液相色谱-质谱法测定水中氨基甲酸酯类农药及其代谢物

建立了直接测定水中10种氨基甲酸酯类农药及其代谢物的超高效液相色谱-质谱分析方法。该方法对水样无需进行富集处理,水样过滤后就可以直接测定。实验结果表明:测定液中各氨基甲酸酯类农药及其代谢物的质量浓度与离子对峰面积在质量浓度0.5～1 000.0μg/L内具有良好的线性关系;方法检出限为0.1～5.0μg/L;加标回收率91%～103%;相对标准偏差为2%～5%。该方法具有简便快捷、灵敏度高的特点。     

介质阻挡放电联合催化臭氧化降解甲苯

采用介质阻挡放电区后结合MnOx/Al2O3/发泡镍去除甲苯,考察甲苯进气方式、臭氧产生方法及湿度对甲苯与O3同时去除的影响。结果表明,O3是等离子体区后催化降解甲苯的主要物种,介质阻挡放电联合催化臭氧化可实现甲苯及O3的同时高效去除。输入电压为9.0 kV时,甲苯的去除效率达92.8%,在80 min内O3的去除效率维持在99%以上。水蒸气对催化剂催化分解臭氧的活性没有直接的影响,O3浓度较高时湿度对甲苯降解效率的影响很小。GC-MS分析结果表明,甲苯降解的主要气相副产物有烷烃、酸、酮和含苯环有机物,提出了甲苯的降解途径。     

Life cycle assessment tool of electricity generation in Portugal

This paper investigates multi-stakeholder arrangements initiated by businesses and NGOs from the North that aim to enhance a more sustainable agricultural production at specific localities in Southern countries. We aim to better understand the search for concerted action in multi-actor arrangements. Therefore, this paper presents a diagnostic framework with three strategic challenges the partnership projects are facing: linking global economic objectives to local needs, values and interests; bridging public and private interests and responsibilities; and seeking trade-offs between social, environmental and economic values. Starting from the partnerships’ Theory of Change, this diagnostic framework is applied to comparative case studies of partnership projects in the cocoa sector in Indonesia, which are part of a Northern-based public–private partnership to improve farmers’ prospective. It is concluded that the economic reality faced by the farmers differs from that of the Northern actors; collaboration with governments is difficult because of different organizational cultures; and the partnership projects underestimate the strength of vested social relations the smallholders are part of. Overall, the initiators of the partnerships seem to work with a too restricted economic interpretation of the local reality.     

Behavioral intentions toward genetically modified crops in Southwest Iran: a multi-stakeholder analysis

This study examined the influencing factors of the self-reported behavioral intentions toward genetically modified (GM) crops using a multi-stakeholder approach in the Khuzestan Province in Southwest Iran. The study focused on three different groups, including: “agricultural students,” “agricultural private firms’ managers” and “rich-resource farmers.” Data were collected using a researcher-made questionnaire and was analyzed by SPSS (V20) and AMOS (V20). Results indicated that the respondents perceive more benefits than risks for GM crops and that the perception of benefits and risks, respectively, had positive and negative impacts on the self-reported behavioral intention of the respondents. The knowledge of the respondents regarding these crops had positive impacts on perception of benefits. The results showed that both managers and students worried about the food safety and impact of GM crops on human health while farmers worried about the environmental risks of GM crops. The results also revealed that those who are the most conscious about GM crops are more trusted. The findings also showed that the majority of the respondents hold a positive view of the potential of GM crops.     

Delineation of potential ground water-bearing zones in the Barind tract of West Bengal,India

The Barind tract of West Bengal is an area of tropical sub-humid region composed of old alluvial soil. The area has high water demand due to growing population pressure and intensification in agricultural activity. These create huge stress on surface and ground water availability. Continuous withdrawal of ground water has become an alternative source of irrigation water which has also again made the condition critical. Ground water level has been lowered down drastically in many parts in this region. Under this circumstance, it is necessary to delineate potential ground water-bearing layers. Therefore, the present study attempts to identify potential ground water-bearing zones to manage ground water effectively. Instead of usually used parameters for ground water potentiality delineation here only some particular litholog parameters like breadth of water-bearing layer, depth of water-bearing layer, presence of clay layer above or below major water-bearing layer have been considered for delimiting the same. The result shows that out of total area, 60% area (405,382.2 ha) falls under very low to low potential ground water-bearing zone and only 8.19% area (55,634.97 ha) is potential. Considering this spatial pattern of ground water availability, harvesting structure and magnitude of water withdrawing should be designed.     

