increases with the nozzle diameter (W)/the plate diameter (D_c). The computed da₅₀/D_c values of the impactors increase with W/D_c at various Reynolds numbers (Re) and with the nozzle-toplate distance (S)/D_c when Re is 100. The value of GSD slightly increases with W/D_c for Re of 10 and 100, although the effect of S/D_c on GSD is not evident at various Res. The particle collection efficiency curve of the impactor with a lower Re is less sharp than that with a high Re at various W/D_c and S/D_c values. Statistical equations closely fitted the obtained numerical results for Res of 10–3000. The equations are useful for directly calculating the cutoff aerodynamic diameter and the sharpness of the particle collection efficiency curve for single round-nozzle impactors with a finite impaction D_c.     

Predicting the combustion behaviour of compression ignition engine fuelled with biodiesel from Stoechospermum marginatum,a macro algae

Environmental Science and Pollution Research - Biodiesel is one among the recent developments in the field of renewable energy research. To enhance the combustion characteristics of compression...     

Laboratory and field investigations of a new and simple design for the parallel plate denuder

Diffusion denuders are commonly used for collection of water soluble atmospheric gases. Denuder plates made of glass with silica coating were however difficult to handle in field measurements, and also had wettability problems. In this paper, we describe a new design of parallel plate denuder consisting of perfluoralkoxy (PFA) plates and polyester sheets. The parallel plate denuder was coupled on-line to ion chromatography for analysis of atmospheric HNO₃ and SO₂. With time resolution of 20 min, the detection limits for both gases were 6 ppt(v). Memory effect was found to be significant for HNO₃ especially at high humidity with the long sample inlet tube. Particle losses due to diffusion and electrostatic effects in the denuder were investigated and compared with theory. Particle loss in the sample inlet tube was found to play an important role by reducing the number of charged particles entering the denuder. The instrument was applied in two European Union field measurement campaigns, and the intercomparison results are presented in this paper.     

Effects of biofilm growth on flow and transport through a glass parallel plate fracture

The effects of biofilm growth on flow and solute transport through a sandblasted glass parallel plate fracture was investigated. The fracture was inoculated using soil microorganisms. Glucose, oxygen and other nutrients were supplied to support growth. The biomass initially formed discrete clusters attached to the glass surfaces, but over time formed a continuous biofilm. From dye tracer tests conducted during biofilm growth, it was observed that channels and low-permeability zones dominated transport. The hydraulic conductivity of the fracture showed a sigmoidal decrease with time. The hydraulic conductivity was reduced by a factor of 0.033, from 18 to 0.6 cm/s, corresponding to a 72% decrease in the hydraulic aperture, from 500 to 140 microm. In contrast, the mass balance aperture, determined from fluoride tracer tests, remained relatively constant, indicating that the impact of biomass growth on effective fracture porosity was much less than the effect on hydraulic conductivity. Analyses of pre-biofilm tracer tests revealed that both Taylor dispersion and macrodispersion were influencing transport. During biofilm growth, only macrodispersion was dominant. The macrodispersion coefficient alpha(macro) was found to increase logarithmically with hydraulic conductivity reduction.     

Comparative toxicity of a brominated flame retardant (tetrabromobisphenol A) on microalgae with single and multi-species bioassays

The potential threat of emerging chemicals to the aquatic flora is a major issue. The purpose of the study was to develop a multispecies microalgae test in order to determine the impact of species interactions on the cytoxicity of an emergent toxic contaminant: the tetrabromobisphenol A (TBBPA). Single and multi-species tests were thus performed to study the effects of this flame retardant on two microalgae (Pseudokirchneriella subcapitata and Nitzschia palea) commonly observed in freshwater. A synthetic medium was designed to allow the growth of both species. The algae were exposed to 1.8, 4.8, 9.2, 12.9 and 16.5 μM of TBBPA for 72 h. After staining with fluorescein diacetate (FDA), viable cells of each alga species were analyzed by flow cytometry based on chlorophyll autofluorescence and intracellular esterase activity. Density and abundance of viable cells were assessed to follow the population growth and the cell viability. In TBBPA treated samples, the growth of the two microalgae was significantly inhibited at the three highest concentrations (9.2, 12.9 and 16.5 μM) in the two tests. At the end of the experiment (t = 72 h), the cell viability was also significantly smaller at these concentrations. The decreases of growth rate and viable cell abundance in TBBPA treated populations of N. palea were significantly higher in multi-species test in comparison with the single-species test. No significant differences were noticed between the two tests for P. subcapitata populations exposed to TBBPA.     

