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Matthew Bates Paolo Bruno Mariangela Caputi Maurizio Caselli Gianluigi de Gennaro Maria Tutino 《Atmospheric environment (Oxford, England : 1994)》2008,42(24):6144-6151
The technique of thermal desorption (TD)–GC/MS was evaluated for measuring airborne, 4–6 ring polycyclic aromatic hydrocarbons (PAHs) collected onto quartz filters. TD provides a more readily automated and sensitive alternative to traditional solvent extraction, decreasing the time/cost of analysis and reducing the risk of analyte loss or sample contamination. The developed method was successfully applied to the analysis of PAH standard solutions loaded on sorbent tubes packed with quartz wool and the graphitized carbon black sorbent Carbograph2. The optimized method showed high desorption efficiency over the whole range of target PAHs with good precision, linearity and sensitivity. The proposed method was verified on an urban dust Standard Reference Material (SRM 1649a); the experimentally determined concentrations agreed with the certified ranges (95% confidence limit) for all target compounds except benzo[a]anthracene, which fell just outside the narrow certified range. The desorption efficiency and the reproducibility of the method was evaluated by analysing pieces of real sample filters sampled from urban air for a period of 24 h. The results confirmed the homogeneity of the filter and showed high recovery efficiencies for all target PAHs. 相似文献
4.
Grant R. Sutherland Elizabeth Baker Stuart Purvis-Smith Athel Hockey Ed Krumins Sam Z. Eichenbaum 《黑龙江环境通报》1987,7(3):197-202
Eleven pregnancies in ten patients at risk for the fragile X were monitored by amniocentesis or chorion villus biopsy and induction of the fragile site using thymidine, methotrexate and FUdR. Three female fetuses and one male fetus were found to have the fragile X. The results obtained using thymidine induction were superior to those using methotrexate induction and probably better than those obtained using FUdR induction. 相似文献
5.
Larisse Montero Matthew Duane Urbano Manfredi Covadonga Astorga Giorgio Martini Massimo Carriero Alois Krasenbrink B.R. Larsen 《Atmospheric environment (Oxford, England : 1994)》2010,44(18):2167-2175
The present paper presents results from the analysis of 29 individual C2–C9 hydrocarbons (HCs) specified in the European Commission Ozone Directive. The 29 HCs are measured in exhaust from common, contemporary vehicle/engine/fuel technologies for which very little or no data is available in the literature. The obtained HC emission fingerprints are compared with fingerprints deriving from technologies that are being phased out in Europe. Based on the total of 138 emission tests, thirteen type-specific fingerprints are extracted (Mean ± SD percentage contributions from individual HCs to the total mass of the 29 HCs), essential for receptor modelling source apportionment. The different types represent exhaust from Euro3 and Euro4 light-duty (LD) diesel and petrol-vehicles, Euro3 heavy-duty (HD) diesel exhaust, and exhaust from 2-stroke preEuro, Euro1 and Euro2 mopeds. The fuels comprise liquefied petroleum gas, petrol/ethanol blends (0–85% ethanol), and mineral diesel in various blends (0–100%) with fatty acid methyl esters, rapeseed methyl esters palm oil methyl esters, soybean oil methyl or sunflower oil methyl esters. Type-specific tracer compounds (markers) are identified for the various vehicle/engine/fuel technologies.An important finding is an insignificant effect on the HC fingerprints of varying the test driving cycle, indicating that combining HC fingerprints from different emission studies for receptor modelling purposes would be a robust approach.The obtained results are discussed in the context of atmospheric ozone formation and health implications from emissions (mg km?1 for LD and mopeds and mg kW h?1 for HD, all normalised to fuel consumption: mg dm?3 fuel) of the harmful HCs, benzene and 1,3-butadiene.Another important finding is a strong linear correlation of the regulated “total” hydrocarbon emissions (tot-HC) with the ozone formation potential of the 29 HCs (ΣPO3 = (1.66 ± 0.04) × tot-RH; r2 = 0.93). Tot-HC is routinely monitored in emission control laboratories, whereas C2–C9 are not. The revealed strong correlations broadens the usability of data from vehicle emission control laboratories and facilitates the comparison of the ozone formation potential of HCs in exhaust from of old and new vehicle/engine/fuel technologies. 相似文献
6.