Modeling of agricultural drought risk pattern using Markov chain and GIS in the western part of Bangladesh

The aim of the study is to assess the agricultural drought risk condition in the context of global climate change in the western part of Bangladesh that covers about 45% area of the country for the period of 1960–2011. Drought Index (DI) and Drought Hazard Index (DHI) have been calculated by Markov Chain analysis and that of Drought Vulnerability Index (DVI) from socioeconomic and physical indicators. The DI values show that the northern part in general is more drought-prone, having less crops prospect, whereas the southern part is less drought-prone with high crop potentiality. The probability of extreme drought occurrence increases in recent decades in some parts as a result the drought events become more frequent in the areas. The DHI ranges from 15 to 32, and northern part suffers from more extreme drought hazards than that of southern part. DVI also indicates that northern part is exposed to high to very high drought vulnerability as higher percentage of illiterate people are involved in agricultural practices and high percentage of irrigation to cultivable land, but southern part exposed to moderate to low vulnerability because of low values of vulnerability indicators. Finally, agricultural drought exists at high risk condition in northern part and low in southern parts and 21.63, 26.54 and 29.68% of the area poses very high, high and moderate risk, respectively. So, immediate adaptation measures are needed keeping in mind climate features like rainfall and temperature variability, drought risk and risk ranking to make viable adaptation measures.     

Assessment of hydrothermally modified fly ash for the treatment of methylene blue dye in the textile industry wastewater

Dyes and pigments are one of the major water pollutants and if not discharged properly cause ecological disturbance. Considering this, the current study investigates the application of thermal power plant by-product, i.e., fly ash for the elimination of a hazardous methylene blue dye from its synthetic aqueous solution. Experiments were conducted in batch mode to study the effect of pH, temperature, adsorbent dose and contact time. Highest dye removal (94.3%) was achieved at pH 10 using adsorbent dose of 10 g/L in 90 min of contact time at 40 °C. However, for cost-effective operation at neutral pH and room temperature (30 °C), it yields 89.3% dye removal having similar dose and contact time. Equilibrium isotherms for adsorption were analyzed by Langmuir and Freundlich, Temkin and Dubinin–Radushkevich isotherm equations. The results revealed that the best fit model of adsorption closely followed Langmuir adsorption. Based on adsorption isotherm models, thermodynamics parameters ΔG, ΔH and ΔS were calculated. The negative value of ΔG and ΔH revealed that adsorption process was exothermic, spontaneous and physical. The present work suggests that through simple process hydrothermally modified fly ash has the potential to be used as cost-effective and efficient adsorbent for the treatment of wastewater from textile industries.     

Human appropriation of net primary production (HANPP) in seagrass ecosystem: an example from the east coast of Bintan Regency,Kepulauan Riau Province,Indonesia

Seagrass ecosystems have a role as providers of ecosystem services and have been used by fisherman for a long time. Information about the connectivity between seagrass ecosystems and fishermen in Indonesia is limited; therefore, this study aims to measure the relationship between the seagrass ecosystem and fishermen in Bintan Regency, Kepulauan Riau Province, Indonesia. The research was conducted from December 2014 to May 2015 in the villages of Teluk Bakau, Malang Rapat, Berakit and Pengudang. The human appropriation of net primary production (HANPP) approach was used to measure that connectivity. Seagrasses, planktons, fishes, crabs, squids and mollusks were observed during the East and North seasons. The results showed that HANPP in the East season (March–May) is 62.8 Gg (77.1%) and in the North season (December–February) is 68.8 Gg (84.5%) with an efficiency of, respectively, 77.7 and 79.7%. The traditional fishermen are highly dependent on the seagrass ecosystem. They use the seagrass ecosystem in both the East and North seasons. The proper management of seagrass ecosystem is needed in order to make the life of a traditional fisherman in the Bintan Regency sustainable.