Development and modeling of a flat plate serpentine reactor for photocatalytic degradation of 17-ethinylestradiol

A flat plate serpentine reactor modified from ultraviolet disinfection pool in municipal wastewater treatment plants was developed for the removal of 17-ethinylestradiol (EE2) for the first time. The photocatalytic degradation performance of EE2 was investigated in this serpentine reactor under different conditions such as inlet concentrations, loaded catalyst concentrations, incident radiations fluxes, and flow velocities. More than 98 % of EE2 was removed under certain conditions within 120 min. An integrated model including a six-flux adsorption–scattering model and a modified flow diffusion model was established to investigate the effect of radiation field and flow velocities, respectively. A satisfactory agreement was observed between the model simulation and experimental results, showing a potential for design and scale-up of photocatalytic reactor for wastewater treatment.     

Comparison of the performance of a single and two-stage variable-throat venturi scrubber

The efficient removal of fine particulate matter from a gas stream by a venturi scrubber is achieved usually at the expense of a high gas-phase pressure drop with a coincident high fan running cost. It is desirable, therefore, to investigate ways of reducing venturi pressure loss for a given overall collection efficiency. This paper is principally a theoretical investigation of the effects of two-stage venturi operation. The theoretical predictions are borne out qualitatively by experimental work.The paper shows that above a certain pressure drop, which is dependent upon particle size, collection efficiencies can be increased significantly (and hence the pressure loss reduced) by using a two-stage design. The value of the main parameters in the collection efficiency—pressure drop relationship for single-stage operation determines to what extent two-stage scrubbing is an advantage. The improvement in performance becomes greater as both the particle size and system pressure drop increase. The lower efficiencies obtained with single-stage venturi operation are shown to be the result of a “diminishing returns” inherent in the scrubbing process at higher Stokes' Numbers.     

A Method for Predicting the Performance of Packed Columns Operating with a Reactive Scrubbing Liquid That Control Gaseous Air Pollutants

Abstract

A method for predicting the performance of packed columns that control gaseous air pollutants has been developed that exploits the advances in both computer software and hardware commonly used by practicing engineers. The solution of the simultaneous partial differential equations that describe the absorption process in packed columns that occurs in the presence of chemical reaction is obtained by converting the partial differential equations to systems of ordinary differential equations. These systems of ordinary differential equations are then solved using the method of lines along with a variable step, variable order numerical method. The method is applicable to systems in which there are multiple reactions within the liquid phase. The reactions can be of any order and can be reversible. The programming is simple and the machine running time is minimal. The method is illustrated here with an example.     

Tomographic reconstruction of tracer gas concentration profiles in a room with the use of a single OP-FTIR and two iterative algorithms: ART and PWLS

Computed tomographic (CT) reconstructions of air contaminant concentration fields were conducted in a room-sized chamber employing a single open-path Fourier transform infrared (OP-FTIR) instrument and a combination of 52 flat mirrors and 4 retroreflectors. A total of 56 beam path data were repeatedly collected for around 1 hr while maintaining a stable concentration gradient. The plane of the room was divided into 195 pixels (13 x 15) for reconstruction. The algebraic reconstruction technique (ART) failed to reconstruct the original concentration gradient patterns for most cases. These poor results were caused by the "highly underdetermined condition" in which the number of unknown values (156 pixels) exceeds that of known data (56 path integral concentrations) in the experimental setting. A new CT algorithm, called the penalized weighted least-squares (PWLS), was applied to remedy this condition. The peak locations were correctly positioned in the PWLS-CT reconstructions. A notable feature of the PWLS-CT reconstructions was a significant reduction of highly irregular noise peaks found in the ART-CT reconstructions. However, the peak heights were slightly reduced in the PWLS-CT reconstructions due to the nature of the PWLS algorithm. PWLS could converge on the original concentration gradient even when a fairly high error was embedded into some experimentally measured path integral concentrations. It was also found in the simulation tests that the PWLS algorithm was very robust with respect to random errors in the path integral concentrations. This beam geometry and the use of a single OP-FTIR scanning system, in combination with the PWLS algorithm, is a system applicable to both environmental and industrial settings.     

