A comparative study on the autoxidation of dimethyl ether (DME) comparison with diethyl ether (DEE) and diisopropyl ether (DIPE)

The Japanese government is planning to introduce DME as a substituted energy for oil and LNG. Introduction of DME could contribute greatly to both the prevention of global warming and the formation of resource-recycling societies. In these circumstances, a safety assessment of DME is very important when DME is used on a large scale. There is a possibility that prolonged exposure in air induces autoxidation to produce explosive organic peroxides during transportation and storage of DME. Therefore, the reactivity of DME with oxygen and the mechanism of the autoxidation were investigated. Accelerating Rate Calorimetry (ARC) was used to evaluate the thermal stability of DME and DIPE, a known peroxide producers, under adiabatic and various atmospheric conditions. In ARC studies of DME under oxygen, exothermic decompositions were detected although its self-heating rate was low in comparison with DIPE. Oven storage tests were carried out and iodimetry was used to measure the concentration of peroxides produced from DME in comparison with DIPE and DEE. However, no products could be found for DME either by GC/MS or by iodimetry, while some evidence of autoxidation of both DEE and DIPE were obtained from these experiments.     

Reduction in toxicity and generation of slag in secondary lead process

This paper focuses on the improvement of a secondary lead recycling processing plant, giving special attention to the generation of lead slag. The study was conducted using two different industrial rotary furnaces that together produce three different slag types, which depend on charge composition and lead-containing raw material obtained from a lead-acid battery recycling process. First, characterization of three slag types from different batches was performed, and such characterization included chemical, mineralogical, and structural analyses. By analyzing these data and the operational conditions of the process, it was possible to identify certain deficiencies in the recycling process and implement modifications in order to improve it. A reduction of up to 25% in the quantity of slag generated could be achieved with certain charges. In addition to this process improvement, it was possible to reduce the toxicity of the slag produced when processing a charge containing the same proportion of paste and grid as the lead-acid battery. This improvement lessens the overall environmental impact of the process. By applying this methodology, it was possible to determine some principles of cleaner production in the lead recycling process. So, waste generation could be reduced via improvements in the process and slag characteristics were modified to decrease its toxicity (as determined by lead content in leaching tests).     

Male mate choice and male–male competition in the hermit crab Pagurus nigrofascia: importance of female quality

Male mate choice has recently been reported in some animals with male–male competition. In the laboratory, we examined whether males choose their mates based on female quality that was indicated by body size and/or days to prenuptial molt, and the effects of female quality on male–male competition in the hermit crab Pagurus nigrofascia. We collected samples from April to May 2009 at an intertidal shore in Hokkaido, Japan (41°N, 140°E). When a male simultaneously encountered two receptive females in the mate choice experiment, males chose females which require less time to molt. When a male guarding a female with less time to molt was challenged by an intruder, the guarding male defended the female for a longer period and was more likely to win the contest. These results indicate that male P. nigrofascia use time to molt to discriminate between females.     

Humic-like substances global levels and extraction methods in aerosols

Environmental Chemistry Letters - The abundance of humic-like substances in the atmosphere has received considerable attention since these substances play an important role in various atmospheric...