用BaCl2滴定法快速测定硫酸盐的研究

用铬酸钡光度法、EDTA滴定法、间接原子吸收法、离子色谱法等方法测定SO42-检测上限都很低(12-200mg/L),且只适用于清洁水,若水样混浊则全引起较大的误差.有的地下水,SO42-浓度高达44000mg/L,用BaCl2滴定法测定SO42-:测试水样,以溴酚蓝做酸碱指示剂,加1∶50盐酸,调为pH=3.5,加入30ml异丙醇,以钍试剂做终点指示剂,滴加0.01mol/L BaCl2,砖红色为终点,根据BaCl2用量计算SO42-浓度.本方法快捷、准确、测定范围大,上限可达2000mg/L,克服了光度法测定浑浊水样引起误差大的缺点.     

Responses of Hyalella azteca and phytoplankton to a simulated agricultural runoff event in a managed backwater wetland

We assessed the aqueous toxicity mitigation capacity of a hydrologically managed floodplain wetland following a synthetic runoff event amended with a mixture of sediments, nutrients (nitrogen and phosphorus), and pesticides (atrazine, S-metolachlor, and permethrin) using 48-h Hyalella azteca survival and phytoplankton pigment, chlorophyll a. The runoff event simulated a 1 h, 1.27 cm rainfall event from a 16 ha agricultural field. Water (1 L) was collected every 30 min within the first 4 h, every 4 h until 48 h, and on days 5, 7, 14, 21, and 28 post-amendment at distances of 0, 10, 40, 300 and 500 m from the amendment point for chlorophyll a, suspended sediment, nutrient, and pesticide analyses. H. azteca 48-h laboratory survival was assessed in water collected at each site at 0, 4, 24, 48 h, 5 d and 7 d. Greatest sediment, nutrient, and pesticide concentrations occurred within 3 h of amendment at 0 m, 10 m, 40 m, and 300 m downstream. Sediments and nutrients showed little variation at 500 m whereas pesticides peaked within 48 h but at <15% of upstream peak concentrations. After 28 d, all mixture components were near or below pre-amendment concentrations. H. azteca survival significantly decreased within 48 h of amendment up to 300 m in association with permethrin concentrations. Chlorophyll a decreased within the first 24 h of amendment up to 40 m primarily in conjunction with herbicide concentrations. Variations in chlorophyll a at 300 and 500 m were associated with nutrients. Managed floodplain wetlands can rapidly and effectively trap and process agricultural runoff during moderate rainfall events, mitigating impacts to aquatic invertebrates and algae in receiving aquatic systems.     

Assessment of pesticide contamination in three Mississippi Delta oxbow lakes using Hyalella azteca

Three oxbow lakes in northwestern Mississippi, USA, an area of intensive agriculture, were assessed for biological impairment from historic and current-use pesticide contamination using the amphipod, Hyalella azteca. Surface water and sediment samples from three sites in each lake were collected from Deep Hollow, Beasley, and Thighman Lakes from September 2000 to February 2001. Samples were analyzed for 17 historic and current-use pesticides and selected metabolites. Ten-day H. azteca survival and growth (as length and dry weight) were measured to determine the degree of biological impairment. Maximum number of detectable pesticides in surface water from Deep Hollow, Beasley and Thighman Lakes was 10, 11, and 17, respectively. Maximum number of detectable pesticides in lake sediments was 17, 17, and 15, respectively. Bioassay results indicated no observable survival effects on H. azteca exposed to surface water or sediment from any lake examined and no growth impairment in animals exposed to lake sediments. However, growth was significantly impaired in surface water exposures from Deep Hollow Lake (2 sites) and Beasley Lake (1 site). Statistically significant relationships between growth impairment (length) and cyanazine, methyl parathion, λ-cyhalothrin, chlorfenapyr, and pp′DDE surface water concentrations in Deep Hollow Lake as well as trifluralin, atrazine, and methyl parathion in Beasley Lake were observed. Although pesticide frequency and concentrations were typically greater in sediment than surface water, bioassay results indicated decreased availability of these pesticides in sediment due to the presence of clay and organic carbon. Growth impairment observed in surface water exposures was likely due to complex interaction of pesticide mixtures that were present.     

用BaCl2滴定法快速测定硫酸盐的研究

用铬酸钡光度法、EDTA滴定法、间接原予吸收法、离子色谱法等方法测定SO4^2-检测上限都很低（12—200mg／L），且只适用于清洁水，若水样混浊则会引起较大的误差。有的地下水，SO4^2-浓度高迭44000mg／L，用BaCl2滴定法测定SO4^2-：测试水样，以溴酚蓝做酸碱指示剂，加1：50盐酸，调为pH=3．5，加入30ml异丙醇，以钍试荆做终点指示荆，滴加0．01mol／L BaCl2，砖红色为终点，根据BaCl2用量计算SO4^2-浓度。本方法快捷、准确、测定范围大，上限可迭2000mg／L，克服了光度法测定浑浊水样引起误差大的缺点。     

Designing Systematic Conservation Assessments that Promote Effective Implementation: Best Practice from South Africa

Abstract:  Systematic conservation assessment and conservation planning are two distinct fields of conservation science often confused as one and the same. Systematic conservation assessment is the technical, often computer-based, identification of priority areas for conservation. Conservation planning is composed of a systematic conservation assessment coupled with processes for development of an implementation strategy and stakeholder collaboration. The peer-reviewed conservation biology literature abounds with studies analyzing the performance of assessments (e.g., area-selection techniques). This information alone, however, can never deliver effective conservation action; it informs conservation planning. Examples of how to translate systematic assessment outputs into knowledge and then use them for "doing" conservation are rare. South Africa has received generous international and domestic funding for regional conservation planning since the mid-1990s. We reviewed eight South African conservation planning processes and identified key ingredients of best practice for undertaking systematic conservation assessments in a way that facilitates implementing conservation action. These key ingredients include the design of conservation planning processes, skills for conservation assessment teams, collaboration with stakeholders, and interpretation and mainstreaming of products (e.g., maps) for stakeholders. Social learning institutions are critical to the successful operationalization of assessments within broader conservation planning processes and should include not only conservation planners but also diverse interest groups, including rural landowners, politicians, and government employees.     