SBR用于高浓度有机污水的处理——单级与两级处理系统的比较研究

对单级和两级序批式反应器 (SBR)用于牛场高浓度有机污水的处理进行了试验研究 ,对其污水处理性能进行了比较。结果表明 ,与单级SBR相比 ,两级SBR处理系统可使用较短的水力停留时间而获得较高的污染物去除率和较好的出水水质 ,并可通过硝化过程实现氨氮的完全硝化。     

Optimization of circular plate separators with cross flow for removal of oil droplets and solid particles

A circular gravity-phase separator using coalescing medium with cross flow was developed to remove oil and suspended solids from wastewaters. Coalescence medium in the form of inclined plates promotes rising of oil droplets through coalescence and settling of solid particles through coagulation. It exhibits 22.67% higher removal of total suspended solids (TSS) compared to separators without coalescing medium. Moreover, it removed more than 70% of oil compared to conventional American Petroleum Institute separators, which exhibit an average of 33% oil removal. The flowrate required to attain an effluent oil concentration of 10 mg/L (Q(o10)) at different influent oil concentrations (C(io)) can be represented by Q(o10) x 10(-5) = -0.0012C(io) + 0.352. The flowrate required to attain an effluent TSS concentration of 50 mg/L (Q(ss50)) at different influent TSS concentrations (C(iss)) can be represented by Q(ss50) x 10(-5) = 1.0 x 10(6) C(iss)(-2.9576). The smallest removable solid particle size was 4.87 microm.     

The role of lime in dredged mud dewatered by a plate and frame filter press and potential substitutes

Environmental Science and Pollution Research - Dredged mud is a kind of construction material that can be reused as waste. It needs to be dehydrated before it is used. At present, plate and frame...     

Effect of diffusion limitation and substrate inhibition on steady states of a biofilm reactor treating a single pollutant

The occurrence of multiple steady states in a toluene biodegrading, diffusion-limited biofilm under aerobic conditions was investigated by computer models: one steady-state, and one nonsteady-state. Two stable and one unstable intermediate steady-state were identified in a narrow set of combinations of parameters values. The nonsteady-state model predicts conditions that evolve to a steady state that is within 0.02–1% of the solution of the steady-state model, depending on the number of grid points used, confirming the algorithms are valid. Multiple steady states occur if, (1) a biofilm is exposed to a constant gas-phase pollution concentration, which exceeds or undershoots a certain threshold, (2) in a narrow range of parameter values and (3) provided that the pollutant degradation follows Haldane kinetics. Such a biofilm displays half-saturation (i.e., Michaelis-Menten)-like apparent (“falsified”) kinetics from a concentration range starting at zero up to the occurrence of a second steady state. Multiple steady states and falsified kinetics can negatively affect a biofilter and the experimental determination of kinetic parameters, respectively.

Implications: The occurrence of multiple steady states in a VOC treating biofilm, shows the significant impact of degradation kinetics and diffusion limitation on the biofilm behavior. Moreover, the implied possible sudden drop of removal efficiency of a biofilter, based on the occurrence of multiple steady states lead to possible bottle-necks in biofilter application and operation.     

