Reduction of ferrate(VI) and oxidation of cyanate in a Fe(VI)-TiO2-UV-NCO- system

The aqueous photocatalytic degradation of cyanate (NCO(-)), which is a long-lived neurotoxin formed during the remediation of cyanide in industrial waste streams, was studied in the ferrate(VI)-UV-TiO2-NCO(-) system. Kinetics measurements of the photocatalytic reduction of ferrate(VI) were carried out as a function of [NCO(-)], [ferrate(VI)], [O(2)], light intensity (I(o)), and amount of TiO2 in suspensions at pH 9.0. The photocatalytic reduction rate of ferrate(VI) in the studied system can be expressed as -d[Fe(VI)]/dt=kI(o)(0.5) [NCO(-)] [TiO2]. The rate of photocatalytic oxidation of cyanate with ferrate(VI) was greater than the rate in the analogous system without ferrate(VI). The possibility of involvement of reactive ferrate(V) species for this enhancement was determined by studying the reactivity of ferrate(V) with NCO(-) in a homogeneous solution using a premix pulse radiolysis technique. The rate constant for the reaction of ferrate(V) and NCO(-) in alkaline medium was estimated to be (9.60+/-0.07) x 10(2) M(-1) s(-1), which is much slower than the ferrate(VI) self-decomposition reaction (k approximately 10(7) M(-1) s(-1)). An analysis of the kinetic data in the Fe(VI)-UV-TiO2-NCO(-) system suggests that ferrate(V) is not directly participating in the oxidation of cyanate. Possible reactions in the system are presented to explain results of ferrate(VI) reduction and oxidation of cyanate.     

WATER SHORTAGES,DEVELOPMENT, AND DROUGHT IN ROCKLAND COUNTY,NEW YORK1

Knowledge of the historical variability of regional climate is an essential element of successful water resource planning. Lacking such perspective, planners and managers can be deceived as to the severity of a recent climate extreme, such as drought, and place a disproportionate blame on the climate, not the integrity of the supply system should water restrictions become necessary to avoid shortages. Presented here is a vivid example of how development, a lack of adequate planning, and climate variability have converged to produce three water emergencies in Rockland County, New York, since 1995. An examination of climate data over the past century indicates that the severity of the recent droughts was well within the range of past variability. Rather than climate alone, the recent water emergencies have highlighted a significant mismatch between supply and demand that has been developing in Rockland County over the past three decades. Substantial development, largely in the form of single‐family homes, has not been matched with a corresponding enhancement of the county's water system. Realistic plans for meeting current water demand will require cooperation among all stakeholders, beginning with an acknowledgement that climate variations are inevitable, not the sole source of blame when water shortages arise.