Two-dimensional spectrophotometry and pseudo-color representation of chemical reaction patterns

The formation of spatio-temporal patterns in layers of chemical and biochemical media is observed and quantified by a two-dimensional spectrophotometer based on a computerized video equipment with high spatial, temporal, and intensity resolution. Images are shown, to some extent, in pseudo-colors. The use of pseudo-colors and three-dimensional perspective representations enhances the perception of the information contained in an image and the inherent order of the spatial structures.     

Coupled abiotic-biotic mineralization of 2,4,6-trinitrotoluene (TNT)

Munitions wastes such as TNT are widespread contaminants in soils and ground waters. We investigated a coupled abiotic-biotic treatment scheme for remediation of aqueous solutions of TNT. Mineralization of aqueous TNT (0.22 mM) was initially optimized with minimum reactant use (Fe3+ and H2O2) in light-assisted and dark, modified Fenton reactions at acidic and neutral pH. Complete TNT degradation occurred under all reaction conditions within 24 h. Using the optimum reactant concentrations, coupled abiotic-biotic reactions showed an increase in TNT mineralization, from 47 to 80%, after biomass addition to the acidic, dark Fenton-like reaction. Comparable increases of TNT mineralization were observed under neutral pH with similar reaction conditions. In light-assisted Fenton-like reactions at neutral pH, no increase in cumulative TNT mineralization (66%) was seen in coupled abiotic-biotic reactions. Abiotic photo-Fenton-like reactions alone, at acidic pH, produced complete TNT mineralization and required no biotic assistance. While light-enhanced Fenton reactions alone can provide high levels of TNT mineralization, the dark abiotic-biotic reaction scheme has perhaps a wider use due to a similar extent of TNT mineralization in the absence of light, leading to possible applications in soil slurry and in situ processes in the subsurface.     

Conditions for successful environmental justice mobilizations: an analysis of 50 cases

ABSTRACT

The environmental justice (EJ) literature can benefit from comparative analysis that helps to identify conditions for more and less successful outcomes. A data set of 50 EJ cases in the U.S. was developed with high and low remediation as the outcome. Causal conditions were selected on theoretical grounds, and included five mobilizing strategies (local and state government coalitions, federal government attention, civil disobedience, litigation, and national NGO support) and three general conditions (absence of industry counter-mobilization, presence of water pollution, and proposed or new siting). Qualitative comparative analysis and other analyses indicated that all causal conditions were found in the high-remediation cases but that some conditions (water pollution and local–state coalitions) were more consistently associated with the high-remediation outcome. The analysis points to the value of systematic studies of the factors that affect local EJ outcomes and to the need for better case study collections.     

Making index insurance attractive to farmers

There are several factors that influence whether people will want to participate in index insurance programs. A number of these influence their attractiveness on economic grounds, including both the size and timing of the premium and potential payouts, and the degree of risk aversion of the potential customers. Other factors make programs attractive for reasons that are not economic, but no less valid. These have to do with the trust that people have in the insurance product and the organizations involved in selling and managing it. Indeed, data from India, Africa, and South America show that these factors may be more important than the economic ones in influencing demand. Index insurance pilot projects, in order to estimate demand for alternative products, have typically involved a great deal of interaction with potential customers. It is important to recognize that such interaction is crucial not just as a research tool, but also as a means to build understanding and trust in the products. When scaling up from isolated pilots to operational programs, it is vital to recognize this trust building function by replicating participation efforts in every community. In this paper, we examine the role of field games in establishing and building trust in three important aspects of these projects for participants: trust in the insurance product, trust in the participating organizations, and trust in their own ability to make good decisions. While games have previously been used as a way to gauge interest in the product and to identify design features, we argue that these games are also valuable tools for constructing these kinds of trust.     

A Sensitivity Analysis of an Integrated Modelling Approach to Assess the Risk of Wind-borne Spread of Foot-and-mouth Disease Virus from Infected Premises

The sensitivity of an integrated model to assess the potential for wind-borne spread of foot-and-mouth disease (FMD) to variations in key parameters controlling different physical and biological processes was evaluated. The estimated number of farms at risk is sensitive to the virus strain used and the accompanying effective contact rate. The C Noville strain increased the estimated number of exposed farms ranked as high and medium risk of being infected by a factor of 5, compared to the baseline, based on the O UKG 2001 strain. The inclusion of a model for biological ageing of the virus can also have a significant effect on the concentration patterns arising from transport and dispersion of the virus. Its inclusion has the practical advantage of markedly reducing the time required for the calculations. The estimated number of farms affected by exposure to high and medium virus concentrations is not grossly sensitive to attenuation caused by temperature or relative humidity effects. Changes in susceptibility to infection, as determined by the parameter θ in the exposure-risk model, does not change the configuration of the virus plumes, but it does change the distribution of farms at risk by risk category. These findings suggest that a good understanding of characteristics (excretion rates from infected animals, susceptibility of different species to infection, virus survival, etc.) of the virus strain involved in an FMD outbreak is necessary to provide a reliable assessment of the risk of wind-borne spread. In the event of an incursion of FMD, provision for laboratory studies on the virus will be an essential component of the disease response and should be factored into contingency plans.

A MANGANESE OXIDATION MODEL FOR RIVERS1

ABSTRACT: The presence of manganese in natural waters (>0.05 mg/L) degrades water-supply quality. A model was devised to predict the variation of manganese concentrations in river water released from an impoundment with the distance downstream. The model is one-dimensional and was calibrated using dissolved oxygen, biochemical oxygen demand, pH, manganese, and hydraulic data collected in the Duck River, Tennessee. The results indicated that the model can predict manganese levels under various conditions. The model was then applied to the Chattahoochee River, Georgia. Discrepancies between observed and predicted may be due to inadequate pH data, precipitation of sediment particles, unsteady flow conditions in the Chattahoochee River, inaccurate rate expressions for the low pH conditions, or their combinations.     

Radon from drinking water — evaluation of water-borne transfer into house air

To determine the transfer of²²²Rn from domestic water into air, nine houses were measured for²²²Rnt, house volume, water use and air exchange by SF₆ and radon. Measurements were done in Maine during April and May, 1986, when sealed up for the winter. Radon in water concentration ranged from 35,000 to 1,250,000 pCi/l. Air peaks of²²²Rn ranged from 13 to 200 pCi/l due to a water use burst experiment. Use of water filters was also examined by repeats with filters on and off. Water use ranged from 200 to 1922 litres/day. House volumes ranged from 380 to 999 m³. Air exchange rates measured by SF₆ was twice as large as air exchange rate measured by²²²Rn.