Antimony availability in highly polluted soils and sediments - a comparison of single extractions

Forest/tilled soils and stream sediments from the highly polluted mining and smelting district of Príbram, Czech Republic, were subjected to single extraction procedures in order to determine the available contents of Sb and As. The results obtained from five widely-used 2-h single extraction tests were compared: deionised water, 0.01M CaCl(2), 1M NH(4)NO(3), 0.005M diethylentriaminpentaacetic acid (DTPA) and 0.1M Na(2)HPO(4). The ICP-MS determinations of Sb and As in the extracts were coupled with measurements of pH and Eh and geochemical modelling (PHREEQC-2) to determine their speciation in extracts and possible solubility-controlling phases. According to the speciation calculations, Sb in extracts was present mainly as Sb(V) with the exception of the DTPA extracts from highly organic and acidic forest soils, where Sb(III) species accounted for up to 34% of total Sb speciation. The highest extractabilities were observed for the 0.1M Na(2)HPO(4) solution (up to 9% of the total Sb and up to 34% of the total As concentration). The other extracting media yielded statistically the same results (p<0.05) with Sb extractabilities below 2% and As extractabilities below 8%. Thus, simple deionised water and 0.1M Na(2)HPO(4) extractions are preferred for quick estimates of easily-exchangeable and specifically-sorbed Sb, respectively.     

Quantitation of hydroxyl radical during fenton oxidation following a single addition of iron and peroxide

Chemical probes were used to study the formation of hydroxyl radical in aqueous iron-hydrogen peroxide reaction. Hydroxyl radical formation rate and time dependent concentration were determined in pure water, in aqueous fulvic acid (FA) and humic acid (HA) solutions, and in natural surface waters. Indirect determinations of hydroxyl radical were made by quantitating hydroxyl radical reactions with probe compounds under controlled conditions. High probe concentrations were used to determine radical formation rates and low probe concentrations were used to determine time dependent radical concentration. Two independent probes were used for intercomparison: benzoic acid and 1-propanol. Good agreement between the two probes was observed. Natural water matrices resulted in lower radical formation rates and lower hydroxyl radical concentrations, with observed formation rate and yield in natural waters up to four times lower than in pure water. HA and FA also reduced hydroxyl radical formation under most conditions, although increased radical formation was observed with FA at certain pH values. Hydroxyl radical formation increased linearly with hydrogen peroxide concentration.     

Aerobic plate count,Salmonella and Campylobacter loads of whole bird carcass rinses from pre-chillers with different water management strategies in a commercial poultry processing plant

Abstract

Salmonella and Campylobacter are significant issues for poultry processors because of increasing regulatory standards as well as public health concerns. The goal of this study is to report the effects of two different pre-chiller systems that utilize different temperatures and water recirculation systems on whole bird carcass rinsates. Both pre-chiller tanks were contained within a single poultry processing facility and operated at different temperatures and water systems. The incidence of Campylobacter spp. and Salmonella spp., as well as the aerobic plate counts on whole bird carcass rinses are reported in this study from each pre-chiller system. The results from this study reveal that there are significant differences in how microbial populations and pathogens change over time in each pre-chiller system. Furthermore, we identify that these patterns are different per system. Such data are impactful as it indicates that measuring carcasses within a plant must consider both temperature and water recirculation as it may prevent comparability of different lines within a single processing facility.     

Electrosorption and photocatalytic one-stage combined process using a new type of nanosized TiO2/activated charcoal plate electrode

In the present study, an activated charcoal (AC) plate was prepared by physical activation method. Its surface was coated with TiO₂ nanoparticles by electrophoretic deposition (EPD) method. The average crystallite size of TiO₂ nanoparticles was determined approximately 28 nm. The nature of prepared electrode was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Brunauer–Emmett–Teller (BET) surface area measurement before and after immobilization. The electrosorption and photocatalytic one-stage combined process was investigated in degradation of Lanasol Red 5B (LR5B), and the effect of dye concentration, electrolyte concentration, pH, voltage, and contact time was optimized and modeled using response surface methodology (RSM) approach. The dye concentration of 30 mg L^?1, Na₂SO₄ concentration of 4.38 g L^?1, pH of 4, voltage of 250 mV, and contact time of 120 min were determined as optimum conditions. Decolorization efficiency increased in combined process to 85.65 % at optimum conditions compared to 66.03 % in TiO₂/AC photocatalytic, 20.09 % in TiO₂/AC electrosorption, and 1.91 % in AC photocatalytic processes.