生物质炭强化FeOOH类芬顿催化性能及其机制

采用醇助水热法制备了新型生物质炭修饰的α-FeOOH类芬顿催化剂（BC-FeOOH）,并通过扫描电子显微镜（SEM）、透射电子显微镜（TEM）、X射线衍射（XRD）、傅里叶变换红外光谱（FTIR）对催化剂进行了表征,证明生物质炭（BC）成功引入到α-FeOOH中.以罗丹明B（RhB）为目标污染物,考察了BC修饰量、催化剂及H₂O₂投加量对其催化效率的影响.结果表明,BC的引入可以极大地提高FeOOH的类芬顿催化性能.在pH中性、催化剂投加量0.6 g·L^-1、H₂O₂初始浓度10 mmol·L^-1的条件下,BC-FeOOH（22.2% BC）对RhB的降解率可达到90%,重复利用5次活性仍可保持在80%左右,且铁离子溶出浓度仅为0.08 mg·L^-1.进一步通过ESR在不同体系中的测试结果表明,BC的引入不仅可促进H₂O₂有效还原分解产生更多的羟基自由基（·OH）,而且增强了催化剂与污染物RhB的相互作用,促使污染物失电子氧化降解,从而提高了FeOOH的催化活性及催化稳定性.     

滦河秋季大型底栖动物群落结构空间格局与关键环境影响因子识别

掌握水生生物的空间分布特征及其关键影响因子是科学制定生物多样性保护策略的基础.于2016年秋季对滦河53个样点开展了大型底栖动物和环境因子的现场调查,分析了大型底栖动物群落结构与空间分布特征,并识别出影响大型底栖动物物种空间分布的关键环境因子.结果表明:①滦河（河北省）共采集并鉴定出大型底栖动物206种,隶属于8纲22目70科144属,以纹石蚕（Hydropsyche sp.）和东方蜉蝣（Ephemera orientalis）为优势种.②根据滦河大型底栖动物群落结构相似性,53个样点在空间上被分为3组.第1组分布在滦河干流的中下游及支流下游,无指示物种;第2组分布在支流上游,指示种为纹石蚕、朝大蚊（Antocha sp.）和中华小长臂虾（Palaemonetes sinensis）;第3组分布在滦河干流中上游,指示种为东方蜉蝣和中华齿米虾（Neocaridina denticulate sinensis）.③第3组的分类单元数显著高于第1组和第2组;第1组的多样性指数显著高于第2组;第1组的均匀度指数显著高于其他2组.单因素方差分析（one-way ANOVA）发现,pH、TN、底质、河道变化、水质状况和河岸土地利用类型等环境因子在第2组与第3组之间差异显著,第2组明显高于第3组.典范对应分析（CCA）表明,栖境复杂性、河水水量状况和河岸土地利用类型是影响滦河大型底栖动物空间分布的关键环境因子.研究显示,降低河岸带干扰强度、恢复河道生境多样性是未来滦河大型底栖动物多样性保护恢复的重要管理措施.      

Methane emission in a rice field of Thailand

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5—Br—PADAP光度法测定海洋底质中微量钴

讨论了用５－Ｂｒ－ＰＡＤＡＰ作显色剂测定海洋底质中微量然的方法和测定条件。在ＰＨ值为４．７的ＨＡｃ－ＮａＡｃ溶液中，试剂与Ｃｏ＾２＋形成一灵敏的紫色络合物。通过使用ＮＨ４Ｆ和Ｚｎ－ＥＤＴＡ掩蔽剂，有效地消除了海洋底质中复杂组分的干扰，方法选择性好，简便快速。     

区域大气污染空间效应及产业结构影响

目前,中国大气污染问题愈发严峻,由大气污染所导致的公共健康风险及经济损失日益突出,探询污染的形成原因、影响因素是制定治理政策的重要依据。本文针对大气污染的主要污染物PM10进行研究,特别探讨中国31个省市自治区本地与异地之间PM10交互影响的问题及产业结构影响。首先,分析全局空间相关性,发现地区间PM10存在着空间自相关,且逐年增强;其次分析局域相关性,发现中国北方部分地区出现高-高类型的集聚,主要集中于北京、天津、河北、山西、山东、河南、黑龙江、吉林和辽宁等9个省份;南方部分地区出现低-低类型的集聚,主要集中于广东、海南、广西、贵州以及云南等5个省份。虽出现个别年份的波动,但从长期看,各集聚区均处于较稳定状态;第三,建立空间计量模型对PM10进行比较全面的模型数据分析,包括经济社会、经济结构以及气候等因素对PM10的影响,以较为新颖的视角刻画PM10的形成,发现地区间PM10的交互影响存在着"负效应",分析表明这种"负效应"具有短期性,而且"负效应"与"溢出效应"可能存在联系。此外,重点分析工业中对PM10贡献较大的典型行业,以及以典型行业为代表的工业结构对我国东、中、西部地区PM10的影响特点,与劣质煤进口量逐年增大的事实相结合,阐述了降低PM10的困难所在。最后,基于实证分析结果论证影响不同地区PM10的主导因素,空间因素对PM10的影响,长期看在部分地区通过产业转移的方式降低PM10的不可行性;论证中,以北京地区为主要分析案例,发现交通拥堵程度以及空间因素是其出现高雾霾的重要原因。根治雾霾,区域间的联合治理势在必行。     

