Preparation of Viscose Fibres Stripped of Reactive Dyes and Wrinkle-Free Crosslinked Cotton Textile Finish

The chemical recycling of cellulosic fibres may represent a next-generation fibre–fibre recycling system for cotton textiles, though remaining challenges include how to accommodate fibre blends, dyes, wrinkle-free finishes, and other impurities from finishing. These challenges may disrupt the regeneration process steps and reduce the fibre quality. This study examines the impact on regenerated viscose fibre properties of a novel alkaline/acid bleaching sequence to strip reactive dyes and dimethyloldihydroxyethyleneureas (DMDHEU) wrinkle-free finish from cotton textiles. Potentially, such a bleaching sequence could advantageously be integrated into the viscose process, reducing the costs and environmental impact of the product. The study investigates the spinning performance and mechanical properties (e.g., tenacity and elongation) of the regenerated viscose fibres. The alkaline/acid bleaching sequence was found to strip the reactive dye and DMDHEU wrinkle-free finish from the cotton fabric, so the resulting pulp could successfully be spun into viscose fibres, though the mechanical properties of these fibres were worse than those of commercial viscose fibres. This study finds that reactive dyes and DMDHEU wrinkle-free finish affect the viscose dope quality and the regeneration performance. The results might lead to progress in overcoming quality challenges in cellulosic chemical recycling.     

Using fuzzy set theory to address the uncertainty of susceptibility to drought

This paper presents the technical aspects of a new methodology for assessing the susceptibility of society to drought. The methodology consists of a combination of inference modelling and fuzzy logic applications. Four steps are followed: (1) model input variables are selected—these variables reflect the main factors influencing susceptibility in a social group, population or region, (2) fuzzification—the uncertainties of the input variables are made explicit by representing them as ‘fuzzy membership functions’, (3) inference modelling—the input variables are used to construct a model made up of linguistic rules, and (4) defuzzification—results from the model in linguistic form are translated into numerical form, also through the use of fuzzy membership functions. The disadvantages and advantages of this methodology became apparent when it was applied to the assessment of susceptibility from three disciplinary perspectives: Disadvantages include the difficulty in validating results and the subjectivity involved with specifying fuzzy membership functions and the rules of the inference model. Advantages of the methodology are its transparency, because all model assumptions have to be made explicit in the form of inference rules; its flexibility, in that informal and expert knowledge can be incorporated through ‘fuzzy membership functions’ and through the rules in the inference model; and its versatility, since numerical data can be converted to linguistic statements and vice versa through the procedures of ‘fuzzification’ and ‘defuzzification’.     

Mikrobielle Sanierung von 2,4,6-Trinitrotoluol (TNT) kontaminierten Böden

Within the limits of a feasability study abouton-site bioremediation methods for TNT-contaminated soils, composting was chosen as a very promising and cheap method. This method was critically compared with those described in the literature and was primarily rated under ecotoxicological aspects. The investigated location is the former munition plant «Tanne» in the aerea of Clausthal-Zellerfeld in Lower Saxony, Germany. To estimate the autochtonic microflora, we assessed the number of aerobic heterotrophic bacteria and determined their respiration activity in soils. In addition, we isolated bacteria and examined their capacity to metabolize TNTin vitro. Both the amount of autochtonic microrganisms (4.7×10⁸ to 1.2×10¹⁰ colony forming units (cfu)/kg dryweight) as well as their respiration activity did not correlate with the concentrations of nitrotoluenes in the soils. With high contaminated soil (20 g TNT/kg dry weight) we carried out a small compost in the range of 10 liters. During 28 days of composting TNT-concentration decrease over 90% and only minor amounts of monoaminodinitrotoluenes were generated. However, an acidic pretreatment of the compost material at the end of the reaction showed that TNT could be partially resolved under these extreme conditions and that an ecotoxicological risk may still exist. Possible changes in the realization of the composting process in order to make sure that the contaminants are savely bound to the humin matrix are discussed.     

Prenatal diagnosis and molecular cytogenetic characterisation of a small de novo interstitial duplication 16q11.2-q13

We describe the first prenatally detected case of a small de novo interstitial duplication of chromosome 16q. This chromosomal aberration is extremely rare. Amniocentesis was indicated by advanced maternal age only. Ultrasound examinations of the foetus showed no abnormalities. Conventional and molecular cytogenetic analyses on cultured amniocytes by comparative genomic hybridisation (CGH) and fluorescence in situ hybridisation (FISH) using partial chromosome paints and a locus-specific YAC clone revealed a de novo direct duplication of the chromosomal region 16q11.2-q13 leading to a partial trisomy 16q (46,XX,dup(16)(q11.2q13)). There are only five postnatal reports of comparable duplications involving this chromosomal region. These patients presented with little or no associated dysmorphic features but with significant neurodevelopmental delay and severe behavioural problems. After genetic counselling, the parents opted for termination of pregnancy. Post-mortem examination showed slight facial dysmorphic signs, minor dysgenesis of the ovaries and an atypical outflow of the arteria thyroidea ima. Copyright © 2006 John Wiley & Sons, Ltd.     

Vulnerability assessment of sea-level rise in Viti Levu, Fiji Islands

Fiji is expected to come under increasing pressure and risk from various threats resulting from climate change and sea-level rise (SLR). Fiji consists of 332 islands and thus has a predominant and large coastline. Viti Levu is the largest and most important of the islands, harboring Fiji’s capital city and most of the major towns concentrated around its coast. The objectives of this study were to evaluate the extent of possible sea-level rise using GIS, and to identify high-risk locations. Potential sea level rise was shown graphically as an output to determine where inundation or flooding would take place. This analysis allowed important areas facing risk to be highlighted for future action. Flooding/inundation can be classified into two kinds: ‘permanent inundation’, which is the result of sea-level rise with tide; and ‘temporary flooding’, also including occasional storm surge events. The inundated area was displayed under different projections and quantified. The results produced output maps showing the distribution of inundation/flooding around the island of Viti Levu as well as the extent of flooding. Six scenarios for sea-level rise were used (0.09, 0.18, 0.48, 0.50, 0.59, 0.88 m). Six scenarios for storm surge were used with return intervals of 1, 2, 5, 10, 25, 50 years. High risk and priority locations are identified as Fiji’s capital Suva, the major tourist center and arrival port of Nadi, and Fiji’s second city Lautoka. Future action, adaptation and response strategies in these identified locations must occur to reduce risk from climate change.