全自动消解-电感耦合等离子体质谱法测定土壤中16种元素

采用HNO_3-HF-HClO_4消解体系,建立了全自动消解-电感耦合等离子体质谱仪测定土壤中~(75)As、~9Be、~(51)V、~(55)Mn、~(59)Co、~(60)Ni、~(63)Cu、~(66)Zn、~(98)Mo、~(111)Cd、~(138)Ba、~(205)Tl、~(208)Pb、~(107)Ag、~(52)Cr、~(121)Sb等16种元素的新方法。通过碰撞池技术和编辑干扰元素校正方程有效校正了质谱干扰,并用内标校正了土壤基体干扰。用土壤标准物质GSS-13验证该方法,其校准曲线相关系数大于0.999 9,方法检出限在0.005~0.5μg/g之间,RSD为0.22%~2.35%,加标回收率为92%~114%。采用该方法测定实际土壤样品,加标回收率为93%~123%。     

Determination of adrenal steroids by microfluidic chip using micellar electrokinetic chromatography

This paper describes a sensitive and convenient method to separate progesterone, 17alpha-hydroxy progesterone, cortexolone, hydrocortisone and cortisone, all of which are steroids and have similar structures, using microfluidic chip-based technology with UV detection at 252 nm. We successfully obtained high-speed separation of the five steroids within 70 s in optimized microfluidic controls and micellar electrokinetic chromatography (MEKC) separation conditions. Fairly good linearity with correlation coefficient of over 0.98 from 10 or 20 to 100 mg/l steroid chemicals was obtained. The limits of detection obtained at a signal to noise ratio of 3 were from 3.89 to 7.80 mg/l. The values of the relative standard deviation (RSD) were 0.98-1.34% for repetitive injection (n = 12) and the intraday and interday RSDs were below 6%. The highly stable response reflected the feasibility of this method.     

脉冲调制介质阻挡放电和催化联用技术降解甲苯

利用低温等离子体处理挥发性有机化合物(VOCs)废气是目前国内外研究的热点。研究利用脉冲调制介质阻挡放电和催化联用技术降解甲苯,对比分析了连续放电和脉冲调制对去除甲苯的影响;研究了脉冲调制后在有无催化剂的情况下的能量效率,比较了两种情况下的臭氧浓度以及中间产物的不同。结果表明:脉冲调制有效提高了甲苯的降解能效,其能量效率几乎是连续放电时的2倍～3倍;在有催化剂的情况下,能量效率是没催化剂的1.5倍～2倍,臭氧浓度明显降低,结焦产物中含苯环的衍生物的量少于无催化的结焦产物。     

环境管制对企业土壤污染防治策略的影响机制研究

环境管制和企业土壤污染防治行为之间关系的研究对于我国相关法规的制定具有十分重要的意义。本文以情境脚本的方式模拟不同外部压力情形下企业可能的土壤污染防治行为,目的在于了解我国尚未通过的《土壤污染防治法》应以何种制度设计为佳。结果发现,正式环境管制压力中违规罚金对企业的土壤污染防治行为的影响程度较大;在非正式环境管制压力中,消费者与客户压力对企业土壤污染防治行为的影响程度较大。本文最后还对模拟实验研究的结果进行了讨论。     

校园安全管理立法研究与探索 ——基于全国地方学校安全管理立法分析

完善学校安全地方法规,加强各省(自治区、直辖市)学校安全工作管理,是我国教育事业的一项重要工作.通过对10个省份、直辖市颁布的学校安全地方立法文本的法律依据、适用范围、原则、安全管理、事故处理、法律责任6个方面进行深入分析,并与国务院办公厅颁发的《关于加强中小学幼儿园安全风险防控体系建设的意见》进行对比,找出学校安全管理存在的问题,并提出完善建议.研究表明:学校安全管理存在缺乏上位法律支持、忽视协同治理机制构建、法律责任过于笼统、学校安全的国家标准体系有待完善等问题.基于此,提出要尽快出台《学校安全法》;健全多元主体协同参与的治理机制;增强立法的可操作性,建立权责统一的追责机制;完善学校安全的国家标准体系;注重预防体系构建等完善措施.     

Characterization of dissolved organic carbon at low levels in environmental waters by microfluidic-chip-based capillary gel electrophoresis with a laser-induced fluorescence detector

A microfluidic analytical system for characterization of dissolved organic carbon (DOC) in environmental waters, based on a capillary gel electrophoresis (CGE) device with a laser-induced fluorescence (LEF) detector, was developed. The applied voltage and the running buffer were investigated to control the simple floating injection and CGE separation for convenient cross-type microchips made from polymethylmethacylate. We obtained reproducible peaks for standard organic solutions and the determination time is less than 70 s. The values of the relative standard deviation (RSD) were 0.17–2.01% for repetitive injection (n?=?12). We demonstrated high-throughput characterization of DOC in environmental water from the Biwa Lake and the Hino River using microfluidic chip and determined that the content of DOC in the Biwa Lake changed with the seasons.     

Monitoring and control methods of harmful algal blooms in Chinese freshwater system: a review

Environmental Science and Pollution Research - Harmful algal blooms (HABs) are a worldwide problem with substantial adverse effects on the aquatic environment as well as human health, which have...