María Pía Areal M. Lorena Arciniegas Fernanda Horst Verónica Lassalle Francisco H. Sánchez Vera A. Alvarez Jimena S. Gonzalez 《Journal of Polymers and the Environment》2018,26(8):3129-3138
Scientific and technological researches are devoted to obtain materials capable of retaining different kinds of pollutants, contributing to contamination solutions. In this context, hydrogels have emerged as great candidates because of their excellent absorption properties as well as good mechanical, thermal and chemical properties. More specifically, ferrogels (magnetic gels) present the extra advantage of being easily manipulated by a permanent magnet. Here, we present the results derived from the application of ferrogels as efficient tools to extract heavy metal pollutants from wastewater samples. The gels were prepared following the method of freezing and thawing of a polyvinyl alcohol aqueous solution with magnetic nanoparticles coated with polyacrylic acid. Ferrogels were fully characterized and their ability to retain Cu2+ and Cd2+, as model heavy metals, was studied. Thus kinetics and mechanisms of adsorption were evaluated and modeled. The concentration of MNPs on the PVA matrix was key to improve the adsorption capability (approximately the double of retention is improved by the MNPs addition). The adsorption kinetics was determined as pseudo-second order model, whereas the Langmuir model was the most appropriate to explain the behavior of the gels. Finally reuse ability was evaluated to determine the real potential of these materials, the ferrogels demonstrated high efficiency up to about five cycles, retaining about 80–90% of their initial adsorption capability. All the results indicated that the materials are promising candidates able to compete with the commercial technology regarding to water remediation. 相似文献
7.
In accelerated weathering tests, specimens are exposed to higher radiation intensity, temperature and humidity than is likely under natural weathering in order to achieve rapid degradation of the polymer in a convenient short time. In the current work, a correlation between the two environments is attempted so that a prediction of lifetimes in the natural environment can be achieved. During aging, surface flaws are created due to the chain scission process. This is initiated by the absorption of ultra-violet light and directly affects visual appearance and impact strength. After natural weathering, the material shows only plastic deformation in an impact test. However, after artificial weathering to 5000 h of UV exposure, there is a decrease of 85% in impact strength. Colour change occurs at a high rate in the early stages of UV exposure. Beyond 2000 h of exposure, the colour change approaches a steady state and a correlation between the changes under natural and artificial weathering becomes apparent for a potential prediction of lifetimes. From the analysis including the specular component (SCI), taking surface roughening into account, 1 year under natural weathering was found to be equivalent to 25 days under accelerated weathering. 相似文献
8.
Natija Barhoumi Nihal Oturan Salah Ammar Abdellatif Gadri Mehmet A. Oturan Enric Brillas 《Environmental Chemistry Letters》2017,15(4):689-693
There is actually increasing concern about the accumulation of antibiotics, such as tetracycline, in soil and water bodies. There is therefore a need for efficient methods to degrade antibiotics and thus clean waters. Here we tested the degradation of tetracycline using the heterogeneous electro-Fenton-pyrite method and compared the results with the conventional electro-Fenton method. The reaction was performed with a boron-doped diamond or Pt anode and carbon-felt cathode allowing electrogeneration of H2O2 from O2 reduction. Results show an increasing tetracycline mineralization using the following methods: anodic oxidation with electrogenerated H2O2, electro-Fenton and then electro-Fenton-pyrite using boron-doped diamond. Ion-exclusion HPLC revealed the complete removal of malic malonic, succinic, acetic, oxalic and oxamic acids. Nitrogen present in tetracycline was mainly mineralized in NH4 +. The higher efficiency of electro-Fenton-pyrite is explained by self-regulation of soluble Fe2+ and pH to 3.0 from pyrite catalyst favoring larger ·OH generation from Fenton’s reaction. 相似文献
9.
Francisca Castilla-Polo M. Isabel Sánchez-Hernández Dolores Gallardo-Vázquez 《Journal of Agricultural and Environmental Ethics》2017,30(1):99-120
The attention to ethics has gradually become a concurrent topic of modern companies’ management. In the last years Social Responsibility has become a key issue in the strategic agenda of competitive agriculture cooperatives. However, reputation management has not been a visible strength in the cooperative enterprises. First of all, this work theoretically analyzes the relationship between Social Responsibility and reputation in cooperatives. Later, from a practical point of view, we carry on an empirical analysis focused on the olive oil cooperatives in the south of Spain, in the province of Jaén. With respect to the previous studies on the topic, this work reveals a main reason of interest reinforcing the role of research in addressing real problems of cooperatives. The article points out the characteristics of this kind of agribusiness and shows the importance of the adoption of a responsible orientation in fostering reputation for creating sustainable competitive advantages. 相似文献
10.
While local food production may be beneficial in terms of developing the local economy and reducing greenhouse gases from transportation, sustainability strategies focused on local food production may generate their own risks due to yield variability. We have developed a robust optimization (RO) model to determine the minimum amount of land (cropland and pasture) required to grow food items that would satisfy a local population’s (accounting for gender and age) calorie and nutrient needs. This model has been applied to Boone County, Missouri, which has a population of approximately 170,000. Boone County is 1790 km2, with 16% of the land defined as cropland and 30% defined as pasture. The model includes 27 nutrients from 17 potential foods that could be produced: six fruits and vegetables, five grains and six animal-sourced foods. Yield estimates are based on the predominate methods of agriculture in the USA. We first run our model assuming no variability, using the midpoint yield estimates. Then, to quantify uncertainty in yield for different food types, we use historical yield data over 10 years to estimate this variability and run our RO model under these variability estimates. We compare the two model results to illustrate the impact of data uncertainty on meeting sustainable local food for communities. Solutions suggest that nutrition needs can be met for the Boone County population within the land area defined. 相似文献