Effects of Cu2+ and humic acids on degradation and fate of TBBPA in pure culture of Pseudomonas sp. strain CDT

Soil contamination with tetrabromobisphenol A(TBBPA) has caused great concerns;however, the presence of heavy metals and soil organic matter on the biodegradation of TBBPA is still unclear. We isolated Pseudomonas sp. strain CDT, a TBBPA-degrading bacterium, from activated sludge and incubated it with ~(14)C-labeled TBBPA for 87 days in the absence and presence of Cu~(2+)and humic acids(HA). TBBPA was degraded to organic-solvent extractable(59.4% ± 2.2%) and non-extractable(25.1% ± 1.3%) metabolites,mineralized to CO_2(4.8% ± 0.8%), and assimilated into cells(10.6% ± 0.9%) at the end of incubation. When Cu~(2+)was present, the transformation of extractable metabolites into non-extractable metabolites and mineralization were inhibited, possibly due to the toxicity of Cu~(2+)to cells. HA significantly inhibited both dissipation and mineralization of TBBPA and altered the fate of TBBPA in the culture by formation of HA-bound residues that amounted to 22.1% ± 3.7% of the transformed TBBPA. The inhibition from HA was attributed to adsorption of TBBPA and formation of bound residues with HA via reaction of reactive metabolites with HA molecules, which decreased bioavailability of TBBPA and metabolites in the culture. When Cu~(2+)and HA were both present, Cu~(2+)significantly promoted the HA inhibition on TBBPA dissipation but not on metabolite degradation. The results provide insights into individual and interactive effects of Cu~(2+)and soil organic matter on the biotransformation of TBBPA and indicate that soil organic matter plays an essential role in determining the fate of organic pollutants in soil and mitigating heavy metal toxicity.     

Cost-performance analysis of nutrient removal in a full-scale oxidation ditch process based on kinetic modeling

A full-scale oxidation ditch process for treating sewage was simulated with the ASM2d model and optimized for minimal cost with acceptable performance in terms of ammonium and phosphorus removal. A unified index was introduced by integrating operational costs (aeration energy and sludge production) with effluent violations for performance evaluation. Scenario analysis showed that,in comparison with the baseline (all of the 9 aerators activated), the strategy of activating 5 aerators could save aeration energy significantly with an ammonium violation below 10%. Sludge discharge scenario analysis showed that a sludge discharge flow of 250–300 m3/day (solid retention time (SRT), 13–15 days) was appropriate for the enhancement of phosphorus removal without excessive sludge production. The proposed optimal control strategy was: activating 5 rotating disks operated with a mode of "111100100" ( "1"represents activation and "0" represents inactivation) for aeration and sludge discharge flow of 200 m3/day (SRT, 19 days). Compared with the baseline, this strategy could achieve ammonium violation below 10% and TP violation below 30% with substantial reduction of aeration energy cost (46%) and minimal increment of sludge production (< 2%). This study provides a useful approach for the optimization of process operation and control.     

Influences of perfluorooctanoic acid on the aggregation of multi-walled carbon nanotubes

The aggregation of multi-walled carbon nanotubes (MWCNTs) in the aqueous phase not only inhibits their extensive utilization in various aspects but also dominates their environmental fate and transport.The role of surfactants at low concentration in the aggregation of MWCNTs has been studied,however the effect of perfluorinated surfactants at low concentration is uncertain.To understand this interfacial phenomenon,the influences of perfluorooctanoic acid (PFOA),and sodium dodecyl sulfate (SDS) as a control,on MWCNT aggregation in the aqueous phase were examined by the UV absorbency method.Influences of pH and cationic species on the critical coagulation concentration (CCC) value were evaluated.The CCC values were dependent on the concentration of PFOA,however a pronounced effect of SDS concentration on the CCC values was not observed.The CCC values of the MWCNTs were 51.6 mmol/L in NaCl and 0.28 mmol/L in CaCl 2 solutions,which suggested pronounced differences in the effects of Na+ and Ca2+ ions on the aggregation of the MWCNTs.The presence of both PFOA and SDS significantly decreased the CCC values of the MWCNTs in NaCl solution.The aggregation of the MWCNTs took place under acidic conditions and was not notably altered under neutral and alkaline conditions due to the electrostatic repulsion of deprotonated functional groups on the surface of the MWCNTs.     

污染源管理信息化建设的思考

污染源管理是环境监管的重点,信息化是提高污染源管理水平的重要手段。阐述污染源管理信息化现状,分析污染源管理信息来源及信息化发展中的不足,提出加强基层环保部门污染源监管信息化建设的建议,为污染源管理信息化建设提供借鉴。     

适应气候变化是当务之急

地球气候变化既有自然因素又有人为因素,全球变暖主要原因是人类活动温室气体排放过度。因此,在应对气候变化问题上,人们对减排温室气高度重视是理所当然,而长期以来对＂适应气候变化＂却有所忽视。其实,对发展中国家《适应气候变化》才是当务之急。本文在＂发展低碳经济,应对全球变暖＂减排二氧化碳温室气体的基础上,论述适应气候变化的迫切性和基本途径。