Influence of varying nutrient and pesticide mixtures on abatement efficiency using a vegetated free water surface constructed wetland mesocosm

The nutrient and pesticide abatement efficiency of varying mixtures was examined in a vegetated free water surface constructed wetland. Three different agricultural chemical pollutant mixture conditions were assessed: nutrients only (N and P); pesticides only (atrazine, S-metolachlor and permethrin); and a mixture of nutrients and pesticides. With nutrients only, 672 h nutrient mitigation of 77–91% total phosphorous (TP) and 74–98% total nitrogen (TN) was associated with distance from the injection point and rainfall, whereas with nutrient and pesticide mixtures, 672 h nutrient mitigation of 11–71% TP and 84–98% TN were associated with distance and time. With pesticides only, 672 h pesticide mitigation of 50–99% was associated with distance and time, whereas with nutrients and pesticide mixtures, 672 h pesticide mitigation of 48–99% was associated primarily with distance. Dissipation half-lives were 2–10 times greater for P and 1.5–5 times greater for N when pesticides were present. Pesticide dissipation half-lives showed no clear differences with or without nutrients. While vegetated free water surface constructed wetlands can be effective best management practice tools to trap and abate agricultural run-off during rainfall events, efficiencies can be affected by different types of complex pollutant mixtures and wetland design and implementation should accommodate varying efficiencies.     

Inundation influences on bioavailability of phosphorus in managed wetland sediments in agricultural landscapes

Agricultural runoff carries high nutrient loads to receiving waters, contributing to eutrophication. Managed wetlands can be used in integrated management efforts to intercept nutrients before they enter downstream aquatic systems, but detailed information regarding sorption and desorption of P by wetland sediments during typical inundation cycles is lacking. This study seeks to quantify and elucidate how inundation of wetland sediments affects bioavailability of P and contributions of P to downstream systems. A managed wetland cell in Tunica County, Mississippi was subjected to a simulated agricultural runoff event and was monitored for bioavailable phosphorus (water-extractable P [P], Fe-P, and Al-P) of wetland sediments and water level during the runoff event and for 130 d afterward. Inundation varied longitudinally within the wetland, with data supporting significant temporal relationships between inundation and P desorption. Concentrations of P were significantly higher at the site that exhibited variable hydroperiods (100 m) as compared with sites under consistent inundation. This suggests that sites that are inundated for longer periods of time desorb less P immediately to the environment than sites that have periodic or ephemeral inundation. Concentrations of iron oxalate and NaOH-P were significantly higher at the least inundated site as compared with all other sites (F = 5.43; = 0.001) irrespective of time. These results support the hypothesis that increased hydraulic residence time decreases the bioavailability of P in wetland sediments receiving agricultural runoff. This finding suggests that the restoration of wetlands in the mid-southern United States may be hydrologically managed to improve P retention.     

PRINCIPLES FOR INTERNATIONAL GROUND-WATER LAW (I)

International ground-water resources have not received their full share of legal investigation. This paper outlines some principles applicable to the development of international co-operation concerning this important resource, bearing in mind that ground and surface waters are the same resource. In the absence of positive international law covering ground-water resources, national laws are investigated to examine their suitability for adaptation to the international level. In a second paper, to be published in the next issue of the Forum , the interjurisdictional experience among federated states and among independent states will be reviewed.     

Sediment quality assessment of Beasley Lake: bioaccumulation and effects of pesticides in Hyalella azteca

Beasley Lake is a Conservation Effects Assessment Program (CEAP) watershed in the intensively cultivated Mississippi Delta, USA. Lake sediment quality at three sites was evaluated in 2004 and 2008 for biological impairment and uptake (animal tissue pesticide residues) from 14 pesticides and three metabolites using Hyalella azteca (Saussure). Eleven pesticides and three metabolites were detected in sediment among the three sites in 2004 and all 17 compounds examined were detected among the three sites in 2008, with the herbicide atrazine having the greatest concentrations. Twenty-eight-day H. azteca survival and growth (mg w/w) indicated no survival effects at any site for either year, but growth impairment occurred in H. azteca exposed to sediments in 2004, whereas growth enhancement occurred in H. azteca exposed to sediments at one site in 2008. Pesticides observed in animal tissue pesticide residues occurred more frequently and in greater concentrations in 2004 compared with 2008. Thirteen pesticides were detected in animal tissue pesticide residues in 2004, with chlorpyrifos occurring in the greatest concentrations, and six pesticides were detected in 2008, with p,p′-DDT occurring in the greatest concentrations. H. azteca tissue pesticide residues of seven pesticides, two herbicides, three insecticides, one insecticide metabolite, and p,p′-DDT, were associated with growth.     

PRINCIPLES FOR INTERNATIONAL GROUND-WATER LAW (II)

This is the second part of a paper outlining some principles applicable to the development of international law in the sub-sector of ground-water resources. In the first part of the paper, in the previous issue of the Forum , national ground-water laws were investigated to examine their suitability for adaptation at the international level. This part of the paper is devoted to reviewing the interjurisdictional experience among federated states and among independent states. It also draws the general conclusion of the entire paper.