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Roadside Rhododendron pulchrum leaves as bioindicators of heavy metal pollution in traffic areas of Okayama, Japan 总被引:2,自引:0,他引:2
The leaves of roadside Rhododendron pulchrum Sweet were examined as a bioindicator of traffic-related heavy metal pollution in Okayama. Total contents of heavy metals in roadside soil and the R. pulchrum leaves were determined. Results of correlation analyses showed significant correlations among Pb, Ni, and Zn contents of roadside soil and leaf samples. These results suggest that R. pulchrum is a useful bioindicator of heavy metal pollution in traffic areas. To identify traffic-related heavy metal pollution sources, traffic-related materials such as tires, asphalt pavement, and road paint were collected and analyzed. The results of analyses of our data show that Zn is emitted mainly from the abrasion of tires; Cr is emitted mainly from wear of the asphalt pavement. Furthermore, the respective lead isotope ratios in R. pulchrum leaves, soil, roadside dust, and traffic-related materials were measured using inductively coupled plasma mass spectrometry. The isotopic compositions of lead in R. pulchrum leaves were 207Pb/206Pb = 0.861-0.871 and 208Pb/206Pb = 2.093-2.127, which agrees well with ratios in automobile wheel balance weights, suggesting that lead-containing products associated with automobiles, such as wheel balance weights, contribute to traffic-related lead pollution. 相似文献
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Takaaki Yamaguchi Masashi Yabuki Shoji Saito Tomoyuki Watanabe Hiroshi Nishimura Naohiko Isobe Fumiaki Shono Masatoshi Matsuo 《Chemosphere》1996,33(12):2441-2468
A new predictive toxicokinetics model was developed to estimate subacute toxicity (target organs, severity, etc.) of non-congeneric industrial chemicals, where the chemical structures and physico-chemical properties are only available. Thus, a physiological pharmacokinetics model, which consists of blood, liver, kidney (these were experimentally found as major toxicological targets), muscle and fat compartments , was established to simulate the chemical concentrations in organs/tissues with pharmacokinetic parameters by means of Runge-Kutta-Gill algorithm. The pliarmacokinetic parameters, i.e. absorption rate, absorption ratio, hepatic extraction ratio of metabolism and renal clearance were calculated by using separately established Quantitative Structure-Pharmacokinetics Relationship equations. The developed predictive model was then applied to simulations of 43 non-congeneric industrial chemicals. The chemical concentrations in organs/tissues after single oral administration were simulated, and their maximum concentrations (Cmax's) and area tinder the concentration-time curves (AUC's) were calculated.Fast Inverse Laplace Transform was newly applied for the purpose of simulation of 28-day repeated dose toxicity.Simulated concentrations of 28 days repeated dose were, however, found to be the same as those of simple repetitions of a single administration per day because of the short half-lives of non-congeneric industrial chemicals.A comparison of subacute toxicity data with Cmax's and AUC's in a single dose scenario suggested that the organs/tissues with relatively high concentrations of tested chemical substances were the most sensitive targets within a chemical.Chemical concentrations in liver, for instance, were correlated with the severity of hepatotoxicity among the chemicals. It was also suggested that to improve and widen the present approach, data of metabolite and reactivity of non-congeneric industrial chemicals to organs/tissues, receptors, etc. should be incorporated into the model. 相似文献
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Kameoka Hiroshi Ito Koji Ono Junko Banno Arisa Matsumura Chisato Haga Yuki Endo Kazuto Mizutani Satoshi Yabuki Yoshinori 《Journal of Material Cycles and Waste Management》2022,24(1):287-296
Journal of Material Cycles and Waste Management - Per- and polyfluoroalkyl substances (PFASs) are used in products, such as aqueous film-forming foam and fluorochemical surfactants, because of... 相似文献
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Lauren Nozomi Marques Yabuki Camila Destro Colaço Amauri Antonio Menegário Roberto Naves Domingos Chang Hung Kiang Domitila Pascoaloto 《Environmental monitoring and assessment》2014,186(2):961-969
Studies concerning the lability and bioavailability of trace metals have played a prominent role in the search for contamination of water resources. This work describes the first application yet of the diffusive gradients in thin films technique (DGT) to the determination of the fraction of free plus labile metals in waters from the Amazon Basin. Due to the complexity of the use of DGT for samples with low ionic strength and high organic matter content (characteristic of Amazonian rivers), a new analytical procedure was developed. The method is based on the determinations of apparent diffusion coefficients (Dap) in the laboratory, by performing deployments in samples collected in the corresponding sites of study. The Dap thereby determined is then used for in situ measurements. The suitability of the proposed approach for determination of labile Al, Cd, Co, Cu, Mn, Ni, and Zn in the Amazon River and Rio Negro (English: Black River) was evaluated. Except for Co, Mn (in a deployment at Rio Negro), Ni and Zn (in a deployment at Amazon River), labile in situ measurements were lower or similar to dissolved concentrations, indicating suitability of the proposed approach. 相似文献
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Yasuhito Igarashi Michio Aoyama Katsumi Hirose Pavel Povinec Sadayo Yabuki 《Water, Air, & Soil Pollution: Focus》2005,5(3-6):51-69
Currently, atmospheric anthropogenic radionuclides (particulate) are controlled by suspension of the surface dust containing
those radionuclides (resuspension). We have found, therefore, that such radionuclides can be used as tracers of the surface
dust suspension, transport and its subsequent deposition in distant areas. The 137Cs/90Sr activity ratios in the atmospheric deposition, without the direct influence of nuclear tests and accidents, at the Meteorological
Research Institute (MRI, Tsukuba, Japan) during the 1990s were fairly low (average: 2.1). This value is not in agreement with
the ratios in Japanese surface soils (range of averages: 4–7), which had been considered as the primary source of the deposited
dust. This suggests that the current atmospheric dust deposition in Japan is a mixture of local and remote components. The
remote component could be an aeolian dust that has been transported long distances from arid areas. The major component is
most likely to be Asian dust. It was further hypothesized that other remote source may exist beyond the Asian domain, based
on accumulated observations and model results. To obtain more information about the dust transport, Sahara dust deposited
in Monaco in 2002 and a suspended dust collected in the Taklamakan area in 2001 were analyzed for 90Sr and 137Cs. The Taklamakan dust exhibited a 137Cs/90Sr ratio of about 4, which is within the range of atmospheric deposition observed at the MRI, while the Sahara dust exhibited
a higher 137Cs/90Sr ratio (about 13). Although the present Sahara datum was negative for our hypothesis of ‘hyper-range transport’, the seasonal
change of the 137Cs/90Sr ratio in the atmospheric deposition observed at the MRI requires an aeolian dust source having a low 137Cs/90Sr ratio, other than Asian dust. 相似文献
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