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对白洋淀地区不同类型纸厂排水口底泥及保定市排污渠底泥进行了GC/ECD分析,可萃取有机氯(EOCl)含量测定,检出了多氯联苯和有机氯农药。用截止分子量为1000道尔顿的透析袋方法对相应地区的水体进行了检测,发现水体中可检出含氯农药六六六,但多氯联苯等由于水中存在浓度低未能检出,同样样品的GC/MS/COM结果表明,水体中主要存在的亲脂性有机污染物为:蒽酮、蒽二酮、苯胺、氯代烃、邻苯二甲酸酯类和苯系物。 相似文献
3.
λDNA体外重包装技术检测环境致突变物新方法及机理的研究 总被引:2,自引:0,他引:2
首次报道使用λDNA体外重包装技术检测化学物和环境污染致封变性取得了成功,辅以辅切和电泳技术,还可初步确定λDNA损伤的机遇。 相似文献
4.
Yangfan Yuan Changai Zhang Chenhao Zhao Bing Wang Xiaozhi Wang Bin Gao Shengsen Wang J?rg Rinklebe 《环境科学学报(英文版)》2023,35(3):26-36
Herein,a one-step co-pyrolysis protocol was adopted for the first time to prepare a novel pyrogenic carbon-Cu0/Fe3O4 heteroatoms (FCBC) in CO2 ambiance to discern the roles of each component in PDS activation.During co-pyrolysis,CO2 catalyzed formation of reducing gases by biomass which facilitated reductive transformation of Fe3+ and Cu2+ to Cu0 and Fe3O4,respectively.According to the a... 相似文献
5.
Per-and polyfluoroalkyl substances(PFASs) are ubiquitous in sludge and water from waste water treatment plants, as a result of their incorporation in everyday products and industrial processes. In this study, we measured several classes of persistent PFASs,precursors, transformation intermediates, and newly identified PFASs in influent and effluent sewage water and sludge from three municipal waste water treatment plants in Sweden, sampled in 2015. For sludge, samples from 2012 and 2014 were analyzed as well.Levels of precursors in sludge exceeded those of perfluoroalkyl acids and sulfonic acids(PFCAs and PFSAs), in 2015 the sum of polyfluoroalkyl phosphoric acid esters(PAPs) were 15–20 ng/g dry weight, the sum of fluorotelomer sulfonic acids(FTSAs) was 0.8–1.3 ng/g,and the sum of perfluorooctane sulfonamides and ethanols ranged from non-detected to 3.2 ng/g. Persistent PFSAs and PFCAs were detected at 1.9–3.9 ng/g and 2.4–7.3 ng/g dry weight, respectively. The influence of precursor compounds was further demonstrated by an observed substantial increase for a majority of the persistent PFCAs and PFSAs in water after waste water treatment. Perfluorohexanoic acid(PFHxA), perfluorooctanoic acid(PFOA), perfluorohexane sulfonic acid(PFHxS), and perfluorooctane sulfonic acid(PFOS)had a net mass increase in all WWTPs, with mean values of 83%, 28%, 37% and 58%,respectively. The load of precursors and intermediates in influent water and sludge combined with net mass increase support the hypothesis that degradation of precursor compounds is a significant contributor to PFAS contamination in the environment. 相似文献
6.
Seepage from Hg mine wastes and calcines contains high concentrations of mercury (Hg). Hg pollution is a major environmental
problem in areas with abandoned mercury mines and retorting units. This study evaluates factors, especially the hydrological and
sedimentary variables, governing temporal and spatial variation in levels and state of mercury in streams impacted by Hg contaminated
runo . Samples were taken during di erent flow regimes in theWanshan Hg mining area in Guizhou Province, China. In its headwaters
the sampled streams/rivers pass by several mine wastes and calcines with high concentration of Hg. Seepage causes serious Hg
contamination to the downstream area. Concentrations of Hg in water samples showed significant seasonal variations. Periods of
higher flow showed high concentrations of total Hg (THg) in water due to more particles being re-suspended and transported. The
concentrations of major anions (e.g., Cl??, F??, NO3?? and SO4
2??) were lower during higher flow due to dilution. Due to both sedimentation
of particles and dilution from tributaries the concentration of THg decreased from 2100 ng/L to background levels (< 50 ng/L) within
10 km distance downstream. Sedimentation is the main reason for the fast decrease of the concentration, it accounts for 69% and 60%
for higher flow and lower flow regimes respectively in the upper part of the stream. Speciation calculation of the dissolved Hg fraction
(DHg) (using Visual MINTEQ) showed that Hg(OH)2 associated with dissolved organic matter is the main form of Hg in dissolved
phase in surface waters in Wanshan (over 95%). 相似文献
7.
<正>今年入秋以来,支原体肺炎就呈现出抢占各地百姓生活头条的趋势,尤其在儿童青少年中发病率居高不下,家长们也特别焦虑,一有风吹草动就要去医院,客观上加剧了当前医院儿科门诊患者扎堆、就诊量居高不下的现象。立冬后气温还会进一步降低,我们如何科学应对支原体肺炎,保持健康的身体?笔者这里就和大家说说有关支原体肺炎及其预防康复事宜。 相似文献
8.
三峡库区水环境多环芳烃和邻苯二甲酸酯类有机污染物健康风险评价 总被引:17,自引:1,他引:16
为研究三峡库区水环境中持久性有机污染物(POPs)对人体健康产生的潜在危害风险,在介绍健康风险评价方法的基础上,建立了水环境健康风险评价模型,根据三峡库区水质监测资料对水源水主要持久性有机物多环芳烃和邻苯二甲酸酯类污染进行健康风险评价. 结果表明,在所评价断面中,长江和嘉陵江汇合的寸滩断面污染较严重,健康危害的风险相对较大. 水源水6种持久性有机污染物由饮水途径所致健康危害的个人年风险为2.79×10-10~4.44×10-13 a-1,按年风险大小依次为DEHP>DBP>Pyr>NA>FLA>DEP;有机污染物对健康危害的年总风险仅为3.70×10-10 a-1,远低于国际辐射防护委员会(ICRP)推荐的最大可接受值(5.0×10-5 a-1). 三峡库区水体中6种POPs污染所致的健康危害年风险度目前还处于很低水平,但应引起管理部门的重视. 相似文献
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This article presents the results of laboratory tests on the combined effect of whole-body vibration (WBV) and hand-arm vibration (HAV). The reactions of subjects exposed to various combinations of vibration were recorded. The vibrotactile perception threshold (VPT) test identified changes caused by exposure to vibration. Ten male subjects met the criteria of the study. There were 4 series of tests: a reference test and tests after exposure to HAV, WBV, and after simultaneous exposure to HAV and WBV. An analysis of the results (6000 ascending and descending VPTs) showed that the changes in VPTs were greatest after simultaneous exposure to both kinds of vibration. The increase in VPT, for all stimulus frequencies, was then higher than after exposure to HAV or WBV only. 相似文献