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Yuan Kang Yi Yin Yubon Man Laisheng Li Qiuyun Zhang Lixuan Zeng Jiwen Luo Ming Hung Wong 《Chemosphere》2013
Human exposure to bioaccessible PCBs via indoor dust is limited around the world. In the present study, the workplace dust sample from commercial office, hospital, secondary school, shopping mall, electronic factory and manufacturing plant were collected from Hong Kong for PCBs analyses. Total PCBs concentrations ranged from 46.8 to 249 ng g−1, with a median of 107 ng g−1. Manufacturing plant showed the highest concentration among all of sampling sites. PCB 77 was found as the dominant congeners. The bioaccessibility of PCBs in small intestinal juice ranging from 8.3% to 26.0% was significantly higher than that in gastric condition, ranging from 4.8% to 12.4%. In addition, significant negative correlations (p < 0.05) were observed between KOW and bioaccessibility for all workplace dust samples. Risk assessment indicated that the averaged daily dose of dioxin-like PCBs via non-dietary intake of workplace dust, considering the bioaccessibility of PCBs, were much lower than the TDI of dioxins (2.3 pg WHO-TEQ kg bw−1 d−1) established by Joint FAO/WHO Expert Committee on Food Additives. 相似文献
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介绍了劣质渣油造成渣油气化装置结垢和腐蚀的情况,分析了原因及危害,总结了解决的措施。 相似文献
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采用添加壳聚糖(CTS)的溶胶-凝胶法制备了具有较高光催化活性的TiO2光催化剂,并用XRD、TEM、BET和IR等手段对其进行表征。结果表明,CTS的添加使TiO2衍射强度增强、分散性提高、比表面积增大从而使光催化活性提高;用所制备的催化剂光催化降解甲基橙反应60min后,其去除率由不添加CTS所制备TiO2的32%提高到48%,TOC去除率由14%提高到23%。 相似文献
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Wang Pengcheng Huang Qiuyun Xiao Henglin Zhang Zhi Qiao Yan Chen Yunfeng Hu Cheng 《Journal of Material Cycles and Waste Management》2022,24(4):1485-1493
Journal of Material Cycles and Waste Management - Limited options and high prices have limited the application of additives in composting. The effect of applying carbonate (SRC) and biochar (BC) to... 相似文献
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电解锰渣是电解锰生产过程中碳酸锰矿经酸浸、中和、压滤工序后产生的废渣。重金属锰是电解锰渣中的主要污染物,在渣中主要以可溶化合物MnSO_4·H_2O,(NH_4)_2Mn(SO_4)_2·6H_2O等形式存在。采用碳酸盐碳化处理电解锰渣,研究渣中可溶性锰固定、硫酸钙转化的矿物学特征和机制。结果表明,Na_2CO_3能够有效固定渣中的锰离子形成MnCO_3矿物。反应时间90 min,Na_2CO_3与渣质量比为0.05时,Na_2CO_3对锰的固定率达到99.9%,渣浆中锰离子质量浓度下降至5.7 mg/L。反应机制主要是渣中MnSO_4·H_2O,(NH_4)_2Mn(SO_4)_2·6H_2O与碳酸盐反应形成球状MnCO_3矿物;当Na_2CO_3与渣质量比大于0.4时,渣中柱状、条状CaSO_4·2H_2O转化为CaCO_3。 相似文献
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界定了旅游水环境的概念,采用资料调查、咨询访问和个别现场调查等方法,对海南省旅游水环境进行了调查与分析。结果表明,海南省1989年至2008年旅游业的用水量占全省生活用水量的比例都很小,对海南水资源总量的影响也很小,2008年三亚市、海口市和万宁市三个城市的旅游业用水量之和占到全省旅游业总用水量的79.9%;海南省河流、水库、海域和地下水环境质量总体优良,仅有少量监测出现超标现象;在旅游水环境重点保护对象中,海南中部山区河流源头水、主要滨海旅游区近岸海域、三大河流和两大水库等水体水质均为优良,城镇、乡镇集中式生活饮用水水源地和城市河段大多数水体水质满足环境功能要求,有少量水体水质超标。河流、水库和个别城镇集中式生活饮用水水源地水质超标主要是农业面源污染和生活污水的污染。乡镇集中式生活饮用水水源地水质超标的主要原因是受海水、生活污水、生活垃圾、分散式畜禽养殖污水等的渗透污染和土壤中铁、猛背景值含量较高所致。 相似文献
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重金属和抗生素广泛存在工业废水、养殖水体中,对硝化细菌活性有不同程度的影响。为研究重金属和抗生素胁迫对亚硝酸盐氧化菌(nitrite-oxidizing bacteria,NOB)及硝化菌群活性的影响,采集珠江水样富集硝化菌群并分离纯化NOB,研究了不同浓度重金属离子(Cu2+、Zn2+、Cd2+、Mn2+、Cr6+)和抗生素(卡那霉素、氨苄青霉素、链霉素、盐酸四环素)对NOB亚硝酸盐氧化活性的影响,揭示了不同重金属和抗生素胁迫对NOB及硝化菌群富集物活性的影响。结果表明:第15代富集培养的硝化菌群中Nitrosomonas丰度由0.11%升高至10.04%,Nitrobacter丰度由0.014%上升到2.104%;经鉴定,分离纯化的NOB菌株与Nitrobacter winogradskyi相似性为99.58%;NOB的亚硝酸盐氧化活性随重金属离子、抗生素浓度升高而下降;在初始NOB量相等情况下,与NOB组相比,硝化菌群富集物实验组在重金属或抗生素胁迫下,亚硝酸盐氧化速率更快,稳定性更高,对重金属和抗生素的抗逆性更强,对于处理含氮废水的实际应用潜力更大。该研究结果可为NOB的研究和在工业、养殖业水体净化的开发应用提供参考。 相似文献